2024/04/03 更新

写真a

ニシオカ タカノリ
西岡 孝訓
NISHIOKA Takanori
担当
大学院理学研究科 化学専攻 准教授
理学部 化学科
職名
准教授
所属
理学研究院

担当・職階

  • 大学院理学研究科 化学専攻 

    准教授  2022年04月 - 継続中

  • 理学部 化学科 

    准教授  2022年04月 - 継続中

取得学位

  • 博士(理学) ( 大阪市立大学 )

研究分野

  • ナノテク・材料 / 無機・錯体化学

  • ナノテク・材料 / 機能物性化学

研究キーワード

  • 触媒

  • クラスター

  • カルベン

研究概要

  • 触媒やセンサーなどへの利用を目指し、新しい機能性をもった糖を導入した遷移金属錯体を合成し、その構造や性質を明らかにする。そしてこれらの錯体を用い、物質変換の効率化や選択的な物質変換法の開発を目指す。

研究歴

  • 硫化物配位子をもつ多核クラスターを用いた二酸化炭素電解還元触媒の開発

    多核クラスター、二酸化炭素還元、触媒  個人研究

    2010年04月 

  • 糖修飾Nーヘテロ環カルベン錯体

    遷移金属錯体、糖、カルベン  個人研究

    2006年04月 

所属学協会

  • アメリカ化学会

      国外

  • 先端錯体工学研究会

      国内

  • 錯体化学会

  • 日本化学会

      国内

委員歴(学外)

  • 副会長   先端錯体工学研究会  

    2023年03月 - 継続中 

  • 会長   先端錯体工学研究会  

    2016年 - 2023年02月 

  • 副会長   先端錯体工学研究会  

    2010年 - 2015年 

  • 庶務   先端錯体工学研究会  

    2007年 - 2009年 

受賞歴

  • 先端錯体工学研究会賞

    2012  

     詳細を見る

    受賞国:日本国

職務経歴(学外)

  • 岡崎国立共同研究機構分子科学研究所   -

    1992年 - 1995年

学歴

  • 大阪市立大学   理学研究科   化学専攻   修士課程   卒業・修了

    - 1992年

  • 大阪市立大学   理学部   化学科     卒業・修了

    - 1990年

論文

  • Red-light responsive photoCORM activated in aqueous acid solution 査読

    Natsuo Nomura, Seiya Tanaka, Masakazu Hirotsu, Takanori Nishioka, Hiroshi Nakajima

    JOURNAL OF ORGANOMETALLIC CHEMISTRY   984   122578 - 122585   2022年11月

     詳細を見る

    掲載種別:研究論文(学術雑誌)   国際・国内誌:国際誌  

    リポジトリURL: http://hdl.handle.net/10466/0002000156

  • Electronic and steric impact of bis-NHC ligands on reactions of Pt3S2 cores in trinuclear complexes bearing bis-NHC ligands with various lengths of alkylene bridges 査読

    Yabune Natsuki, Nakajima Hiroshi, Nishioka Takanori

    DALTON TRANSACTIONS   50 ( 35 )   12079 - 12082   2021年09月( ISSN:1477-9226

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/d1dt02747f

  • Synthesis of iron(III)-carbonyl complex with variable wavelength range for CO release depending on protonation and deprotonation of axial phosphorous ligands 査読

    Tanaka Seiya, Nomura Natsuo, Nishioka Takanori, Hirotsu Masakazu, Nakajima Hiroshi

    Elsevier BV JOURNAL OF ORGANOMETALLIC CHEMISTRY   943   121843 - 121843   2021年06月( ISSN:0022-328X

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.jorganchem.2021.121843

  • Use of a Ferritin L134P Mutant for the Facile Conjugation of Prussian Blue in the Apoferritin Cavity 査読

    Ikenoue Yuta, Tahara Yuhei O., Miyata Makoto, Nishioka Takanori, Aono Shigetoshi, Nakajima Hiroshi

    INORGANIC CHEMISTRY   60 ( 7 )   4693 - 4704   2021年04月( ISSN:0020-1669

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/acs.inorgchem.0c03660

  • Dibenzoate esters of cis-tetralin-2,3-diol as analogs of (-)-epigallocatechin gallate: synthesis and crystal structure of anticancer drug candidates 査読

    Rutherford Ryan Noboru, Ura Shinji, Chan Tak-Hang, Fukumoto Kozo, Nishioka Takanori, Renzetti Andrea

    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY   76   1085 - +   2020年12月( ISSN:2053-2296

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1107/S2053229620014916

  • Metal-metal bond formation of triplatinum cores with a silver(i) ion affording a heptanuclear cluster bearing four Pt-Ag bonds 査読

    Yabune Natsuki, Nakajima Hiroshi, Nishioka Takanori

    DALTON TRANSACTIONS   49 ( 23 )   7680 - 7683   2020年06月( ISSN:1477-9226

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/d0dt01227k

  • Reduction-triggered Ligand Dissociation of Trinuclear Complex Bearing Three Kinds of Metal-ligand Units 査読

    Yabune Natsuki, Monju Ryosuke, Nakajima Hiroshi, Nishioka Takanori

    公益社団法人 日本化学会 CHEMISTRY LETTERS   48 ( 12 )   1511 - 1514   2019年12月( ISSN:0366-7022

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    <p>A heterometallic trinuclear complex with three metal-metal bonds, which is constituted of three kinds of metal-ligand units bridged by two sulfido ligands, reacts with a 2-electron donor to afford an adduct accompanied with elongation of the metal-metal bonds. Cyclic voltammograms of the complexes showed that the adduct releases the 2-electron donor after electrochemical 1-electron reduction.</p>

    DOI: 10.1246/cl.190707

    CiNii Article

  • Sugar-Incorporated Chelating Bis-N-Heterocyclic Carbene Palladium Complexes. Synthesis, Structures, and Catalytic Ability for Suzuki-Miyaura Cross-Coupling Reactions in Water 査読

    Imanaka Yosuke, Nakao Keita, Maeda Yuri, Nishioka Takanori

    公益社団法人 日本化学会 BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   90 ( 9 )   1050 - 1057   2017年09月( ISSN:0009-2673

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    <p>Sugar-incorporated chelating bis-N-heterocyclic carbene ligand precursors 1,1′-bis(2,3,4,6-tetra-<i>O</i>-acetyl-β-<span style="font-variant: small-caps;">d</span>-glucopyranosyl)-3,3′-ethylene-diimidazolyl ([(bisNHC-C2)H<sub>2</sub>]<sup>2+</sup>) and 1,1′-bis(2,3,4,6-tetra-<i>O</i>-acetyl-β-<span style="font-variant: small-caps;">d</span>-glucopyranosyl)-3,3′-propylene-diimidazolyl ([(bisNHC-C3)H<sub>2</sub>]<sup>2+</sup>) were synthesized and used to prepare palladium complexes [Pd(bisNHC-C2)Cl<sub>2</sub>] and [Pd(bisNHC-C3)Cl<sub>2</sub>], respectively, by direct metallation reaction using dichlorobis(acetonitrile)palladium as a metal source. Catalytic abilities of the complexes for Suzuki-Miyaura coupling in aqueous media were examined and moderate TON (85,000) and TOF (170,000 h<sup>−1</sup>) were obtained. Because the terminal chloro ligands in the complexes were substituted with solvent molecules or chloride anion and hence <sup>1</sup>H NMR spectra of the chloro complexes were complicated, hydrosulfido complexes [Pd(bisNHC-C<i>n</i>)(SH)<sub>2</sub>] (<i>n</i> = 2 and 3) were prepared to confirm structures in solution. Dynamic behavior of flapping-wing motion of the bisNHC ligand in [Pd(bisNHC-C3)(SH)<sub>2</sub>] in solution was evaluated using the signals of the SH protons, which are inequivalent in <sup>1</sup>H NMR spectra attributed to the chirality of the glucopyranosyl units.</p>

    DOI: 10.1246/bcsj.20170082

    CiNii Article

  • The Arrangement of Two N-Heterocyclic Carbene Moieties in Palladium Pincer Complexes Affects Their Catalytic Activity towards Suzuki-Miyaura Cross-Coupling Reactions in Water 査読

    Imanaka Yosuke, Shiomoto Naotoshi, Tamaki Mako, Maeda Yuri, Nakajima Hiroshi, Nishioka Takanori

    公益社団法人 日本化学会 BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   90 ( 1 )   59 - 67   2017年01月( ISSN:0009-2673

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    <p>Palladium complexes with pincer ligands containing one pyridine and two N-heterocyclic carbene units with acetyl-protected <span style="font-variant: small-caps;">d</span>-glucopyranosyl groups in C-C-N and C-N-C arrangements were synthesized. The complexes form diastereomers due to the twisted pincer ligands and chiral <span style="font-variant: small-caps;">d</span>-glucopyranosyl units. The diastereomers of the C-C-N complex are in equilibrium in solution, whereas only one of the diastereomers of the C-N-C complex forms kinetically. Deprotection of the acetyl groups in the ligands afforded water-soluble complexes with one of the hydroxide groups in the <span style="font-variant: small-caps;">d</span>-glucopyranosyl groups coordinated to the metal ion. In CD<sub>3</sub>OD, the deprotected complex with the C-N-C ligand gradually decomposed, whereas that with the C-C-N ligand was stable at room temperature. The complexes catalyzed Suzuki–Miyaura cross-coupling reactions in water with turnover numbers of 75,000 for the C-C-N and 8,900 for C-N-C complexes. The C-C-N complex was not deactivated by the addition of metallic Hg meaning that the active species is the complex itself or its derivatives having the pincer ligand. On the other hand, the C-N-C complex exhibited no catalytic activity for the coupling reaction in the presence of metallic Hg, meaning that the active species are heterogeneous catalysts, such as Pd nanoparticles.</p>

    DOI: 10.1246/bcsj.20160300

    CiNii Article

  • Observation of hybrid artificial photosynthetic membranes using peripheral and core antennae from two different species of photosynthetic bacteria by AFM and fluorescence micro-spectroscopy 査読

    Uragami Chiasa, Sugai Yuko, Hanjo Kohei, Sumino Ayumi, Fujii Ritsuko, Nishioka Takanori, Kinoshita Isamu, Dewa Takehisa, Nango Mamoru, Gardiner Alastair T., Cogdell Richard J., Hashimoto Hideki

    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY   313   60 - 71   2015年12月( ISSN:1010-6030

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.jphotochem.2015.06.009

  • Syntheses and Catalytic Ability of Sugar-Incorporated N-Heterocyclic Carbene Pincer Pd Complexes Possessing Various N-Substituents 査読

    Imanaka Yosuke, Hashimoto Hideki, Nishioka Takanori

    公益社団法人 日本化学会 BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   88 ( 8 )   1135 - 1143   2015年08月( ISSN:0009-2673

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    Exploration of catalysts for organic reactions in water, which is a nontoxic and nonexplosive liquid, has been studied to achieve environmentally friendly chemical processes. For such a purpose, we utilized click chemistry to incorporate sugar units into transition-metal complexes affording water-soluble complexes. In this study, a series of palladium complexes with C&ndash;C&ndash;N pincer ligands, each of which consisted of two <i>N</i>-heterocyclic carbenes (NHCs) and a triazole moiety with a <small>D</small>-glucopyranosyl unit were synthesized. These complexes possess various <i>N</i>-substituents, namely, methyl, isopropyl, benzyl, or <small>D</small>-glucopyranosyl units on the terminal NHC moieties. The diastereoselectivity in the formation of the complexes and their catalytic ability toward the Suzuki&ndash;Miyaura cross-coupling reactions in water exhibited clear <i>N</i>-substituent effects. The tridentate ligand with an acetylated <small>D</small>-glucopyranosyl unit on the terminal NHC moiety led to high diastereoselectivity in the formation of its complex, while each of the other ligands with achiral substituents on the terminal NHC units afforded both of the diastereomers with low selectivity. Catalytic reactions using the complexes were examined for the Suzuki&ndash;Miyaura cross-coupling reactions of phenylboronic acid and 4&prime;-bromoacetophenone in water. The complex possessing an isopropyl group on the terminal NHC moiety exhibited excellent catalytic activity with TON (800000), which is comparable to the best value reported for a similar reaction.

    DOI: 10.1246/bcsj.20150083

    CiNii Article

  • Formation of Acyl and Dioxycarbene Ruthenium Complexes via Double C-S Bond Cleavage and CO Insertion 査読

    Santo Kiyokazu, Hirotsu Masakazu, Kawamoto Keisuke, Nishioka Takanori, Kinoshita Isamu

    公益社団法人 日本化学会 BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   88 ( 4 )   613 - 615   2015年04月( ISSN:0009-2673

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    Ruthenium complexes containing an N,N,C,S-metalloligand or an N,N,C,O-organoligand with a sulfido carbonyl Ru cluster were obtained by the reaction of 6-(4&prime;&prime;-dibenzothienyl)-2,2&prime;-bipyridine with [Ru<sub>3</sub>(CO)<sub>12</sub>]. The dibenzothienyl group undergoes double carbon&ndash;sulfur bond cleavage and CO insertion reactions to give a bridging acyl group and a metallacyclic dioxycarbene donor.

    DOI: 10.1246/bcsj.20140379

    CiNii Article

  • Redox Properties and Catalytic Ability toward Electrochemical Proton Reduction of Sulfur-Bridged Trinuclear Mo3S4 Complexes Containing Acetate, Trifluoroacetate, and/or Dithiophosphate as Bridging Ligands 査読

    Kawamoto Keisuke, Ichimura Akio, Hashimoto Hideki, Kinoshita Isamu, Hirotsu Masakazu, Nishioka Takanori

    公益社団法人 日本化学会 BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   88 ( 4 )   565 - 571   2015年04月( ISSN:0009-2673

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    A novel complex with the terminal acetonitrile and bridging trifluoroacetate (tfa) ligands of [Mo<sub>3</sub>S<sub>4</sub>(dtp)<sub>3</sub>(&mu;-tfa)(NCCH<sub>3</sub>)] (dtp: diethyl dithiophospate) (<b>1-tfa</b>) was prepared from the substitution reaction of [Mo<sub>3</sub>S<sub>4</sub>(dtp)<sub>3</sub>(&mu;-dtp)(NCCH<sub>3</sub>)] (<b>1-dtp</b>) with trifluoroacetate anhydride in acetonitrile. The reaction of <b>1-dtp</b> with trifluoroacetic acid in dichloromethane also afforded <b>1-tfa</b>. Complex <b>1-tfa</b> reacts with pyridine in ethanol resulting in the formation of a complex with the terminal pyridine ligand (py), [Mo<sub>3</sub>S<sub>4</sub>(dtp)<sub>3</sub>(&mu;-tfa)(py)] (<b>2-tfa</b>). Structures of <b>1-tfa</b> and <b>2-tfa</b> were determined by single-crystal X-ray structural analysis showing that one of three Mo&ndash;Mo distances depend on a kind of the bridging ligands, dtp, OAc, and tfa, while no trends in the other two Mo&ndash;Mo distances in each of the complexes with the different bridging ligands. Each of the cyclic voltammograms of <b>1-dtp</b>, [Mo<sub>3</sub>S<sub>4</sub>(dtp)<sub>3</sub>(&mu;-OAc)(NCCH<sub>3</sub>)] (OAc: acetate) (<b>1-OAc</b>), <b>1-tfa</b>, [Mo<sub>3</sub>S<sub>4</sub>(dtp)<sub>3</sub>(&mu;-OAc)(py)] (<b>2-OAc</b>), and <b>2-tfa</b> showed two consecutive one-electron reduction waves and an oxidation wave, which are formally assigned to the Mo(IV IV IV)/Mo(III IV IV), Mo(III IV IV)/Mo(III III IV), and Mo(V IV IV)/Mo(IV IV IV) couples, respectively. The re-oxidation and re-reduction peaks for the second reduction and the oxidation processes were not observed for all of the complexes. The redox potentials of the first reduction processes were shifted up to ca. 200 mV with the bridging and terminal ligands, for example, the redox potentials appeared at &minus;0.98 and &minus;1.19 V vs. Fc/Fc<sup>+</sup> <b>2-OAc</b> and <b>1-tfa</b>, respectively, due to the lower electron-donating ability of CH<sub>3</sub>CN and tfa ligands compared to that of the py and OAc ligands. The re-oxidation peak for the second reduction process of <b>2-OAc</b> was observed at &minus;80 &deg;C suggesting that this is an EC process and the chemical reaction following the second electrochemical reduction is probably inhibited at low temperature. On the other hand, no re-reduction peak for the oxidation process appeared even at &minus;80 &deg;C implying that the oxidation process is accompanied by a significant structural change. This argument is supported by the results of the DFT calculation. The HOMO component of the complex contains a bonding character between the two acetate-bridged Mo centers and the other acetate-unbridged one, and the spin densities of the 1-electron oxidized complex mostly located at the one of two acetate-bridged Mo centers and the other acetate-unbridged one. Cyclic voltammograms of these complexes in the presence of trifluoroacetic acid as a proton source exhibited catalytic currents around the first reduction wave for each complex. The DFT calculations for <b>2-OAc</b> and <b>2-tfa</b> demonstrated that the HOMO components are also distributed over the doubly bridged sulfur ligands in addition to the Mo centers in the Mo<sub>3</sub>S<sub>4</sub> core. These result suggests that a protonation reaction of <b>2-OAc</b> and <b>2-tfa</b> probably occurs on the doubly bridged sulfur ligand in the Mo<sub>3</sub>S<sub>4</sub> core.

    DOI: 10.1246/bcsj.20140364

    CiNii Article

  • Chelated Bis-N-heterocyclic Carbene Platinum and Palladium Units as Tunable Components of Multinuclear Complexes 査読

    Maeda Yuri, Hashimoto Hideki, Kinoshita Isamu, Nishioka Takanori

    INORGANIC CHEMISTRY   54 ( 2 )   448 - 459   2015年01月( ISSN:0020-1669

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ic502039d

  • Syntheses and Redox Properties of Complexes with Mo₃S₄ Cores and Tridentate Schiff Base Ligands 査読

    Kawamoto Keisuke, Ichimura Akio, Hashimoto Hideki, Kinoshita Isamu, Nishioka Takanori

    The Chemical Society of Japan Bulletin of the Chemical Society of Japan   88 ( 2 )   292 - 299   2015年( ISSN:0009-2673

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    A series of potentially tridentate Schiff base ligands, {HOPhC=N-(CH<sub>2</sub>)<sub>3</sub>-XMe: X = S (HLSMe), Se (HLSeMe)}, was prepared by condensation reactions of salicylaldehyde and the corresponding functionalized propylamines. These ligands were used to form the monocationic complexes, [Mo<sub>3</sub>S<sub>4</sub>(LXMe)<sub>3</sub>]<sup>+</sup> (X = S (<b>1<sup>+</sup></b>), Se (<b>2<sup>+</sup></b>)), through treatment of [Mo<sub>3</sub>S<sub>4</sub>(H<sub>2</sub>O)<sub>9</sub>]<sup>4+</sup> with the appropriate Schiff base ligand in methanol. Single-crystal X-ray structural analysis of <b>1-PF<sub>6</sub></b> revealed that one Schiff base ligand coordinates to each Mo via the O, N, and SMe donor atoms, and then the mono cationic cluster [Mo<sub>3</sub>S<sub>4</sub>(LSMe)<sub>3</sub>]<sup>+</sup> has a pseudo <i>C</i><sub>3</sub> symmetry if the chirality around the coordinated sulfur atoms is not taken into account. Because of the arrangements of the asymmetric Schiff base ligand, this monocationic cluster possibly adopts one of two axial chiralities. Furthermore, each sulfur atom of the three coordinated SMe groups in the complex cation is also chiral affording the two enantiomers observed in the unit cell. Dynamic behaviors of complexes <b>1-PF<sub>6</sub></b> and <b>2-PF<sub>6</sub></b> in solution were examined using line shape analyses of variable temperature NMR spectra revealing that the rate constant of the chiral inversion at the S atoms in <b>1-PF<sub>6</sub></b> is greater than that at the Se atoms in <b>2-PF<sub>6</sub></b> and the difference in the Δ<i>H</i><sup>‡</sup> values of <b>1-PF<sub>6</sub></b> (47.1 kJ mol<sup>−1</sup>) and <b>2-PF<sub>6</sub></b> (56.7 kJ mol<sup>−1</sup>) and the negative Δ<i>S</i><sup>‡</sup> values (−39.9 and −57.5 J mol<sup>−1</sup> K<sup>−1</sup> for <b>1-PF<sub>6</sub></b> and <b>2-PF<sub>6</sub></b>, respectively) suggest that the inversion processes involve bond cleavage between the metal centers and S or Se atoms followed by coordination of solvent molecules. The electrochemical properties of <b>1-PF<sub>6</sub></b> and <b>2-PF<sub>6</sub></b> were evaluated using cyclic voltammetry and this revealed that both <b>1<sup>+</sup></b> and <b>2<sup>+</sup></b> exhibit two consecutive, reversible one-electron reduction waves that are assigned to formal Mo(IV IV IV)/Mo(III IV IV) and Mo(III IV IV)/Mo(III III IV) couples, respectively. The ability of <b>1-PF<sub>6</sub></b> and <b>2-PF<sub>6</sub></b> to catalyze the electroreduction of H<sup>+</sup> was also examined using CH<sub>3</sub>CO<sub>2</sub>H or CF<sub>3</sub>CO<sub>2</sub>H as a proton source. Noteworthy, the redox potentials for the catalytic wave depend on the acidity of the added acids. Thus, the catalytic current around the first reduction wave is observed in the presence of the stronger trifluoroacetic acid as a proton source, while the current around the second reduction wave appears when the weaker acetic acid is used.

    DOI: 10.1246/bcsj.20140275

    CiNii Article

  • Incorporation of a Sugar Unit into a C-C-N Pincer Pd Complex Using Click Chemistry and Its Dynamic Behavior in Solution and Catalytic Ability toward the Suzuki-Miyaura Coupling in Water 査読

    Imanaka Yosuke, Hashimoto Hideki, Kinoshita Isamu, Nishioka Takanori

    公益社団法人 日本化学会 CHEMISTRY LETTERS   43 ( 5 )   687 - 689   2014年05月( ISSN:0366-7022

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    A Pd complex with a pincer ligand constituted of two <i>N</i>-heterocyclic carbenes and a triazole moiety containing a sugar unit, which was incorporated using click chemistry, was synthesized. Two diastereomers of the complex, which were in equilibrium, were observed in solution. The complex worked as a catalyst for the Suzuki&ndash;Miyaura cross-coupling reaction in aqueous media showing a turnover number of up to 76000.

    DOI: 10.1246/cl.140017

    CiNii Article

  • Removal of Two Hydrogen Atoms from Ketones or Aldehyde: Reaction of a Sulfur-Bridged Incomplete Cubane-Type Molybdenum Cluster with Acetone, Acetaldehyde, Acetylacetone, Ethyl Acetoacetate, and Acetophenone 査読

    Shibahara Takashi, Kawamoto Keisuke, Matsuura Akihiko, Takagi Hideaki, Nishioka Takanori, Kinoshita Isamu, Akashi Haruo

    公益社団法人 日本化学会 BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   87 ( 4 )   459 - 469   2014年04月( ISSN:0009-2673

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    The reaction of sulfur-bridged incomplete cubane-type molybdenum complex [Mo<sub>3</sub>(&micro;-S)<sub>3</sub>(&micro;<sub>3</sub>-S)(dtp)<sub>3</sub>(CH<sub>3</sub>CN)(&micro;-OAc)] (<b>1</b>) (dtp: diethyl dithiophosphate) with dimethyl acetylenedicarboxylate (H<sub>3</sub>COOCC&equiv;CCOOCH<sub>3</sub>, DMAD) in several kinds of solvents gave solvent-dependent adducts. The use of acetone, acetaldehyde, acetylacetone, ethyl acetoacetate, and acetophenone as reaction solvents gave the following adducts, respectively: [Mo<sub>3</sub>{&micro;-SCH(COCH<sub>3</sub>)}(&micro;<sub>3</sub>-S){&micro;<sub>3</sub>-SC(CO<sub>2</sub>CH<sub>3</sub>)=C(CO<sub>2</sub>CH<sub>3</sub>)S}(dtp)<sub>3</sub>(&micro;-OAc)] (<b>2</b>), [Mo<sub>3</sub>{&micro;-SCH(CHO)}(&micro;<sub>3</sub>-S){&micro;<sub>3</sub>-SC(CO<sub>2</sub>CH<sub>3</sub>)=C(CO<sub>2</sub>CH<sub>3</sub>)S}(dtp)<sub>3</sub>(&micro;-OAc)] (<b>3</b>), [Mo<sub>3</sub>{&micro;-SC(COCH<sub>3</sub>)(COCH<sub>3</sub>)}(&micro;<sub>3</sub>-S){&micro;<sub>3</sub>-SC(CO<sub>2</sub>CH<sub>3</sub>)=C(CO<sub>2</sub>CH<sub>3</sub>)S}(dtp)<sub>3</sub>(&micro;-OAc)] (<b>4</b>) (and [Mo<sub>3</sub>{&micro;-SC(COCH<sub>3</sub>)(COCH<sub>3</sub>)}(&micro;<sub>3</sub>-S){&micro;<sub>3</sub>-SC(CO<sub>2</sub>CH<sub>3</sub>)=C(CO<sub>2</sub>CH<sub>3</sub>)S}(dtp)<sub>2</sub>(acac)(&micro;-OAc)] (<b>4&prime;</b>)), [Mo<sub>3</sub>{&micro;-SC(COCH<sub>3</sub>)(COOC<sub>2</sub>H<sub>5</sub>)}(&micro;<sub>3</sub>-S){&micro;<sub>3</sub>-SC(CO<sub>2</sub>CH<sub>3</sub>)=C(CO<sub>2</sub>CH<sub>3</sub>)S}(dtp)<sub>3</sub>(&micro;-OAc)] (<b>5</b>), and [Mo<sub>3</sub>{&micro;-SCH(COC<sub>6</sub>H<sub>5</sub>)}(&micro;<sub>3</sub>-S){&micro;<sub>3</sub>-SC(CO<sub>2</sub>CH<sub>3</sub>)=C(CO<sub>2</sub>CH<sub>3</sub>)S}(dtp)<sub>3</sub>(&micro;-OAc)] (<b>6</b>). X-ray crystallography and <sup>1</sup>H NMR spectroscopy have revealed that in all six cases, the solvent adduct-formation resulted in the removal of two hydrogen atoms from the methyl (or methylene) group of the solvent used and in the formation of a carbon&ndash;sulfur bond; it also revealed that in some cases (<b>2</b>, <b>3</b>, <b>4&prime;</b>, and <b>6</b>) additional carbon&ndash;molybdenum bond formations occurred. Mass spectroscopy indicates that the presence of DMAD is indispensable in the two-hydrogen elimination reaction. Electronic spectra of <b>2</b>, <b>3</b>, and <b>6</b> have absorption bands in the visible and near-infrared region, and those of the two complexes <b>4</b> and <b>5</b> have significantly larger absorption bands in the longer wavelength region than the former group. The complex <b>4&prime;</b>, where one of the three dtp ligands is replaced by an acetylacetone anion also has a larger peak in the longer wavelength region, but the intensity is between those of the former and the latter groups. All six complexes show a chemically reversible one-electron-oxidation process corresponding to a V, IV, IV/IV, IV, IV couple and the oxidation products of these six complexes are stable under a time scale in CV measurements. The reduction processes of <b>2</b>, <b>3</b>, and <b>6</b> are chemically irreversible; those of <b>4</b>, <b>4&prime;</b>, and <b>5</b> are reversible, and the processes correspond to a IV, IV, IV/IV, IV, III couple. A mechanism for the formation of the doubly-dehydrogenated species is suggested.

    DOI: 10.1246/bcsj.20130269

    CiNii Article

  • pi-Back-Bonding Interaction Depending on the Bridging Chain Lengths of Chelated N-Heterocyclic Carbene Platinum Units in Heterometallic Trinuclear Complexes Affecting Their Electrochemical Property 査読

    Maeda Yuri, Hashimoto Hideki, Kinoshita Isamu, Nishioka Takanori

    INORGANIC CHEMISTRY   53 ( 2 )   661 - 663   2014年01月( ISSN:0020-1669

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ic402063f

  • Syntheses, structures, and photochemical properties of (mu(3)-O) tris {bis(mu-carboxylato)} trimanganese complexes with naphthylacetate ligands with relevance to artificial solar energy-harvesting systems 査読

    Nakai Misaki, Funabiki Takuzo, Ohtsuki Chikara, Harada Masafumi, Ichimura Akio, Tanaka Rika, Nishioka Takanori, Kinoshita Isamu, Mikuriya Masahiro, Guo Jiamo, Benten Hiroaki, Ohkita Hideo, Ito Shinzaburo, Obata Makoto, Nakabayashi Yasuo, Yano Shigenobu

    INORGANICA CHIMICA ACTA   406   130 - 137   2013年09月( ISSN:0020-1693

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.ica.2013.07.011

  • Synthesis and structural characterization of novel ruthenium(II) complexes bearing hydroxypicolinato ligands 査読

    Nakasone Takayuki, Nishioka Takanori, Asato Eiji, Kinoshita Isamu, Takara Satoshi

    POLYHEDRON   45 ( 1 )   152 - 157   2012年09月( ISSN:0277-5387

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.poly.2012.07.058

  • Syntheses, Characterization, and Antitumor Activities of Platinum(II) and Palladium(II) Complexes with Sugar-Conjugated Triazole Ligands 査読

    Yano Shigenobu, Ohi Hiromi, Ashizaki Mizue, Obata Makoto, Mikata Yuji, Tanaka Rika, Nishioka Takanori, Kinoshita Isamu, Sugai Yuko, Okura Ichiro, Ogura Shun-ichiro, Czaplewska Justyna A., Gottschaldt Michael, Schubert Ulrich S., Funabiki Takuzo, Morimoto Keiko, Nakai Misaki

    CHEMISTRY & BIODIVERSITY   9 ( 9 )   1903 - 1915   2012年09月( ISSN:1612-1872

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/cbdv.201100426

  • Synthesis and Reactivity of a Platinum(II) Complex with Hydrosulfido Ligands Induced by a Chelated N-Heterocyclic Carbene Ligand 査読

    Maeda Yuri, Hashimoto Hideki, Nishioka Takanori

    公益社団法人 日本化学会 CHEMISTRY LETTERS   41 ( 2 )   145 - 147   2012年02月( ISSN:0366-7022

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    A bis(hydrosulfido)platinum(II) complex with a bidentate chelate <i>N</i>-heterocyclic carbene ligand was oxidized by O<sub>2</sub> to give a linear tetrasulfide complex in the presence of excess hydrogen sulfide and a thiosulfato-bridged dinuclear complex without hydrogen sulfide.

    DOI: 10.1246/cl.2012.145

    CiNii Article

  • Sulfur containing platinum(II) complexes with N-heterocyclic carbene ligands obtained by reactions of a hydrosulfido complex 査読

    Maeda Yuri, Hashimoto Hideki, Nishioka Takanori

    DALTON TRANSACTIONS   41 ( 39 )   12038 - 12047   2012年( ISSN:1477-9226

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c2dt30597f

  • Redox-Controlled, Reversible Rearrangement of a Tris(2-pyridylthio)methyl Ligand on Nickel to an Isomer with an "N,S-Confused" 2-Pyridylthiolate Arm 査読

    Kuwamura Naoto, Kitano Ken'ichi, Hirotsu Masakazu, Nishioka Takanori, Teki Yoshio, Santo Ryoko, Ichimura Akio, Hashimoto Hideki, Wright L. James, Kinoshita Isamu

    CHEMISTRY-A EUROPEAN JOURNAL   17 ( 38 )   10708 - 10715   2011年09月( ISSN:0947-6539

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/chem.201100875

  • Sulfur-Bridged Ta-M (M = Mo, Cr) Multinuclear Complexes Bearing a Four-Electron-Reduced Dinitrogen Ligand 査読

    Takada Ryoichi, Hirotsu Masakazu, Nishioka Takanori, Hashimoto Hideki, Kinoshita Isamu

    ORGANOMETALLICS   30 ( 16 )   4232 - 4235   2011年08月( ISSN:0276-7333

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om200596v

  • Preparation and Structural Features of Cu(I)Cu(II) Coordination Polymers Obtained by Using Tripodal Complexes as Bridging Ligands 査読

    Yoshida Yuki, Miyamoto Riichi, Nakato Ayami, Santo Ryoko, Kuwamura Naoto, Gobo Kenji, Nishioka Takanori, Hirotsu Masakazu, Ichimura Akio, Hashimoto Hideki, Kinoshita Isamu

    公益社団法人 日本化学会 BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   84 ( 6 )   600 - 611   2011年06月( ISSN:0009-2673

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    A tripodal complex [CuCl(tpmtm)] (tpmtm: tris(2-pyrimidylthio)methanide) is used to synthesize coordination polymers. The tripodal complex unit worked as bidentate, tridentate, or tetradentate bridging ligands for [Cu<i><sub>n</sub></i>Cl<i><sub>m</sub></i>] units via coordination of three outer nitrogen atoms of the tpmtm ligand and also an axial chloro ligand. X-ray crystallography exhibited that obtained coordination polymers contained novel structures of [Cu<i><sub>n</sub></i>Cl<i><sub>m</sub></i>] moieties such as chloride-bridged linear Cu<sup>I</sup>Cu<sup>II</sup>Cu<sup>I</sup> and Cu<sup>I</sup>Cu<sup>II</sup>Cu<sup>II</sup>Cu<sup>I</sup> and cage-shaped Cu<sup>I</sup>Cu<sup>II</sup>Cu<sup>II</sup>Cu<sup>I</sup> mixed-valence copper cluster units. The relationship between the numbers of the outer coordination sites on the tripodal complex and structures of the coordination polymers is observed showing that participation in the coordination of two, three, or four outer coordination sites on the tripodal complex afforded the one-dimensional chain, two-dimensional sheet, or three-dimensional structures, respectively.

    DOI: 10.1246/bcsj.20100361

    CiNii Article

  • Unprecedented diastereoselective generation of chiral-at-metal, half sandwich Ir(III) and Rh(III) complexes via anomeric isomerism on "sugar-coated" N-heterocyclic carbene ligands 査読

    Shibata Teppei, Hashimoto Hideki, Kinoshita Isamu, Yano Shigenobu, Nishioka Takanori

    DALTON TRANSACTIONS   40 ( 18 )   4826 - 4829   2011年( ISSN:1477-9226

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c0dt01634a

  • Dynamic behaviour attributed to chiral carbohydrate substituents of N-heterocyclic carbene ligands in square planar nickel complexes 査読

    Shibata Teppei, Ito Satoru, Doe Matsumi, Tanaka Rika, Hashimoto Hideki, Kinoshita Isamu, Yano Shigenobu, Nishioka Takanori

    DALTON TRANSACTIONS   40 ( 25 )   6778 - 6784   2011年( ISSN:1477-9226

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c0dt01833c

  • Carbon-sulfur bond cleavage reactions of dibenzothiophene derivatives mediated by iron and ruthenium carbonyls 査読

    Hirotsu Masakazu, Tsuboi Chiaki, Nishioka Takanori, Kinoshita Isamu

    DALTON TRANSACTIONS   40 ( 4 )   785 - 787   2011年( ISSN:1477-9226

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c0dt00768d

  • Synthesis and structures of N,N,O-scorpionatoruthenium(II) complexes featuring "non-innocent" o-benzoquinonediimines 査読

    Oh Jae-Hwan, Nishioka Takanori, Masui Ryoji, Asato Eiji, Kinoshita Isamu, Takara Satoshi

    POLYHEDRON   29 ( 8 )   1964 - 1967   2010年05月( ISSN:0277-5387

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.poly.2010.03.009

  • Synthesis and structural characterization of novel ruthenium(II) complexes featuring an N,N,O-scorpionate ligand: A versatile synthetic precursor for open-face scorpionatoruthenium(II) complexes 査読

    Yogi Akira, Oh Jae-Hwan, Nishioka Takanori, Tanaka Rika, Asato Eiji, Kinoshita Isamu, Takara Satoshi

    POLYHEDRON   29 ( 5 )   1508 - 1514   2010年03月( ISSN:0277-5387

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.poly.2010.01.016

  • Synthesis and Crystal Structure of [RuCl(6-hydroxypicolinato)(2,2';6',2"-terpyridine)] (N,N-dimethylformamide) 査読

    NAKAMA Yukitoshi, NISHIOKA Takanori, NAKASONE Takayuki, ASATO Eiji, KINOSHITA Isamu, TAKARA Satoshi

    社団法人 日本分析化学会 X-ray Structure Analysis Online   26   33 - 34   2010年

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    The structure of [RuCl(6-hydroxypicolinato)(2,2&prime;;6&prime;,2&Prime;-terpyridine)]&middot;(<i>N</i>,<i>N</i>-dimethylformamide) was determined by X-ray crystallography. The compound crystallized in a monoclinic system and was characterized thus: <i>P</i>2<sub>1</sub>/<i>c</i>, <i>a</i> = 15.7325(19), <i>b</i> = 10.0621(10), <i>c</i> = 15.6422(19)&Aring;, <i>&beta;</i> = 105.112(3)&deg;, <i>Z</i> = 4, <i>V</i> = 2390.6(5)&Aring;<sup>3</sup>. The crystal structure was solved by the SIR97 direct method and refined by full-matrix least-squares on <i>F</i><sup>2</sup> to final values of <i>R</i>1 = 0.1155 and <i>wR</i>2 = 0.1018 for all data.

    DOI: 10.2116/xraystruct.26.33

    CiNii Article

  • Carbene-carbanion equilibrium for tris(2-pyridylthio)methanido Fe(II) complexes 査読

    Kuwamura Naoto, Kato Ryo, Kitano Ken'ichi, Hirotsu Masakazu, Nishioka Takanori, Hashimoto Hideki, Kinoshita Isamu

    DALTON TRANSACTIONS   39 ( 41 )   9988 - 9993   2010年( ISSN:1477-9226

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c0dt00615g

  • Rh(I)-Catalyzed CO Gas-Free Carbonylative Cyclization Reactions of Alkynes with 2-Bromophenylboronic Acids Using Formaldehyde 査読

    Morimoto Tsumoru, Yamasaki Kae, Hirano Akihisa, Tsutsumi Ken, Kagawa Natsuko, Kakiuchi Kiyomi, Harada Yasuyuki, Fukumoto Yoshiya, Chatani Naoto, Nishioka Takanori

    ORGANIC LETTERS   11 ( 8 )   1777 - 1780   2009年04月( ISSN:1523-7060

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ol900327x

  • "Compressed" Icelike Structures between Molecular Films Comparable with Ice Phase III 査読

    Yoshida Yuki, Miyamoto Riichi, Nishioka Takanori, Hashimoto Hideki, Kinoshita Isamu

    公益社団法人 日本化学会 CHEMISTRY LETTERS   38 ( 4 )   366 - 367   2009年04月( ISSN:0366-7022

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    An icelike supramolecular structure is found in a self-assembled quasi 3-D crystalline hydrate in-between the layers of Cu<SUP>II</SUP> tris(pyridylthio)methyl hydroxide complexes, which is comparable with compressed pure ice III.

    DOI: 10.1246/cl.2009.366

    CiNii Article

  • Photochromism of an Organorhodium Dithionite Complex in the Crystal line-State: Molecular Motion of Pentamethylcyclopentadienyl Ligands Coupled to Atom Rearrangement in a Dithionite Ligand 査読

    Nakai Hidetaka, Nonaka Takashi, Miyano Yousuke, Mizuno Motohiro, Ozawa Yoshiki, Toriumi Koshiro, Koga Nobuaki, Nishioka Takanori, Irie Masahiro, Isobe Kiyoshi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   130 ( 52 )   17836 - 17845   2008年12月( ISSN:0002-7863

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ja807150a

  • Ruthenium and rhodium complexes with thiolate-containing pincer ligands produced by C - S bond cleavage of pyridyl-substituted dibenzothiophenes 査読

    Shibue Mayuko, Hirotsu Masakazu, Nishioka Takanori, Kinoshita Isamu

    ORGANOMETALLICS   27 ( 17 )   4475 - 4483   2008年09月( ISSN:0276-7333

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om8003916

  • Synthesis and characterization of tris(2-pyridylthio)methanido Zn complex with a Zn-C bond and DFT calculation of its one-electron oxidized species 査読

    Kitano Ken'ichi, Kuwamura Naoto, Tanaka Rika, Santo Ryoko, Nishioka Takanori, Ichimura Akio, Kinoshita Isamu

    CHEMICAL COMMUNICATIONS   ( 11 )   1314 - 1316   2008年03月( ISSN:1359-7345

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/b715996j

  • Mimicking the photosynthetic system with strong hydrogen bonds to promote proton electron concerted reactions 査読

    Kinoshita Isamu, Hashimoto Hideki, Nishioka Takanori, Miyamoto Riichi, Kuwamura Naoto, Yoshida Yuki

    PHOTOSYNTHESIS RESEARCH   95 ( 2-3 )   363 - 371   2008年02月( ISSN:0166-8595

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1007/s11120-007-9263-0

  • Observation of halide-induced conformational conversion of dinuclear copper complexes having a tetradentate polypyridine ligand with a p-xylene backbone 査読

    Nishioka Takanori, Mitsui Shigeru, Kinoshita Isamu, Koshiyama Tamami, Kato Masako

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   80 ( 7 )   1357 - 1367   2007年07月( ISSN:0009-2673

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

  • Structure and dynamic properties of substituted carbonylhydride clusters H2RuOs3(CO)(13) and H4Ru4(CO)(12) containing functionalized phosphines 査読

    Andreev I. A., Grachova E. V., Tunik S. P., Oparina L. A., Sukhov B. G., Malysheva S. F., Kinoshita I., Nishioka T.

    RUSSIAN CHEMICAL BULLETIN   56 ( 7 )   1343 - 1350   2007年07月( ISSN:1066-5285

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1007/s11172-007-0205-y

  • Sugar-incorporated N-heterocyclic carbene complexes 査読

    Nishioka Takanori, Shibata Teppei, Kinoshita Isamu

    ORGANOMETALLICS   26 ( 5 )   1126 - 1128   2007年02月( ISSN:0276-7333

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om061128d

  • Thiacalix[3]pyridine produces a stable mononuclear rhodium(II) complex with mutual Jahn-Teller effect 査読

    Hamazawa RT, Nishioka T, Kinoshita I, Takui T, Santo R, Ichimura A

    DALTON TRANSACTIONS   ( 11 )   1374 - 1376   2006年03月( ISSN:1477-9226

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/b515926a

  • Direct observation of photochromic dynamics in the crystalline state of an organorhodium dithionite complex 査読

    Nakai Hidetaka, Mizuno Motohiro, Nishioka Takanori, Koga Nobuaki, Shiomi Kimie, Miyano Yousuke, Irie Masahiro, Breedlove Brian K., Kinoshita Isamu, Hayashi Yoshihito, Ozawa Yoshiki, Yonezawa Takae, Toriumi Koshiro, Isobe Kiyoshi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   45 ( 39 )   6473 - 6476   2006年( ISSN:1433-7851

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/anie.200601702

  • Diamagnetic-Paramagnetic Conversion of Tris(2-pyridylthio)methylcopper(III) through a Structural Change From Trigonal Bipyramidal to Octahedral.

    R. Santo, R. Miyamoto, R. Tanaka, T. Nishioka, I. Kinoshita et al.

    Angew. Chem, Int. Ed.   45   7611 - 7614   2006年

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

  • Steric control of tritolylphosphines on the, nuclearity of Cu(I) complexes: Syntheses and structures of the iodo-bridged [Cu-4(mu(3)-I)(4)(p-tolyl(3)P)(4)] cubane and the [Cu-2(mu-I)(2)(o-tolyl(3)P)(2)] dimer 査読

    Lobana TS, Kumar R, Sharma R, Nishioka T, Castineiras A

    JOURNAL OF COORDINATION CHEMISTRY   58 ( 10 )   849 - 855   2005年07月( ISSN:0095-8972

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1080/00958970412331336330

  • Syntheses, NMR (H-1, P-31) spectroscopy and crystal structures of complexes of copper(I) halides with isatin-3-thiosemicarbazones 査読

    Lobana TS, Rekha, Sidhu BS, Castineiras A, Bermejo E, Nishioka T

    JOURNAL OF COORDINATION CHEMISTRY   58 ( 9 )   803 - 809   2005年06月( ISSN:0095-8972

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1080/00958970500110974

  • Structure study and luminescence thermochromism in hexanuclear 6-methyl-2-pyridinethiolato copper(I) crystals 査読

    Xie HY, Kinoshita I, Karasawa T, Kimura K, Nishioka T, Akai I, Kanemoto K

    JOURNAL OF PHYSICAL CHEMISTRY B   109 ( 19 )   9339 - 9345   2005年05月( ISSN:1520-6106

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/jp0446985

  • Catalytically active mu-oxodiiron(IV) oxidants from iron(III) and dioxygen 査読

    Ghosh A, de Oliveira FT, Yano T, Nishioka T, Beach ES, Kinoshita I, Munck E, Ryabov AD, Horwitz CP, Collins TJ

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   127 ( 8 )   2505 - 2513   2005年03月( ISSN:0002-7863

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ja0460458

  • A two-dimensional clathrate hydrate sandwiched by planar arrays of a copper complex 査読

    Miyamoto R, Hamazawa RT, Hirotsu M, Nishioka T, Kinoshita I, Wright LJ

    CHEMICAL COMMUNICATIONS   ( 32 )   4047 - 4049   2005年( ISSN:1359-7345

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/b505681k

  • A complete series of copper(II) halide complexes (X = F, Cl, Br, I) with a novel Cu(II)-C(sp(3)) bond 査読

    Miyamoto R, Santo R, Matsushita T, Nishioka T, Ichimura A, Teki Y, Kinoshita I

    DALTON TRANSACTIONS   ( 19 )   3179 - 3186   2005年( ISSN:1477-9226

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/b507073b

  • Selective oxygenation of amphiphilic thiacalix[3]pyridine Rh(I) diene complexes in both water and organic solvents.

    T. Nishioka, Y. Onishi, K. Nakajo, R. Tanaka, I. Kinoshita et al.

    Dalton Trans.   2130 - 2137   2005年

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

  • Copper-sulfur interactions: synthesis and structure of a trigonal planar copper(I) complex with bis(diphenylthiophosphinyl)methane, [CuI(dppmS2)]·MeCN. 査読 国際共著

    Lobana, T S, Singh, G, Nishioka, T

    J. Coord. Chem.   57   955 - 960   2004年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Nucleophilicity of Ligated S22- Ions. Conversion of Organic Chlorides into Organosulfur Compounds in cis-[(MCp*)2(μ-CH2)2(μ-S2R)]+ (M = Rh, Ir).

    T. S. Lobana, K. Isobe, H. Kitayama, T. Nishioka, I. Kinoshita et al.

    Organometallics   23   5347 - 5352   2004年

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

  • Activation of C-Cl and C-H bonds by Ligated S22- in Unusual Way. Conversion of Organic Chlorides into Organosulfur Compounds Coordinated to Iridium Metal Atom in cis-[(IrCp*)2(μ-CH2)2(μ-S2R)]+.

    T. S. Lobana, K. Isobe, H. Kitayama, T. Nishioka, I. Kinoshita

    Angew. Chem., Int. Ed. Eng.   43   213 - 215   2004年

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

  • Novel Nucleophilic Reactivity of Disulfide Ligands Coordinated Parallel to M-M (M = Rh, Ir) Bonds.

    T. Nishioka, H. Kitayama, B. K. Breedlove, K. Shiomi, I. Kinoshita et al.

    Inorg. Chem.   43   5688 - 5697   2004年

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

  • Pyridine-2-Sulfonates as Versatile Ligands for the Synthesis of Novel Coordinative and Hydrogen Bonded Supramolecules. 査読 国際共著

    Lobana, T S, Kinoshita, I, Kimura, K, Nishioka, T, Shiomi, D, Isobe, K

    Eur. J. Inorg. Chem.   356 - 367   2004年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Synthesis of an Unprecedented Bicapped Adamantoid [Cu6(μ2-I)(μ3-I)(μ4-I)(m-tolyl3P)4(CH3CN)2] Cluster. 査読 国際共著

    Lobana, T S, Kaur, P, Nishioka, T

    Inorganic Chemistry   43   3766 - 3767   2004年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Synthesis and behavior in solution of the triple cubane- and windmill-type framework isomers of an organorhodium tungsten oxide cluster [(Cp*Rh)4W4O16]. 査読 国際共著

    Nishikawa, K, Kido, K, Yoshida, J, Nishioka, T, Kinoshita, I, Breedlove, B K, Hayashi, Y, Uehara, A, Isobe, K

    Appl. Organomet. Chem.   17   446 - 448   2003年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Introduction of Chirality to the Remote, Open Face of Metalloporphyrin through Coordination to the Metal of Specially Designed Pendant Arm. 査読 国際共著

    Hamazawa, A, Yano, T, Nishioka, T, Kinoshita, I, Isobe, K: Yano, S, Wright, L J, Collins, T J

    Chemistry Letters   20 - 21   2003年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Laser photolysis studies on CuI complexes of thia-calix[3]pyridine. Phosphorescence from the intramolecular charge-transfer excited state. 査読

    Kinoshita, I, Hamazawa, A, Nishioka, T, Adachi, H, Suzuki, H, Miyazaki, Y, Tsuboyama, A, Okada, S, Hoshino, M

    Chem. Phys. Lett.   371   451 - 457   2003年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Design and synthesis of copper complexes of novel ligands based on the pyridine thiolate group. 査読 国際共著

    Kinoshita, I, Wright, L J, Kubo, S, Kimura, K, Sakata, A, Yano, T, Miyamoto, R, Nishioka, T, Isobe, K

    Dalton Trans.   1993 - 2003   2003年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Thia-calix[n]pyridines, synthesis and coordination to Cu(I,II) ions with both N and S donor atoms. 査読

    Tanaka, R, Yano, T, Nishioka, T, Nakajo, K, Breedlove, B K, Kimura, K, Kinoshita, I, Isobe, I

    Chem. Commun.   1686 - 1687   2002年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Structure and reactivity of a novel parallel thiosulfito (SSO2-S:S') rhodium dinuclear complex.

    K. Shiomi, B. K. breedlove, H. kitayama, I. Kinoshita, K. isobe et al.

    Chem. Commun.   1756 - 1757   2002年

     詳細を見る

    掲載種別:研究論文(学術雑誌)  

  • Mononuclear–dinuclear helicate interconversion of dibromo{N,N’-bis[(S)-1-2-(pyridyl)ethyl]pyridine-2,6-dicarboxamidate}copper(II) via a deprotonation–protonation process. 査読 国際共著

    Yano, T, Tanaka, R, Nishioka, T, Kinoshita, I, Isobe, K, Wright, L J, Collins, T J

    Chem. Commum.   1396 - 1397   2002年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Synthesis and X-ray Analysis of Mn–Mo Mixed Metal Oxide Cluster with Cubic Framework. 査読

    Nishikawa, K, Kinoshita, I, Nishioka, T, Isobe, K,

    Chemistry Letters   1342 - 1343   2000年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Lantern-type dinuclear CrIIIPtII and VIVPtII complexes bridged by pyridine-2-thiolate. Synthesis and characterization. 査読

    Kitano, K, Tanaka, R, Kimura, T, Tsuda, T, Shimizu, S, Takagi, H, Nishioka, T, Shiomi, D, Ichimura, A, Kinoshita, I, Isobe, K, Ooi, S

    J. Chem. Soc. Dalton Trans   995 - 1000   2000年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Formation of μ4-Se2 complexe by the oxidative coupling of μ-SeH complex: double-site atomic inversion of the μ4-Se2 complex [{(Cp*Rh)2(μ-CH2)2}2(μ4-Se2)]2+ (Cp* = η5-C5Me5) 査読

    Shimomura, H, Nishioka, T, Abe, M, Kinoshita, I, Isobe, K

    J. Organomet. Chem.   611   386 - 391   2000年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Aerobic oxidation of a disulfide to its sulfonate leading to supramolecular pyridine-2-sulfonato Cu(II) and Zn(II) complexes. 査読

    Kimura, K, Kimura, T, Kinoshita, I, Nakashima, N, Kitano, K, Nishioka, T, Isobe, K

    J. Chem. Soc., Chem. Commun.   497 - 498   1999年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Structural Diversity of Copper Complexes with 2,2'-Dipyridyldisulfide. From Dimer to Infinite Sheet Structure Both in Solid State and in Solution. 査読

    Kubo, S, Nishioka, T, Ishikawa, K, Kinoshita, I, Isobe, K

    Chemistry Letters   1067 - 1068   1998年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Catalytic Generation of Oxalate through a Coupling Reaction of Two CO2 Molecules Activated on [(Ir(η5-C5Me5))2(Ir(η4-C5Me5)CH2CN)(μ3-S)2]. 査読

    Tanaka K, Kushi Y, Tsuge K, Toyohara K, Nishioka T, Isobe K

    Inorganic Chemistry   37   120 - 126   1998年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Formation and Dynamic Properties of Triangular Rhodium μ3-SulfidoComplex, [Rh3Cp*3(μ3-η2-||-C2H2)(μ2-S)]2+ (Cp* = η5-C5Me5), Including Acetylene Ligand Generated by the Coupling and Deprotonation of Two Bridging Methylene Units in Dirhodium Complex. 査読 国際共著

    Nishioka, T, Isobe, K, Kinoshita, I, Ozawa, Y, Vázquez de Miguel, A, Nakai, T, Miyajima, S

    Organometallics   17   1637 - 1639   1998年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Lantern Type Heterobimetallic Complexes. Tetra-μ-4-methylpyridine-2-thiolato Bridged Platinum(II)-Cobalt(II) and the Oxidation Complexes. 査読

    Kitano, K, Tanaka, K, Nishioka, T, Ichimura, A, Kinoshita, I, Isobe, K, Ooi, S

    J. Chem. Soc. Dalton Trans.   3177 - 3182   1998年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Synthesis and characterization of pentamethylcyclopentadienylrhodium(III) and-iridium(III) complexes with 1,2-benzenedithiolate: [(Cp*Rh)2(μ(S)-1,2-C6H4S2-S,S')2], [(Cp*Rh)2(μ(S)-1,2-C6H4S2-S,S')(μ(S)-1,2-C6H4S(SO2)-S,S') and [(Cp*Ir)(1,2-C6H4S2-S,S')] (Cp* = η5-C5(CH3)5). 査読

    Xi R, Abe M, Suzuki T, Nishioka T, Isobe K

    J. Organomet. Chem.   549   117 - 125   1997年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • A Novel Type of Acid Amino Coordination: The Metallocycle Rh-Rh-NH-C(Me)=O. 査読 国際共著

    Kukushkin V Yu, Nishioka T, Nakamura S, Kinoshita I, Isobe K

    Chemistry Letters   189 - 190   1997年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • A novel organometallic oxide cluster with multi valley sites: synthesis and structure of [NBun4]2[{(η5-C5Me5)Rh}2Mo6O20(OMe)2]and its framework transformations. 査読

    Takara S, Nishioka T, Kinoshita I, Isobe K

    J. Chem. Soc., Chem. Commun.   891 - 892   1997年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Hydrogen-bonding Patterns in Oxime/Oximato Platinum(II) Species Providing the Formation of One Dimensional Chains, Two-Dimensional Networks, and Cages. 査読 国際共著

    Kukushkin V Yu, Nishioka T, Tudela D, Isobe K, Kinoshita I

    Inorganic Chemistry   36   6157 - 6165   1997年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Conversion of Rectangular Tetrasulfide Ligand in Tetrarhodium Complex, [{(RhCp*)2(μ-CH2)2}2(μ4-S4)]2+ (Cp* = η5-C5Me5), into Disulfide Ligands in Dirhodium Complex, [(RhCp*)2(μ-CH2)2(μ-S2)] by Chemical Reduction. 査読

    Nishioka T, Nakamura S, Kaneko Y, Suzuki T, Kinoshita I, Kiyooka S, Isobe K

    Chemistry Letters   911 - 912   1996年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • C=S Bond Fission in Coordinated Thioureas and Formation of a Sulfide-bridged Dinuclear Pd(II) Complex. 査読

    Okeya S, Kameda H, Kawashima H, Shimomura H, Nishioka T, Isobe K

    Chemistry Letters   501 - 502   1995年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Remarkable Decrease in Overpotential of Oxalate Formation in Electrochemical CO2 Reduction by a Metal-Sulfide Cluster. 査読

    Kushi Y, Nagao H, Nishioka T, Isobe K, Tanaka K

    J. Chem. Soc., Chem. Commun.   1223 - 1224   1995年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Oxalate Formation in Electrochemical CO2 Reduction Catalyzed by Rhodium-Sulfur Cluster. 査読

    Kushi Y, Nagao H, Nishioka T, Isobe K, Tanaka K

    Chemistry Letters   2175 - 2178   1994年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Isolation and X-ray Crystal Structure of a New Octamolybdate: [(RhCp*)2(μ2-SCH3)3]4- [Mo8O26]·2CH3CN (Cp* = η5-C5Me5). 査読 国際共著

    Xi R, Wang B, Isobe K, Nishioka T, Toriumi K, Ozawa Y

    Inorganic Chemistry   33   833 - 836   1994年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • A Tetranuclear Rhodium Complex with a μ4-S Ligand, [{Cp*2Rh2(μ2-CH2)2}2(μ4-S)]2+ (Cp* =η5-C5Me5),Obtained from Stepwise Abstraction of the SH- Ligand from a Dinuclear RhodiumDihydrosulfide Precursor by Ag+. 査読 国際共著

    Nishioka T, Kukushkin V Y, Isobe K, Vázquez deMiguel A

    Inorganic Chemistry   33   2501 - 2502   1994年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Synthesis and Crystal Structure of [(IrCp*)2(μ-OH)3]2(Cr2O7)•8H2O (Cp* = η5-C5Me5). A Novel Two-Dimensional Hydrogen-Bonding Network. 査読 国際共著

    Park J T, Nishioka T, Suzuki T, Isobe K

    Bull. Chem. Soc. Jpn.   33   2501 - 2502   1994年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Syntheses and Crystal Structures of Triangular Rhodium and Iridium Complexes with Triply Bridging Sulfido Ligands. 査読

    Nishioka T, Isobe K

    Chemistry Letters   1661 - 1664   1994年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • [{Rh2Cp*2(μ-CH2)2}2(μ-S4)]2+:A Novel Tetranuclear Cationic Complex with a Rectangular S4Unit. 査読 国際共著

    Isobe K, Ozawa Y, Vázquez de Miguel A, Zhu T-W, Zhao K-M, Nishioka T, Ogura T, Kitagawa T

    Angew. Chem. Int. Ed. Engl.   33   1882 - 1884   1994年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

  • Synthesis of Lantern-type Dinuclear Mixed-Metal Complex of Platinum(II) and Nickel(II). 査読

    Nishioka T, Kinoshita I, Kitano K, Ooi S

    Chemistry Letters   883 - 886   1992年

     詳細を見る

    掲載種別:研究論文(学術雑誌)   共著区分:共著  

▼全件表示

書籍等出版物

講演・口頭発表等

  • Activation of closed-shell trinuclear clusters bearing chelating bis-N-heterocyclic carbene and triply bridging sulfide ligands 招待 国際会議

    Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka

    The 28th International SPACC Symposium  2023年12月  The Society of Pure and Applied Coordination Chemistry

     詳細を見る

    会議種別:口頭発表(招待・特別)  

    開催地:Remote  

  • Enhancement of reactivity of a trinuclear core bearing triply-bridging sulfides using structurally flexible bis-NHC ligands 招待 国際会議

    Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka

    The 2023 Annual SPACC Meeting and The 3rd International OUS Frontier Symposium  2023年09月 

     詳細を見る

    会議種別:口頭発表(招待・特別)  

    開催地:Okayama, Japan  

  • Catalytic Ability of Nickel Complex with Sugar-Incorporated N-Heterocyclic Carbene Ligand 国際会議

    Taichi Kobayashi, Hiroshi Nakajima, Takanori Nishioka

    The 2023 Annual SPACC Meeting and The 3rd International OUS Frontier Symposium  2023年09月 

     詳細を見る

    会議種別:ポスター発表  

    開催地:Okayama, Japan  

  • Activation of Mixed-Metal Trinuclear Complexes with Triply Bridging Sulfide Ligands by Electrochemical and Chemical Reduction 国際会議

    Amiru Yokoyama, Ryotaro Nishino, Hiroshi Nakajima, Takanori Nishioka

    The 2023 Annual SPACC Meeting and The 3rd International OUS Frontier Symposium  2023年09月 

     詳細を見る

    会議種別:ポスター発表  

    開催地:Okayama, Japan  

  • 二座キレートNHC配位子をもつ白金ーパラジウム混合金属錯体の反応性の調査 国内会議

    籔根夏希、中島洋、西岡孝訓

    錯体化学会第73回討論会  2023年09月 

     詳細を見る

    会議種別:ポスター発表  

    開催地:水戸市民会館  

  • C-S bond formation using palladium thiolato complexes bearing sugar-incorporated N-heterocyclic carbene ligands 国際会議

    Takanori Nishioka, Itsuki Kobayashi, Hiroshi Nakajima

    20th International Conference on Biological Inorganic Chemistry  2023年07月 

     詳細を見る

    会議種別:ポスター発表  

    開催地:Adelaide, Australia  

  • Effects of structures of bis N-heterocyclic carbene ligands in M3S2 complexes on their reactions with silver(I) ion 国際会議

    Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka

    20th International Conference on Biological Inorganic Chemistry  2023年07月 

     詳細を見る

    会議種別:ポスター発表  

    開催地:Adelaide, Australia  

  • メチレン架橋ビスN−ヘテロ環カルベン−白金二核部位を組み込んだ混合配位子白金三核錯体および混合金属ロジウム白金錯体の構造と銀(I)イオンの反応 国内会議

    籔根 夏希、中島 洋、西岡 孝訓

    第103回日本化学会春季年会  2023年03月  日本化学会

     詳細を見る

    会議種別:口頭発表(一般)  

    開催地:東京理科大学野田キャンパス  

  • Activation of M3S2core in trinuclear sulfide complexes 国際会議

    Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka

    The 27th International SPACC Symposium  2022年12月  The Society of Pure and Applied Coordination Chemistry

     詳細を見る

    会議種別:口頭発表(一般)  

    開催地:Remote  

  • 二座キレート N-ヘテロ環カルベン配位部位をもつ糖修飾パラジウムチオラト錯体の合成と性質 国内会議

    小林 樹、中島 洋、西岡 孝訓

    2022年日本化学会中国四国支部大会 広島大会  2022年11月  日本化学会中国四国支部

     詳細を見る

    会議種別:ポスター発表  

    開催地:広島大学  

  • 生体透過性にする優れた光に応答する鉄(Ⅲ)-カルボニル錯体 国内会議

    中島 洋、野村夏生、西岡訓孝、廣津昌和

    第72回錯体化学討論会  2022年09月  錯体化学会

     詳細を見る

    会議種別:口頭発表(一般)  

    開催地:九州大学  

  • 二座キレートNHC配位子の架橋アルキル鎖長による白金三核錯体の反応制御 国内会議

    籔根 夏希、中島 洋、西岡 孝訓

    第72回錯体化学討論会  2022年09月  錯体化学会

     詳細を見る

    会議種別:ポスター発表  

    開催地:九州大学  

▼全件表示

科研費

  • 硫黄架橋三核錯体の反応活性化による硫黄移動型炭素-硫黄結合生成触媒の開発

    基盤研究(C)  2023年

  • 硫黄架橋三核錯体の反応活性化による硫黄移動型炭素-硫黄結合生成触媒の開発

    基盤研究(C)  2022年

  • 非対称チオエーテルのワンポット合成に向けた水中C-S結合生成タンデム触媒の創生

    基盤研究(C)  2017年04月

  • 糖のアノマー異性を用いた金属錯体の普遍的光学活性制御

    基盤研究(C)  2010年

  • 新規有機金属錯体被膜金ナノクラスター創成を目指した均一系合成法の開発

    若手研究(B)  2001年

  • テトラカルコゲニド配位子を持つ四核ロジウム錯体の合成と化学的性質

    奨励研究(A)  1997年

▼全件表示

担当教育概要

  • 物質を理解するための原子、分子の基本的な概念や、物質の構造を知るための測定法などについて、講義、実験、実習を行っている。

担当授業科目

  • 基礎無機・分析化学A

    2023年度   週間授業   大学院

  • 創成分子科学演習

    2023年度   集中講義   大学院

  • 基幹無機化学

    2023年度   集中講義   大学院

  • 後期特別研究

    2023年度   集中講義   大学院

  • 創成分子科学ゼミナール

    2023年度   集中講義   大学院

  • 化学実験Ⅰ

    2023年度   週間授業   大学

  • 特別研究

    2023年度   集中講義   大学

  • 基礎化学実験

    2023年度   週間授業   大学院

  • 化学実験Ⅳ

    2023年度   週間授業   大学

  • 無機化学演習

    2023年度   週間授業   大学

  • 基礎化学実験Ⅱ

    2023年度   集中講義   大学院

  • 基礎化学実験2

    1900年度     大学

  • 基礎化学実験1

    1900年度     大学

  • 物質科学実験2

    1900年度     大学

  • 物質設計学特論I

    1900年度    

  • 計算機物質科学I

    1900年度     大学

▼全件表示

論文・研究指導集計

  • 2023年度

    卒業論文指導数:2名  卒業論文審査数:2件

    博士前期課程学生指導数:2名  博士後期課程学生指導数:1名

    修士論文審査数(主査):0件  修士論文審査数(副査):1件

    博士論文審査数(主査):0件  博士論文審査数(副査):1件

学術貢献活動

  • The 27th International SPACC Symposium

    役割:企画立案・運営等

    The Society of Pure and Applied Coordination Chemistry  2022年

     詳細を見る

    種別:大会・シンポジウム等 

その他

  • 職務経歴

    2007年

      詳細を見る

    大阪市立大学 准教授

  • 職務経歴

    2006年

      詳細を見る

    大阪市立大学 助教授

  • 職務経歴

    1996年

      詳細を見る

    大阪市立大学 講師

  • 職務経歴

    1995年

      詳細を見る

    大阪市立大学 助手