研究者詳細 - 西岡　孝訓

写真a

ニシオカ　タカノリ

西岡　孝訓

NISHIOKA Takanori

担当

大学院理学研究科化学専攻准教授
理学部化学科

所属

理学研究院

担当・職階

大学院理学研究科化学専攻

准教授 2022年04月 - 継続中
理学部化学科

准教授 2022年04月 - 継続中

取得学位

博士(理学) （大阪市立大学）

研究分野

ナノテク・材料 / 無機・錯体化学
ナノテク・材料 / 機能物性化学

研究キーワード

触媒
クラスター
カルベン

研究概要

触媒やセンサーなどへの利用を目指し、新しい機能性をもった糖を導入した遷移金属錯体を合成し、その構造や性質を明らかにする。そしてこれらの錯体を用い、物質変換の効率化や選択的な物質変換法の開発を目指す。

研究歴

硫化物配位子をもつ多核クラスターを用いた二酸化炭素電解還元触媒の開発

多核クラスター、二酸化炭素還元、触媒個人研究

2010年04月
糖修飾Nーヘテロ環カルベン錯体

遷移金属錯体、糖、カルベン個人研究

2006年04月

所属学協会

アメリカ化学会

国外
先端錯体工学研究会

国内
錯体化学会
日本化学会

国内

委員歴（学外）

副会長先端錯体工学研究会

2023年03月 - 継続中
会長先端錯体工学研究会

2016年 - 2023年02月
副会長先端錯体工学研究会

2010年 - 2015年
庶務先端錯体工学研究会

2007年 - 2009年

受賞歴

先端錯体工学研究会賞

2012

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受賞国：日本国

職務経歴（学外）

岡崎国立共同研究機構分子科学研究所 -

1992年 - 1995年

学歴

大阪市立大学理学研究科化学専攻修士課程卒業・修了

- 1992年
大阪市立大学理学部化学科卒業・修了

- 1990年

論文

Red-light responsive photoCORM activated in aqueous acid solution 査読

Natsuo Nomura, Seiya Tanaka, Masakazu Hirotsu, Takanori Nishioka, Hiroshi Nakajima

JOURNAL OF ORGANOMETALLIC CHEMISTRY 984 122578 - 122585 2022年11月

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掲載種別：研究論文（学術雑誌）国際・国内誌：国際誌

リポジトリURL： http://hdl.handle.net/10466/0002000156
Electronic and steric impact of bis-NHC ligands on reactions of Pt3S2 cores in trinuclear complexes bearing bis-NHC ligands with various lengths of alkylene bridges 査読

Yabune Natsuki, Nakajima Hiroshi, Nishioka Takanori

DALTON TRANSACTIONS 50 ( 35 ) 12079 - 12082 2021年09月（ ISSN:1477-9226 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1039/d1dt02747f
Synthesis of iron(III)-carbonyl complex with variable wavelength range for CO release depending on protonation and deprotonation of axial phosphorous ligands 査読

Tanaka Seiya, Nomura Natsuo, Nishioka Takanori, Hirotsu Masakazu, Nakajima Hiroshi

Elsevier BV　JOURNAL OF ORGANOMETALLIC CHEMISTRY 943 121843 - 121843 2021年06月（ ISSN:0022-328X ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1016/j.jorganchem.2021.121843
Use of a Ferritin L134P Mutant for the Facile Conjugation of Prussian Blue in the Apoferritin Cavity 査読

Ikenoue Yuta, Tahara Yuhei O., Miyata Makoto, Nishioka Takanori, Aono Shigetoshi, Nakajima Hiroshi

INORGANIC CHEMISTRY 60 ( 7 ) 4693 - 4704 2021年04月（ ISSN:0020-1669 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1021/acs.inorgchem.0c03660
Dibenzoate esters of cis-tetralin-2,3-diol as analogs of (-)-epigallocatechin gallate: synthesis and crystal structure of anticancer drug candidates 査読

Rutherford Ryan Noboru, Ura Shinji, Chan Tak-Hang, Fukumoto Kozo, Nishioka Takanori, Renzetti Andrea

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY 76 1085 - + 2020年12月（ ISSN:2053-2296 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1107/S2053229620014916
Metal-metal bond formation of triplatinum cores with a silver(i) ion affording a heptanuclear cluster bearing four Pt-Ag bonds 査読

Yabune Natsuki, Nakajima Hiroshi, Nishioka Takanori

DALTON TRANSACTIONS 49 ( 23 ) 7680 - 7683 2020年06月（ ISSN:1477-9226 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1039/d0dt01227k
Reduction-triggered Ligand Dissociation of Trinuclear Complex Bearing Three Kinds of Metal-ligand Units 査読

Yabune Natsuki, Monju Ryosuke, Nakajima Hiroshi, Nishioka Takanori

公益社団法人日本化学会　CHEMISTRY LETTERS 48 ( 12 ) 1511 - 1514 2019年12月（ ISSN:0366-7022 ）

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掲載種別：研究論文（学術雑誌）

A heterometallic trinuclear complex with three metal-metal bonds, which is constituted of three kinds of metal-ligand units bridged by two sulfido ligands, reacts with a 2-electron donor to afford an adduct accompanied with elongation of the metal-metal bonds. Cyclic voltammograms of the complexes showed that the adduct releases the 2-electron donor after electrochemical 1-electron reduction.

DOI： 10.1246/cl.190707

CiNii Article
Sugar-Incorporated Chelating Bis-N-Heterocyclic Carbene Palladium Complexes. Synthesis, Structures, and Catalytic Ability for Suzuki-Miyaura Cross-Coupling Reactions in Water 査読

Imanaka Yosuke, Nakao Keita, Maeda Yuri, Nishioka Takanori

公益社団法人日本化学会　BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 90 ( 9 ) 1050 - 1057 2017年09月（ ISSN:0009-2673 ）

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掲載種別：研究論文（学術雑誌）

Sugar-incorporated chelating bis-N-heterocyclic carbene ligand precursors 1,1′-bis(2,3,4,6-tetra-O-acetyl-β-d-glucopyranosyl)-3,3′-ethylene-diimidazolyl ([(bisNHC-C2)H2]2+) and 1,1′-bis(2,3,4,6-tetra-O-acetyl-β-d-glucopyranosyl)-3,3′-propylene-diimidazolyl ([(bisNHC-C3)H2]2+) were synthesized and used to prepare palladium complexes [Pd(bisNHC-C2)Cl2] and [Pd(bisNHC-C3)Cl2], respectively, by direct metallation reaction using dichlorobis(acetonitrile)palladium as a metal source. Catalytic abilities of the complexes for Suzuki-Miyaura coupling in aqueous media were examined and moderate TON (85,000) and TOF (170,000 h−1) were obtained. Because the terminal chloro ligands in the complexes were substituted with solvent molecules or chloride anion and hence 1H NMR spectra of the chloro complexes were complicated, hydrosulfido complexes [Pd(bisNHC-Cn)(SH)2] (n = 2 and 3) were prepared to confirm structures in solution. Dynamic behavior of flapping-wing motion of the bisNHC ligand in [Pd(bisNHC-C3)(SH)2] in solution was evaluated using the signals of the SH protons, which are inequivalent in 1H NMR spectra attributed to the chirality of the glucopyranosyl units.

DOI： 10.1246/bcsj.20170082

CiNii Article
The Arrangement of Two N-Heterocyclic Carbene Moieties in Palladium Pincer Complexes Affects Their Catalytic Activity towards Suzuki-Miyaura Cross-Coupling Reactions in Water 査読

Imanaka Yosuke, Shiomoto Naotoshi, Tamaki Mako, Maeda Yuri, Nakajima Hiroshi, Nishioka Takanori

公益社団法人日本化学会　BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 90 ( 1 ) 59 - 67 2017年01月（ ISSN:0009-2673 ）

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掲載種別：研究論文（学術雑誌）

Palladium complexes with pincer ligands containing one pyridine and two N-heterocyclic carbene units with acetyl-protected d-glucopyranosyl groups in C-C-N and C-N-C arrangements were synthesized. The complexes form diastereomers due to the twisted pincer ligands and chiral d-glucopyranosyl units. The diastereomers of the C-C-N complex are in equilibrium in solution, whereas only one of the diastereomers of the C-N-C complex forms kinetically. Deprotection of the acetyl groups in the ligands afforded water-soluble complexes with one of the hydroxide groups in the d-glucopyranosyl groups coordinated to the metal ion. In CD3OD, the deprotected complex with the C-N-C ligand gradually decomposed, whereas that with the C-C-N ligand was stable at room temperature. The complexes catalyzed Suzuki–Miyaura cross-coupling reactions in water with turnover numbers of 75,000 for the C-C-N and 8,900 for C-N-C complexes. The C-C-N complex was not deactivated by the addition of metallic Hg meaning that the active species is the complex itself or its derivatives having the pincer ligand. On the other hand, the C-N-C complex exhibited no catalytic activity for the coupling reaction in the presence of metallic Hg, meaning that the active species are heterogeneous catalysts, such as Pd nanoparticles.

DOI： 10.1246/bcsj.20160300

CiNii Article
Observation of hybrid artificial photosynthetic membranes using peripheral and core antennae from two different species of photosynthetic bacteria by AFM and fluorescence micro-spectroscopy 査読

Uragami Chiasa, Sugai Yuko, Hanjo Kohei, Sumino Ayumi, Fujii Ritsuko, Nishioka Takanori, Kinoshita Isamu, Dewa Takehisa, Nango Mamoru, Gardiner Alastair T., Cogdell Richard J., Hashimoto Hideki

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY 313 60 - 71 2015年12月（ ISSN:1010-6030 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1016/j.jphotochem.2015.06.009
Syntheses and Catalytic Ability of Sugar-Incorporated N-Heterocyclic Carbene Pincer Pd Complexes Possessing Various N-Substituents 査読

Imanaka Yosuke, Hashimoto Hideki, Nishioka Takanori

公益社団法人日本化学会　BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 88 ( 8 ) 1135 - 1143 2015年08月（ ISSN:0009-2673 ）

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掲載種別：研究論文（学術雑誌）

Exploration of catalysts for organic reactions in water, which is a nontoxic and nonexplosive liquid, has been studied to achieve environmentally friendly chemical processes. For such a purpose, we utilized click chemistry to incorporate sugar units into transition-metal complexes affording water-soluble complexes. In this study, a series of palladium complexes with C–C–N pincer ligands, each of which consisted of two N-heterocyclic carbenes (NHCs) and a triazole moiety with a D-glucopyranosyl unit were synthesized. These complexes possess various N-substituents, namely, methyl, isopropyl, benzyl, or D-glucopyranosyl units on the terminal NHC moieties. The diastereoselectivity in the formation of the complexes and their catalytic ability toward the Suzuki–Miyaura cross-coupling reactions in water exhibited clear N-substituent effects. The tridentate ligand with an acetylated D-glucopyranosyl unit on the terminal NHC moiety led to high diastereoselectivity in the formation of its complex, while each of the other ligands with achiral substituents on the terminal NHC units afforded both of the diastereomers with low selectivity. Catalytic reactions using the complexes were examined for the Suzuki–Miyaura cross-coupling reactions of phenylboronic acid and 4′-bromoacetophenone in water. The complex possessing an isopropyl group on the terminal NHC moiety exhibited excellent catalytic activity with TON (800000), which is comparable to the best value reported for a similar reaction.

DOI： 10.1246/bcsj.20150083

CiNii Article
Formation of Acyl and Dioxycarbene Ruthenium Complexes via Double C-S Bond Cleavage and CO Insertion 査読

Santo Kiyokazu, Hirotsu Masakazu, Kawamoto Keisuke, Nishioka Takanori, Kinoshita Isamu

公益社団法人日本化学会　BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 88 ( 4 ) 613 - 615 2015年04月（ ISSN:0009-2673 ）

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掲載種別：研究論文（学術雑誌）

Ruthenium complexes containing an N,N,C,S-metalloligand or an N,N,C,O-organoligand with a sulfido carbonyl Ru cluster were obtained by the reaction of 6-(4′′-dibenzothienyl)-2,2′-bipyridine with [Ru3(CO)12]. The dibenzothienyl group undergoes double carbon–sulfur bond cleavage and CO insertion reactions to give a bridging acyl group and a metallacyclic dioxycarbene donor.

DOI： 10.1246/bcsj.20140379

CiNii Article
Redox Properties and Catalytic Ability toward Electrochemical Proton Reduction of Sulfur-Bridged Trinuclear Mo3S4 Complexes Containing Acetate, Trifluoroacetate, and/or Dithiophosphate as Bridging Ligands 査読

Kawamoto Keisuke, Ichimura Akio, Hashimoto Hideki, Kinoshita Isamu, Hirotsu Masakazu, Nishioka Takanori

公益社団法人日本化学会　BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 88 ( 4 ) 565 - 571 2015年04月（ ISSN:0009-2673 ）

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掲載種別：研究論文（学術雑誌）

A novel complex with the terminal acetonitrile and bridging trifluoroacetate (tfa) ligands of [Mo3S4(dtp)3(μ-tfa)(NCCH3)] (dtp: diethyl dithiophospate) (1-tfa) was prepared from the substitution reaction of [Mo3S4(dtp)3(μ-dtp)(NCCH3)] (1-dtp) with trifluoroacetate anhydride in acetonitrile. The reaction of 1-dtp with trifluoroacetic acid in dichloromethane also afforded 1-tfa. Complex 1-tfa reacts with pyridine in ethanol resulting in the formation of a complex with the terminal pyridine ligand (py), [Mo3S4(dtp)3(μ-tfa)(py)] (2-tfa). Structures of 1-tfa and 2-tfa were determined by single-crystal X-ray structural analysis showing that one of three Mo–Mo distances depend on a kind of the bridging ligands, dtp, OAc, and tfa, while no trends in the other two Mo–Mo distances in each of the complexes with the different bridging ligands. Each of the cyclic voltammograms of 1-dtp, [Mo3S4(dtp)3(μ-OAc)(NCCH3)] (OAc: acetate) (1-OAc), 1-tfa, [Mo3S4(dtp)3(μ-OAc)(py)] (2-OAc), and 2-tfa showed two consecutive one-electron reduction waves and an oxidation wave, which are formally assigned to the Mo(IV IV IV)/Mo(III IV IV), Mo(III IV IV)/Mo(III III IV), and Mo(V IV IV)/Mo(IV IV IV) couples, respectively. The re-oxidation and re-reduction peaks for the second reduction and the oxidation processes were not observed for all of the complexes. The redox potentials of the first reduction processes were shifted up to ca. 200 mV with the bridging and terminal ligands, for example, the redox potentials appeared at −0.98 and −1.19 V vs. Fc/Fc+ 2-OAc and 1-tfa, respectively, due to the lower electron-donating ability of CH3CN and tfa ligands compared to that of the py and OAc ligands. The re-oxidation peak for the second reduction process of 2-OAc was observed at −80 °C suggesting that this is an EC process and the chemical reaction following the second electrochemical reduction is probably inhibited at low temperature. On the other hand, no re-reduction peak for the oxidation process appeared even at −80 °C implying that the oxidation process is accompanied by a significant structural change. This argument is supported by the results of the DFT calculation. The HOMO component of the complex contains a bonding character between the two acetate-bridged Mo centers and the other acetate-unbridged one, and the spin densities of the 1-electron oxidized complex mostly located at the one of two acetate-bridged Mo centers and the other acetate-unbridged one. Cyclic voltammograms of these complexes in the presence of trifluoroacetic acid as a proton source exhibited catalytic currents around the first reduction wave for each complex. The DFT calculations for 2-OAc and 2-tfa demonstrated that the HOMO components are also distributed over the doubly bridged sulfur ligands in addition to the Mo centers in the Mo3S4 core. These result suggests that a protonation reaction of 2-OAc and 2-tfa probably occurs on the doubly bridged sulfur ligand in the Mo3S4 core.

DOI： 10.1246/bcsj.20140364

CiNii Article
Chelated Bis-N-heterocyclic Carbene Platinum and Palladium Units as Tunable Components of Multinuclear Complexes 査読

Maeda Yuri, Hashimoto Hideki, Kinoshita Isamu, Nishioka Takanori

INORGANIC CHEMISTRY 54 ( 2 ) 448 - 459 2015年01月（ ISSN:0020-1669 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1021/ic502039d
Syntheses and Redox Properties of Complexes with Mo₃S₄ Cores and Tridentate Schiff Base Ligands 査読

Kawamoto Keisuke, Ichimura Akio, Hashimoto Hideki, Kinoshita Isamu, Nishioka Takanori

The Chemical Society of Japan　Bulletin of the Chemical Society of Japan 88 ( 2 ) 292 - 299 2015年（ ISSN:0009-2673 ）

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掲載種別：研究論文（学術雑誌）

A series of potentially tridentate Schiff base ligands, {HOPhC=N-(CH2)3-XMe: X = S (HLSMe), Se (HLSeMe)}, was prepared by condensation reactions of salicylaldehyde and the corresponding functionalized propylamines. These ligands were used to form the monocationic complexes, [Mo3S4(LXMe)3]+ (X = S (1+), Se (2+)), through treatment of [Mo3S4(H2O)9]4+ with the appropriate Schiff base ligand in methanol. Single-crystal X-ray structural analysis of 1-PF6 revealed that one Schiff base ligand coordinates to each Mo via the O, N, and SMe donor atoms, and then the mono cationic cluster [Mo3S4(LSMe)3]+ has a pseudo C3 symmetry if the chirality around the coordinated sulfur atoms is not taken into account. Because of the arrangements of the asymmetric Schiff base ligand, this monocationic cluster possibly adopts one of two axial chiralities. Furthermore, each sulfur atom of the three coordinated SMe groups in the complex cation is also chiral affording the two enantiomers observed in the unit cell. Dynamic behaviors of complexes 1-PF6 and 2-PF6 in solution were examined using line shape analyses of variable temperature NMR spectra revealing that the rate constant of the chiral inversion at the S atoms in 1-PF6 is greater than that at the Se atoms in 2-PF6 and the difference in the ΔH‡ values of 1-PF6 (47.1 kJ mol−1) and 2-PF6 (56.7 kJ mol−1) and the negative ΔS‡ values (−39.9 and −57.5 J mol−1 K−1 for 1-PF6 and 2-PF6, respectively) suggest that the inversion processes involve bond cleavage between the metal centers and S or Se atoms followed by coordination of solvent molecules. The electrochemical properties of 1-PF6 and 2-PF6 were evaluated using cyclic voltammetry and this revealed that both 1+ and 2+ exhibit two consecutive, reversible one-electron reduction waves that are assigned to formal Mo(IV IV IV)/Mo(III IV IV) and Mo(III IV IV)/Mo(III III IV) couples, respectively. The ability of 1-PF6 and 2-PF6 to catalyze the electroreduction of H+ was also examined using CH3CO2H or CF3CO2H as a proton source. Noteworthy, the redox potentials for the catalytic wave depend on the acidity of the added acids. Thus, the catalytic current around the first reduction wave is observed in the presence of the stronger trifluoroacetic acid as a proton source, while the current around the second reduction wave appears when the weaker acetic acid is used.

DOI： 10.1246/bcsj.20140275

CiNii Article
Incorporation of a Sugar Unit into a C-C-N Pincer Pd Complex Using Click Chemistry and Its Dynamic Behavior in Solution and Catalytic Ability toward the Suzuki-Miyaura Coupling in Water 査読

Imanaka Yosuke, Hashimoto Hideki, Kinoshita Isamu, Nishioka Takanori

公益社団法人日本化学会　CHEMISTRY LETTERS 43 ( 5 ) 687 - 689 2014年05月（ ISSN:0366-7022 ）

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掲載種別：研究論文（学術雑誌）

A Pd complex with a pincer ligand constituted of two N-heterocyclic carbenes and a triazole moiety containing a sugar unit, which was incorporated using click chemistry, was synthesized. Two diastereomers of the complex, which were in equilibrium, were observed in solution. The complex worked as a catalyst for the Suzuki–Miyaura cross-coupling reaction in aqueous media showing a turnover number of up to 76000.

DOI： 10.1246/cl.140017

CiNii Article
Removal of Two Hydrogen Atoms from Ketones or Aldehyde: Reaction of a Sulfur-Bridged Incomplete Cubane-Type Molybdenum Cluster with Acetone, Acetaldehyde, Acetylacetone, Ethyl Acetoacetate, and Acetophenone 査読

Shibahara Takashi, Kawamoto Keisuke, Matsuura Akihiko, Takagi Hideaki, Nishioka Takanori, Kinoshita Isamu, Akashi Haruo

公益社団法人日本化学会　BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 87 ( 4 ) 459 - 469 2014年04月（ ISSN:0009-2673 ）

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掲載種別：研究論文（学術雑誌）

The reaction of sulfur-bridged incomplete cubane-type molybdenum complex [Mo3(µ-S)3(µ3-S)(dtp)3(CH3CN)(µ-OAc)] (1) (dtp: diethyl dithiophosphate) with dimethyl acetylenedicarboxylate (H3COOCC&equiv;CCOOCH3, DMAD) in several kinds of solvents gave solvent-dependent adducts. The use of acetone, acetaldehyde, acetylacetone, ethyl acetoacetate, and acetophenone as reaction solvents gave the following adducts, respectively: [Mo3{µ-SCH(COCH3)}(µ3-S){µ3-SC(CO2CH3)=C(CO2CH3)S}(dtp)3(µ-OAc)] (2), [Mo3{µ-SCH(CHO)}(µ3-S){µ3-SC(CO2CH3)=C(CO2CH3)S}(dtp)3(µ-OAc)] (3), [Mo3{µ-SC(COCH3)(COCH3)}(µ3-S){µ3-SC(CO2CH3)=C(CO2CH3)S}(dtp)3(µ-OAc)] (4) (and [Mo3{µ-SC(COCH3)(COCH3)}(µ3-S){µ3-SC(CO2CH3)=C(CO2CH3)S}(dtp)2(acac)(µ-OAc)] (4′)), [Mo3{µ-SC(COCH3)(COOC2H5)}(µ3-S){µ3-SC(CO2CH3)=C(CO2CH3)S}(dtp)3(µ-OAc)] (5), and [Mo3{µ-SCH(COC6H5)}(µ3-S){µ3-SC(CO2CH3)=C(CO2CH3)S}(dtp)3(µ-OAc)] (6). X-ray crystallography and 1H NMR spectroscopy have revealed that in all six cases, the solvent adduct-formation resulted in the removal of two hydrogen atoms from the methyl (or methylene) group of the solvent used and in the formation of a carbon–sulfur bond; it also revealed that in some cases (2, 3, 4′, and 6) additional carbon–molybdenum bond formations occurred. Mass spectroscopy indicates that the presence of DMAD is indispensable in the two-hydrogen elimination reaction. Electronic spectra of 2, 3, and 6 have absorption bands in the visible and near-infrared region, and those of the two complexes 4 and 5 have significantly larger absorption bands in the longer wavelength region than the former group. The complex 4′, where one of the three dtp ligands is replaced by an acetylacetone anion also has a larger peak in the longer wavelength region, but the intensity is between those of the former and the latter groups. All six complexes show a chemically reversible one-electron-oxidation process corresponding to a V, IV, IV/IV, IV, IV couple and the oxidation products of these six complexes are stable under a time scale in CV measurements. The reduction processes of 2, 3, and 6 are chemically irreversible; those of 4, 4′, and 5 are reversible, and the processes correspond to a IV, IV, IV/IV, IV, III couple. A mechanism for the formation of the doubly-dehydrogenated species is suggested.

DOI： 10.1246/bcsj.20130269

CiNii Article
pi-Back-Bonding Interaction Depending on the Bridging Chain Lengths of Chelated N-Heterocyclic Carbene Platinum Units in Heterometallic Trinuclear Complexes Affecting Their Electrochemical Property 査読

Maeda Yuri, Hashimoto Hideki, Kinoshita Isamu, Nishioka Takanori

INORGANIC CHEMISTRY 53 ( 2 ) 661 - 663 2014年01月（ ISSN:0020-1669 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1021/ic402063f
Syntheses, structures, and photochemical properties of (mu(3)-O) tris {bis(mu-carboxylato)} trimanganese complexes with naphthylacetate ligands with relevance to artificial solar energy-harvesting systems 査読

Nakai Misaki, Funabiki Takuzo, Ohtsuki Chikara, Harada Masafumi, Ichimura Akio, Tanaka Rika, Nishioka Takanori, Kinoshita Isamu, Mikuriya Masahiro, Guo Jiamo, Benten Hiroaki, Ohkita Hideo, Ito Shinzaburo, Obata Makoto, Nakabayashi Yasuo, Yano Shigenobu

INORGANICA CHIMICA ACTA 406 130 - 137 2013年09月（ ISSN:0020-1693 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1016/j.ica.2013.07.011
Synthesis and structural characterization of novel ruthenium(II) complexes bearing hydroxypicolinato ligands 査読

Nakasone Takayuki, Nishioka Takanori, Asato Eiji, Kinoshita Isamu, Takara Satoshi

POLYHEDRON 45 ( 1 ) 152 - 157 2012年09月（ ISSN:0277-5387 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1016/j.poly.2012.07.058
Syntheses, Characterization, and Antitumor Activities of Platinum(II) and Palladium(II) Complexes with Sugar-Conjugated Triazole Ligands 査読

Yano Shigenobu, Ohi Hiromi, Ashizaki Mizue, Obata Makoto, Mikata Yuji, Tanaka Rika, Nishioka Takanori, Kinoshita Isamu, Sugai Yuko, Okura Ichiro, Ogura Shun-ichiro, Czaplewska Justyna A., Gottschaldt Michael, Schubert Ulrich S., Funabiki Takuzo, Morimoto Keiko, Nakai Misaki

CHEMISTRY & BIODIVERSITY 9 ( 9 ) 1903 - 1915 2012年09月（ ISSN:1612-1872 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1002/cbdv.201100426
Synthesis and Reactivity of a Platinum(II) Complex with Hydrosulfido Ligands Induced by a Chelated N-Heterocyclic Carbene Ligand 査読

Maeda Yuri, Hashimoto Hideki, Nishioka Takanori

公益社団法人日本化学会　CHEMISTRY LETTERS 41 ( 2 ) 145 - 147 2012年02月（ ISSN:0366-7022 ）

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掲載種別：研究論文（学術雑誌）

A bis(hydrosulfido)platinum(II) complex with a bidentate chelate N-heterocyclic carbene ligand was oxidized by O2 to give a linear tetrasulfide complex in the presence of excess hydrogen sulfide and a thiosulfato-bridged dinuclear complex without hydrogen sulfide.

DOI： 10.1246/cl.2012.145

CiNii Article
Sulfur containing platinum(II) complexes with N-heterocyclic carbene ligands obtained by reactions of a hydrosulfido complex 査読

Maeda Yuri, Hashimoto Hideki, Nishioka Takanori

DALTON TRANSACTIONS 41 ( 39 ) 12038 - 12047 2012年（ ISSN:1477-9226 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1039/c2dt30597f
Redox-Controlled, Reversible Rearrangement of a Tris(2-pyridylthio)methyl Ligand on Nickel to an Isomer with an "N,S-Confused" 2-Pyridylthiolate Arm 査読

Kuwamura Naoto, Kitano Ken'ichi, Hirotsu Masakazu, Nishioka Takanori, Teki Yoshio, Santo Ryoko, Ichimura Akio, Hashimoto Hideki, Wright L. James, Kinoshita Isamu

CHEMISTRY-A EUROPEAN JOURNAL 17 ( 38 ) 10708 - 10715 2011年09月（ ISSN:0947-6539 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1002/chem.201100875
Sulfur-Bridged Ta-M (M = Mo, Cr) Multinuclear Complexes Bearing a Four-Electron-Reduced Dinitrogen Ligand 査読

Takada Ryoichi, Hirotsu Masakazu, Nishioka Takanori, Hashimoto Hideki, Kinoshita Isamu

ORGANOMETALLICS 30 ( 16 ) 4232 - 4235 2011年08月（ ISSN:0276-7333 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1021/om200596v
Preparation and Structural Features of Cu(I)Cu(II) Coordination Polymers Obtained by Using Tripodal Complexes as Bridging Ligands 査読

Yoshida Yuki, Miyamoto Riichi, Nakato Ayami, Santo Ryoko, Kuwamura Naoto, Gobo Kenji, Nishioka Takanori, Hirotsu Masakazu, Ichimura Akio, Hashimoto Hideki, Kinoshita Isamu

公益社団法人日本化学会　BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 84 ( 6 ) 600 - 611 2011年06月（ ISSN:0009-2673 ）

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掲載種別：研究論文（学術雑誌）

A tripodal complex [CuCl(tpmtm)] (tpmtm: tris(2-pyrimidylthio)methanide) is used to synthesize coordination polymers. The tripodal complex unit worked as bidentate, tridentate, or tetradentate bridging ligands for [CunClm] units via coordination of three outer nitrogen atoms of the tpmtm ligand and also an axial chloro ligand. X-ray crystallography exhibited that obtained coordination polymers contained novel structures of [CunClm] moieties such as chloride-bridged linear CuICuIICuI and CuICuIICuIICuI and cage-shaped CuICuIICuIICuI mixed-valence copper cluster units. The relationship between the numbers of the outer coordination sites on the tripodal complex and structures of the coordination polymers is observed showing that participation in the coordination of two, three, or four outer coordination sites on the tripodal complex afforded the one-dimensional chain, two-dimensional sheet, or three-dimensional structures, respectively.

DOI： 10.1246/bcsj.20100361

CiNii Article
Dynamic behaviour attributed to chiral carbohydrate substituents of N-heterocyclic carbene ligands in square planar nickel complexes 査読

Shibata Teppei, Ito Satoru, Doe Matsumi, Tanaka Rika, Hashimoto Hideki, Kinoshita Isamu, Yano Shigenobu, Nishioka Takanori

DALTON TRANSACTIONS 40 ( 25 ) 6778 - 6784 2011年（ ISSN:1477-9226 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1039/c0dt01833c
Carbon-sulfur bond cleavage reactions of dibenzothiophene derivatives mediated by iron and ruthenium carbonyls 査読

Hirotsu Masakazu, Tsuboi Chiaki, Nishioka Takanori, Kinoshita Isamu

DALTON TRANSACTIONS 40 ( 4 ) 785 - 787 2011年（ ISSN:1477-9226 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1039/c0dt00768d
Unprecedented diastereoselective generation of chiral-at-metal, half sandwich Ir(III) and Rh(III) complexes via anomeric isomerism on "sugar-coated" N-heterocyclic carbene ligands 査読

Shibata Teppei, Hashimoto Hideki, Kinoshita Isamu, Yano Shigenobu, Nishioka Takanori

DALTON TRANSACTIONS 40 ( 18 ) 4826 - 4829 2011年（ ISSN:1477-9226 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1039/c0dt01634a
Synthesis and structures of N,N,O-scorpionatoruthenium(II) complexes featuring "non-innocent" o-benzoquinonediimines 査読

Oh Jae-Hwan, Nishioka Takanori, Masui Ryoji, Asato Eiji, Kinoshita Isamu, Takara Satoshi

POLYHEDRON 29 ( 8 ) 1964 - 1967 2010年05月（ ISSN:0277-5387 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1016/j.poly.2010.03.009
Synthesis and structural characterization of novel ruthenium(II) complexes featuring an N,N,O-scorpionate ligand: A versatile synthetic precursor for open-face scorpionatoruthenium(II) complexes 査読

Yogi Akira, Oh Jae-Hwan, Nishioka Takanori, Tanaka Rika, Asato Eiji, Kinoshita Isamu, Takara Satoshi

POLYHEDRON 29 ( 5 ) 1508 - 1514 2010年03月（ ISSN:0277-5387 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1016/j.poly.2010.01.016
Synthesis and Crystal Structure of [RuCl(6-hydroxypicolinato)(2,2';6',2"-terpyridine)] (N,N-dimethylformamide) 査読

NAKAMA Yukitoshi, NISHIOKA Takanori, NAKASONE Takayuki, ASATO Eiji, KINOSHITA Isamu, TAKARA Satoshi

社団法人日本分析化学会　X-ray Structure Analysis Online 26 33 - 34 2010年

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掲載種別：研究論文（学術雑誌）

The structure of [RuCl(6-hydroxypicolinato)(2,2′;6′,2″-terpyridine)]·(N,N-dimethylformamide) was determined by X-ray crystallography. The compound crystallized in a monoclinic system and was characterized thus: P21/c, a = 15.7325(19), b = 10.0621(10), c = 15.6422(19)Å, β = 105.112(3)°, Z = 4, V = 2390.6(5)Å3. The crystal structure was solved by the SIR97 direct method and refined by full-matrix least-squares on F2 to final values of R1 = 0.1155 and wR2 = 0.1018 for all data.

DOI： 10.2116/xraystruct.26.33

CiNii Article
Carbene-carbanion equilibrium for tris(2-pyridylthio)methanido Fe(II) complexes 査読

Kuwamura Naoto, Kato Ryo, Kitano Ken'ichi, Hirotsu Masakazu, Nishioka Takanori, Hashimoto Hideki, Kinoshita Isamu

DALTON TRANSACTIONS 39 ( 41 ) 9988 - 9993 2010年（ ISSN:1477-9226 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1039/c0dt00615g
Rh(I)-Catalyzed CO Gas-Free Carbonylative Cyclization Reactions of Alkynes with 2-Bromophenylboronic Acids Using Formaldehyde 査読

Morimoto Tsumoru, Yamasaki Kae, Hirano Akihisa, Tsutsumi Ken, Kagawa Natsuko, Kakiuchi Kiyomi, Harada Yasuyuki, Fukumoto Yoshiya, Chatani Naoto, Nishioka Takanori

ORGANIC LETTERS 11 ( 8 ) 1777 - 1780 2009年04月（ ISSN:1523-7060 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1021/ol900327x
"Compressed" Icelike Structures between Molecular Films Comparable with Ice Phase III 査読

Yoshida Yuki, Miyamoto Riichi, Nishioka Takanori, Hashimoto Hideki, Kinoshita Isamu

公益社団法人日本化学会　CHEMISTRY LETTERS 38 ( 4 ) 366 - 367 2009年04月（ ISSN:0366-7022 ）

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掲載種別：研究論文（学術雑誌）

An icelike supramolecular structure is found in a self-assembled quasi 3-D crystalline hydrate in-between the layers of CuII tris(pyridylthio)methyl hydroxide complexes, which is comparable with compressed pure ice III.

DOI： 10.1246/cl.2009.366

CiNii Article
Photochromism of an Organorhodium Dithionite Complex in the Crystal line-State: Molecular Motion of Pentamethylcyclopentadienyl Ligands Coupled to Atom Rearrangement in a Dithionite Ligand 査読

Nakai Hidetaka, Nonaka Takashi, Miyano Yousuke, Mizuno Motohiro, Ozawa Yoshiki, Toriumi Koshiro, Koga Nobuaki, Nishioka Takanori, Irie Masahiro, Isobe Kiyoshi

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130 ( 52 ) 17836 - 17845 2008年12月（ ISSN:0002-7863 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1021/ja807150a
Ruthenium and rhodium complexes with thiolate-containing pincer ligands produced by C - S bond cleavage of pyridyl-substituted dibenzothiophenes 査読

Shibue Mayuko, Hirotsu Masakazu, Nishioka Takanori, Kinoshita Isamu

ORGANOMETALLICS 27 ( 17 ) 4475 - 4483 2008年09月（ ISSN:0276-7333 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1021/om8003916
Synthesis and characterization of tris(2-pyridylthio)methanido Zn complex with a Zn-C bond and DFT calculation of its one-electron oxidized species 査読

Kitano Ken'ichi, Kuwamura Naoto, Tanaka Rika, Santo Ryoko, Nishioka Takanori, Ichimura Akio, Kinoshita Isamu

CHEMICAL COMMUNICATIONS ( 11 ) 1314 - 1316 2008年03月（ ISSN:1359-7345 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1039/b715996j
Mimicking the photosynthetic system with strong hydrogen bonds to promote proton electron concerted reactions 査読

Kinoshita Isamu, Hashimoto Hideki, Nishioka Takanori, Miyamoto Riichi, Kuwamura Naoto, Yoshida Yuki

PHOTOSYNTHESIS RESEARCH 95 ( 2-3 ) 363 - 371 2008年02月（ ISSN:0166-8595 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1007/s11120-007-9263-0
Observation of halide-induced conformational conversion of dinuclear copper complexes having a tetradentate polypyridine ligand with a p-xylene backbone 査読

Nishioka Takanori, Mitsui Shigeru, Kinoshita Isamu, Koshiyama Tamami, Kato Masako

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 80 ( 7 ) 1357 - 1367 2007年07月（ ISSN:0009-2673 ）

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掲載種別：研究論文（学術雑誌）
Structure and dynamic properties of substituted carbonylhydride clusters H2RuOs3(CO)(13) and H4Ru4(CO)(12) containing functionalized phosphines 査読

Andreev I. A., Grachova E. V., Tunik S. P., Oparina L. A., Sukhov B. G., Malysheva S. F., Kinoshita I., Nishioka T.

RUSSIAN CHEMICAL BULLETIN 56 ( 7 ) 1343 - 1350 2007年07月（ ISSN:1066-5285 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1007/s11172-007-0205-y
Sugar-incorporated N-heterocyclic carbene complexes 査読

Nishioka Takanori, Shibata Teppei, Kinoshita Isamu

ORGANOMETALLICS 26 ( 5 ) 1126 - 1128 2007年02月（ ISSN:0276-7333 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1021/om061128d
Thiacalix[3]pyridine produces a stable mononuclear rhodium(II) complex with mutual Jahn-Teller effect 査読

Hamazawa RT, Nishioka T, Kinoshita I, Takui T, Santo R, Ichimura A

DALTON TRANSACTIONS ( 11 ) 1374 - 1376 2006年03月（ ISSN:1477-9226 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1039/b515926a
Direct observation of photochromic dynamics in the crystalline state of an organorhodium dithionite complex 査読

Nakai Hidetaka, Mizuno Motohiro, Nishioka Takanori, Koga Nobuaki, Shiomi Kimie, Miyano Yousuke, Irie Masahiro, Breedlove Brian K., Kinoshita Isamu, Hayashi Yoshihito, Ozawa Yoshiki, Yonezawa Takae, Toriumi Koshiro, Isobe Kiyoshi

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 45 ( 39 ) 6473 - 6476 2006年（ ISSN:1433-7851 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1002/anie.200601702
Diamagnetic-Paramagnetic Conversion of Tris(2-pyridylthio)methylcopper(III) through a Structural Change From Trigonal Bipyramidal to Octahedral.

R. Santo, R. Miyamoto, R. Tanaka, T. Nishioka, I. Kinoshita et al.

Angew. Chem, Int. Ed. 45 7611 - 7614 2006年

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掲載種別：研究論文（学術雑誌）
Steric control of tritolylphosphines on the, nuclearity of Cu(I) complexes: Syntheses and structures of the iodo-bridged [Cu-4(mu(3)-I)(4)(p-tolyl(3)P)(4)] cubane and the [Cu-2(mu-I)(2)(o-tolyl(3)P)(2)] dimer 査読

Lobana TS, Kumar R, Sharma R, Nishioka T, Castineiras A

JOURNAL OF COORDINATION CHEMISTRY 58 ( 10 ) 849 - 855 2005年07月（ ISSN:0095-8972 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1080/00958970412331336330
Syntheses, NMR (H-1, P-31) spectroscopy and crystal structures of complexes of copper(I) halides with isatin-3-thiosemicarbazones 査読

Lobana TS, Rekha, Sidhu BS, Castineiras A, Bermejo E, Nishioka T

JOURNAL OF COORDINATION CHEMISTRY 58 ( 9 ) 803 - 809 2005年06月（ ISSN:0095-8972 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1080/00958970500110974
Structure study and luminescence thermochromism in hexanuclear 6-methyl-2-pyridinethiolato copper(I) crystals 査読

Xie HY, Kinoshita I, Karasawa T, Kimura K, Nishioka T, Akai I, Kanemoto K

JOURNAL OF PHYSICAL CHEMISTRY B 109 ( 19 ) 9339 - 9345 2005年05月（ ISSN:1520-6106 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1021/jp0446985
Catalytically active mu-oxodiiron(IV) oxidants from iron(III) and dioxygen 査読

Ghosh A, de Oliveira FT, Yano T, Nishioka T, Beach ES, Kinoshita I, Munck E, Ryabov AD, Horwitz CP, Collins TJ

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 127 ( 8 ) 2505 - 2513 2005年03月（ ISSN:0002-7863 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1021/ja0460458
A two-dimensional clathrate hydrate sandwiched by planar arrays of a copper complex 査読

Miyamoto R, Hamazawa RT, Hirotsu M, Nishioka T, Kinoshita I, Wright LJ

CHEMICAL COMMUNICATIONS ( 32 ) 4047 - 4049 2005年（ ISSN:1359-7345 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1039/b505681k
A complete series of copper(II) halide complexes (X = F, Cl, Br, I) with a novel Cu(II)-C(sp(3)) bond 査読

Miyamoto R, Santo R, Matsushita T, Nishioka T, Ichimura A, Teki Y, Kinoshita I

DALTON TRANSACTIONS ( 19 ) 3179 - 3186 2005年（ ISSN:1477-9226 ）

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掲載種別：研究論文（学術雑誌）

DOI： 10.1039/b507073b
Selective oxygenation of amphiphilic thiacalix[3]pyridine Rh(I) diene complexes in both water and organic solvents.

T. Nishioka, Y. Onishi, K. Nakajo, R. Tanaka, I. Kinoshita et al.

Dalton Trans. 2130 - 2137 2005年

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掲載種別：研究論文（学術雑誌）
Copper-sulfur interactions: synthesis and structure of a trigonal planar copper(I) complex with bis(diphenylthiophosphinyl)methane, [CuI(dppmS2)]·MeCN. 査読国際共著

Lobana, T S, Singh, G, Nishioka, T

J. Coord. Chem. 57 955 - 960 2004年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Nucleophilicity of Ligated S₂^2- Ions. Conversion of Organic Chlorides into Organosulfur Compounds in cis-[(MCp*)₂(μ-CH₂)₂(μ-S₂R)]⁺ (M = Rh, Ir).

T. S. Lobana, K. Isobe, H. Kitayama, T. Nishioka, I. Kinoshita et al.

Organometallics 23 5347 - 5352 2004年

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掲載種別：研究論文（学術雑誌）
Activation of C-Cl and C-H bonds by Ligated S₂^2- in Unusual Way. Conversion of Organic Chlorides into Organosulfur Compounds Coordinated to Iridium Metal Atom in cis-[(IrCp*)₂(μ-CH₂)₂(μ-S₂R)]⁺.

T. S. Lobana, K. Isobe, H. Kitayama, T. Nishioka, I. Kinoshita

Angew. Chem., Int. Ed. Eng. 43 213 - 215 2004年

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掲載種別：研究論文（学術雑誌）
Novel Nucleophilic Reactivity of Disulfide Ligands Coordinated Parallel to M-M (M = Rh, Ir) Bonds.

T. Nishioka, H. Kitayama, B. K. Breedlove, K. Shiomi, I. Kinoshita et al.

Inorg. Chem. 43 5688 - 5697 2004年

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掲載種別：研究論文（学術雑誌）
Pyridine-2-Sulfonates as Versatile Ligands for the Synthesis of Novel Coordinative and Hydrogen Bonded Supramolecules. 査読国際共著

Lobana, T S, Kinoshita, I, Kimura, K, Nishioka, T, Shiomi, D, Isobe, K

Eur. J. Inorg. Chem. 356 - 367 2004年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Synthesis of an Unprecedented Bicapped Adamantoid [Cu6(μ2-I)(μ3-I)(μ4-I)(m-tolyl3P)4(CH3CN)2] Cluster. 査読国際共著

Lobana, T S, Kaur, P, Nishioka, T

Inorganic Chemistry 43 3766 - 3767 2004年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Synthesis and behavior in solution of the triple cubane- and windmill-type framework isomers of an organorhodium tungsten oxide cluster [(Cp*Rh)4W4O16]. 査読国際共著

Nishikawa, K, Kido, K, Yoshida, J, Nishioka, T, Kinoshita, I, Breedlove, B K, Hayashi, Y, Uehara, A, Isobe, K

Appl. Organomet. Chem. 17 446 - 448 2003年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Introduction of Chirality to the Remote, Open Face of Metalloporphyrin through Coordination to the Metal of Specially Designed Pendant Arm. 査読国際共著

Hamazawa, A, Yano, T, Nishioka, T, Kinoshita, I, Isobe, K: Yano, S, Wright, L J, Collins, T J

Chemistry Letters 20 - 21 2003年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Laser photolysis studies on CuI complexes of thia-calix[3]pyridine. Phosphorescence from the intramolecular charge-transfer excited state. 査読

Kinoshita, I, Hamazawa, A, Nishioka, T, Adachi, H, Suzuki, H, Miyazaki, Y, Tsuboyama, A, Okada, S, Hoshino, M

Chem. Phys. Lett. 371 451 - 457 2003年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Design and synthesis of copper complexes of novel ligands based on the pyridine thiolate group. 査読国際共著

Kinoshita, I, Wright, L J, Kubo, S, Kimura, K, Sakata, A, Yano, T, Miyamoto, R, Nishioka, T, Isobe, K

Dalton Trans. 1993 - 2003 2003年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Thia-calix[n]pyridines, synthesis and coordination to Cu(I,II) ions with both N and S donor atoms. 査読

Tanaka, R, Yano, T, Nishioka, T, Nakajo, K, Breedlove, B K, Kimura, K, Kinoshita, I, Isobe, I

Chem. Commun. 1686 - 1687 2002年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Structure and reactivity of a novel parallel thiosulfito (SSO₂-S:S') rhodium dinuclear complex.

K. Shiomi, B. K. breedlove, H. kitayama, I. Kinoshita, K. isobe et al.

Chem. Commun. 1756 - 1757 2002年

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掲載種別：研究論文（学術雑誌）
Mononuclear–dinuclear helicate interconversion of dibromo{N,N’-bis[(S)-1-2-(pyridyl)ethyl]pyridine-2,6-dicarboxamidate}copper(II) via a deprotonation–protonation process. 査読国際共著

Yano, T, Tanaka, R, Nishioka, T, Kinoshita, I, Isobe, K, Wright, L J, Collins, T J

Chem. Commum. 1396 - 1397 2002年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Synthesis and X-ray Analysis of Mn–Mo Mixed Metal Oxide Cluster with Cubic Framework. 査読

Nishikawa, K, Kinoshita, I, Nishioka, T, Isobe, K,

Chemistry Letters 1342 - 1343 2000年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Lantern-type dinuclear CrIIIPtII and VIVPtII complexes bridged by pyridine-2-thiolate. Synthesis and characterization. 査読

Kitano, K, Tanaka, R, Kimura, T, Tsuda, T, Shimizu, S, Takagi, H, Nishioka, T, Shiomi, D, Ichimura, A, Kinoshita, I, Isobe, K, Ooi, S

J. Chem. Soc. Dalton Trans 995 - 1000 2000年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Formation of μ4-Se2 complexe by the oxidative coupling of μ-SeH complex: double-site atomic inversion of the μ4-Se2 complex [{(Cp*Rh)2(μ-CH2)2}2(μ4-Se2)]2+ (Cp* = η5-C5Me5) 査読

Shimomura, H, Nishioka, T, Abe, M, Kinoshita, I, Isobe, K

J. Organomet. Chem. 611 386 - 391 2000年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Aerobic oxidation of a disulfide to its sulfonate leading to supramolecular pyridine-2-sulfonato Cu(II) and Zn(II) complexes. 査読

Kimura, K, Kimura, T, Kinoshita, I, Nakashima, N, Kitano, K, Nishioka, T, Isobe, K

J. Chem. Soc., Chem. Commun. 497 - 498 1999年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Structural Diversity of Copper Complexes with 2,2'-Dipyridyldisulfide. From Dimer to Infinite Sheet Structure Both in Solid State and in Solution. 査読

Kubo, S, Nishioka, T, Ishikawa, K, Kinoshita, I, Isobe, K

Chemistry Letters 1067 - 1068 1998年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Catalytic Generation of Oxalate through a Coupling Reaction of Two CO2 Molecules Activated on [(Ir(η5-C5Me5))2(Ir(η4-C5Me5)CH2CN)(μ3-S)2]. 査読

Tanaka K, Kushi Y, Tsuge K, Toyohara K, Nishioka T, Isobe K

Inorganic Chemistry 37 120 - 126 1998年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Formation and Dynamic Properties of Triangular Rhodium μ3-SulfidoComplex, [Rh3Cp*3(μ3-η2-||-C2H2)(μ2-S)]2+ (Cp* = η5-C5Me5), Including Acetylene Ligand Generated by the Coupling and Deprotonation of Two Bridging Methylene Units in Dirhodium Complex. 査読国際共著

Nishioka, T, Isobe, K, Kinoshita, I, Ozawa, Y, Vázquez de Miguel, A, Nakai, T, Miyajima, S

Organometallics 17 1637 - 1639 1998年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Lantern Type Heterobimetallic Complexes. Tetra-μ-4-methylpyridine-2-thiolato Bridged Platinum(II)-Cobalt(II) and the Oxidation Complexes. 査読

Kitano, K, Tanaka, K, Nishioka, T, Ichimura, A, Kinoshita, I, Isobe, K, Ooi, S

J. Chem. Soc. Dalton Trans. 3177 - 3182 1998年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Synthesis and characterization of pentamethylcyclopentadienylrhodium(III) and-iridium(III) complexes with 1,2-benzenedithiolate: [(Cp*Rh)2(μ(S)-1,2-C6H4S2-S,S')2], [(Cp*Rh)2(μ(S)-1,2-C6H4S2-S,S')(μ(S)-1,2-C6H4S(SO2)-S,S') and [(Cp*Ir)(1,2-C6H4S2-S,S')] (Cp* = η5-C5(CH3)5). 査読

Xi R, Abe M, Suzuki T, Nishioka T, Isobe K

J. Organomet. Chem. 549 117 - 125 1997年

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掲載種別：研究論文（学術雑誌）共著区分：共著
A Novel Type of Acid Amino Coordination: The Metallocycle Rh-Rh-NH-C(Me)=O. 査読国際共著

Kukushkin V Yu, Nishioka T, Nakamura S, Kinoshita I, Isobe K

Chemistry Letters 189 - 190 1997年

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掲載種別：研究論文（学術雑誌）共著区分：共著
A novel organometallic oxide cluster with multi valley sites: synthesis and structure of [NBun4]2[{(η5-C5Me5)Rh}2Mo6O20(OMe)2]and its framework transformations. 査読

Takara S, Nishioka T, Kinoshita I, Isobe K

J. Chem. Soc., Chem. Commun. 891 - 892 1997年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Hydrogen-bonding Patterns in Oxime/Oximato Platinum(II) Species Providing the Formation of One Dimensional Chains, Two-Dimensional Networks, and Cages. 査読国際共著

Kukushkin V Yu, Nishioka T, Tudela D, Isobe K, Kinoshita I

Inorganic Chemistry 36 6157 - 6165 1997年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Conversion of Rectangular Tetrasulfide Ligand in Tetrarhodium Complex, [{(RhCp*)2(μ-CH2)2}2(μ4-S4)]2+ (Cp* = η5-C5Me5), into Disulfide Ligands in Dirhodium Complex, [(RhCp*)2(μ-CH2)2(μ-S2)] by Chemical Reduction. 査読

Nishioka T, Nakamura S, Kaneko Y, Suzuki T, Kinoshita I, Kiyooka S, Isobe K

Chemistry Letters 911 - 912 1996年

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掲載種別：研究論文（学術雑誌）共著区分：共著
C=S Bond Fission in Coordinated Thioureas and Formation of a Sulfide-bridged Dinuclear Pd(II) Complex. 査読

Okeya S, Kameda H, Kawashima H, Shimomura H, Nishioka T, Isobe K

Chemistry Letters 501 - 502 1995年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Remarkable Decrease in Overpotential of Oxalate Formation in Electrochemical CO2 Reduction by a Metal-Sulfide Cluster. 査読

Kushi Y, Nagao H, Nishioka T, Isobe K, Tanaka K

J. Chem. Soc., Chem. Commun. 1223 - 1224 1995年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Oxalate Formation in Electrochemical CO2 Reduction Catalyzed by Rhodium-Sulfur Cluster. 査読

Kushi Y, Nagao H, Nishioka T, Isobe K, Tanaka K

Chemistry Letters 2175 - 2178 1994年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Isolation and X-ray Crystal Structure of a New Octamolybdate: [(RhCp*)2(μ2-SCH3)3]4- [Mo8O26]·2CH3CN (Cp* = η5-C5Me5). 査読国際共著

Xi R, Wang B, Isobe K, Nishioka T, Toriumi K, Ozawa Y

Inorganic Chemistry 33 833 - 836 1994年

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掲載種別：研究論文（学術雑誌）共著区分：共著
A Tetranuclear Rhodium Complex with a μ4-S Ligand, [{Cp*2Rh2(μ2-CH2)2}2(μ4-S)]2+ (Cp* =η5-C5Me5),Obtained from Stepwise Abstraction of the SH- Ligand from a Dinuclear RhodiumDihydrosulfide Precursor by Ag+. 査読国際共著

Nishioka T, Kukushkin V Y, Isobe K, Vázquez deMiguel A

Inorganic Chemistry 33 2501 - 2502 1994年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Synthesis and Crystal Structure of [(IrCp*)2(μ-OH)3]2(Cr2O7)•8H2O (Cp* = η5-C5Me5). A Novel Two-Dimensional Hydrogen-Bonding Network. 査読国際共著

Park J T, Nishioka T, Suzuki T, Isobe K

Bull. Chem. Soc. Jpn. 33 2501 - 2502 1994年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Syntheses and Crystal Structures of Triangular Rhodium and Iridium Complexes with Triply Bridging Sulfido Ligands. 査読

Nishioka T, Isobe K

Chemistry Letters 1661 - 1664 1994年

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掲載種別：研究論文（学術雑誌）共著区分：共著
[{Rh2Cp*2(μ-CH2)2}2(μ-S4)]2+:A Novel Tetranuclear Cationic Complex with a Rectangular S4Unit. 査読国際共著

Isobe K, Ozawa Y, Vázquez de Miguel A, Zhu T-W, Zhao K-M, Nishioka T, Ogura T, Kitagawa T

Angew. Chem. Int. Ed. Engl. 33 1882 - 1884 1994年

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掲載種別：研究論文（学術雑誌）共著区分：共著
Synthesis of Lantern-type Dinuclear Mixed-Metal Complex of Platinum(II) and Nickel(II). 査読

Nishioka T, Kinoshita I, Kitano K, Ooi S

Chemistry Letters 883 - 886 1992年

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掲載種別：研究論文（学術雑誌）共著区分：共著

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書籍等出版物

無機化学演習 : 大学院入試問題を中心に

中沢浩, 西岡孝訓, 篠田哲史, 廣津昌和, 三宅弘之, 板崎真澄（担当：単著）

東京化学同人 2012年（ ISBN:9784807907960 ）

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著書種別：学術書

CiNii Books

講演・口頭発表等

Activation of closed-shell trinuclear clusters bearing chelating bis-N-heterocyclic carbene and triply bridging sulfide ligands 招待国際会議

Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka

The 28th International SPACC Symposium 2023年12月 The Society of Pure and Applied Coordination Chemistry

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会議種別：口頭発表（招待・特別）

開催地：Remote
Enhancement of reactivity of a trinuclear core bearing triply-bridging sulfides using structurally flexible bis-NHC ligands 招待国際会議

Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka

The 2023 Annual SPACC Meeting and The 3rd International OUS Frontier Symposium 2023年09月

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会議種別：口頭発表（招待・特別）

開催地：Okayama, Japan
Catalytic Ability of Nickel Complex with Sugar-Incorporated N-Heterocyclic Carbene Ligand 国際会議

Taichi Kobayashi, Hiroshi Nakajima, Takanori Nishioka

The 2023 Annual SPACC Meeting and The 3rd International OUS Frontier Symposium 2023年09月

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会議種別：ポスター発表

開催地：Okayama, Japan
Activation of Mixed-Metal Trinuclear Complexes with Triply Bridging Sulfide Ligands by Electrochemical and Chemical Reduction 国際会議

Amiru Yokoyama, Ryotaro Nishino, Hiroshi Nakajima, Takanori Nishioka

The 2023 Annual SPACC Meeting and The 3rd International OUS Frontier Symposium 2023年09月

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会議種別：ポスター発表

開催地：Okayama, Japan
二座キレートＮＨＣ配位子をもつ白金ーパラジウム混合金属錯体の反応性の調査国内会議

籔根夏希、中島洋、西岡孝訓

錯体化学会第73回討論会 2023年09月

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会議種別：ポスター発表

開催地：水戸市民会館
C-S bond formation using palladium thiolato complexes bearing sugar-incorporated N-heterocyclic carbene ligands 国際会議

Takanori Nishioka, Itsuki Kobayashi, Hiroshi Nakajima

20th International Conference on Biological Inorganic Chemistry 2023年07月

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会議種別：ポスター発表

開催地：Adelaide, Australia
Effects of structures of bis N-heterocyclic carbene ligands in M₃S₂ complexes on their reactions with silver(I) ion 国際会議

Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka

20th International Conference on Biological Inorganic Chemistry 2023年07月

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会議種別：ポスター発表

開催地：Adelaide, Australia
メチレン架橋ビスＮ−ヘテロ環カルベン−白金二核部位を組み込んだ混合配位子白金三核錯体および混合金属ロジウム白金錯体の構造と銀(I)イオンの反応国内会議

籔根夏希、中島洋、西岡孝訓

第103回日本化学会春季年会 2023年03月日本化学会

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会議種別：口頭発表（一般）

開催地：東京理科大学野田キャンパス
Activation of M₃S₂core in trinuclear sulfide complexes 国際会議

Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka

The 27th International SPACC Symposium 2022年12月 The Society of Pure and Applied Coordination Chemistry

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会議種別：口頭発表（一般）

開催地：Remote
二座キレート N-ヘテロ環カルベン配位部位をもつ糖修飾パラジウムチオラト錯体の合成と性質国内会議

小林樹、中島洋、西岡孝訓

2022年日本化学会中国四国支部大会広島大会 2022年11月日本化学会中国四国支部

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会議種別：ポスター発表

開催地：広島大学
生体透過性にする優れた光に応答する鉄（Ⅲ）－カルボニル錯体国内会議

中島洋、野村夏生、西岡訓孝、廣津昌和

第72回錯体化学討論会 2022年09月錯体化学会

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会議種別：口頭発表（一般）

開催地：九州大学
二座キレートNHC配位子の架橋アルキル鎖長による白金三核錯体の反応制御国内会議

籔根夏希、中島洋、西岡孝訓

第72回錯体化学討論会 2022年09月錯体化学会

　詳細を見る

会議種別：ポスター発表

開催地：九州大学

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科研費

硫黄架橋三核錯体の反応活性化による硫黄移動型炭素-硫黄結合生成触媒の開発

基盤研究（Ｃ） 2023年
硫黄架橋三核錯体の反応活性化による硫黄移動型炭素-硫黄結合生成触媒の開発

基盤研究（Ｃ） 2022年
非対称チオエーテルのワンポット合成に向けた水中Ｃ－Ｓ結合生成タンデム触媒の創生

基盤研究（Ｃ） 2017年04月
糖のアノマー異性を用いた金属錯体の普遍的光学活性制御

基盤研究（Ｃ） 2010年
新規有機金属錯体被膜金ナノクラスター創成を目指した均一系合成法の開発

若手研究(B) 2001年
テトラカルコゲニド配位子を持つ四核ロジウム錯体の合成と化学的性質

奨励研究(A) 1997年

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担当教育概要

物質を理解するための原子、分子の基本的な概念や、物質の構造を知るための測定法などについて、講義、実験、実習を行っている。

担当授業科目

基礎無機・分析化学A

2023年度週間授業大学院
創成分子科学演習

2023年度集中講義大学院
基幹無機化学

2023年度集中講義大学院
後期特別研究

2023年度集中講義大学院
創成分子科学ゼミナール

2023年度集中講義大学院
化学実験Ⅰ

2023年度週間授業大学
特別研究

2023年度集中講義大学
基礎化学実験

2023年度週間授業大学院
基礎化学実験Ⅱ

2023年度集中講義大学院
化学実験Ⅳ

2023年度週間授業大学
無機化学演習

2023年度週間授業大学
基礎化学実験2

1900年度大学
基礎化学実験1

1900年度大学
物質科学実験2

1900年度大学
物質設計学特論I

1900年度
計算機物質科学I

1900年度大学

▼全件表示

論文・研究指導集計

2023年度

卒業論文指導数：2名卒業論文審査数：2件

博士前期課程学生指導数：2名博士後期課程学生指導数：1名

修士論文審査数（主査）：0件修士論文審査数（副査）：1件

博士論文審査数（主査）：0件博士論文審査数（副査）：1件

学術貢献活動

The 27th International SPACC Symposium

役割：企画立案・運営等

The Society of Pure and Applied Coordination Chemistry 2022年

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種別：大会・シンポジウム等

その他

職務経歴

2007年

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大阪市立大学准教授
職務経歴

2006年

　詳細を見る

大阪市立大学助教授
職務経歴

1996年

　詳細を見る

大阪市立大学講師
職務経歴

1995年

　詳細を見る

大阪市立大学助手