Updated on 2024/02/20

写真a

 
NISHIMURA Takahiro
 
Organization
Graduate School of Science Department of Chemistry Professor
School of Science Department of Chemistry
Title
Professor
Affiliation
Institute of Science

Position

  • Graduate School of Science Department of Chemistry 

    Professor  2022.04 - Now

  • School of Science Department of Chemistry 

    Professor  2022.04 - Now

Degree

  • Doctor (Engineering) ( Kyoto University )

Research Areas

  • Nanotechnology/Materials / Synthetic organic chemistry

  • Nanotechnology/Materials / Green sustainable chemistry and environmental chemistry

Research Interests

  • organic chemistry

  • catalysis

  • asymmetric synthesis

  • Transition-Metal-Catalysts

  • Atom Econimy

  • Green Chemistry

Research subject summary

  • Transition metal-catalyzed functionalization of aromatic compounds via C-H bond activation has realized the step-economy synthesis of useful compounds. In particular, an ortho-selective functionalization has been achieved by use of directing groups, and in the past few decades, many catalytic systems for the C-H bond activation have been developed. We are interested in development of atom-economical organic transformations to realize stereoselective synthesis of useful organic molecules.

Professional Memberships

  • 近畿化学協会

      Domestic

  • 有機合成化学協会

      Domestic

  • American Chemical Society

      Overseas

  • 日本化学会

      Domestic

Awards

  • 宇部興産学術振興財団第52回学術奨励賞

    2012  

  • Banyu Chemist Award

    2010  

  • Incentive Award in Synthetic Organic Chemistry, Japan

    2008  

  • 有機合成化学協会東レ研究企画賞

    2003  

Job Career (off-campus)

  • 京都大学   大学院理学研究科化学専攻   講師

    2005.04 - 2017.03

  • 京都大学   大学院工学研究科物質エネルギー化学専攻   助手

    2001.04 - 2005.03

  • 日本学術振興会特別研究員   DC2

    1999.01 - 2001.03

  • 出光興産株式会社   技術職

    1996.04 - 1997.06

Education

  • Kyoto University   Doctor's Course   Graduated/Completed

    1997.10 - 2001.03

  • Kyoto University   Master's Course   Graduated/Completed

    1994.04 - 1996.03

  • Kyoto University     Graduated/Completed

    1989.04 - 1994.03

Papers

  • Iridium-catalyzed asymmetric addition of imides to alkenes Reviewed

    Kentaro Yamakawa, Kana Sakamotoa, Takahiro Nishimura

    Chemical Communications   59   12871 - 12874   2023.10

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    Authorship:Last author, Corresponding author   Publishing type:Research paper (scientific journal)   International / domestic magazine:International journal  

    DOI: 10.1039/D3CC04406H

    Other URL: https://pubs.rsc.org/en/content/articlelanding/2023/cc/d3cc04406h

  • Ruthenium-catalysed <i>N</i>-alkylation of anilines with primary carbohydrate alcohols <i>via</i> borrowing hydrogen strategy Reviewed

    Kouki Tsuge, Shunnichi Kubota, Kana Sakamoto, Kenji Kitayama, Takahiro Nishimura

    CHEMICAL COMMUNICATIONS   59 ( 46 )   7052 - 7055   2023.06( ISSN:1359-7345

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    Publishing type:Research paper (scientific journal)  

    Ruthenium-catalysed N-alkylation of anilines with sugar derivatives proceeded via the borrowing hydrogen strategy. Primary carbohydrate alcohols were successfully applied to N-alkylation of aniline derivatives to give the corresponding aminosugars in high yields.

    DOI: 10.1039/d3cc01931d

  • Iridium-Catalyzed Branch-Selective and Enantioselective C2-Alkylation of N-Benzimidazolyl Indoles Reviewed

    Kentaro Yamakawa, Takahiro Nishimura

    ADVANCED SYNTHESIS & CATALYSIS   365 ( 12 )   2013 - 2017   2023.06( ISSN:1615-4150

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    Publishing type:Research paper (scientific journal)  

    Iridium-catalyzed enantioselective C2-alkylation of indole derivatives with terminal alkenes proceeded to give branched alkylation products with high enantioselectivity (39-99% yields, 20-91% ee). The reaction of indole derivatives having an N-substituted benzimidazolyl as a directing group gave the branch-selective alkylated products. Styrene derivatives and allylsilanes were good substrates displaying high enantioselectivity. The directing group was readily removed in several ways.

    DOI: 10.1002/adsc.202300370

  • Synthesis of Chiral Spiro[45]decadienones via Chirality-Transferring Oxidative Intramolecular Cyclization of Allenylsilane-Tethered Phenols Reviewed

    Kishimoto R.

    Synthesis (Germany)   55 ( 17 )   2713 - 2729   2023.03( ISSN:00397881

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1055/a-2075-3258

  • Ir-Catalyzed α-Alkylation of Methyl Ketones with Primary Carbohydrate Alcohols Reviewed

    Kouki Tsuge, Shunnichi Kubota, Kana Sakamoto, Kenji Kitayama, Takahiro Nishimura

    Advanced Synthesis & Catalysis   2023.03

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    Authorship:Last author, Corresponding author   Publishing type:Research paper (scientific journal)   International / domestic magazine:International journal  

    DOI: 10.1002/adsc.202300124

  • Iridium-Catalyzed Enantioselective Intermolecular Hydroarylation of 1,1-Disubstituted Alkenes Reviewed

    Kentaro Yamakawa, Ikumi Nakamura, Kana Sakamoto, Takahiro Nishimura

    The Journal of Organic Chemistry   2023.02

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    Authorship:Last author, Corresponding author   Publishing type:Research paper (scientific journal)   International / domestic magazine:International journal  

    DOI: 10.1021/acs.joc.2c02619

  • Asymmetric addition of an N-methyl C(sp3)–H bond to cyclic alkenes enabled by an iridium/phosphine-olefin catalyst Reviewed

    Kana Sakamoto, Takahiro Nishimura

    Chemical Communications   84 ( 58 )   11783 - 11786   2022.09

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    Authorship:Last author, Corresponding author   Publishing type:Research paper (scientific journal)   International / domestic magazine:International journal  

    DOI: 10.1039/D2CC04642C

  • Iridium-Catalyzed Enantioselective Direct α-C–H Alkylation of Saturated Cyclic Amines with Alkenes Reviewed

    Daisuke Yamauchi, Kentaro Yamakawa, Takahiro Nishimura

    Organic Letters   37 ( 24 )   6828 - 6833   2022.09

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    Authorship:Last author, Corresponding author   Publishing type:Research paper (scientific journal)   International / domestic magazine:International journal  

    DOI: 10.1021/acs.orglett.2c02733

  • Ir-Catalyzed cyclization of α,ω-dienes with an N-methyl group via two C–H activation steps Reviewed

    Katsumasa Tanaka, Hiroshi Hattori, Ryota Yabe, Takahiro Nishimura

    Chemical Communications   35 ( 58 )   5371 - 5374   2022.04

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    Authorship:Last author, Corresponding author   Publishing type:Research paper (scientific journal)   International / domestic magazine:International journal  

    DOI: 10.1039/D2CC01275H

  • Iridium-Catalyzed Hydroarylation via C-H Bond Activation Reviewed

    Nishimura Takahiro

    CHEMICAL RECORD   21 ( 12 )   3532 - 3545   2021.12( ISSN:1527-8999

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    Publishing type:Research paper (scientific journal)   Kind of work:Single Work  

    DOI: 10.1002/tcr.202100109

    PubMed

  • Iridium-catalyzed enantioselective addition of an N-methyl C-H bond to alpha-trifluoromethylstyrenes via C-H activation Reviewed

    Yamauchi Daisuke, Nakamura Ikumi, Nishimura Takahiro

    CHEMICAL COMMUNICATIONS   57 ( 89 )   11787 - 11790   2021.11( ISSN:1359-7345

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d1cc05076a

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  • Enantioselective C-H Alkylation of N-Arylbenzamides with Vinyl Ethers Catalyzed by an Iridium/Chiral Phosphoramidite-Olefin Complex Reviewed

    Murakami Kotone, Sakamoto Kana, Nishimura Takahiro

    SYNTHESIS-STUTTGART   2021.10( ISSN:0039-7881

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1055/a-1672-6284

  • Iridium-Catalyzed Direct C-H Allylation of Ketimines Reviewed

    Yabe Ryota, Ebe Yusuke, Nishimura Takahiro

    SYNTHESIS-STUTTGART   53 ( 17 )   3051 - 3056   2021.09( ISSN:0039-7881

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1055/a-1477-7059

  • Iridium-catalyzed stereoselective [3+2] annulation of alpha-oxocarboxylic acids with 1,3-dienes Reviewed

    Yabe Ryota, Ebe Yusuke, Nishimura Takahiro

    CHEMICAL COMMUNICATIONS   57 ( 48 )   5917 - 5920   2021.06( ISSN:1359-7345

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d1cc02003j

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  • Enantioselective synthesis of 3-substituted dihydrobenzofurans through iridium-catalyzed intramolecular hydroarylation Reviewed

    Sakamoto Kana, Nishimura Takahiro

    ORGANIC & BIOMOLECULAR CHEMISTRY   19 ( 3 )   684 - 690   2021.01( ISSN:1477-0520

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d0ob02421j

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  • Enantioselective Synthesis of Chiral Indane Derivatives by RhodiumCatalyzed Addition of Arylboron Reagents to Substituted Indenes Reviewed

    Umeda Moeko, Noguchi Hikaru, Nishimura Takahiro

    ORGANIC LETTERS   22 ( 24 )   9597 - 9602   2020.12( ISSN:1523-7060

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.orglett.0c03651

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  • Synthesis of Allene-Containing Apocarotenoids by Cross-Coupling Strategy Reviewed

    Sakaguchi Kazuhiko, Nishioka Yuto, Kinashi Naoto, Yukihira Nao, Shinada Tetsuro, Nishimura Takahiro, Hashimoto Hideki, Katsumura Shigeo

    SYNTHESIS-STUTTGART   52 ( 20 )   3007 - 3017   2020.10( ISSN:0039-7881

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1055/s-0040-1707906

  • Iridium-catalyzed Annulation of alpha,beta-Unsaturated Amides with Electron-deficient Conjugated Dienes Reviewed

    Murakami Kotone, Nagamoto Midori, Nishimura Takahiro

    公益社団法人 日本化学会 CHEMISTRY LETTERS   49 ( 6 )   732 - 735   2020.06( ISSN:0366-7022

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    Publishing type:Research paper (scientific journal)  

    <p>Annulation of α,β-unsaturated amides with electron-deficient 1,3-dienes gave 5,6-dihydropyridin-2(1<i>H</i>)-ones in the presence of a hydroxoiridium catalyst. The reaction proceeded via direct C–H alkylation of acrylamides with conjugated dienes, followed by intramolecular aza-Michael addition, thus giving dihydropyridinones stereoselectively in good yields.</p>

    DOI: 10.1246/cl.200193

    CiNii Article

  • Rhodium-catalyzed asymmetric addition of arylboronic acids to 2H-chromenes leading to 3-arylchromane derivatives Reviewed

    Umeda Moeko, Sakamoto Kana, Nagai Tomotaka, Nagamoto Midori, Ebe Yusuke, Nishimura Takahiro

    CHEMICAL COMMUNICATIONS   55 ( 79 )   11876 - 11879   2019.10( ISSN:1359-7345

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c9cc06221a

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  • Acid-catalyzed chirality-transferring intramolecular Friedel-Crafts cyclization of alpha-hydroxy-alpha-alkenylsilanes Reviewed

    Sakaguchi Kazuhiko, Kubota Shunnichi, Akagi Wataru, Ikeda Naoko, Higashino Masato, Ariyoshi Shoma, Shinada Tetsuro, Ohfune Yasufumi, Nishimura Takahiro

    CHEMICAL COMMUNICATIONS   55 ( 59 )   8635 - 8638   2019.07( ISSN:1359-7345

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c9cc03509e

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  • Iridium-Catalyzed Asymmetric Hydroarylation of Chromene Derivatives with Aromatic Ketones: Enantioselective Synthesis of 2-Arylchromanes Reviewed

    Sakamoto Kana, Nishimura Takahiro

    ADVANCED SYNTHESIS & CATALYSIS   361 ( 9 )   2124 - 2128   2019.04( ISSN:1615-4150

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/adsc.201801664

  • Iridium-Catalyzed Direct Hydroarylation of Glycals via C-H Activation: Ligand-Controlled Stereoselective Synthesis of alpha- and beta-C-Glycosyl Arenes Reviewed

    Sakamoto Kana, Nagai Masaki, Ebe Yusuke, Yorimitsu Hideki, Nishimura Takahiro

    ACS CATALYSIS   9 ( 2 )   1347 - 1352   2019.02( ISSN:2155-5435

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acscatal.8b04686

  • Iridium-Catalyzed Direct Hydroarylation of Glycals via C−H Activation: Ligand-Controlled Stereoselective Synthesis of α- and β‐C‐Glycosyl Arenes Reviewed

    Kana Sakamoto, Masaki Nagai, Yusuke Ebe, Hideki Yorimitsu, Takahiro Nishimura

    ACS Catalysis   9 ( 2 )   1347 - 1352   2019.01

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    Publishing type:Research paper (scientific journal)   Kind of work:Joint Work  

  • Iridium-Catalyzed Sequential sp(3) C-H Alkylation of an N-Methyl Group with Alkenes Towards the Synthesis of alpha-Substituted Amines Reviewed

    Hattori Hiroshi, Nishimura Takahiro

    ADVANCED SYNTHESIS & CATALYSIS   360 ( 24 )   4827 - 4831   2018.12( ISSN:1615-4150

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/adsc.201801131

  • Hydroxoiridium-Catalyzed sp(3) C-H Alkylation of Indoline Derivatives with Terminal Alkenes Reviewed

    Nakamura Ikumi, Yamauchi Daisuke, Nishimura Takahiro

    ASIAN JOURNAL OF ORGANIC CHEMISTRY   7 ( 7 )   1347 - 1350   2018.07( ISSN:2193-5807

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/ajoc.201800189

  • Iridium/Chiral Diene-Catalyzed Enantioselective (3+2) Annulation of Aromatic Ketimines with 1,3-Enynes via C-H Activation Reviewed

    Nagamoto Midori, Sakamoto Kana, Nishimura Takahiro

    ADVANCED SYNTHESIS & CATALYSIS   360 ( 4 )   791 - 795   2018.02( ISSN:1615-4150

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/adsc.201701378

  • Iridium-Catalyzed Hydroarylation of Conjugated Dienes via π-Allyliridium Intermediates. Reviewed

    Nagamoto M, Yorimitsu H, Nishimura T

    Organic letters   20 ( 3 )   828 - 831   2018.02( ISSN:1523-7060

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.orglett.7b03969

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  • Hydroxoiridium-Catalyzed Hydroarylation of Alkynes and Bicycloalkenes With N-Sulfonylbenzamides Reviewed

    Nagamoto Midori, Fukuda Jun-ichi, Hatano Miyuki, Yorimitsu Hideki, Nishimura Takahiro

    ORGANIC LETTERS   19 ( 21 )   5952 - 5955   2017.11( ISSN:1523-7060

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.orglett.7b02950

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  • Iridium-Catalyzed Intramolecular Oxidative Cyclization of Alkenyl Amides and Alkenoic Acids Reviewed

    Nagamoto Midori, Nishimura Takahiro, Yorimitsu Hideki

    SYNTHESIS-STUTTGART   49 ( 18 )   4272 - 4282   2017.09( ISSN:0039-7881

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1055/s-0036-1588435

  • Regularized regression analysis of digitized molecular structures in organic reactions for quantification of steric effects Reviewed

    Yamaguchi Shigeru, Nishimura Takahiro, Hibe Yuta, Nagai Masaki, Sato Hirofumi, Johnston Ian

    JOURNAL OF COMPUTATIONAL CHEMISTRY   38 ( 21 )   1825 - 1833   2017.08( ISSN:0192-8651

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/jcc.24791

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  • Iridium-catalyzed sp3 C-H Alkylation of 3-Carbonyl-2-(alkylamino)pyridines with Alkenes Reviewed

    Nagai Masaki, Nagamoto Midori, Nishimura Takahiro, Yorimitsu Hideki

    公益社団法人 日本化学会 CHEMISTRY LETTERS   46 ( 8 )   1176 - 1178   2017.08( ISSN:0366-7022

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    Publishing type:Research paper (scientific journal)   Kind of work:Joint Work  

    <p>Iridium-catalyzed C–H alkylation of 3-carbonyl-2-(alkylamino)pyridines via secondary sp<sup>3</sup> C–H activation adjacent to the nitrogen atom, with terminal alkenes proceeded to give the corresponding α-secondary amines in high yields. The reaction was efficiently catalyzed by a cationic iridium complex coordinated with 1,5-cyclooctadiene.</p>

    DOI: 10.1246/cl.170373

    CiNii Article

  • Iridium-catalyzed Cleavage of C-O Bonds Using Alcohols as Reducing Reagents Reviewed

    Hibe Yuta, Ebe Yusuke, Nishimura Takahiro, Yorimitsu Hideki

    公益社団法人 日本化学会 CHEMISTRY LETTERS   46 ( 7 )   953 - 955   2017.07( ISSN:0366-7022

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    <p>A cationic iridium/binap catalyst-enabled reductive cleavage of C(sp<sup>2</sup>)–O bonds of aromatic compounds having nitrogen-based directing groups was carried out in the presence of alcohols as reducing reagents.</p>

    DOI: 10.1246/cl.170239

    CiNii Article

  • Hydroxoiridium-Catalyzed Hydroalkylation of Terminal Alkenes with Ureas by C(sp3)-H Bond Activation Reviewed

    Yamauchi Daisuke, Nishimura Takahiro, Yorimitsu Hideki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   56 ( 25 )   7200 - 7204   2017.06( ISSN:1433-7851

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    Publishing type:Research paper (scientific journal)   Kind of work:Joint Work  

    DOI: 10.1002/anie.201702169

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  • Iridium-Catalyzed Regio- and Enantioselective Hydroarylation of Alkenyl Ethers by Olefin Isomerization Reviewed

    Ebe Yusuke, Onoda Mitsuki, Nishimura Takahiro, Yorimitsu Hideki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   56 ( 20 )   5607 - 5611   2017.05( ISSN:1433-7851

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.201702286

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  • Iridium-Catalyzed Asymmetric Reactions Realizing High Atom Efficiency Reviewed

    Nagamoto Midori, Ebe Yusuke, Nishimura Takahiro

    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN   75 ( 5 )   421 - 431   2017.05( ISSN:0037-9980

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  • Asymmetric hydroarylation of vinyl ethers catalyzed by a hydroxoiridium complex: azoles as effective directing groups Reviewed

    Yamauchi Daisuke, Nishimura Takahiro, Yorimitsu Hideki

    CHEMICAL COMMUNICATIONS   53 ( 18 )   2760 - 2763   2017.03( ISSN:1359-7345

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c7cc00238f

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  • Asymmetric Transformations under Iridium/Chiral Diene Catalysis Reviewed

    Nagamoto Midori, Nishimura Takahiro

    ACS CATALYSIS   7 ( 1 )   833 - 847   2017.01( ISSN:2155-5435

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acscatal.6b02495

  • Asymmetric Cyclization of N-Sulfonyl Alkenyl Amides Catalyzed by Iridium/Chiral Diene Complexes Reviewed

    Nagamoto Midori, Yanagi Tomoyuki, Nishimura Takahiro, Yorimitsu Hideki

    ORGANIC LETTERS   18 ( 18 )   4474 - 4477   2016.09( ISSN:1523-7060

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.orglett.6b01954

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  • Selective H/D Exchange at Vinyl and Methylidene Groups with D2O Catalyzed by an Iridium Complex Reviewed

    Hatano Miyuki, Nishimura Takahiro, Yorimitsu Hideki

    ORGANIC LETTERS   18 ( 15 )   3674 - 3677   2016.08( ISSN:1523-7060

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    Publishing type:Research paper (scientific journal)   Kind of work:Joint Work  

    DOI: 10.1021/acs.orglett.6b01721

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  • Rhodium-Catalyzed Enantioselective Addition of Tricyclopropylboroxin to N-Sulfonylimines Reviewed

    Nishimura Takahiro, Nagai Tomotaka, Takechi Ryosuke, Ebe Yusuke

    SYNTHESIS-STUTTGART   48 ( 16 )   2612 - 2618   2016.08( ISSN:0039-7881

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1055/s-0035-1561605

  • Asymmetric Alkylation of N-Sulfonylbenzamides with Vinyl Ethers via C-H Bond Activation Catalyzed by Hydroxoiridium/Chiral Diene Complexes Reviewed

    Hatano Miyuki, Ebe Yusuke, Nishimura Takahiro, Yorimitsu Hideki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   138 ( 12 )   4010 - 4013   2016.03( ISSN:0002-7863

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jacs.6b01591

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  • Iridium-catalyzed asymmetric [3+2] annulation of aromatic ketimines with alkynes via C-H activation: unexpected inversion of the enantioselectivity induced by protic acids Reviewed

    Nagamoto Midori, Yamauchi Daisuke, Nishimura Takahiro

    CHEMICAL COMMUNICATIONS   52 ( 34 )   5876 - 5879   2016( ISSN:1359-7345

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c6cc01398h

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  • Hydroxoiridium/Chiral Diene Complexes as Effective Catalysts for Asymmetric Annulation of alpha-Oxo- and Iminocarboxamides with 1,3-Dienes Reviewed

    Hatano Miyuki, Nishimura Takahiro

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   54 ( 37 )   10949 - 10952   2015.09( ISSN:1433-7851

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.201505382

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  • Mechanistic Insights into Bicyclic Guanidine-Catalyzed Reactions from Microscopic and Macroscopic Perspectives Reviewed

    Xue Hansong, Jiang Danfeng, Jiang Huan, Kee Choon Wee, Hirao Hajime, Nishimura Takahiro, Wong Ming Wah, Tan Choon-Hong

    JOURNAL OF ORGANIC CHEMISTRY   80 ( 11 )   5745 - 5752   2015.06( ISSN:0022-3263

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.joc.5b00709

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  • Formation of Carbocycles via a 1,4-Rh Shift Triggered by a Rhodium-Catalyzed Addition of Terminal Alkynes to 3,3-Diarylcyclopropenes. Reviewed

    Sawano T, Hashizume M, Nishimoto S, Ou K, Nishimura T

    Organic letters   17 ( 11 )   2630 - 2633   2015.06( ISSN:1523-7060

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    Sawano T, Hashizume M, Nishimoto S, Ou K, Nishimura T, Organic letters, 2015, vol. 17, no. 11, pp. 2630-2633, 2015

    DOI: 10.1021/acs.orglett.5b00984

    PubMed

    J-GLOBAL

    Other URL: http://orcid.org/0000-0002-7032-8613

  • Iridium-Catalyzed Branch-Selective Hydroarylation of Vinyl Ethers via C-H Bond Activation Reviewed

    Ebe Yusuke, Nishimura Takahiro

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   137 ( 18 )   5899 - 5902   2015.05( ISSN:0002-7863

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jacs.5b03099

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  • Iridium-Catalyzed Annulation of Aromatic Imines with 1,3-Dienes via Direct Functionalization of an Aromatic C-H Bond Reviewed

    Ebe Yusuke, Hatano Miyuki, Nishimura Takahiro

    ADVANCED SYNTHESIS & CATALYSIS   357 ( 7 )   1425 - 1436   2015.05( ISSN:1615-4150

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/adsc.201401171

  • Enantioselective 1,4-addition of cyclopropylboronic acid catalyzed by rhodium/chiral diene complexes Reviewed

    Takechi Ryosuke, Nishimura Takahiro

    CHEMICAL COMMUNICATIONS   51 ( 40 )   8528 - 8531   2015( ISSN:1359-7345

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c5cc02140e

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  • Rhodium-catalyzed asymmetric addition of arylboronic acids to cyclic N-sulfonyl ketimines towards the synthesis of alpha,alpha-diaryl-alpha-amino acid derivatives Reviewed

    Takechi Ryosuke, Nishimura Takahiro

    ORGANIC & BIOMOLECULAR CHEMISTRY   13 ( 17 )   4918 - 4924   2015( ISSN:1477-0520

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c5ob00431d

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  • Iridium-catalyzed asymmetric cyclization of alkenoic acids leading to gamma-lactones Reviewed

    Nagamoto Midori, Nishimura Takahiro

    CHEMICAL COMMUNICATIONS   51 ( 70 )   13466 - 13469   2015( ISSN:1359-7345

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c5cc05393e

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  • Stereoselective hydroacylation of bicyclic alkenes with 2-hydroxybenzaldehydes catalyzed by hydroxoiridium/diene complexes Reviewed

    Nagamoto Midori, Nishimura Takahiro

    CHEMICAL COMMUNICATIONS   51 ( 72 )   13791 - 13794   2015( ISSN:1359-7345

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    DOI: 10.1039/c5cc05432j

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  • Iridium-Catalyzed Annulation of Salicylimines with 1,3-Dienes Reviewed

    Ebe Yusuke, Nishimura Takahiro

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   136 ( 26 )   9284 - 9287   2014.07( ISSN:0002-7863

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    DOI: 10.1021/ja504990a

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  • Catalytic [3+2] annulation of ketimines with alkynes via C-H activation by a cationic iridium(cod) complex Reviewed

    Nagamoto Midori, Nishimura Takahiro

    CHEMICAL COMMUNICATIONS   50 ( 47 )   6274 - 6277   2014( ISSN:1359-7345

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    DOI: 10.1039/c4cc01874e

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  • Cobalt-Catalyzed Asymmetric Addition of Silylacetylenes to 1,1-Disubstituted Allenes Reviewed

    Sawano Takahiro, Ou Keiyu, Nishimura Takahiro, Hayashi Tamio

    JOURNAL OF ORGANIC CHEMISTRY   78 ( 18 )   8986 - 8993   2013.09( ISSN:0022-3263

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    DOI: 10.1021/jo401604n

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  • Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Ene-ynamides Reviewed

    Nishimura Takahiro, Takiguchi Yuka, Maeda Yuko, Hayashi Tamio

    ADVANCED SYNTHESIS & CATALYSIS   355 ( 7 )   1374 - 1382   2013.05( ISSN:1615-4150

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    DOI: 10.1002/adsc.201300148

  • Iridium-Catalyzed [3+2] Annulation of Cyclic N-Sulfonyl Ketimines with 1,3-Dienes via C-H Activation Reviewed

    Nishimura Takahiro, Ebe Yusuke, Hayashi Tamio

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   135 ( 6 )   2092 - 2095   2013.02( ISSN:0002-7863

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    DOI: 10.1021/ja311968d

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  • Enantioselective [3+2] annulation via C-H activation between cyclic N-acyl ketimines and 1,3-dienes catalyzed by iridium/chiral diene complexes Reviewed

    Nishimura Takahiro, Nagamoto Midori, Ebe Yusuke, Hayashi Tamio

    CHEMICAL SCIENCE   4 ( 12 )   4499 - 4504   2013( ISSN:2041-6520

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    DOI: 10.1039/c3sc52379a

  • Asymmetric synthesis of gem-diaryl substituted cyclic sulfamidates and sulfamides by rhodium-catalyzed arylation of cyclic ketimines Reviewed

    Nishimura Takahiro, Ebe Yusuke, Fujimoto Hiroto, Hayashi Tamio

    CHEMICAL COMMUNICATIONS   49 ( 48 )   5504 - 5506   2013( ISSN:1359-7345

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    DOI: 10.1039/c3cc42071j

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  • Hydroxorhodium/Chiral Diene Complexes as Effective Catalysts for the Asymmetric Arylation of 3-Aryl-3-hydroxyisoindolin-1-ones Reviewed

    Nishimura Takahiro, Noishiki Akira, Ebe Yusuke, Hayashi Tamio

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   52 ( 6 )   1777 - 1780   2013( ISSN:1433-7851

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.201208593

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  • Cobalt-Catalyzed Asymmetric 1,6-Addition of (Triisopropylsilyl)acetylene to α,β,γ,δ-Unsaturated Carbonyl Compounds Reviewed

    Sawano Takahiro, Ashouri Akram, Nishimura Takahiro, Hayashi Tamio

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   134 ( 46 )   18936 - 18939   2012.11( ISSN:0002-7863

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    DOI: 10.1021/ja309756k

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  • Effect of Chiral Diene Ligands in Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to alpha,beta-Unsaturated Sulfonyl Compounds Reviewed

    Nishimura Takahiro, Takiguchi Yuka, Hayashi Tamio

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   134 ( 22 )   9086 - 9089   2012.06( ISSN:0002-7863

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    DOI: 10.1021/ja303109q

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  • Rhodium/chiral diene-catalyzed asymmetric methylation of N-sulfonylarylimines with trimethylboroxine Reviewed

    Nishimura Takahiro, Ashouri Akram, Ebe Yusuke, Maeda Yuko, Hayashi Tamio

    TETRAHEDRON-ASYMMETRY   23 ( 9 )   655 - 658   2012.05( ISSN:0957-4166

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    DOI: 10.1016/j.tetasy.2012.04.021

  • Asymmetric Synthesis of (Triaryl)methylamines by Rhodium-Catalyzed Addition of Arylboroxines to Cyclic N-Sulfonyl Ketimines Reviewed

    Nishimura Takahiro, Noishiki Akira, Tsui Gavin Chit, Hayashi Tamio

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   134 ( 11 )   5056 - 5059   2012.03( ISSN:0002-7863

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    DOI: 10.1021/ja300697c

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  • Electronic tuning of chiral diene ligands in iridium-catalyzed asymmetric 1,6-addition of arylboroxines to δ-aryl-α,β,γ,δ-unsaturated ketones Reviewed

    Nishimura Takahiro, Noishiki Akira, Hayashi Tamio

    CHEMICAL COMMUNICATIONS   48 ( 7 )   973 - 975   2012.01( ISSN:1359-7345

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    DOI: 10.1039/c2cc16973h

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  • Cobalt-catalyzed asymmetric addition of silylacetylenes to oxa- and azabenzonorbornadienes Reviewed

    Sawano Takahiro, Ou Keiyu, Nishimura Takahiro, Hayashi Tamio

    CHEMICAL COMMUNICATIONS   48 ( 49 )   6106 - 6108   2012( ISSN:1359-7345

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    DOI: 10.1039/c2cc31880f

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  • Rhodium/diene-catalyzed tandem 1,4-shift/1,4-addition of (E)-1,2-diphenylethenylboronic acid to enones: density functional theory modeling and asymmetric catalysis Reviewed

    Sasaki Keigo, Nishimura Takahiro, Shintani Ryo, Kantchev Eric Assen B., Hayashi Tamio

    CHEMICAL SCIENCE   3 ( 4 )   1278 - 1283   2012( ISSN:2041-6520

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    DOI: 10.1039/c2sc01093c

  • Concise Synthesis of beta,beta-Diaryl Esters and Ketones from Ethynylcarbonyl Compounds by Rhodium-catalyzed Double Arylation with Arylboroxins Reviewed

    Nishimura Takahiro, Noishiki Akira, Hayashi Tamio

    The Chemical Society of Japan CHEMISTRY LETTERS   40 ( 11 )   1285 - 1287   2011.11( ISSN:0366-7022

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    3,3-Diarylpropanoate esters were prepared from <i>tert</i>-butyl propiolate and arylboroxins in high yields through the rhodium-catalyzed double arylation of β-alkoxyacrylate, which was generated in situ from <i>tert</i>-butyl propiolate and 2,2,2-trifluoroethanol. The present method was also successfully applied to the double arylation of ethynyl ketones.

    DOI: 10.1246/cl.2011.1285

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  • Chiral Diene-Phosphine Tridentate Ligands for Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Enynes Reviewed

    Nishimura Takahiro, Maeda Yuko, Hayashi Tamio

    ORGANIC LETTERS   13 ( 14 )   3674 - 3677   2011.07( ISSN:1523-7060

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    DOI: 10.1021/ol2013236

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  • Rhodium-catalyzed oxidative alkynylation of acrylate esters with propargylic alcohols Reviewed

    Nishimura Takahiro, Nagaosa Makoto, Hayashi Tamio

    TETRAHEDRON LETTERS   52 ( 17 )   2185 - 2187   2011.04( ISSN:0040-4039

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    DOI: 10.1016/j.tetlet.2010.11.120

  • Rhodium/Chiral Diene-Catalyzed Asymmetric Cyclopolymerization of Achiral 1,8-Diynes Reviewed

    Ichikawa Yoshitaka, Nishimura Takahiro, Hayashi Tamio

    ORGANOMETALLICS   30 ( 8 )   2342 - 2348   2011.04( ISSN:0276-7333

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    DOI: 10.1021/om200088q

  • Rhodium-catalyzed asymmetric addition of arylboroxines to beta-alkoxyacrylate esters Reviewed

    Nishimura Takahiro, Kasai Atsuyuki, Nagaosa Makoto, Hayashi Tamio

    CHEMICAL COMMUNICATIONS   47 ( 37 )   10488 - 10490   2011( ISSN:1359-7345

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    DOI: 10.1039/c1cc14150c

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  • Cobalt-catalyzed conjugate addition of silylacetylenes to alpha,beta-unsaturated ketones Reviewed

    Nishimura Takahiro, Sawano Takahiro, Ou Keiyu, Hayashi Tamio

    CHEMICAL COMMUNICATIONS   47 ( 36 )   10142 - 10144   2011( ISSN:1359-7345

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    DOI: 10.1039/c1cc14098a

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  • Asymmetric cyclopropanation of alkenes with dimethyl diazomalonate catalyzed by chiral diene-rhodium complexes. Reviewed

    Nishimura T, Maeda Y, Hayashi T

    Angewandte Chemie (International ed. in English)   49 ( 40 )   7324 - 7   2010.09( ISSN:1433-7851

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    DOI: 10.1002/anie.201003775

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  • Rhodium-Catalyzed Enantioselective 1,6-Addition of Arylboronic Acids to Enynamides: Asymmetric Synthesis of Axially Chiral Allenylsilanes Reviewed

    Nishimura Takahiro, Makino Hiroki, Nagaosa Makoto, Hayashi Tamio

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   132 ( 37 )   12865 - 12867   2010.09( ISSN:0002-7863

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    DOI: 10.1021/ja1066509

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  • Rhodium-catalyzed enantioselective alkynylative cyclization of allenyl aldehydes with terminal alkynes Reviewed

    Guo Xun-Xiang, Sawano Takahiro, Nishimura Takahiro, Hayashi Tamio

    TETRAHEDRON-ASYMMETRY   21 ( 13-14 )   1730 - 1736   2010.07( ISSN:0957-4166

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    DOI: 10.1016/j.tetasy.2010.04.039

  • Iridium/Chiral Diene-Catalyzed Asymmetric 1,6-Addition of Arylboroxines to alpha,beta,gamma,delta-Unsaturated Carbonyl Compounds Reviewed

    Nishimura Takahiro, Yasuhara Yuichi, Sawano Takahiro, Hayashi Tamio

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   132 ( 23 )   7872 - +   2010.06( ISSN:0002-7863

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    DOI: 10.1021/ja1034842

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  • Chiral tetrafluorobenzobarrelene ligands for the rhodium-catalyzed asymmetric cycloisomerization of oxygen- and nitrogen-bridged 1,6-enynes. Reviewed

    Nishimura T, Kawamoto T, Nagaosa M, Kumamoto H, Hayashi T

    Angewandte Chemie (International ed. in English)   49 ( 9 )   1638 - 41   2010.02( ISSN:1433-7851

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    DOI: 10.1002/anie.200906792

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  • Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to beta-Phthaliminoacrylate Esters toward the Synthesis of beta-Amino Acids Reviewed

    Nishimura Takahiro, Wang Jun, Nagaosa Makoto, Okamoto Kazuhiro, Shintani Ryo, Kwong Fuk-yee, Yu Wing-yiu, Chan Albert S. C., Hayashi Tamio

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   132 ( 2 )   464 - +   2010.01( ISSN:0002-7863

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    DOI: 10.1021/ja909642h

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  • Rhodium-catalyzed aryl- and alkylation-oligomerization of alkynoates with organoboron reagents giving salicylates Reviewed

    Yasuhara Yuichi, Nishimura Takahiro, Hayashi Tamio

    CHEMICAL COMMUNICATIONS   46 ( 12 )   2130 - 2132   2010( ISSN:1359-7345

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    DOI: 10.1039/c000402b

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  • Rhodium-catalyzed asymmetric conjugate alkynylation of nitroalkenes Reviewed

    Nishimura Takahiro, Sawano Takahiro, Tokuji Sumito, Hayashi Tamio

    CHEMICAL COMMUNICATIONS   46 ( 36 )   6837 - 6839   2010( ISSN:1359-7345

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    DOI: 10.1039/c0cc02181d

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  • Chiral Tetrafluorobenzobarrelenes as Effective Ligands for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboroxines to beta,beta-Disubstituted alpha,beta-Unsaturated Ketones Reviewed

    Shintani Ryo, Takeda Momotaro, Nishimura Takahiro, Hayashi Tamio

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   49 ( 23 )   3969 - 3971   2010( ISSN:1433-7851

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    DOI: 10.1002/anie.201000467

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  • Sodium Tetraarylborates as Effective Nucleophiles in Rhodium/Diene-Catalyzed 1,4-Addition to beta,beta-Disubstituted alpha,beta-Unsaturated Ketones: Catalytic Asymmetric Construction of Quaternary Carbon Stereocenters Reviewed

    Shintani Ryo, Tsutsumi Yosuke, Nagaosa Makoto, Nishimura Takahiro, Hayashi Tamio

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   131 ( 38 )   13588 - +   2009.09( ISSN:0002-7863

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    DOI: 10.1021/ja905432x

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  • Asymmetric Polymerization of Achiral Arylacetylenes Giving Helical Polyacetylenes in the Presence of a Rhodium Catalyst with a C-2-Symmetric Tetrafluorobenzobarrelene Ligand Reviewed

    Nishimura Takahiro, Ichikawa Yoshitaka, Hayashi Tamio, Onishi Naoya, Shiotsuki Masashi, Masuda Toshio

    ORGANOMETALLICS   28 ( 16 )   4890 - 4893   2009.08( ISSN:0276-7333

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    DOI: 10.1021/om9003797

  • Rhodium-Catalyzed Asymmetric Conjugate Alkynylation of Enones with Alkynylsilanols Reviewed

    Nishimura Takahiro, Tokuji Sumito, Sawano Takahiro, Hayashi Tamio

    ORGANIC LETTERS   11 ( 15 )   3222 - 3225   2009.08( ISSN:1523-7060

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    DOI: 10.1021/ol901119d

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  • Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes Reviewed

    Kawamoto Takahiro, Hirabayashi Sho, Guo Xun-Xiang, Nishimura Takahiro, Hayashi Tamio

    CHEMICAL COMMUNICATIONS   ( 24 )   3528 - 3530   2009( ISSN:1359-7345

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    DOI: 10.1039/b900976k

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  • Asymmetric synthesis of beta-alkynyl aldehydes by rhodium-catalyzed conjugate alkynylation. Reviewed

    Nishimura T, Sawano T, Hayashi T

    Angewandte Chemie (International ed. in English)   48 ( 43 )   8057 - 9   2009( ISSN:1433-7851

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    DOI: 10.1002/anie.200904486

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  • The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes Reviewed

    Nishimura Takahiro, Kumamoto Hana, Nagaosa Makoto, Hayashi Tamio

    CHEMICAL COMMUNICATIONS   ( 38 )   5713 - 5715   2009( ISSN:1359-7345

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    DOI: 10.1039/b911118b

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  • Rhodium-catalyzed Alkynylation of Alkynes, Allenes, and Conjugate Enones Reviewed

    NISHIMURA Takahiro

    The Society of Synthetic Organic Chemistry, Japan, J. Synth. Org. Chem. Jpn.   66 ( 12 )   1160 - 1167   2008.12( ISSN:00379980

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    Rhodium-catalyzed alkynylation of carbon-carbon unsaturated bonds giving hydroalkynylation products took place in high yields with high stereoselectivity. Selective hydroalkynylation of internal alkynes with silylacetylenes giving 1, 3-enynes was realized by use of a hydroxorhodium catalyst. Asymmetric 1, 3-rearrangement of an alkynyl group of alkynyl alkenyl carbinols giving β-alkynylketones took place in high yields with high enantioselectivity in the presence of a hydroxorhodium/(R)-binap catalyst, which includes a key β-alkynyl elimination step in the cat-alytic cycle. Rhodium-catalyzed asymmetric conjugate alkynylation of α, β-unsaturated ketones giving β-alkynylketones was realized by use of (triisopropylsilyl) acetylene combined with (R)-DTBM-segphos as a chiral phosphine ligand, where the sterically bulky substituents on the silicon and phosphorus atoms suppress the alkyne dimerization. It was found that the presence of an acid was essential in the rhodium-catalyzed asymmetric addition of terminal alkynes to diarylphosphinylallenes giving exo-enynes in high yields with high regio- and enantioselectivity, where the stereochemical outcome is determined at the protonolysis of the π-allylrhodium(I) intermediate involved in the catalytic cycle.

    DOI: 10.5059/yukigoseikyokaishi.66.1160

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  • Rhodium-catalyzed asymmetric ring-opening alkynylation of azabenzonorbornadienes Reviewed

    Nishimura Takahiro, Tsurumaki Eiji, Kawamoto Takahiro, Guo Xun-Xiang, Hayashi Tamio

    ORGANIC LETTERS   10 ( 18 )   4057 - 4060   2008.09( ISSN:1523-7060

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    DOI: 10.1021/ol801549t

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  • Rhodium-catalyzed asymmetric addition of terminal alkynes to diarylphosphinylallenes. Reviewed

    Nishimura T, Guo XX, Hayashi T

    Chemistry, an Asian journal   3 ( 8-9 )   1505 - 10   2008.09( ISSN:1861-4728

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    DOI: 10.1002/asia.200800042

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  • C2-Symmetric tetrafluorobenzobarrelenes as highly efficient ligands for the iridium-catalyzed asymmetric annulation of 1,3-dienes with 2-formylphenylboron reagents Reviewed

    Nishimura Takahiro, Yasuhara Yuichi, Nagaosa Makoto, Hayashi Tamio

    TETRAHEDRON-ASYMMETRY   19 ( 15 )   1778 - 1783   2008.08( ISSN:0957-4166

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    DOI: 10.1016/j.tetasy.2008.07.014

  • Chiral tetrafluorobenzobarrelenes as highly efficient ligands for the rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids Reviewed

    Nishimura Takahiro, Nagaosa Makoto, Hayashi Tamio

    The Chemical Society of Japan CHEMISTRY LETTERS   37 ( 8 )   860 - 861   2008.08( ISSN:0366-7022

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    New <I>C</I><SUB>2</SUB>-symmetric chiral diene ligands bearing a tetrafluorobenzobarrelene framework and (−)-menthyl groups as chiral auxiliaries were prepared through [4 + 2] cycloaddition of 1,4-bis((−)-menthoxymethyl)benzene with tetrafluorobenzyne. The diene ligands realized the rhodium-catalyzed asymmetric addition of arylboronic acids to α,β-unsaturated carbonyl compounds giving β-arylcarbonyl compounds in high yields with high enantioselectivity.

    DOI: 10.1246/cl.2008.860

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  • Steric tuning of silylacetylenes and chiral phosphine ligands for rhodium-catalyzed asymmetric conjugate alkynylation of enones Reviewed

    Nishimura Takahiro, Guo Xun-Xiang, Uchiyama Nanase, Katoh Taisuke, Hayashi Tamio

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   130 ( 5 )   1576 - +   2008.02( ISSN:0002-7863

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    DOI: 10.1021/ja710540s

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  • Rhodium-catalyzed rearrangement of aryl bis(alkynyl) carbinols to 3-alkynyl-1-indanones Reviewed

    Shintani Ryo, Takatsu Keishi, Katoh Taisuke, Nishimura Takahiro, Hayashi Tamio

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   47 ( 8 )   1447 - 1449   2008( ISSN:1433-7851

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    DOI: 10.1002/anie.200704818

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  • Rhodium-catalyzed hydroalkynylation of internal Alkynes with silylacetylenes: An Alkynylrhodium(I) intermediate generated from the Hydroxorhodium(I) complex [Rh(OH)(binap)]2 Reviewed

    Nishimura Takahiro, Guo Xun-Xiang, Ohnishi Kohei, Hayashi Tamio

    ADVANCED SYNTHESIS & CATALYSIS   349 ( 17-18 )   2669 - 2672   2007.12( ISSN:1615-4150

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    DOI: 10.1002/adsc.200700334

  • Ruthenium/halide catalytic system for C-C bond forming reaction between alkynes and unsaturated carbonyl compounds Reviewed

    Nishimura Takahiro, Washitake Yosuke, Uemura Sakae

    ADVANCED SYNTHESIS & CATALYSIS   349 ( 17-18 )   2563 - 2571   2007.12( ISSN:1615-4150

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    DOI: 10.1002/adse.200700371

  • Rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols: Synthetic equivalent to asymmetric conjugate alkynylation of enones Reviewed

    Nishimura Takahiro, Katoh Taisuke, Takatsu Keishi, Shintani Ryo, Hayashi Tamio

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   129 ( 46 )   14158 - +   2007.11( ISSN:0002-7863

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    DOI: 10.1021/ja076346s

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  • Iridium-catalyzed [3+2] annulation of 1,3-dienes with ortho-carbonylated phenylboronic acids. A catalytic process involving regioselective 1,2-addition Reviewed

    Nishimura Takahiro, Yasuhara Yuichi, Hayashi Tamio

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   129 ( 24 )   7506 - +   2007.06( ISSN:0002-7863

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    DOI: 10.1021/ja072369v

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  • Rhodium-catalyzed asymmetric cyclodimerization of oxa- and azabicyclic alkenes Reviewed

    Nishimura Takahiro, Kawamoto Takahiro, Sasaki Keigo, Tsurumaki Eiji, Hayashi Tamio

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   129 ( 6 )   1492 - +   2007.02( ISSN:0002-7863

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    DOI: 10.1021/ja068488c

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  • Rhodium-catalyzed aryl transfer from trisubstituted aryl methanols to alpha,beta-unsaturated carbonyl compounds. Reviewed

    Nishimura T, Katoh T, Hayashi T

    Angewandte Chemie (International ed. in English)   46 ( 26 )   4937 - 9   2007( ISSN:1433-7851

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    DOI: 10.1002/anie.200700902

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  • Kinetic studies prove high catalytic activity of a diene-rhodium complex in 1,4-addition of phenylboronic acid to alpha,beta-unsaturated ketones Reviewed

    Kina Asato, Yasuhara Yuichi, Nishimura Takahiro, Iwamura Hiroshi, Hayashi Tamio

    CHEMISTRY-AN ASIAN JOURNAL   1 ( 5 )   707 - 711   2006.11( ISSN:1861-4728

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    DOI: 10.1002/asia.200600184

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  • Highly selective 1,6-addition of aryl boronic acids to alpha,beta,gamma,delta-unsaturated carbonyl compounds catalyzed by an iridium complex. Reviewed

    Nishimura T, Yasuhara Y, Hayashi T

    Angewandte Chemie (International ed. in English)   45 ( 31 )   5164 - 6   2006.08( ISSN:1433-7851

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    DOI: 10.1002/anie.200601719

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  • Asymmetric addition of dimethylzinc to N-tosylarylimines catalyzed by a rhodium-diene complex toward the synthesis of chiral 1-arylethylamines Reviewed

    Nishimura T, Yasuhara Y, Hayashi T

    ORGANIC LETTERS   8 ( 5 )   979 - 981   2006.03( ISSN:1523-7060

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    DOI: 10.1021/ol060213e

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  • Rhodium-catalyzed asymmetric hydroarylation of diphenylphosphinylallenes with arylboronic acids Reviewed

    Nishimura T, Hirabayashi S, Yasuhara Y, Hayashi T

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   128 ( 8 )   2556 - 2557   2006.03( ISSN:0002-7863

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    DOI: 10.1021/ja058763f

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  • Metal Cation-Exchanged Montmorillonite-Catalyzed Addition of Organic Disulfides to Alkenes Reviewed

    Nishimura Takahiro, Yoshinaka Tomoaki, Uemura Sakae

    Chemical Society of Japan Bulletin of the Chemical Society of Japan   78 ( 6 )   1138 - 1141   2005.06( ISSN:00092673

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    Publishing type:Research paper (scientific journal)  

    CiNii Article

  • Metal cation-exchanged montmorillonite-catalyzed addition of organic disulfides to alkenes Reviewed

    Nishimura T, Yoshinaka T, Uemura S

    The Chemical Society of Japan BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   78 ( 6 )   1138 - 1141   2005.06( ISSN:0009-2673

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    The addition of organic disulfides to alkenes, giving <I>vic</I>-bis(alkylthio)alkanes and <I>vic</I>-bis(arylthio)alkanes, proceeds in chlorobenzene in the presence of a catalytic amount of a variety of metal cation-exchanged montmorillonites (abbreviated as M<SUP><I>n</I>+</SUP>-monts), Al<SUP>3+</SUP>, Fe<SUP>3+</SUP>, Zr<SUP>4+</SUP>, and In<SUP>3+</SUP> being effective as M<SUP><I>n</I>+</SUP>. The most effective Fe<SUP>3+</SUP>-mont can be reused for the addition of diphenyl disulfide to cyclohexene at least 8 times without an appreciable loss of catalytic activity.

    DOI: 10.1246/bcsj.78.1138

    CiNii Article

  • Iridium-catalyzed ring cleavage reaction of cyclobutanone O-benzoyloximes providing nitriles Reviewed

    Nishimura T, Yoshinaka T, Nishiguchi Y, Maeda Y, Uemura S

    ORGANIC LETTERS   7 ( 12 )   2425 - 2427   2005.06( ISSN:1523-7060

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    DOI: 10.1021/ol0507120

    PubMed

  • Molybdenum- and Rhenium-catalyzed Isomerization of Cyclopropanemethanols to Tetrahydrofurans Reviewed

    MAEDA Yasunari, NISHIMURA Takahiro, UEMURA Sakae

    Chemistry letters   34 ( 6 )   790 - 791   2005.06( ISSN:03667022

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    CiNii Article

  • Vanadium-catalyzed isomerization of cyclopropanemethanols to homoallylic alcohols involving C-C bond cleavage Reviewed

    Maeda Y, Nishimura T, Uemura S

    公益社団法人 日本化学会 CHEMISTRY LETTERS   34 ( 3 )   380 - 381   2005.03( ISSN:0366-7022

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    Some vanadium compounds work as effective catalysts for isomerization of cyclopropanemethanols to the corresponding homoallylic alcohols. This reaction may proceed via [3,3]sigmatropic rearrangement involving an oxovanadium cyclopropane-methanolate accompanied by the C&ndash;C bond cleavage.

    DOI: 10.1246/cl.2005.380

    CiNii Article

  • γ-Cyclodextrin-Bicapped C60-Mediated Asymmetric Reduction of Ketones with NaBH4 Reviewed

    Nishimura Takahiro, Nakajima Mitsuru, Maeda Yasunari, UEMURA Sakae, TAKEKUMA Shin-ichi, TAKEKUMA Hideko, YOSHIDA Zen-ichi

    Chemical Society of Japan Bulletin of the Chemical Society of Japan   77 ( 11 )   2047 - 2050   2004.11( ISSN:00092673

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    CiNii Article

  • Vanadium-catalyzed sulfenylation of indoles and 2-naphthols with thiols under molecular oxygen Reviewed

    Maeda Y, Koyabu M, Nishimura T, Uemura S

    JOURNAL OF ORGANIC CHEMISTRY   69 ( 22 )   7688 - 7693   2004.10( ISSN:0022-3263

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jo048758e

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  • Calcium phosphate-vanadate apatite (CPVAP)-catalyzed aerobic oxidation of propargylic alcohols with molecular oxygen Reviewed

    Maeda Y, Washitake Y, Nishimura T, Iwai K, Yamauchi T, Uemura S

    TETRAHEDRON   60 ( 41 )   9031 - 9036   2004.10( ISSN:0040-4020

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    DOI: 10.1016/j.tet.2004.08.004

  • Metal cation-exchanged montmorillonite (Mn+-Mont)catalyzed Friedel-Crafts acylation of 1-methyl-1-cyclohexene and 1-trimethylsilyl-1-alkynes Reviewed

    Nishimura T, Ohtaka S, Hashimoto K, Yamauchi T, Hasegawa T, Imanaka K, Tateiwa J, Takeuchi H, Uemura S

    The Chemical Society of Japan BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   77 ( 9 )   1765 - 1766   2004.09( ISSN:0009-2673

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    The acylation of 1-methyl-1-cyclohexene and 1-trimethylsilyl-1-alkynes with acyl chlorides has been investigated in the presence of a variety of metal cation-exchanged montmorillonites (abbreviated as M<SUP><I>n</I>+</SUP>-monts), where the catalysts are recyclable for several times after simple washing.

    DOI: 10.1246/bcsj.77.1765

    CiNii Article

  • Palladium-catalyzed transformation of cyclobutanone O-benzoyloximes to nitriles via C-C bond cleavage Reviewed

    Nishimura T, Nishiguchi Y, Maeda Y, Uemura S

    JOURNAL OF ORGANIC CHEMISTRY   69 ( 16 )   5342 - 5347   2004.08( ISSN:0022-3263

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    DOI: 10.1021/jo049385k

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  • Ruthenium/chloride catalytic system for conjugate addition of terminal alkynes to acrylate esters Reviewed

    Nishimura T, Washitake Y, Nishiguchi Y, Maeda Y, Uemura S

    CHEMICAL COMMUNICATIONS   ( 11 )   1312 - 1313   2004.06( ISSN:1359-7345

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/b403616f

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  • Novel palladium catalytic systems for organic transformations Reviewed

    Nishimura T, Uemura S

    SYNLETT   ( 2 )   201 - 216   2004.02( ISSN:0936-5214

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1055/s-2004-815412

  • Copper-catalyzed oxidation of amines with molecular oxygen Reviewed

    Maeda Y, Nishimura T, Uemura S

    The Chemical Society of Japan BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   76 ( 12 )   2399 - 2403   2003.12( ISSN:0009-2673

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    An improved system for selective aerobic oxidation of amines to imines or nitriles is presented. It involves commercially available and inexpensive copper(I) or (II) chloride as catalyst, toluene as solvent, and MS3A as dehydrating agent under an atmospheric pressure of oxygen. A variety of amines can be used as substrates for this oxidation system to give the corresponding nitriles from primary amines (up to 97% yield; TON, up to 60) and the imines from secondary amines (up to 90% yield; TON, up to 45).

    DOI: 10.1246/bcsj.76.2399

    CiNii Article

  • Palladium-catalyzed oxidative alkynylation of alkenes via C-C bond cleavage under oxygen atmosphere Reviewed

    Nishimura T, Araki H, Maeda Y, Uemura S

    ORGANIC LETTERS   5 ( 17 )   2997 - 2999   2003.08( ISSN:1523-7060

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ol0348405

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  • Palladium-catalyzed asymmetric arylation, vinylation, and allenylation of tert-cyclobutanois via enantioselective C-C bond cleavage Reviewed

    Matsumura S, Maeda Y, Nishimura T, Uemura S

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   125 ( 29 )   8862 - 8869   2003.07( ISSN:0002-7863

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ja035293l

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  • Metal-Modified Clays as Catalysts for Organic Synthesis Reviewed

    NISHIMURA TAKAHIRO, UEMURA SAKAE

    45 ( 4 )   313 - 318   2003.06( ISSN:05598958

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    CiNii Article

  • Oxovanadium complex-catalyzed aerobic oxidation of propargylic alcohols Reviewed

    Maeda Y, Kakiuchi N, Matsumura S, Nishimura T, Kawamura T, Uemura S

    JOURNAL OF ORGANIC CHEMISTRY   67 ( 19 )   6718 - 6724   2002.09( ISSN:0022-3263

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jo025918i

  • Palladium-catalyzed kinetic resolution of tert-cyclobutanols via C-C bond cleavage Reviewed

    Nishimura T, Matsumura S, Maeda Y, Uemura S

    TETRAHEDRON LETTERS   43 ( 16 )   3037 - 3039   2002.04( ISSN:0040-4039

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  • Palladium-catalysed asymmetric arylation of tert-cyclobutanols via enantioselective C-C bond cleavage. Reviewed

    Nishimura T, Matsumura S, Maeda Y, Uemura S

    Chemical communications (Cambridge, England)   ( 1 )   50 - 1   2002.01( ISSN:1359-7345

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  • Oxovanadium complex-catalyzed oxidation of propargylic alcohols using molecular oxygen Reviewed

    Maeda Y, Kakiuchi N, Matsumura S, Nishimura T, Uemura S

    TETRAHEDRON LETTERS   42 ( 50 )   8877 - 8879   2001.12( ISSN:0040-4039

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  • Pd(II)-hydrotalcite-catalyzed oxidation of alcohols to aldehydes and ketones using atmospheric pressure of air Reviewed

    Kakiuchi N, Maeda Y, Nishimura T, Uemura S

    JOURNAL OF ORGANIC CHEMISTRY   66 ( 20 )   6620 - 6625   2001.10( ISSN:0022-3263

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  • Oxidative transformation of tert-cyclobutanols by palladium catalysis under oxygen atmosphere Reviewed

    Nishimura T, Ohe K, Uemura S

    JOURNAL OF ORGANIC CHEMISTRY   66 ( 4 )   1455 - 1465   2001.02( ISSN:0022-3263

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jo0016475

  • Pd(II)-Hydrotalcite-Catalyzed Selective Oxidation of Alcohols Using Molecular Oxygen Reviewed

    Kakiuchi Nobuyuki, Nishimura Takahiro, Inoue Masashi, UEMURA Sakae

    Chemical Society of Japan Bulletin of the Chemical Society of Japan   74 ( 1 )   165 - 172   2001.01( ISSN:00092673

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    CiNii Article

  • Palladium(0)-catalyzed ring cleavage of cyclobutanone grimes leading to nitriles via beta-carbon elimination Reviewed

    Nishimura T, Uemura S

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   122 ( 48 )   12049 - 12050   2000.12( ISSN:0002-7863

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  • Metal cation-exchanged montmorillonite (Mn+-mont)-catalyzed reductive alkylation of phenol and 1-naphthol with cyclohexanones Reviewed

    Nishimura T, Ohtaka S, Kimura A, Hayama E, Haseba Y, Takeuchi H, Uemura S

    APPLIED CATALYSIS A-GENERAL   194   415 - 425   2000.03( ISSN:0926-860X

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  • Development of a novel homogeneous and heterogeneous Pd catalytic system for organic transformations Reviewed

    Nishimura T, Uemura S

    CATALYSIS SURVEYS FROM JAPAN   4 ( 2 )   135 - 147   2000( ISSN:1384-6574

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  • Palladium(II)-supported hydrotalcite as a catalyst for selective oxidation of alcohols using molecular oxygen Reviewed

    Nishimura T, Kakiuchi N, Inoue M, Uemura S

    CHEMICAL COMMUNICATIONS   ( 14 )   1245 - 1246   2000( ISSN:1359-7345

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  • Palladium(II)-catalysed oxidation of alcohols under an oxygen atmosphere in a fluorous biphase system (FBS) Reviewed

    Nishimura T, Maeda Y, Kakiuchi N, Uemura S

    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1   ( 24 )   4301 - 4305   2000( ISSN:1472-7781

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/b006874h

  • Palladium(II)-catalyzed oxidation of terminal alkenes to methyl ketones using molecular oxygen Reviewed

    Nishimura T, Kakiuchi N, Onoue T, Ohe K, Uemura S

    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1   ( 12 )   1915 - 1918   2000( ISSN:1470-4358

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  • Palladium-catalyzed arylation of tert-cyclobutanols with aryl bromide via C-C bond cleavage: New approach for the gamma-arylated ketones Reviewed

    Nishimura T, Uemura S

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   121 ( 47 )   11010 - 11011   1999.12( ISSN:0002-7863

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  • Palladium(II)-Catalyzed Oxidation of Alcohols to Aldehydes and Ketones by Molecular Oxygen. Reviewed

    Nishimura T, Onoue T, Ohe K, Uemura S

    The Journal of organic chemistry   64 ( 18 )   6750 - 6755   1999.09( ISSN:0022-3263

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    PubMed

  • Palladium(II)-catalyzed oxidative ring cleavage of tert-cyclobutanols under oxygen atmosphere Reviewed

    Nishimura T, Ohe K, Uemura S

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   121 ( 11 )   2645 - 2646   1999.03( ISSN:0002-7863

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  • Pd(OAc)2-catalyzed oxidation of alcohols to aldehydes and ketones by molecular oxygen Reviewed

    Nishimura T, Onoue T, Ohe K, Uemura S

    TETRAHEDRON LETTERS   39 ( 33 )   6011 - 6014   1998.08( ISSN:0040-4039

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  • Ruthenium(II)-bipyridine anchored montmorillonite-catalyzed oxidation of aromatic alkenes with tert-butyl hydroperoxide Reviewed

    Nishimura T, Onoue T, Ohe K, Tateiwa J, Uemura S

    TETRAHEDRON LETTERS   39 ( 24 )   4359 - 4362   1998.06( ISSN:0040-4039

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  • Metal cation-exchanged montmorillonite (Mn+-mont)-catalysed aromatic alkylation with aldehydes and ketones Reviewed

    Tateiwa J, Hayama E, Nishimura T, Uemura S

    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1   ( 13 )   1923 - 1928   1997.07( ISSN:0300-922X

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Books and Other Publications

  • ロジウム,有機合成実験法ハンドブック第2版

    西村 貴洋( Role: Sole author ,  608–627)

    有機合成化学協会  2015 

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    Book type:Scholarly book

  • Preparation of Fluoroalkylated-Pyridines

    NISHIMURA Takahiro( Role: Sole author)

    Handbook on Fluorous Chemistry; Eds. J. A. Gladysz, D. P. Curran, I. H. Horváth, Wiley-VCH  2004 

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    Book type:Scholarly book

MISC

Presentations

  • Ir-Catalyzed Asymmetric [3+2] Annulation of ortho-Keto Arylboron Reagents with 1,3-Dienes International conference

    Ryota Yabe, Takahiro Nishimura

    The 15th International Kyoto Conference on New Aspects of Organic Chemistry  2023.11 

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    Presentation type:Poster presentation  

    Venue:Rihga Royal Hotel KYOTO  

  • Iridium-Catalyzed Branch-Selective and Enantioselective Alkylation of N-Benzimidazolyl Indoles International conference

    Kentaro Yamakawa, Takahiro Nishimura

    The 15th International Kyoto Conference on New Aspects of Organic Chemistry  2023.11 

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    Presentation type:Poster presentation  

    Venue:Rihga Royal Hotel KYOTO  

  • Synthesis of Chiral Spiro[4.5]decadienones via Chirality-transferring Oxidative Intramolecular Cyclization of Allenylsilane-tethered Phenols International conference

    Ryoma Kishimoto, Yuka Iwakiri, Kazuhiko Sakaguchi, Takahiro Nishimura

    The 15th International Kyoto Conference on New Aspects of Organic Chemistry  2023.11 

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    Presentation type:Poster presentation  

    Venue:Rihga Royal Hotel KYOTO  

  • Tuning of Directing Groups for Iridium-Catalyzed Enantioselective α-C–H Alkylation of Pyrrolidine Derivatives International conference

    Daisuke Yamauchi, Kentaro Yamakawa, Takahiro Nishimura

    The 15th International Kyoto Conference on New Aspects of Organic Chemistry  2023.11 

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    Presentation type:Poster presentation  

    Venue:Rihga Royal Hotel KYOTO  

  • アレニルシランが連結したジエノンの分子内環化反応 Domestic conference

    岩切 夕香,岸本 遼真,坂口 和彦,西村 貴洋

    第13回 CSJ化学フェスタ2023  2023.10  日本化学会

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    Presentation type:Poster presentation  

    Venue:タワーホール船堀  

  • イリジウム触媒によるC–Hアルキル化反応 Invited

    西村貴洋

    物質科学特論II 講演会  2023.09 

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    Presentation type:Public lecture, seminar, tutorial, course, or other speech  

    Venue:岡山県立大学  

  • Iridium-Catalyzed Branch-Selective and Enantioselective Alkylation of Indoles Domestic conference

    2023.09 

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    Presentation type:Poster presentation  

  • Ir-Catalyzed Asymmetric [3+2] Annulation of ortho-Keto Arylboron Compounds with 1,3-Dienes Domestic conference

    2023.09 

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    Presentation type:Poster presentation  

  • Iridium-Catalyzed Cyclization of Alkynyl Amines via C–H Activation Domestic conference

    2023.09 

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    Presentation type:Poster presentation  

  • アレニルシランが連結したフェノール類の酸化的分子内環化 Domestic conference

    岩切夕香,岸本遼真,坂口和彦,西村貴洋

    第43回有機合成若手セミナー「明日の有機合成を担う人のために」  2023.08  有機合成化学協会

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    Presentation type:Poster presentation  

    Venue:京都工芸繊維大学 60周年記念館  

  • イリジウム触媒を用いたオルト-ケトアリールホウ素化合物と1,3-ジエンによる[3+2]不斉付加環化反応 Domestic conference

    矢部亮太,西村貴洋

    日本化学会第103春季年会  2023.03  日本化学会

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    Presentation type:Oral presentation (general)  

    Venue:東京理科大学野田キャンパス  

  • イリジウム触媒によるインドール誘導体の不斉アルキル化反応 Domestic conference

    山川健太郎,西村貴洋

    日本化学会第103春季年会  2023.03  日本化学会

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    Presentation type:Oral presentation (general)  

    Venue:東京理科大学野田キャンパス  

  • イリジウム触媒を用いたジビニルシランによるN-メチル基の連続的なC–H結合アルキル化を介した環化反応 Domestic conference

    田中克昌,西村貴洋

    日本化学会第103春季年会  2023.03  日本化学会

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    Presentation type:Oral presentation (general)  

    Venue:東京理科大学野田キャンパス  

  • イリジウム触媒による分子内C(sp3)–Hアルケニル化反応 Domestic conference

    高橋裕稀,山川健太郎,西村貴洋

    日本化学会第103春季年会  2023.03  日本化学会

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    Presentation type:Oral presentation (general)  

    Venue:東京理科大学野田キャンパス  

  • アレニルシランが連結したフェノール類の酸化的分子内環化 Domestic conference

    坂口和彦,岸本遼真,岩切夕香,西村貴洋

    日本化学会第103春季年会  2023.03  日本化学会

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    Presentation type:Oral presentation (general)  

    Venue:東京理科大学野田キャンパス  

  • 炭素ー水素結合活性化を経る不斉付加反応 Invited Domestic conference

    西村貴洋

    2022学生シンポジウム  2022.12  有機合成化学協会

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    Presentation type:Public lecture, seminar, tutorial, course, or other speech  

    Venue:オンライン  

  • カチオン性イリジウム触媒を用いた1,1-二置換アルケンの不斉ヒドロアリール化反応 Domestic conference

    山川健太郎,中村威久海,坂本佳那,西村貴洋

    第12回CSJ化学フェスタ2022  2022.10  日本化学会

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    Presentation type:Poster presentation  

    Venue:タワーホール船堀  

  • イリジウム触媒を用いたsp3C–Hアルキル化による分子内環化反応 Domestic conference

    田中克昌,西村貴洋

    第12回CSJ化学フェスタ2022  2022.10  日本化学会

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    Presentation type:Poster presentation  

    Venue:タワーホール船堀  

  • アレニルシランが連結したフェノール類の酸化的分子内環化 Domestic conference

    岸本遼真,岩切夕香,坂口和彦,西村貴洋

    第43回有機合成若手セミナー  2022.08  有機合成化学協会

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    Presentation type:Poster presentation  

    Venue:オンライン  

  • アレニルシランが連結したジエノンの分子内環化反応 Domestic conference

    岩切夕香,岸本遼真,坂口和彦,西村貴洋

    第42回有機合成若手セミナー  2022.08  有機合成化学協会

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    Presentation type:Poster presentation  

    Venue:オンライン  

  • アレニルシランが連結したフェノールの酸化的分子内環化 Domestic conference

    岸本遼真,岩切夕香,坂口和彦,西村貴洋

    日本化学会第102春季年会  2022.03  日本化学会

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    Presentation type:Oral presentation (general)  

    Venue:オンライン  

  • ルテニウム触媒による糖類を用いたアニリン類のN-アルキル化反応 Domestic conference

    柘植康希,久保田駿一,西村貴洋,北山健司

    日本化学会第102春季年会  2022.03  日本化学会

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    Presentation type:Oral presentation (general)  

    Venue:オンライン  

  • アレニルシランを有するジエノンの分子内環化反応 Domestic conference

    岩切夕香,岸本遼真,坂口和彦,西村貴洋

    日本化学会第102春季年会  2022.03  日本化学会

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    Presentation type:Oral presentation (general)  

    Venue:オンライン  

  • イリジウム触媒による1,1-二置換アルケンの不斉ヒドロアリール化反応 Domestic conference

    山川健太郎,中村威久海,坂本佳那,西村貴洋

    日本化学会第102春季年会  2022.03  日本化学会

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    Presentation type:Oral presentation (general)  

    Venue:オンライン  

  • キラルなリン-オレフィン配位子を有するイリジウム触媒によるサリチルイミンと1,3-ジエンの不斉環化反応 Domestic conference

    矢部亮太,西村貴洋

    日本化学会第102春季年会  2022.03  日本化学会

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    Presentation type:Oral presentation (general)  

    Venue:オンライン  

  • イリジウム触媒によるN-メチル基C–H結合の環状アルケンへの不斉付加反応 Domestic conference

    坂本佳那,西村貴洋

    日本化学会第102春季年会  2022.03  日本化学会

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    Presentation type:Oral presentation (general)  

    Venue:オンライン  

  • イリジウム触媒を用いたN-アルキル基のα位C–H活性化を経る分子内環化反応 Domestic conference

    田中克昌,西村貴洋

    日本化学会第102春季年会  2022.03  日本化学会

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    Presentation type:Oral presentation (general)  

    Venue:オンライン  

  • イリジウム触媒によるα-オキソカルボン酸と1,3-ジエンの環化反応 Domestic conference

    矢部亮太,江邉裕祐,西村貴洋

    第67回有機金属化学討論会  2021.09  近畿化学協会

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    Presentation type:Poster presentation  

    Venue:オンライン  

  • イリジウム触媒によるエナンチオ選択的なN-メチル基のアルキル化反応 Domestic conference

    坂本佳那,西村貴洋

    第67回有機金属化学討論会  2021.09  近畿化学協会

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    Presentation type:Poster presentation  

    Venue:オンライン  

  • イリジウム触媒を用いたα,ω-ジエンによるN-メチル基C–H結合のアルキル化を経る環化反応 Domestic conference

    田中克昌,矢部亮太,服部大志,西村貴洋

    第67回有機金属化学討論会  2021.09  近畿化学協会

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    Presentation type:Poster presentation  

    Venue:オンライン  

  • イリジウム触媒を用いたα-トリフルオロメチルスチレンの不斉ヒドロアルキル化反応 Domestic conference

    山内大輔,中村威久海,西村貴洋

    第67回有機金属化学討論会  2021.09  近畿化学協会

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    Presentation type:Poster presentation  

    Venue:オンライン  

  • アレニルシランを有するフェノールの酸化的分子内環化 Domestic conference

    岸本遼真、坂口和彦、西村貴洋

    第41回有機合成若手セミナー  2021.08  有機合成化学協会

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    Venue:オンライン  

  • イリジウム触媒による糖類を用いたメチルケトンのα-アルキル化反応 Domestic conference

    柘植康希, 久保田駿一, 坂本佳那, 西村貴洋, 北山健司

    日本化学会第101春季年会  2021.03 

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    Presentation type:Oral presentation (general)  

  • イリジウム触媒を用いたsp3 C-H活性化を経るα-トリフルオロメチルスチレンの不斉ヒドロアルキル化反応 Domestic conference

    山内大輔, 中村威久海, 西村貴洋

    日本化学会第101春季年会  2021.03 

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    Presentation type:Oral presentation (general)  

  • イリジウム触媒を用いたN−スルホニルケチミンのC–Hアリル化反応 Domestic conference

    矢部亮太, 西村貴洋

    日本化学会第101春季年会  2021.03 

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    Presentation type:Oral presentation (general)  

  • イリジウム触媒を用いたN-メチル基C–H結合のα,ω-ジエンによる直接アルキル化を経る環化反応 Domestic conference

    田中克昌, 矢部亮太, 服部大志, 西村貴洋

    日本化学会第101春季年会  2021.03 

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  • フェノールが連結したアレニルシランの酸化的分子内環化 Domestic conference

    岸本遼真, 坂口和彦, 西村貴洋

    日本化学会第101春季年会  2021.03 

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  • β-シリル-γ-アルキリデン-γ-ブチロラクトンとアルデヒドおよびケトンを用いた四置換テトラヒドロピラノンの立体選択的合成 Domestic conference

    有吉将馬, 坂口和彦, 西村貴洋

    日本化学会第101春季年会  2021.03 

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    Presentation type:Oral presentation (general)  

  • パラジウム触媒によるアリル位置換反応とイリジウム触媒によるヒドロアリール化によるジヒドロベンゾフランの不斉合成 Domestic conference

    坂本佳那, 西村貴洋

    日本化学会第101春季年会  2021.03 

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    Presentation type:Oral presentation (general)  

  • 1) β-シリル-γ-アルキリデン-γ-ブチロラクトンとアルデヒドおよびケトンとの立体選択的環化反応 Domestic conference

    有吉将馬, 坂口和彦, 西村貴洋

    日本化学会第100春季年会  2020.03 

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  • ロジウム触媒を用いたアリールボロン酸のインデン誘導体への不斉付加反応 Domestic conference

    梅田萌子, 西村貴洋

    日本化学会第100春季年会  2020.03 

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  • ロジウム触媒を用いたアリールボロン酸のアセナフチレン誘導体への不斉付加反応 Domestic conference

    野口輝, 梅田萌子, 西村貴洋

    日本化学会第100春季年会  2020.03 

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  • イリジウム触媒を用いたベンズアミドのビニルエーテルへのエナンチオ選択的付加反応 Domestic conference

    村上琴音, 西村貴洋

    日本化学会第100春季年会  2020.03 

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  • イリジウム触媒を用いたα-オキソカルボン酸と1,3-ジエンによる立体選択的[3+2]環化付加反応 Domestic conference

    矢部亮太, 村上琴音, 西村貴洋

    日本化学会第100春季年会  2020.03 

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  • アリルフェニル炭酸エステル誘導体のアリル位置換反応に続く分子内ヒドロアリール化によるジヒドロベンゾフラン類の不斉合成 Domestic conference

    坂本佳那, 西村貴洋

    日本化学会第100春季年会  2020.03 

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    Presentation type:Oral presentation (general)  

  • ロジウム触媒によるアリールボロン酸のクロメン誘導体への不斉付加反応 Domestic conference

    梅田萌子,坂本佳那,永井 智隆,永本 翠,江邉 裕祐,西村 貴洋

    第66回有機金属化学討論会  2019.09 

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  • イリジウム触媒によるエナンチオ選択的な分子内ヒドロアリール化反応 Domestic conference

    坂本佳那,西村貴洋

    第66回有機金属化学討論会  2019.09 

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    Presentation type:Poster presentation  

  • イリジウム触媒を用いた電子不足共役ジエンによるN-スルホニルアクリルアミドのC–Hアルキル化反応 Domestic conference

    村上琴音,永本翠,西村貴洋

    第66回有機金属化学討論会  2019.09 

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    Presentation type:Poster presentation  

  • β–シリル–γ–エチリデン–γ–ブチロラクトンを用いた四置換テトラヒドロピラノンの立体選択的合成 Domestic conference

    有吉将馬,坂口和彦,西村貴洋

    第39回有機合成若手セミナー「明日の有機合成を担う人のために」  2019.08 

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  • イリジウム触媒によるグリカールのジアステレオ選択的なヒドロアリール化反応 Domestic conference

    坂本佳那,永井将貴,江邉裕祐,依光英樹,西村貴洋

    第39回有機合成若手セミナー「明日の有機合成を担う人のために」  2019.08 

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    Presentation type:Poster presentation  

  • β-シリル-γ-エチリデン-γ-ブチロラクトンを用いた四置換テトラヒドロピラノンの合成 Domestic conference

    有吉将馬,坂口和彦,西村貴洋

    日本化学会第99春季年会  2019.03 

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  • ロジウム触媒を用いたアリールボロン酸の2H-クロメンへの不斉付加反応 Domestic conference

    梅田萌子,坂本佳那,永井智隆,永本翠,江邉裕祐,西村貴洋

    日本化学会第99春季年会  2019.03 

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    Presentation type:Oral presentation (general)  

  • カチオン性イリジウム触媒による分子内ヒドロアリール化反応 Domestic conference

    坂本佳那,西村貴洋

    日本化学会第99春季年会  2019.03 

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    Presentation type:Oral presentation (general)  

  • 中村威久海,永井将貴,西村貴洋 Domestic conference

    NISHIMURA Takahiro

    中村威久海,永井将貴,西村貴洋  2019.03 

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    Presentation type:Oral presentation (general)  

  • イリジウム触媒を用いたN-メチルC−H結合の1,1-二置換アルケンへの付加反応 Domestic conference

    中村威久海,永井将貴,西村貴洋

    日本化学会第99春季年会  2019.03 

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    Presentation type:Oral presentation (general)  

  • イリジウム触媒を用いたN-スルホニルアクリルアミドの電子不足共役ジエンによるC–Hアルキル化反応とそれに続く環化反応 Domestic conference

    村上琴音,永本翠,西村貴洋

    日本化学会第99春季年会  2019.03 

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    Presentation type:Oral presentation (general)  

  • Iridium-Catalyzed Enantioselective Hydroarylation of Chromene Derivatives International conference

    Kana Sakamoto, Takahiro Nishimura

    10th OCARINA International Symposium  2019.03 

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    Presentation type:Poster presentation  

  • Iridium-Catalyzed sp3 C−H bond Alkylation of Indoline Derivatives with Terminal Alkenes Domestic conference

    I. Nakamura, T. Nishimura

    10th OCARINA International Symposium  2019.03 

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    Presentation type:Oral presentation (general)  

  • Acid-Catalyzed Chirality-Transferring Intramolecular Friedel-Crafts Reaction of α-Hydroxy-α-alkenylsilanes International conference

    Shunichi Nakamura, Takahiro Nishimura, K. Sakaguchi

    10th OCARINA International Symposium  2019.03 

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    Presentation type:Poster presentation  

  • Iridium-Catalyzed sp3 C−H bond Alkylation of Indoline Delivatives with Terminal Alkenes International conference

    Ikumi Nakamura, Masaki Nagai, Takahiro Nishimura

    10th OCARINA International Symposium  2019.03 

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    Presentation type:Poster presentation  

  • Iridium-Catalyzed Direct sp3 C–H Alkylation of Aminoalkyl Groups with Alkenes International conference

    Hattori Hattori, Ikumi Nakamura, Daisuke Yamauchi, Takahiro Nishimura

    The 14th International Kyoto Conference on New Aspects of Organic Chemistry  2018.11 

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    Presentation type:Poster presentation  

  • Ir-Catalyzed Enantioselective Hydroarylation of 2H-Chromene with Aromatic Ketones International conference

    Kana Sakamoto, Takahiro Nishimura

    The 14th International Kyoto Conference on New Aspects of Organic Chemistry  2018.11 

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    Presentation type:Poster presentation  

  • Catalytic C–H Alkylation by Way of Amidoiridium Species Invited International conference

    Takahiro Nishimura

    International Congress on Pure & Applied Chemistry (ICPAC) Langkawi 2018  2018.10 

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    Presentation type:Oral presentation (invited, special)  

  • Catalytic C–H Alkylation by Way of Amidoiridium Species Domestic conference

    Takahiro Nishimura

    International Congress on Pure & Applied Chemistry (ICPAC) Langkawi 2018  2018.10 

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    Presentation type:Oral presentation (general)  

  • Ir-Catalyzed Enantioselective Hydroarylation of Chromene Derivatives Domestic conference

    SAKAMOTO Kana, NISHIMURA Takahiro

    Ir-Catalyzed Enantioselective Hydroarylation of Chromene Derivatives  2018.09 

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    Presentation type:Oral presentation (general)  

  • イリジウム触媒によるインドリン誘導体のsp3 C–Hアルキル化反応 Domestic conference

    中村威久海,山内大輔,西村貴洋

    第38回有機合成若手セミナー「明日の有機合成を担う人のために」  2018.08 

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    Presentation type:Oral presentation (general)  

  • 酸触媒によるα-ヒドロキシ-α-アルケニルシランの分子内Friedel-Crafts反応における不斉転写 Domestic conference

    久保田 駿一.赤木 航,池田 直子,東野 勝人,品田 哲郎,大船 泰史,西村 貴洋,坂口 和彦

    第38回有機合成若手セミナー「明日の有機合成を担う人のために」  2018.08 

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    Presentation type:Oral presentation (general)  

  • イリジウム/キラルジエン触媒による芳香族ケチミンと1,3-エンインのエナンチオ選択的(3 + 2)環化反応 Domestic conference

    坂本佳那,西村貴洋

    第38回有機合成若手セミナー「明日の有機合成を担う人のために」  2018.08 

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    Presentation type:Oral presentation (general)  

  • イリジウム触媒を使った高原子効率型付加反応 Domestic conference

    西村 貴洋

    第38回有機合成若手セミナー「明日の有機合成を担う人のために」  2018.08 

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    Presentation type:Oral presentation (general)  

  • イリジウム触媒を用いたインドリン誘導体の末端アルケンによるsp3 C–Hアルキル化反応 Domestic conference

    中村 威久海,山内 大輔,西村 貴洋

    日本化学会第98春季年会  2018.03 

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    Presentation type:Oral presentation (general)  

  • 酸触媒によるα-ヒドロキシ-α-アルケニルシランの不斉転写型分子内Friedel-Crafts 反応 Domestic conference

    久保田 駿一,赤木 航,池田 直子,東野 勝人,品田 哲郎,大船 泰史,西村 貴洋,坂口 和彦

    日本化学会第98春季年会  2018.03 

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    Presentation type:Oral presentation (general)  

  • イリジウム触媒を用いるクロメン誘導体のエナンチオ選択的ヒドロアリール化反応 Domestic conference

    坂本佳那,西村貴洋

    日本化学会第98春季年会  2018.03 

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    Presentation type:Oral presentation (general)  

  • イリジウム触媒を用いたアミノメチル基のアルケンによる sp3 C−H ジアルキル化反応 Domestic conference

    服部大志,西村貴洋

    日本化学会第98春季年会  2018.03 

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    Presentation type:Oral presentation (general)  

  • Hydroxoiridium-Catalyzed Regioselective Hydroarylation of Conjugated Dienes via π-Allyliridium Intermediates Domestic conference

    Midori Nagamoto, Hideki Yorimitsu, Takahiro Nishimura

    日本化学会第98春季年会  2018.03 

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    Presentation type:Oral presentation (general)  

  • 遷移金属触媒による高原子効率型の不斉反応 Invited Domestic conference

    西村 貴洋

    第26回京大有機金属化学若手勉強会  2017.11 

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    Presentation type:Oral presentation (invited, special)  

  • ヒドロキソイリジウム触媒を用いた芳香族アミドの直接オルト位アルケニル化およびアルキル化反応 Domestic conference

    福田淳一,永本翠,幡野幸,西村貴洋,依光英樹

    第34回有機合成化学セミナー  2017.09 

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    Presentation type:Oral presentation (general)  

  • ヒドロキソイリジウム触媒による1,3-ジエンの位置選択的ヒドロアリール化反応 Domestic conference

    永本翠,依光英樹,西村貴洋

    第64回有機金属化学討論会  2017.09 

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    Presentation type:Oral presentation (general)  

  • イリジウム触媒を用いた芳香族アミドのオルト位C-H活性化を経るアルケニル化およびアルキル化反応 Domestic conference

    福田淳一,永本翠,幡野幸,西村貴洋,依光英樹

    第37回有機合成若手セミナー「明日の有機合成を担う人のために」  2017.08 

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  • 遷移金属触媒を用いた高原子効率型反応の開発 Invited Domestic conference

    西村 貴洋

    第79回講演会 有機化学研究会(白鷺セミナー)  2017.04 

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    Presentation type:Oral presentation (invited, special)  

  • 9族金属触媒を用いる不斉合成反応の開発 Invited Domestic conference

    西村 貴洋

    大阪市立大学理学部化学科談話会  2017.04 

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    Presentation type:Oral presentation (invited, special)  

  • Iridium-Catalyzed Asymmetric Reactions with High Atom Efficiency by Way of C−H Bond Activation Invited International conference

    Takahiro Nishimura

    Kyoto Symposium on Organic and Organometallic Chemistry  2017.03 

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    Presentation type:Oral presentation (invited, special)  

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Grant-in-Aid for Scientific Research

  • 炭素-水素結合の立体選択的付加反応を利用した新反応プロセスの開発

    Grant-in-Aid for Scientific Research(B)  2019.04

  • Development of Stereoselective Hydrofuctionalizations

    Grant-in-Aid for Scientific Research(B)  2015.04

  • 分子活性化による有機金属活性種の発生と高原子効率型分子変換反応への応用

    新学術領域研究(研究領域提案型)  2013.04

  • Asymmetric construction of a stereogenic carbon center substituted with aryl groups

    Grant-in-Aid for Scientific Research(C)  2012.04

  • Development ofπ-Accepting Chiral Ligands and their Application to Catalytic Asymmetric Reactions

    Grant-in-Aid for Young Scientists(B)  2010

  • Advanced Control of Catalytic Activity and Stereoselectivity in Catalytic Asymmetric Reactions

    Grant-in-Aid for Scientific Research(S)  2007

  • Selective Transformations of Cycloalkanes via Carbon-Carbon Bond Cleavage

    Grant-in-Aid for Scientific Research on Priority Areas  2005

  • 遷移金属触媒による選択的炭素-炭素結合開裂を鍵とする新規合成反応の開発

    Grant-in-Aid for Young Scientists(B)  2002

  • Development of Novel Molecular Functions of γ-Cyclodextrin-Bicapped C60 Supramolecular Complex and Supermacroheterocyccs with C60

    Grant-in-Aid for Scientific Research(A)  2001

  • 金属交換ならびに金属担持モンモリロナイトを触媒とする新規有機合成反応の開発

    Grant-in-Aid for JSPS Fellows  1999

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Outline of education staff

  • 全学共通科目:基礎有機化学B
    専門科目:有機化学3,化学実験Ⅲ,化学実験S,特別研究
    大学院講義:創成分子科学演習,機能分子科学演習,化学前期特別研究II,創成分子科学ゼミナール,機能分子化学ゼミナール,後期特別研究,研究企画ゼミナール,有機金属化学特論,化学特別演習1A,1B,化学特別研究1A,1B,化学特別演習3A,3B,化学特別研究3A,3B

Charge of on-campus class subject

  • 有機化学3

    2020     Undergraduate

  • 特別研究(化学)

    2020     Undergraduate

  • 化学後期特別研究

    2020     Graduate school

  • 化学前期特別研究I,II

    2020     Graduate school

  • 化学実験S

    2020     Undergraduate

  • 創成分子科学演習

    2020     Graduate school

  • 化学実験Ⅲ

    2020     Undergraduate

  • 基礎化学実験Ⅰ

    2020     Undergraduate

  • 創成分子科学ゼミナール

    2020     Graduate school

  • 体験で知る科学と技術

    2020     Undergraduate

  • 有機化学演習2

    2020     Undergraduate

  • 化学後期特別研究

    2019     Graduate school

  • 機能分子科学

    2019     Graduate school

  • Basic Organic Chemistry I

    2019     Undergraduate

  • 創成分子科学ゼミナール1

    2019     Graduate school

  • 体験で知る科学と技術

    2019     Undergraduate

  • 創成分子科学ゼミナール2

    2019     Graduate school

  • 基礎化学実験Ⅰ

    2019     Undergraduate

  • 化学実験Ⅲ

    2019     Undergraduate

  • 創成分子科学演習

    2019     Graduate school

  • 化学前期特別研究

    2019     Graduate school

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Charge of off-campus class subject

  • 物質科学特論II

    2023.09
    Institution:Okayama Prefectural University

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    Level:Postgraduate  Country:Japan

Number of papers published by graduate students

  • 2022

    Number of graduate students presentations:5

Number of instructed thesis, researches

  • 2022

    Number of instructed the graduation thesis:Number of graduation thesis reviews:2

    [Number of instructed the Master's Program] (previous term):[Number of instructed the Master's Program] (letter term):3

    [Number of master's thesis reviews] (chief):[Number of master's thesis reviews] (vice-chief):3

    [Number of doctoral thesis reviews] (chief):[Number of doctoral thesis reviews] (vice-chief):0

Social Activities

  • 有機金属化学セミナー

    Role(s): Lecturer

    近畿化学協会  2019.06

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    Audience: University students, Graduate students, Teachers, Researchesrs, General public, Company

    Type:Seminar, workshop

  • 化学セミナー/先端科学研修

    Role(s): Lecturer

    大阪市立大学理学部  大阪市立大学  2018.07

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    Audience: High school students, General public

    Type:Seminar, workshop