Updated on 2024/04/03

写真a

 
Tsurusaki Akihiro
 
Organization
Graduate School of Science Department of Chemistry Associate Professor
School of Science Department of Chemistry
Title
Associate Professor
Affiliation
Institute of Science
Homepage
https://www.omu.ac.jp/sci/kamikawa/
Affiliation campus
Sugimoto Campus

Position

  • Graduate School of Science Department of Chemistry 

    Associate Professor  2022.04 - Now

  • School of Science Department of Chemistry 

    Associate Professor  2022.04 - Now

Degree

  • 博士（理学） （ Kyoto University ）

Research Areas

  • Nanotechnology/Materials / Synthetic organic chemistry

  • Nanotechnology/Materials / Structural organic chemistry and physical organic chemistry

Research Interests

  • π共役化合物

  • 典型元素化学

  • 有機金属化学

  • 構造有機化学

Research Career

  • 典型元素を活用した新しい配位子および機能性分子の開発

    有機化学、典型元素、触媒反応、配位子、機能性分子  Individual

    2016.04 - Now 

Professional Memberships

  • The Society of Physical Organic Chemistry, Japan

    2022.04 - Now   Domestic

  • Kinka Chemical Society, Japan

    2014.11 - Now

  • The Society of Synthetic Organic Chemistry, Japan

    2012.08 - Now

  • ケイ素化学協会

    2012.08 - Now

  • The Chemical Society of Japan

    2004.12 - Now

Awards

  • ケイ素化学協会 奨励賞

    2022.11   ケイ素化学協会   新規ケイ素クラスターの開発

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    Country：Japan

  • 宇部興産学術振興財団　第57回学術奨励賞

    2017.06   宇部興産学術振興財団  

  • 高砂香料工業 研究企画賞

    2016.12   有機合成化学協会  

  • 日本化学会第95春季年会(2015)　優秀講演賞(学術)

    2015.04   日本化学会  

  • 日本化学会第93春季年会(2013)　優秀講演賞(学術)

    2013.04   日本化学会  

  • 日本化学会BCSJ賞

    2010.05   日本化学会  

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Job Career (off-campus)

  • Osaka Metropolitan University.

    2022.04 - Now

  • Osaka Prefecture University

    2021.04 - 2022.03

  • Osaka Prefecture University   Graduate School of Science

    2016.04 - 2021.03

  • 産業技術総合研究所太陽光発電研究センター 産総研特別研究員

    2015.04 - 2016.03

  • 群馬大学大学院工学研究科　博士研究員

    2011.07 - 2015.03

  • 京都大学化学研究所　博士研究員

    2010.04 - 2011.07

  • 日本学術振興会　特別研究員 (DC2)

    2008.04 - 2010.03

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Education

  • Kyoto University   Graduate School, Division of Natural Science   Department of Chemistry   Doctor's Course   Graduated/Completed

    2005.04 - 2010.03

  • Kyoto University   Faculty of Science   Bachelor's Course   Graduated/Completed

    2001.04 - 2005.03

Papers

  • Diphosphene with a phosphineborane tether and its rhodium complex Reviewed

    Akihiro Tsurusaki, Shingo Takechi, Ken Kamikawa

    Dalton Transactions   53 ( 7 )   2929 - 2936   2023.12（ ISSN:1477-9226 ） （ eISSN:1477-9234 ）

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    Authorship：Lead author,　Corresponding author   Publishing type：Research paper (scientific journal)   International / domestic magazine：International journal  

    A diphosphene ligand possessing a P P bond and a phosphineborane moiety in its molecule was synthesized. The reaction of the new bidentate diphosphene-phosphineborane ligand with [Rh(cod)2]BF4 provided a cationic diphosphene-rhodium complex with cis-coordination through the η1-P P and η2-BH3 moieties. The complex was applied to the coupling reaction of benzimidazole with cyclohexylallene. The complex also underwent a ligand exchange reaction with N-donor reagents such as N-methylpyrrolidine and N,N,N,N-tetramethylethylenediamine. In particular, the addition reaction of pyridine with the rhodium complex provided an equilibrium mixture of the rhodium complex, pyridine, the diphosphene-phosphineborane ligand, and [Rh(pyridine)2(cod)]BF4

    DOI： 10.1039/d3dt03509c

    PubMed

  • Synthesis and Properties of Optically Active [7]Helicene-Fused Oxanorbornene Polymers by Ring-Opening Metathesis Reviewed

    Kazuki Fujikata, Masayuki Gon, Kazuo Tanaka, Yoshiki Chujo, Akihiro Tsurusaki, Ken Kamikawa

    Macromolecules   56 ( 12 )   4550 - 4555   2023.06（ ISSN:0024-9297 ） （ eISSN:1520-5835 ）

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    Publishing type：Research paper (scientific journal)   International / domestic magazine：International journal  

    Optically active [7]helicene-fused oxanorbornene polymers poly-1 were synthesized by ring-opening-metathesis polymerization (ROMP) of monomer 2, which was easily accessed by [4 + 2] cycloaddition of in situ-generated [7]helicenyl aryne and furan. The optical resolution of rac-2 using a chiral stationary phase afforded optically active (P)-2 and (M)-2. Of the various Grubbs catalysts tested, the first-generation one was found to be optimal for this ROMP. The chiroptical properties of the polymers were studied using circular dichroism and circularly polarized luminescence.

    DOI： 10.1021/acs.macromol.3c00588

  • Rh(I)-Catalyzed Enantioselective Arylation of Cyclic N-Sulfonyl Diketimines Using Planar-Chiral Phosphine-Olefin Ligands Based on a (Cyclopentadienyl)manganese(I) Scaffold with a Highly Fluorinated Aryl Phosphino Group. Reviewed

    Ryosuke Shimamoto, Akihiro Tsurusaki, Ken Kamikawa

    The Journal of organic chemistry   88 ( 12 )   7882 - 7887   2023.02（ ISSN:0022-3263 ）

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    Publishing type：Research paper (scientific journal)   International / domestic magazine：International journal  

    Catalytic enantioselective 1,2-addition reactions of arylboronic acids with 1,2,5-thiadiazoline 1,1-dioxide derivatives were achieved using planar-chiral phosphine-olefin ligand L5 with a bis[(2,3,4,5,6-pentafluoro)phenyl]phosphino group, showing ≤98% ee. The enantioselectivities of the addition products were improved by increasing the number of fluoro substituents on the aromatic ring of the ligand. X-ray crystallographic studies of 3aa and [RhCl/L5]2 revealed the absolute configuration of the enantioenriched addition product 3 and the mode of phosphine-olefin bidentate coordination of L5 to a rhodium(I) cation.

    DOI： 10.1021/acs.joc.2c02930

    PubMed

  • Synthesis, Structures, and Properties of π-Extended Phosphindolizine Derivatives Reviewed

    Akihiro Tsurusaki, Sana Tahara, Makoto Nakamura, Hiroyo Matsumoto, Ken Kamikawa

    Chemistry - A European Journal   29 ( 8 )   e202203321   2023.02（ ISSN:09476539 ） （ eISSN:1521-3765 ）

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    Authorship：Lead author,　Corresponding author   Publishing type：Research paper (scientific journal)   International / domestic magazine：International journal  

    Dibenzo[b,g]phosphindolizine oxide and three types of benzo[e]naphthophosphindolizine oxides have been synthesized by the ring-closing metathesis of benzo[b]phosphole oxide and naphthophosphole oxides with two olefin tethers. Their molecular structures and properties were revealed by X-ray crystallographic analysis, UV-vis spectroscopy, and electrochemical analysis. The number and position of the benzene rings were found to alter the structural geometry and the HOMO/LUMO energy levels, and their effects were investigated by theoretical calculations. Among the phosphindolizine oxide derivatives investigated, only benzo[e]naphtho[2,3-b]phosphindolizine oxide with the naphthalene ring fused at 2,3-positions showed weak yellow fluorescence with a large Stokes shift.

    DOI： 10.1002/chem.202203321

    PubMed

  • Palladium(II) Complexes of Bis(diphosphene) with Different Coordination Behaviors Reviewed

    Rikako Ura, Akihiro Tsurusaki, Ken Kamikawa

    Dalton Transactions   51 ( 7 )   2943 - 2952   2022.02（ ISSN:1477-9226 ） （ eISSN:1477-9234 ）

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)   International / domestic magazine：International journal  

    Organophosphorus compounds possessing a P-P double-bond character are intriguing materials in coordination chemistry because it is possible to form a variety of coordination modes from the π-bond in addition to the lone pairs. We report herein the complexation of a new bidentate ligand, ethylene-tethered bis(binaphthyldiphosphene) (S,S)-2, with palladium(ii) species. The reaction of (S,S)-2 with [Pd(π-allyl)(cod)](SbF6) and PdCl2(cod) afforded η1/η1-bis(diphosphene) complex 7 and η1-diphosphene/η2-phosphanylphosphide complex 8, respectively. The latter was characterized by a chloride migration from the palladium atom to a phosphorus atom due to the high electron-accepting character of the PP moiety. Theoretical calculations revealed the migration process and nature of complex 8.

    DOI： 10.1039/D1DT03806K

    Other URL： https://pubs.rsc.org/en/content/articlelanding/2022/dt/d1dt03806k

  • Multiple Helicenes Featuring Synthetic Approaches and Molecular Structures

    Akihiro Tsurusaki, Ken Kamikawa

    Chemistry Letters   50 ( 11 )   1913 - 1932   2021.11（ ISSN:0366-7022 ） （ eISSN:1348-0715 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1246/cl.210409

  • Transformation from triple helicene to double helicene embedding adjacent stereogenic carbon atoms and axial stereogenicity Reviewed

    Ayaka Yubuta, Akihiro Tsurusaki, Ken Kamikawa

    Chemical Communications 雑誌 Royal Chemical Society   57 ( 54 )   6600 - 6603   2021.07

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    Kind of work：Joint Work  

  • Clusterization Effect on the 29Si NMR Signal of a Spiro Silicon Atom Reviewed

    Akihiro Tsurusaki, Hiroyasu Sato, Soichiro Kyushin

    Organometallics 雑誌 American Chemical Society   40 ( 16 )   2852 - 2858   2021.07

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    Kind of work：Joint Work  

  • Metal-metal multiple bond formation induced by σ-acceptor Lewis acid ligands Reviewed

    Shin Takemoto, Kaname Yoshii, Takahiro Yamano, Akihiro Tsurusaki, Hiroyuki Matsuzaka

    Chemical Communications   57 ( 7 )   923 - 926   2021.01

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    Kind of work：Joint Work  

  • Gold(I)-Catalyzed Intramolecular Hydroarylation of o-Ethynylarylphosphonium Salt Leading to the Formation of Seven- and Six-membered Phosphacycles Reviewed

    Akihiro Tsurusaki, Hiroki Shimatani, Ken Kamikawa

    Asian Journal of Organic Chemistry 雑誌   10 ( 1 )   154 - 159   2021.01

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    Kind of work：Joint Work  

  • Gold(I)‐Catalyzed Intramolecular Hydroarylation of o ‐Ethynylarylphosphonium Salt Leading to the Formation of Seven‐ and Six‐membered Phosphacycles

    Akihiro Tsurusaki, Hiroki Shimatani, Ken Kamikawa

    Asian Journal of Organic Chemistry   10 ( 1 )   154 - 159   2021.01（ ISSN:2193-5807 ） （ eISSN:2193-5815 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/ajoc.202000669

    Other URL： https://onlinelibrary.wiley.com/doi/full-xml/10.1002/ajoc.202000669

  • Transformation from triple helicene to double helicene embedding adjacent stereogenic carbon atoms and axial stereogenicity

    Ayaka Yubuta, Akihiro Tsurusaki, Ken Kamikawa

    Chemical Communications   57 ( 54 )   6600 - 6603   2021（ ISSN:1359-7345 ） （ eISSN:1364-548X ）

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    Publishing type：Research paper (scientific journal)  

    <p>The conjugate addition of alkyl- or aryllithium to the central aromatic ring of triple helicene is described. The obtained double helicene has two helicities along with the two adjacent stereogenic centers and an axial stereogenicity.</p>

    DOI： 10.1039/d1cc02393d

  • Metal–metal multiple bond formation induced by σ-acceptor Lewis acid ligands Reviewed

    Shin Takemoto, Kaname Yoshii, Takahiro Yamano, Akihiro Tsurusaki, Hiroyuki Matsuzaka

    Chemical Communications   2021

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1039/D0CC07278H

  • Assembly of [5]Helicene Subunits by Palladium-Catalyzed Reactions: Synthesis, Structures, Properties, and Theoretical Study of Multiple Helicenes

    Tomoka Hosokawa, Akihiro Tsurusaki, Ken Kamikawa

    Journal of Synthetic Organic Chemistry, Japan   78 ( 11 )   1013 - 1020   2020.11（ ISSN:0037-9980 ） （ eISSN:1883-6526 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.5059/yukigoseikyokaishi.78.1013

  • Synthesis, Structure, and Complexation of an S-Shaped Double Azahelicene with Inner-Edge Nitrogen Atoms.

    Takahiro Kawashima, Yuki Matsumoto, Takuma Sato, Yoichi M A Yamada, Choji Kono, Akihiro Tsurusaki, Ken Kamikawa

    Chemistry (Weinheim an der Bergstrasse, Germany)   26 ( 58 )   13107 - 13107   2020.10

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    Publishing type：Research paper (scientific journal)   International / domestic magazine：International journal  

    Invited for the cover of this issue is Ken Kamikawa and co-workers at Osaka Prefecture University and RIKEN Center for Sustainable Resource Science. The image depicts an S-shaped double azahelicene capturing the palladium in a trans-chelating fashion. Read the full text of the article at 10.1002/chem.202002405.

    DOI： 10.1002/chem.202002901

    PubMed

  • Synthesis, Structure, and Complexation of an S-Shaped Double Azahelicene with Inner-Edge Nitrogen Atoms.

    Takahiro Kawashima, Yuki Matsumoto, Takuma Sato, Yoichi M A Yamada, Choji Kono, Akihiro Tsurusaki, Ken Kamikawa

    Chemistry (Weinheim an der Bergstrasse, Germany)   26 ( 58 )   13170 - 13176   2020.10

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    Publishing type：Research paper (scientific journal)   International / domestic magazine：International journal  

    An S-shaped double azahelicene (1) was synthesized in excellent yield by a palladium-catalyzed double dehydrogenative C-H coupling reaction. The stereochemistry of 1 was confirmed to be dl by single-crystal X-ray diffraction analysis. Selective formation of dl-1 was attributed to the isomerization of the kinetically controlled product (meso-1) into the more thermodynamically stable dl-1 under the applied reaction conditions. dl-1 can coordinate to palladium(II) in a bidentate trans-chelating fashion, which was confirmed by X-ray absorption fine structure (XAFS) as well as by X-ray photoelectron spectroscopy (XPS), diffuse reflectance (DR) UV/Vis, and far-infrared (FIR) absorption spectroscopy. Theoretical calculations of palladium complex 16 revealed a weak attractive interaction between palladium and carbon atoms on the central dimethoxynaphthalene core, which could facilitate a disproportionation between a trans-chelating (dl-1)⋅PdCl2 complex and PdCl2 to form 16.

    DOI： 10.1002/chem.202002405

    PubMed

  • Synthesis, Structure, and Complexation of an S-Shaped Double Azahelicene with Inner-Edge Nitrogen Atoms Reviewed

    Takahiro Kawashima, Yuki Matsumoto, Takuma Sato, Yoichi M. A. Yamada, Choji Kono, Akihiro Tsurusaki, Ken Kamikawa

    Chemistry - A European Journal 雑誌   26 ( 58 )   13170 - 13176   2020.10

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    Kind of work：Joint Work  

  • Enantioselective Synthesis of Triple Helicenes by Cross-Cyclotrimerization of a Helicenyl Aryne and Alkynes via Dynamic Kinetic Resolution Reviewed

    Ayaka Yubuta, Tomoka Hosokawa, Masayuki Gon, Kazuo Tanaka, Yoshiki Chujo, Akihiro Tsurusaki, Ken Kamikawa

    Journal of the American Chemical Society 雑誌   142 ( 22 )   10025 - 10033   2020.06

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    Kind of work：Joint Work  

  • Enantioselective Synthesis of Triple Helicenes by Cross-Cyclotrimerization of a Helicenyl Aryne and Alkynes via Dynamic Kinetic Resolution Reviewed

    Ayaka Yubuta, Tomoka Hosokawa, Masayuki Gon, Kazuo Tanaka, Yoshiki Chujo, Akihiro Tsurusaki, Ken Kamikawa

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   142 ( 22 )   10025 - 10033   2020.06（ ISSN:0002-7863 ） （ eISSN:1520-5126 ）

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    Publishing type：Research paper (scientific journal)  

    Optically active triple helicenes (TH-1) were prepared via a palladium-catalyzed enantioselective cross-cyclotrimerization of two helicenyl arynes 5, which are generated in situ from 3, with dialkyl acetylenedicarboxylate 4. Enantiomeric ratios of up to 98:2 were obtained when using 4a and (S)-QUINAP as the alkyne and chiral ligand, respectively. The absolute stereochemistry of TH-1a was revealed to be (M,P,M) by a single-crystal X-ray diffraction analysis. Kinetic studies of the racemization of enantiomerically pure TH-1a at elevated temperatures were conducted based on a high-performance liquid chromatography analysis. The activation energy for the racemization was found to be 29.1 kcal mol(-1). Density functional theory calculations revealed that the palladium-catalyzed enantioselective cross-cyclotrimerization reactions proceed via the dynamic kinetic resolution of a five-membered palladacycle 6a with two [5]helicenes. Several initially formed stereoisomers of 6a eventually isomerize into the most thermodynamically stable palladacycle intermediate (M,P,M)-6a by inversion of the [5]helicenyl moiety. Then, the insertion of 4 into 6a to form (M,P,M)-12a, followed by a reductive elimination, leads to the formation of (M,P,M)-TH-1a in a stereoselective manner. The optical properties of TH-1a were studied by circular dichroism and circularly polarized luminescence.

    DOI： 10.1021/jacs.0c01723

  • Gold(I) Complex with 1,1’-Binaphthyl-Substituted Diphosphene: Synthesis, Structure, and Catalytic Application to Intramolecular Hydroarylation Reaction Reviewed

    Akihiro Tsurusaki, Rikako Ura, Ken Kamikawa

    Organometallics 雑誌   39 ( 1 )   87 - 92   2020.01

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    Kind of work：Joint Work  

  • A Gold(I) Complex with a 1,1 '-Binaphthyl-Substituted Diphosphene: Synthesis, Structure, and Catalytic Application to Intramolecular Hydroarylation Reactions Reviewed

    Akihiro Tsurusaki, Rikako Ura, Ken Kamikawa

    ORGANOMETALLICS   39 ( 1 )   87 - 92   2020.01（ ISSN:0276-7333 ） （ eISSN:1520-6041 ）

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    Publishing type：Research paper (scientific journal)  

    A gold(I) complex with a 1,1'-binaphthyl-substituted diphosphene was synthesized and fully characterized. A phosphorus atom with a less-hindered binaphthyl group coordinates to a gold(I) moiety in an eta(1) fashion. Both experiment and theoretical calculations supported the facile rotation around the C(Naph)-P bond in neutral and cationic diphosphene-gold(I) complexes. The newly obtained complex 2 was applied to the intramolecular hydroarylation of aryl propynyl ethers 5, and 2H-chromenes 6 were formed in 83-94% yield. Furthermore, the chiral diphosphene-gold(I) complex (S)-2 was used in the atropselective reaction to furnish 6b,c with up to 9% ee, which is the first example of the use of a diphosphene as a ligand for the transition-metal-catalyzed organic transformation.

    DOI： 10.1021/acs.organomet.9b00665

  • Effects of Perpendicular Aryl Groups on Electronic Properties and Complexation of 4,4-Dihydrodithienosilole Reviewed

    Akihiro Tsurusaki, Soichiro Kyushin

    Bulletin of the Chemical Society of Japan 雑誌   92 ( 6 )   039 - 1046   2019.06

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    Kind of work：Joint Work  

  • Effects of Perpendicular Aryl Groups on Electronic Properties and Complexation of 4,4-Dihydrodithienosilole Reviewed

    Akihiro Tsurusaki, Soichiro Kyushin

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   92 ( 6 )   1039 - 1046   2019.06（ ISSN:0009-2673 ） （ eISSN:1348-0634 ）

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    Publishing type：Research paper (scientific journal)  

    4,4-Dihydrodithienosilole bearing perpendicular Tip groups at the 3,5-positions (1) was synthesized. Compound 1 was characterized by NMR, IR, and mass spectroscopy and X-ray crystallography. The lowest energy absorption band in the UV/Vis spectrum is shifted bathochromically compared with the parent 4,4-dihydrodithienosilole II The fluorescence quantum yield of 1 is much higher than that of II The oxidative addition of 1 to Pt(PPh3)(2)(C2H4) gave the isolable silylplatinum hydride complex 7 in contrast to II and a related compound. These results indicate that the Tip groups affect the electronic properties and complexation.

    DOI： 10.1246/bcsj.20190007

  • Dibenzo[b,e]phosphindolizines Synthesized by Ring-Closing Metathesis of Benzo[b]phospholes with Two Vinyl Tethers Reviewed

    Akihiro Tsurusaki, Hiroyo Matsumoto, Ken Kamikawa

    Chemical Communications 雑誌   55 ( 34 )   4909 - 4912   2019.05

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    Kind of work：Joint Work  

  • Dibenzo[b,e]phosphindolizines synthesized by a ring-closing metathesis of benzo[b]phospholes with two vinyl tethers Reviewed

    Akihiro Tsurusaki, Hiroyo Matsumoto, Ken Kamikawa

    CHEMICAL COMMUNICATIONS   55 ( 34 )   4909 - 4912   2019.05（ ISSN:1359-7345 ） （ eISSN:1364-548X ）

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    Publishing type：Research paper (scientific journal)  

    Dibenzo[b, e] phosphindolizines 1 were successfully synthesized by a ring-closing metathesis of benzo[b] phosphole chalcogenides 2a-2c with two vinyl tethers (for chalcogen analogs 1a-1c), and by a deselenization reaction (for lone-pair analog 1d). The structures, properties, and bowl inversion derived from a phosphorus atom were fully investigated.

    DOI： 10.1039/c9cc00463g

  • Synthesis of Substituted Helicenes by Ir-Catalyzed Annulative Coupling of Biarylcarboxylic Acid Chlorides with Alkynes Reviewed

    Ken Kamikawa, Hiroakira Den, Akihiro Tsurusaki, Tomoya Nagata, Masahiro Miura

    Bulletin of the Chemical Society of Japan 雑誌   91 ( 7 )   1069 - 1074   2018.07

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    Kind of work：Joint Work  

  • Reaction of N,N’-dimethylformamide and divalent viologen molecule to generate an organic dopant for molybdenum disulfide Reviewed

    Akito Fukui, Kohei Miura, Hisashi Ichimiya, Akihiro Tsurusaki, Kento Kariya, Takeshi Yoshimura, Atsushi Ashida, Norifumi Fujimura, Daisuke Kiriya

    AIP Advances 雑誌   8   2018.05

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    Kind of work：Joint Work  

  • 1,1’-Binaphthyl-substituted diphosphene: synthesis, structures, and chiral optical properties Reviewed

    Akihiro Tsurusaki, Rikako Ura, Ken Kamikawa

    Dalton Transactions 雑誌   47 ( 13 )   4437 - 4441   2018.04

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    Kind of work：Joint Work  

  • Synthesis, Structures, and Properties of Hexapole Helicenes: Assembling Six [5]Helicene Substructures into Highly Twisted Aromatic Systems Reviewed

    Tomoka Hosokawa, Yusuke Takahashi, Tomoya Matsushima, Soichiro Watanabe, Shoko Kikkawa, Isao Azumaya, Akihiro Tsurusaki, Ken Kamikawa

    Journal of the American Chemical Society 雑誌   139 ( 51 )   18512 - 18521   2017.09

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    Kind of work：Joint Work  

  • Synthesis and structures of lithium alkoxytris(dimethylphenylsilyl)borates Reviewed

    Akihiro Tsurusaki, Keisuke Yoshida, Soichiro Kyushin

    Dalton Transactions 雑誌   46 ( 27 )   8705 - 8708   2017.07

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    Kind of work：Joint Work  

  • Synthesis, Structures, and Electronic Properties of Dithienosiloles Bearing Bulky Aryl Groups: Conjugation between a pi-Electron System and “Perpendicular” Aryl Groups Reviewed

    Akihiro Tsurusaki, Atsushi Kobayashi, Soichiro Kyushin

    Asian Journal of Organic Chemistry 雑誌   6 ( 6 )   737 - 745   2017.06

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    Kind of work：Joint Work  

  • Aqueous phase homogeneous formic acid disproportionation into methanol Reviewed

    Katerina Sordakis, Akihiro Tsurusaki, Masayuki Iguchi, Hajime Kawanami, Yuichiro Himeda, Gábor Laurenczy

    Green Chemistry 雑誌   19 ( 10 )   2371 - 2378   2017.05

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    Kind of work：Joint Work  

  • Decasilahexahydrotriquinacene and Decasilaisotwistane: sigma Conjugation on a Bowl Surface Reviewed

    Akihiro Tsurusaki, Yu Koyama, Soichiro Kyushin

    Journal of the American Chemical Society 雑誌   139 ( 11 )   3982 - 3985   2017.03

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    Kind of work：Joint Work  

  • Investigation of Hydrogenation of Formic Acid to Methanol using H2 or Formic Acid as a Hydrogen Source Reviewed

    Akihiro Tsurusaki, Kazuhisa Murata, Naoya Onishi, Katerina Sordakis, Gábor Laurenczy, Yuichiro Himeda

    ACS Catalysis 雑誌   7 ( 2 )   1123 - 1131   2017.02

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    Kind of work：Joint Work  

  • Carbon Dioxide to Methanol: The Aqueous Catalytic Way at Room Temperature Reviewed

    Katerina Sordakis, Akihiro Tsurusaki, Masayuki Iguchi, Hajime Kawanami, Yuichiro Himeda, Gábor Laurenczy

    Chemistry − A European Journal 雑誌   22 ( 44 )   15605 - 15608   2016.10

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    Kind of work：Joint Work  

  • Direction to practical production of hydrogen by formic acid dehydrogenation with Cp*Ir complexes bearing imidazoline ligands Reviewed

    Naoya Onishi, Mehmed Z. Ertem, Shaoan Xu, Akihiro Tsurusaki, Yuichi Manaka, James T. Muckerman, Etsuko Fujita, Yuichiro Himeda

    Catalysis Science & Technology 雑誌   4 ( 4 )   988 - 992   2016.02

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    Kind of work：Joint Work  

  • The Radical Anion of Cyclopentasilane-Fused Hexasilabenzvalene Reviewed

    Akihiro Tsurusaki, Soichiro Kyushin

    Chemistry − A European Journal 雑誌   22 ( 1 )   134 - 137   2016.01

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    Kind of work：Joint Work  

  • Efficient Cp*Ir Catalysts with Imidazoline Ligands for CO2 Hydrogenation Reviewed

    Shaoan Xu, Naoya Onishi, Akihiro Tsurusaki, Yuichi Manaka, Wan-Hui Wang, James T. Muckerman, Etsuko Fujita, Yuichiro Himeda

    European Journal of Inorganic Chemistry 雑誌   ( 34 )   5591 - 5594   2015.12

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    Kind of work：Joint Work  

  • Tetrasilane-Bridged Bicyclo[4.1.0]heptasil-1(6)-ene Reviewed

    Akihiro Tsurusaki, Jun Kamiyama, Soichiro Kyushin

    Journal of the American Chemical Society 雑誌   136 ( 37 )   12896 - 12898   2014.10

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    Kind of work：Joint Work  

  • Two Pentasilahousanes Fused Together Reviewed

    Akihiro Tsurusaki, Makoto Koganezono, Kyohei Otsuka, Shintaro Ishida, Soichiro Kyushin

    Chemistry − A European Journal 雑誌   20 ( 30 )   9263 - 9266   2014.07

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    Kind of work：Joint Work  

  • Synthesis and Structure of a 1-Phospha-2-boraacenaphthene Derivative and Its Chalcogenation Reactions Reviewed

    Akihiro Tsurusaki, Takahiro Sasamori, Norihiro Tokitoh

    Chemistry − A European Journal 雑誌   20 ( 13 )   3752 - 3758   2014.03

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    Kind of work：Joint Work  

  • Cyclopentasilane-fused Hexasilabenzvalene Reviewed

    Akihiro Tsurusaki, Chisato Iizuka, Kyohei Otsuka, Soichiro Kyushin

    Journal of the American Chemical Society 雑誌   135 ( 44 )   16340 - 16343   2013.10

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    Kind of work：Joint Work  

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MISC

  • Multiple Helicenes Featuring on the Synthetic Approaches and Molecular Structures Reviewed

    Akihiro Tsurusaki, Ken Kamikawa

    The Chemical Society of Japan Chemistry Letters   50 ( 11 )   2021.09

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  • Assembly of [5]Helicene Subunits by Palladium-Catalyzed Reactions: Synthesis, Structures, Properties, and Theoretical Study of Multiple Helicenes Reviewed

    Tomoka Hosokawa, Akihiro Tsurusaki, Ken Kamikawa

    有機合成化学協会誌   78 ( 11 )   1013 - 1020   2020.11

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  • 遠隔位にC2キラル部位を導入した金(I)触媒によるエナンチオ選択的環化異性化反応 Reviewed

    津留﨑陽大

    Organometallic News   1   2020.03

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Presentations

  • 金(I)触媒を用いたビアリールビス(フェニルエチニル)ホスフィン誘導体の分子内ヒドロアリール化反応 Domestic conference

    小村 明寛・岸本 真理衣・津留崎 陽大・神川 憲

    日本化学会第104春季年会(2024)  2024.03 

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    Presentation type：Oral presentation (general)  

    Venue：日本大学理工学部  

  • ジホスフェン－ホスフィンボラン配位子を有するロジウム錯体の合成と反応性 Domestic conference

    津留崎　陽大・武智　紳吾・神川　憲

    第50回有機典型元素化学討論会  2023.12 

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    Presentation type：Oral presentation (general)  

    Venue：レイボックホール(市民会館おおみや)  

  • 新規ケイ素クラスターの開発 Invited Domestic conference

    津留﨑 陽大

    第27回ケイ素化学協会シンポジウム  2023.11 

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    Presentation type：Oral presentation (invited, special)  

    Venue：ラフォーレ那須  

  • 特異な有機リン化合物の開発 Invited Domestic conference

    津留崎陽大

    第12回化学フロンティア研究会  2023.10 

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    Presentation type：Oral presentation (invited, special)  

    Venue：名古屋大学  

  • アリール縮環ホスフィノリジン誘導体の合成と性質 Domestic conference

    荒木 美沙・津留崎 陽大・神川 憲

    第33回基礎有機化学討論会  2023.09 

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    Presentation type：Poster presentation  

    Venue：岡山コンベンションセンター  

  • 環縮合位にリン原子を有する縮環ホスファフェナレンの合成と性質 Domestic conference

    荒木 美沙・西本 聡一郎・津留崎 陽大・神川 憲

    日本化学会第103春季年会(2023)  2023.03 

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    Presentation type：Oral presentation (general)  

    Venue：東京理科大学  

  • クロロ置換ジベンゾホスフィンドリジンの変換反応 Domestic conference

    中村 誠・津留崎 陽大・神川 憲

    第49回有機典型元素化学討論会  2022.12 

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    Presentation type：Poster presentation  

    Venue：富山大学  

  • 金(I)触媒を用いた分子内ヒドロアリール化反応によるホスフェピン誘導体の合成 Domestic conference

    岸本 真理衣・津留崎 陽大・神川 憲

    第49回有機典型元素化学討論会  2022.12 

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    Presentation type：Oral presentation (general)  

    Venue：富山大学  

  • π拡張ホスフィンドリジン誘導体の合成と性質 Domestic conference

    津留崎 陽大・田原 紗奈・中村 誠・松本 啓世・神川 憲

    第32回基礎有機化学討論会  2022.09 

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    Presentation type：Oral presentation (general)  

    Venue：京都パルスプラザ  

  • ヘリセニルアラインとベンザインの交差[2+2+2]環化三量化によるシリルおよびトリフラート置換五重ヘリセンの合成 Domestic conference

    太中 惇斗・細川 朋佳・津留崎 陽大・神川 憲

    第68回有機金属化学討論会  2022.09 

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    Presentation type：Poster presentation  

    Venue：オンライン  

  • 異なる配位様式をとるビス(ジホスフェン)パラジウム(II)錯体 Domestic conference

    津留崎 陽大・浦 里華子・神川 憲

    第68回有機金属化学討論会  2022.09 

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    Presentation type：Poster presentation  

    Venue：オンライン  

  • 1,1’-ビナフチル基およびテルアリール基を有するジホスフェン－金(I)錯体の合成 Domestic conference

    細見 陸広、浦 里華子、津留崎 陽大、神川 憲

    日本化学会第102春季年会(2022)  2022.03 

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    Presentation type：Oral presentation (general)  

    Venue：オンライン  

  • ジホスフェン含有二座配位子の合成と錯形成 Domestic conference

    井戸　愛美香、武智　紳吾、津留崎　陽大、神川　憲

    日本化学会第102春季年会(2022)  2022.03 

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    Presentation type：Poster presentation  

  • 金(I)触媒を用いた分子内ヒドロアリール化反応による環状リン化合物の合成 Domestic conference

    岸本 真理衣、浦 里華子、津留崎 陽大、神川 憲

    日本化学会第102春季年会(2022)  2022.03 

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    Presentation type：Oral presentation (general)  

  • ジホスフェン-ホスフィンボラン二座配位子を有するロジウム錯体の合成とその触媒反応 Domestic conference

    津留崎 陽大、武智 紳吾、神川 憲

    第67回有機金属化学討論会  2021.09 

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    Presentation type：Poster presentation  

  • 1,1’-ビナフチル基を有する架橋型ビスジホスフェン二座配位子の合成 Domestic conference

    浦　里華子・津留崎　陽大・神川　憲

    日本化学会第100春季年会(2020)  2020.03 

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    Presentation type：Oral presentation (general)  

  • ナフタレン縮環ホスフィンドリジン誘導体の合成と性質 Domestic conference

    田原　紗奈・松本　啓世・津留崎　陽大・神川　憲

    日本化学会第100春季年会(2020)  2020.03 

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    Presentation type：Oral presentation (general)  

  • リン原子を有する新しい配位子とπ共役分子の開発 Invited Domestic conference

    津留崎陽大

    滋賀県立大学工学部材料科学セミナー  2020.01 

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    Presentation type：Oral presentation (invited, special)  

  • ジホスフェンを有する二座配位子の合成 Domestic conference

    武智　紳吾・津留崎　陽大・神川　憲

    第46回典型元素化学討論会  2019.12 

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    Presentation type：Poster presentation  

  • 6つの[5]ヘリセン構造を有する六重ヘリセンの合成、構造、および理論化学的考察 Domestic conference

    細川　朋佳、麻田　俊雄、津留崎　陽大、神川　憲

    第66回有機金属化学討論会  2019.09 

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    Presentation type：Oral presentation (general)  

  • Rh触媒不斉開環反応による面不斉フェロセン錯体の触媒的不斉合成 Domestic conference

    磯田　隆夢、津留崎　陽大、神川　憲

    第66回有機金属化学討論会  2019.09 

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    Presentation type：Poster presentation  

  • 1,1’-ビナフチル置換ジホスフェン-金(I)錯体による分子内ヒドロアリール化反応 Domestic conference

    浦　里華子、津留崎　陽大、神川　憲

    第66回有機金属化学討論会  2019.09 

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    Presentation type：Poster presentation  

  • π共役拡張ホスフィンドリジン誘導体の合成・構造・性質

    田原　紗奈、松本　啓世、津留崎　陽大、神川　憲

    第30回基礎有機化学討論会  2019.09 

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    Presentation type：Poster presentation  

  • ジホスフェンを配位子とする後周期遷移金属錯体の合成と触媒反応 Domestic conference

    浦　里華子、津留崎 陽大、神川 憲

    第122回触媒討論会  2018.09 

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    Presentation type：Oral presentation (general)  

  • Synthesis and Structures of 1,1’-Binaphthyl-Substituted Diphosphene and its Gold(I) Complex International conference

    Rikako Ura, Akihiro Tsurusaki, Ken Kamikawa

    The 4th Joint Symposium of NTUT, NTNU, and OPU on Chemistry  2018.04 

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    Presentation type：Oral presentation (general)  

  • Ring-Closing Metathesis of Arylphosphines with Vinyl Groups at ortho Position International conference

    Hiroki Shimatani, Akihiro Tsurusaki, Ken Kamikawa

    The 4th Joint Symposium of NTUT, NTNU, and OPU on Chemistry  2018.04 

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    Presentation type：Poster presentation  

  • Synthesis of Dibenzo[b,e]phosphindolizine-4-chalcogenides International conference

    Hiroyo Matsumoto, Akihiro Tsurusaki, Ken Kamikawa

    The 4th Joint Symposium of NTUT, NTNU, and OPU on Chemistry  2018.04 

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    Presentation type：Poster presentation  

  • ジベンゾ[b,e]ホスフィンドリジン-4-スルフィドの合成 Domestic conference

    松本　啓世・津留崎　陽大・神川　憲

    日本化学会第98春季年会(2018)  2018.03 

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    Presentation type：Poster presentation  

  • 軸不斉ビナフチル置換ジホスフェンの光学特性 Domestic conference

    浦 里華子・津留崎 陽大・神川 憲

    日本化学会第98春季年会(2018)  2018.03 

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    Presentation type：Oral presentation (general)  

  • トリス(2,6-ジビニルフェニル)ホスフィンの閉環メタセシス反応 Domestic conference

    嶋谷　洋輝・津留崎　陽大・神川　憲

    日本化学会第98春季年会(2018)  2018.03 

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    Presentation type：Poster presentation  

  • Synthesis and Structures of 1,1’-Binaphthyl-Substituted Diphosphene and its Gold(I) Complex International conference

    Rikako Ura, Akihiro Tsurusaki, Ken Kamikawa

    Joint Symposium of Asia Five Universities  2017.11 

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    Presentation type：Poster presentation  

  • 1,1'-ビナフチル置換ジホスフェンとその金(I)錯体の合成と構造 Domestic conference

    浦 里華子・津留崎 陽大・神川 憲

    第64回有機金属化学討論会  2017.09 

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    Presentation type：Poster presentation  

  • 1,1'-ビナフチル置換ジホスフェンの合成 Domestic conference

    浦 里華子・津留崎 陽大・神川 憲

    日本化学会第97春季年会(2017)  2017.03 

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    Presentation type：Poster presentation  

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Grant-in-Aid for Scientific Research

  • 高活性・高選択的な遷移金属触媒反応を実現するジホスフェン配位子の開発

    Grant-in-Aid for Scientific Research(C)  2021

  • ホスフィンドリジン誘導体の開発

    Grant-in-Aid for Scientific Research(C)  2018

  • 超電子受容性ジホスフェン配位子の開発および光学活性らせん分子合成への応用

    Grant-in-Aid for Research Activity Start-up  2016

Charge of on-campus class subject

  • 化学実験1

    2024   Weekly class   Undergraduate

  • 化学特別演習2A

    2024   Intensive lecture   Graduate school

  • 化学特別演習1A

    2024   Intensive lecture   Graduate school

  • 化学特別研究2A

    2024   Intensive lecture   Graduate school

  • 化学特別研究1A

    2024   Intensive lecture   Graduate school

  • 研究企画ゼミナール

    2024   Intensive lecture   Graduate school

  • 化学特別演習5A

    2024   Intensive lecture   Graduate school

  • 化学特別演習4A

    2024   Intensive lecture   Graduate school

  • 化学特別演習3A

    2024   Intensive lecture   Graduate school

  • 化学特別研究5A

    2024   Intensive lecture   Graduate school

  • 化学特別研究4A

    2024   Intensive lecture   Graduate school

  • 化学特別研究3A

    2024   Intensive lecture   Graduate school

  • 化学実験Ⅱ

    2024   Weekly class   Undergraduate

  • 化学実験Ⅰ

    2024   Weekly class   Undergraduate

  • 有機化学特論

    2023   Weekly class   Graduate school

  • 研究企画ゼミナール

    2023   Intensive lecture   Graduate school

  • 科学英語

    2023   Weekly class   Undergraduate

  • 有機化学演習II

    2023   Weekly class   Undergraduate

  • 分子科学実験I

    2023   Weekly class   Undergraduate

  • 有機化学IV

    2023   Weekly class   Undergraduate

  • 科学英語

    2022   Weekly class   Undergraduate

  • 研究企画ゼミナール

    2022   Intensive lecture   Graduate school

  • 有機化学特論

    2022   Weekly class   Graduate school

  • 有機化学IV

    2022   Weekly class   Undergraduate

  • 分子科学実験I

    2022   Weekly class   Undergraduate

  • 有機化学演習II

    2022   Weekly class   Undergraduate

  • Chemistry Laboratory I

    2021   Practical Training  

  • Organic Chemistry IV

    2021    

  • Exercises in Organic Chemistry II

    2021    

  • English for Scientists

    2021    

  • Laboratory Chemistry

    2021   Practical Training  

  • Chemistry Laboratory I

    2020   Practical Training  

  • Exercises in Organic Chemistry II

    2020    

  • Laboratory Chemistry

    2020   Practical Training  

  • Chemistry Laboratory II

    2020   Practical Training  

  • Laboratory Chemistry

    2019   Practical Training  

  • Exercises in Organic Chemistry II

    2019    

  • Laboratory Chemistry

    2018   Practical Training  

  • Exercises in Organic Chemistry II

    2018    

  • Chemistry Laboratory II

    2017   Practical Training  

▼display all