2024/03/06 更新

写真a

スズキ ヤスヒト
鈴木 祥仁
Suzuki Yasuhito
担当
大学院工学研究科 物質化学生命系専攻 准教授
工学部 応用化学科
職名
准教授
所属
工学研究院

担当・職階

  • 大学院工学研究科 物質化学生命系専攻 

    准教授  2023年04月 - 継続中

  • 工学部 応用化学科 

    准教授  2023年04月 - 継続中

取得学位

  • 博士 ( マインツ大学(ドイツ) )

研究分野

  • ナノテク・材料 / 高分子化学

  • ナノテク・材料 / 高分子材料

  • ナノテク・材料 / 高分子化学

研究キーワード

  • 高分子材料

  • 高分子化学

  • 結晶

  • 界面

  • 力学物性

  • ガラス

研究概要

  • 高分子化学

  • 高分子ダイナミクス・緩和

  • バルク重合

研究歴

  • バルク重合中の熱暴走の理解と制御

    トロムスドルフ効果、重合誘起相分離、ガラス化  個人研究

    2018 - 継続中 

  • 重合誘起相分離を利用した機能性材料開発

    重合誘起相分離、PMMA、モノリス 

    2018 - 継続中 

  • 剛直高分子のβ緩和挙動

    β緩和、誘電緩和、ポリフマル酸エステル 

    2018 - 継続中 

所属学協会

  • 高分子学会

    2018年04月 - 継続中   国内

  • 一般社団法人日本レオロジー学会

    2020年04月 - 継続中   国内

  • アメリカ化学会

    2018年04月 - 継続中   国外

  • 接着学会

    2018年04月 - 継続中   国内

委員歴(学外)

  • コンテンツ委員会委員   一般社団法人 日本接着学会  

    2022年08月 - 継続中 

  • 接着の技術誌 編集委員   一般社団法人 日本接着学会  

    2022年08月 - 継続中 

  • 関西支部 若手研究会 幹事   公益社団法人 高分子学会  

    2020年04月 - 継続中 

  • 関西支部 若手の会 幹事   一般社団法人 日本接着学会  

    2019年04月 - 継続中 

受賞歴

  • 2023年度大阪公立大学若手研究者奨励賞 基礎科学部門

    2023年08月   大阪公立大学  

  • 高分子研究奨励賞

    2022年03月   公益財団法人 高分子学会   ガラス化近傍における局所的高分子ダイナミクスの解析と制御

  • 日本接着学会 奨励賞

    2021年06月   日本接着学会  

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    受賞国:日本国

  • Polymer Journal論文賞-日本ゼオン賞

    2020年05月   公益社団法人 高分子学会  

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    受賞国:日本国

職務経歴(学外)

  • 大阪公立大学大学院, 工学研究科, 准教授

    2023年04月 - 継続中

  • 大阪公立大学大学院, 工学研究科, 助教

    2022年04月 - 2023年03月

  • 大阪府立大学大学院, 工学研究科, 助教

    2018年04月 - 2021年03月

論文

  • Study on the deformation and fracture of epoxy monoliths through mechanical tensile and compressive tests and X-ray CT imaging

    Aragishi K.

    Polymer Journal   2024年02月( ISSN:00323896

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  • マレイミドベンゾオキソジンとチオール変性シルセスキオキサンの付加物から得られる熱硬化物の熱および機械的性質

    杉浦幹太, 鈴木祥仁, 松本章一

    日本接着学会誌   2024年01月

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    国際・国内誌:国内誌  

  • Fabrication of a BOC-Protected 2-Hydroxyethyl Methacrylate Brush and Deprotection of the BOC Group to Control the Surface Hydrophilicity

    Suzuki Y.

    Langmuir   39 ( 48 )   17216 - 17221   2023年12月( ISSN:07437463

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    担当区分:筆頭著者, 責任著者  

    DOI: 10.1021/acs.langmuir.3c02259

    PubMed

  • ポリフマル酸エステルのβ緩和 査読

    鈴木祥仁, 松本章一

    日本接着学会誌   2023年12月

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    担当区分:筆頭著者, 責任著者  

  • Synthesis of thermosets from maleimidobenzoxazines and tetrafunctional thiols and their thermal and mechanical properties

    Takasu M.

    Polymer Journal   56 ( 1 )   17 - 30   2023年10月( ISSN:00323896

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1038/s41428-023-00841-1

  • マレイミド共重合体のエステル交換反応とチオール・エン反応による耐熱透明ポリマー材料の合成

    山本紘希, 鈴木祥仁, 松本章一

    日本接着学会誌   2023年10月

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    国際・国内誌:国内誌  

  • Effect of adding lithium chloride on the radical copolymerization of lithium p-styrenesulfonate and acrylamide

    Uesaka H.

    Polymer Journal   55 ( 10 )   1057 - 1066   2023年10月( ISSN:00323896

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1038/s41428-023-00802-8

  • Radical copolymerization of lithium p-styrenesulfonate followed by homopolymerization of a less-reactive comonomer with spontaneous delay

    Uesaka H.

    Polymer   283   2023年09月( ISSN:00323861

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  • Heterogeneities at the Onset of Reaction Acceleration during Bulk Polymerization of Methyl Methacrylate Investigated by Small-Angle Neutron Scattering

    Suzuki Y.

    Macromolecules   56 ( 10 )   3731 - 3738   2023年05月( ISSN:0024-9297

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    担当区分:筆頭著者, 責任著者   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/acs.macromol.3c00176

  • Comparative Study of PEG and PEGylated Dendrimer in Their Eutectic Mixtures of Water Analyzed Using X-ray Diffraction and Infrared Spectroscopy 査読

    C. Kojima, Y. Suzuki, Y. Ikemoto, M. Tanaka, and A. Matsumoto

    Polym. J.   55 ( 1 )   63 - 73   2023年03月

  • Analysis of Glass Effect and Trommsdorff Effect during Bulk Polymerization of Methyl Methacrylate, Ethyl Methacrylate, and Butyl Methacrylate 査読

    Y. Suzuki, R. Mishima, E. Kato, and A. Matsumoto

    Polym. J.   53 ( 3 )   229 - 238   2023年03月( ISSN:0032-3896

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    担当区分:筆頭著者, 責任著者   掲載種別:研究論文(学術雑誌)  

    It has been reported that the hydration state of biocompatible polymers, such as poly(ethylene glycol) (PEG), affects their bioinertness. PEGylated dendrimers have been studied for use as drug carriers. In our previous study, the hydration behaviors of PEG and PEGylated dendrimers were analyzed using differential scanning calorimetry (DSC) to investigate the relationship between hydration and in vivo behaviors. In this study, the hydration behaviors of PEG and PEGylated dendrimer were analyzed using X-ray diffraction (XRD) and infrared (IR) spectroscopy. According to the XRD analysis, ice was formed and melted in the PEG/water mixture with a 20% water content below 0 degrees C during the heating process; however, PEG crystals were formed in the PEG/water mixture containing 70% water. The XRD and IR results of the PEGylated dendrimer/water mixture were similar to those of the PEG/water system containing 70% water. Our IR spectral studies indicated that the hydration state of the PEGylated dendrimer was different from that of PEG containing 20% water. These results suggested that a comprehensive study is important for the analysis of such eutectic mixtures of PEG compounds and water.

    DOI: 10.1038/s41428-022-00700-5

  • Polymerization-Induced Vitrification, Apparent Phase Separation, and Reaction Acceleration during Bulk Polymerization 招待 査読

    Y. Suzuki

    Polym. J.   2023年03月

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    担当区分:筆頭著者, 最終著者, 責任著者   掲載種別:研究論文(学術雑誌)   国際・国内誌:国際誌  

  • 分子内および分子間水素結合を有するポリジアセチレンの色調変化と熱安定性

    中村純也, 畑 敏達, 鈴木祥仁, 松本章一

    色材協会誌   2023年02月

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    国際・国内誌:国内誌  

  • Precise control of thermal deprotection behavior and dismantlable adhesion property of the acrylate copolymers containing BOC-protected hydroxy group

    Sakamoto T.

    Polymer   262   125416   2022年12月( ISSN:0032-3861

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.polymer.2022.125416

  • Non-destructive Observation of Internal Structures of Epoxy Monolith and Co-continuous Network Polymer Using X-ray CT Imaging for Elucidation of Their Unique Mechanical Features and Fracture Mechanism 査読

    Tominaga R.

    Polymer   263   125433   2022年12月( ISSN:0032-3861

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.polymer.2022.125433

  • Relaxation and Amorphous Structure of Polymers Containing Rigid Fumarate Segments 査読

    Suzuki Y.

    Polymers   14 ( 22 )   4876   2022年11月

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    担当区分:筆頭著者, 責任著者   掲載種別:研究論文(学術雑誌)  

    DOI: 10.3390/polym14224876

    PubMed

  • Microporous Structure Formation of Poly(methyl methacrylate) via Polymerization-Induced Phase Separation in the Presence of Poly(ethylene glycol) 査読

    Suzuki Y.

    ACS Omega   7 ( 43 )   38933 - 38941   2022年10月( ISSN:2470-1343

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    担当区分:筆頭著者, 責任著者   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/acsomega.2c04690

    PubMed

  • バルク重合中の反応加速(トロムスドルフ効果)に関する新展開 査読

    鈴木祥仁

    日本接着学会誌 雑誌   2022年04月

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    共著区分:単著  

  • Dielectric Relaxation and Glassy Dynamics in Poly(diisopropyl fumarate) and its Copolymers with Acrylate Segments

    Polymer   245   124671   2022年04月( ISSN:0032-3861

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.polymer.2022.124671

  • RAFT Polymerization of 2-(tert-Butoxycarbonyloxy)Ethyl Methacrylate and Transformation to Functional Polymers via Deprotection and the Subsequent Polymer Reactions

    Chu Jing, Kaito Osada, Chie Kojima, Yasuhito Suzuki, Akikazu Matsumoto

    MACROMOLECULAR CHEMISTRY AND PHYSICS   223 ( 1 )   2022年01月( ISSN:1022-1352

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    掲載種別:研究論文(学術雑誌)  

    Reversible addition-fragmentation chain transfer (RAFT) polymerization of 2-(tert-butoxycarbonyloxy)ethyl methacrylate (BHEMA) is carried out using 4-cyano-4-((dodecylsulfanylthiocarbonyl)sulfanyl)pentanoic acid as the RAFT agent. The polymers with a controlled molecular weight and polydispersity are produced when a large amount of the RAFT agent is used. The RAFT polymerization of isobutyl methacrylate is also carried out using poly(2-(tert-butoxycarbonyloxy)ethyl methacrylate) (PBHEMA) as the macro-RAFT agent in order to synthesize diblock copolymers with a narrow molecular weight distribution. It is revealed that the control of the polymerization of BHEMA is achieved under limited polymerization conditions. Then, the acid-catalyzed deprotection of tert-butoxycarbonyloxy groups of PBHEMA is performed in the presence of trifluoroacetic acid at room temperature to obtain polymers with a hydroxy group in the side chain. The hydroxy-containing polymers are further reacted with 2-isocyanatoethyl acrylate and methacrylate to synthesize precursor polymers used for a thermally curing system.

    DOI: 10.1002/macp.202100336

  • Co-continuous network polymers using epoxy monolith for the design of tough materials

    11 ( 1 )   2021年12月( ISSN:2045-2322

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1038/s41598-021-80978-2

    PubMed

    その他URL: http://www.nature.com/articles/s41598-021-80978-2

  • チオール変性ランダム型シルセスキオキサンとN-アリルマレイミド共重合体のチオール-エン反応による耐熱透明ポリマー材料の設計 査読

    山本紘希, 鈴木祥仁, 松本章一

    ネットワークポリマー論文集 雑誌   2021年11月

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    共著区分:共著  

  • Controlled Deprotection of Poly(2-(tert-butoxycarbonyloxy)ethyl methacrylate) Using p-Toluenesulfonic Esters as Thermally Latent Acid Catalysts 査読

    K. Osada, R. Akahori, Y. Suzuki, and A. Matsumoto

    Polym. Degrad. Stab.   205   110127   2021年11月( ISSN:0141-3910

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.polymdegradstab.2022.110127

  • Bulk Polymerization Kinetics of Methyl Methacrylate at Broad Temperature Range Investigated by Differential Scanning Calorimetry 査読

    54 ( 6 )   361 - 370   2021年11月( ISSN:0538-8066

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    担当区分:筆頭著者, 責任著者   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/kin.21564

  • Characteristic Features of α and β Relaxations of Poly(diethyl fumarate) as the Poly(substituted methylene)

    222 ( 16 )   2100124 - 2100124   2021年07月( ISSN:1022-1352

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/macp.202100124

    その他URL: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/macp.202100124

  • Polymerization-Induced Vitrification and Kinetic Heterogenization at the Onset of the Trommsdorff Effect

    Yasuhito Suzuki, Yuya Shinagawa, Eri Kato, Ryutaro Mishima, Koji Fukao, Akikazu Matsumoto

    MACROMOLECULES   54 ( 7 )   3293 - 3303   2021年04月( ISSN:0024-9297

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    掲載種別:研究論文(学術雑誌)  

    The reaction kinetics during bulk free radical polymerization is still not fully understood. As the reaction proceeds, many parameters, including monomer/polymer fraction, radical concentration, viscosity, and temperature, change in a non-equilibrium manner. In this study, we investigate the bulk polymerization of methyl methacrylate, focusing on a sudden acceleration in reaction kinetics known as the Trommsdorff effect. Dielectric spectroscopy shows that a temperature increase occurs at the vicinity of polymerization-induced vitrification. At the same timing as the temperature increase, the polymerization solution becomes heterogeneous. This heterogenization causes a decrease in transmittance at a wavelength of 400 nm. We discuss phenomena related to the Trommsdorff effect, including the kinetic heterogenization, vitrification, change in the amorphous structure, and the formation of discontinuously high-molecular-weight polymers.

    DOI: 10.1021/acs.macromol.0c02260

  • Co-continuous Network Polymers Using Epoxy Monolith for the Design of Tough Materials 査読

    R. Tominaga, Y. Nishimura, Y. Suzuki, Y. Takeda, M. Kotera, and A. Matsumoto

    Scientific reports 雑誌   2021年01月

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    共著区分:共著  

  • Interfacial Structure Control and Three-Dimensional X-ray Imaging of an Epoxy Monolith Bonding System with Surface Modification 査読

    Nanako Sakata, Yoshihiro Takeda, Masaru Kotera, Yasuhito Suzuki, Akikazu Matsumoto

    Langmuir   36 ( 37 )   10923 - 10932   2020年09月( ISSN:0743-7463

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    掲載種別:研究論文(学術雑誌)  

    Copyright © 2020 American Chemical Society. A monolith bonding system has a high reliability for dissimilar material bonding. The epoxy monolith layer fabricated on a substrate guarantees bond strength by the anchor effect, regardless of the compatibility of the used materials. Designing a high-performance monolith bonding system requires the suppression of an interfacial failure between the monolith and the substrate. In this study, silane and phosphine coupling agents containing amino and epoxy groups were used to construct a robust interfacial structure between the monolith and the substrates such as glass and metals. The internal and interfacial monolith structures were characterized by three-dimensional X-ray imaging as a nondestructive observation method in addition to the scanning electron microscopy of the sample cross sections. The modification of the substrate-monolith interface using the coupling agents improved the strength of dissimilar material bonding of the glass and metal substrates in combination with thermoplastic resins such as poly(ethylene terephthalate) and polycarbonate bisphenol-A.

    DOI: 10.1021/acs.langmuir.0c01481

    PubMed

  • Interfacial Structure Control and Three-Dimensional X-ray Imaging of an Epoxy Monolith Bonding System with Surface Modification

    N. Sakata, Y. Takeda, M. Kotera, Y. Suzuki, A. Matsumoto

    Langmuir   2020年08月

  • One-shot Radical Polymerization of Conjugated and Non-conjugated Monomers Accompanying Spontaneous Delay of Polymerization for the Synthesis of Double Network Hydrogels

    S. Dohi, Y. Suzuki, A. Matsumoto

    Polym. Int.   2020年05月

  • Relaxation behavior of poly(diisopropyl fumarate) including no methylene spacer in the main chain 査読

    Yasuhito Suzuki, Kairi Miyata, Masashi Sato, Nagisa Tsuji, Koji Fukao, Akikazu Matsumoto

    Polymer   196   122479 - 122479   2020年05月( ISSN:0032-3861

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    掲載種別:研究論文(学術雑誌)  

    © 2020 Elsevier Ltd Poly(diisopropyl fumarate) (PDiPF) has dynamic mechanical properties different from the relaxation processes of conventional vinyl polymers, due to the absence of a methylene spacer in the main chain. In this study, we investigated the relaxation behavior of PDiPF using dielectric spectroscopy (DS), differential scanning calorimetry (DSC), wide angle X-ray scattering (WAXS), and dynamic mechanical analysis (DMA). We have demonstrated that the β relaxation of PDiPF has unusual characteristics originating from the absence of a methylene spacer; for example, the β relaxation of PDiPF follows the Vogel–Fulcher–Tammann (VFT) equation, causes a clear step in the DSC curve, and enhances the microscopic packing of the polymer chains in the solid state. These β relaxation behaviors of PDiPF reflect the enlarged cooperative rearranging region (CRR).

    DOI: 10.1016/j.polymer.2020.122479

  • Synthesis of Heat‐resistant Polymers by Thiol–Ene Reaction of N ‐Allylmaleimide Copolymers Using Glycoluril Crosslinkers with Rigid Molecular Structures 査読

    Yuto Kurasaki, Yasuhito Suzuki, Akikazu Matsumoto

    Journal of Polymer Science   58 ( 7 )   923 - 931   2020年04月( ISSN:2642-4150

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    掲載種別:研究論文(学術雑誌)  

    © 2020 Wiley Periodicals, Inc. We carried out the thermal curing of the copolymers of N-allylmaleimide (AMI) and 2-ethylhexyl acrylate (2EHA) using 1,3,4,6-tetra(2-mercaproethyl)glycoluril (G1), 1,3,4,6-tetra(3-mercaptopropyl)glycoluril (G2), 1,3,4,6-tetraallylglycoluril (G3), triallylisocyanurate (TAIC), and pentaerythritol tetrakis(3-mercaptobutyrate) (PEMB) as the crosslinkers. Based on the results for the analysis of thiol–ene reactions monitored by IR spectroscopy, it was confirmed that the curing rate significantly depended on the combination of the used crosslinkers. The insoluble fraction after curing was more than 90% for the systems using the glycoluril crosslinkers, while the conversion of the allyl groups was suppressed due to the rigid structure of these crosslinkers. The heat resistance and the mechanical properties of the crosslinked polymers were investigated by thermogravimetric analysis, differential scanning calorimetry, dynamic mechanical analysis, and mechanical tensile tests. For the products cured using the glycoluril crosslinkers, the glass transition temperature (Tg) and the maximum temperature of thermal decomposition (Tmax) were 54–59 °C and 395–409 °C, respectively, being higher than those for the cured product prepared with PEMB and TAIC as the conventional crosslinkers. The elasticity (75–139 MPa), the maximum strength (3.0–4.1 MPa), and the adhesion strength (6.7–10.7 MPa) for the polymers cured with the glycoluril crosslinkers, determined by the mechanical tensile and single lap-shear adhesion tests, were higher than those for cured materials produced with PEMB. Thus, the thermal and mechanical properties of the maleimide copolymers were efficiently enhanced by crosslinking using the rigid glycoluril compounds. © 2020 Wiley Periodicals, Inc. J. Polym. Sci. 2020, 58, 923–931.

    DOI: 10.1002/pol.20190188

    その他URL: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/pol.20190188

  • 種々のエポキシ樹脂とジアミン硬化剤から得られるエポキシモノリスを用いた金属樹脂接合の耐熱性評価 査読

    杉本由佳, 鈴木祥仁, 松本章一

    日本接着学会誌 雑誌   2020年

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    共著区分:単著  

  • Relaxation Behavior of Poly(diisopropyl fumarate) Including No Methylene Spacer in the Main Chain 査読

    Y. Suzuki, K. Miyata, M. Sato, N. Tsuji, K. Fukao, and A. Matsumoto

    2020年

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    担当区分:筆頭著者, 責任著者   共著区分:共著  

  • 細胞内での液体ー液体相分離

    鈴木祥仁

    化学工学   2020年

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    共著区分:単著  

  • エーテル結合を含む多官能チオール架橋剤を用いたN-アリルマレイミド共重合体熱硬化物の特性解析

    倉崎佑斗, 鈴木祥仁, 松本章一

    ネットワークポリマー論文集 雑誌   2020年

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    共著区分:共著  

  • One-Shot Preparation of Polyacrylamide/Poly(sodium styrenesulfonate) Double-Network Hydrogels for Rapid Optical Tissue Clearing 査読

    Koda, Takayuki, Dohi, Shunsuke, Tachi, Hedeki, Suzuki, Yasuhito, Kojima, Chie, Matsumoto, Akikazu

    ACS OMEGA   4 ( 25 )   21083 - 21090   2019年12月( ISSN:2470-1343

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    掲載種別:研究論文(学術雑誌)  

    In this study, we propose a convenient method for the synthesis of double-network gels by the one-shot radical polymerization for their application to rapid optical tissue clearing. Double-network gels were produced during the radical polymerization of acrylamide (AAm) and sodium styrenesulfonate (SS) in the presence of N,N'-methylenebisacrylamide and sodium divinylbenzenesulfonate as the cross-linkers by simultaneous addition, that is, one-shot polymerization accompanying the delay of polymerization for a second network monomer. We analyzed the polymerization process based on the consumption rates of each monomer during the reactions in the absence of the cross-linkers in order to estimate the repeating unit structure of the resulting polymers. We then fabricated the AAm/SS gels by the polymerization of AAm and SS in the presence of the cross-linkers. We analyzed the swelling, viscoelastic, and mechanical properties of the produced gels to investigate their network structure. Finally, we demonstrated the validity of the double-network gels for the application to rapid optical tissue clearing.

    DOI: 10.1021/acsomega.9b02493

  • Adamantane-containing poly(dialkyl fumarate)s with rigid chain structures 査読

    Tsuji, Nagisa, Suzuki, Yasuhito, Matsumoto, Akikazu

    POLYMER JOURNAL   51 ( 11 )   1147 - 1161   2019年11月( ISSN:0032-3896

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    掲載種別:研究論文(学術雑誌)  

    Four dialkyl fumarates containing bulky adamantyl ester groups, i.e., di(1-adamantyl) fumarate (1), bis(3,5-dimethyl-1-adamantyl) fumarate (2), 1-adamantyl isopropyl fumarate (3), and 3,5-dimethyl-1-adamantyl isopropyl fumarate (4), were polymerized to obtain poly( dialkyl fumarate)s (PDRFs) with rigid chain structures. We carried out the conventional radical polymerization of these adamantane-containing DRFs in the presence of a radical initiator either in toluene or in bulk at 80 or 60 degrees C. Reversible addition-fragmentation chain transfer (RAFT) polymerization was also performed using 1,1'-(1,2ethanediyl) bis[2-[[(dodecylthio)thioxymethyl]thio]-2-methylpropionate] and 2,2,2-trifluoroethyl 2-[[(dodecylthio)thioxymethyl]thio]-2-methylpropionate as the chain transfer agents (CTAs). Triblock copolymers consisting of rigid and flexible segments were synthesized by the polymerization of 2-ethylhexyl acrylate, which was used as the second monomer, using the PDRFs as the macro-CTA containing trithiocarbonate groups at the chain ends. The excellent thermal stability of the adamantane-containing PDRFs was confirmed by thermogravimetric analysis in a nitrogen stream. The alignment of the rigid PDRF chains in the solid-state was revealed based on the appearance of a peak in the small angle regions of the X-ray diffraction profiles.

    DOI: 10.1038/s41428-019-0228-x

  • Relaxation behavior of random copolymers containing rigid fumarate and flexible acrylate segments by dynamic mechanical analysis 査読

    Suzuki, Yasuhito, Tsujimura, Tomoya, Funamoto, Kenji, Matsumoto, Akikazu

    POLYMER JOURNAL   51 ( 11 )   1163 - 1172   2019年11月( ISSN:0032-3896

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    掲載種別:研究論文(学術雑誌)  

    Due to the absence of a methylene spacer in the main chain, poly(substituted methylene)s with rigid structures possess some distinguished properties including a unique beta-relaxation process. In this study, two series of random copolymers of diisopropyl fumarate (DiPF) with 1-adamantyl acrylate (AdA) and n-butyl acrylate (nBA) with various compositions were synthesized. The relaxation behavior of the copolymers was investigated using dynamic mechanical analysis (DMA) and differential scanning calorimetry (DSC). The alpha-relaxation temperature of the copolymers decreased as the acrylate content increased. Depending on the glass transition temperature (T-g) of the counterpart copolymers, that is, T-g = 156 degrees C for the homopolymer of AdA and T-g = -53 degrees C for the homopolymer of nBA, the beta-relaxation temperature from the DiPF segments systematically shifted. While the beta-relaxation temperature increased when copolymerized with AdA, the temperature decreased when copolymerized with nBA. Both copolymers maintained a high storage modulus of more than 10MPa in the range between the alpha- and ss-relaxation temperatures. The merging of the alpha and beta processes at an intermediate composition was also observed. The random copolymerization of DiPF and acrylates enables us to fine tune the properties associated with the beta-relaxation of DiPF segments.

    DOI: 10.1038/s41428-019-0226-z

  • Infusible acrylic thermoplastic resins: Tailoring of chemorheological properties 査読

    Cousins, Dylan S., Howell, Jackson, Suzuki, Yasuhito, Samaniuk, Joseph R., Stebner, Aaron P., Dorgan, John R.

    JOURNAL OF APPLIED POLYMER SCIENCE   136 ( 40 )   2019年10月( ISSN:0021-8995

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    掲載種別:研究論文(学術雑誌)  

    Infusible liquid resins that polymerize into a thermoplastic are desirable for many applications. Similar to unsaturated and vinylester thermosetting systems, they consist of polymers dissolved in reactive monomer. This work presents a method to decrease cycle time by tuning the molecular weight and concentration of the predissolved polymer in the resin. Variation of these properties allows precise control of the viscosity which in turn controls the time at which peak exotherm is reached, the maximum temperature for a given part thickness, and cure time. Predictive models for the viscosity dependence on molecular weight, polymer concentration, shear rate, and temperature are developed. Two fiberglass panels are fabricated and tested; one with a lower molecular weight (M-w similar to 30 kg mol(-1)) poly(methyl methacrylate) dissolved in methyl methacrylate and the second with higher molecular weight (M-w similar to 500 kg mol(-1)) predissolved polymer in the resin. Mechanical properties are indistinguishable but the lower molecular weight panel cures up to three times faster. (c) 2019 Wiley Periodicals, Inc.

    DOI: 10.1002/app.48006

  • Thermal decomposition of methacrylate polymers containing tert-butoxycarbonyl moiety 査読

    Jing, Chu, Suzuki, Yasuhito, Matsumoto, Akikazu

    POLYMER DEGRADATION AND STABILITY   166   145 - 154   2019年08月( ISSN:0141-3910

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    掲載種別:研究論文(学術雑誌)  

    In organic synthesis and polymer materials chemistry, a tert-butoxycarbonyl (BOC) group is often used as one of tools for the protection of functional groups. In this study, we carried out radical polymerization of 2-(tert-butoxycarbonyloxy)ethyl methacrylate (BHEMA) and copolymerizations of BHEMA with methyl methacrylate (MMA), n-butyl methacrylate (nBMA), isobutyl methacrylate (iBMA), tert-butyl methacrylate (tBMA), dodecyl methacrylate (DMA), alpha-methylstyrene (AMS), and limonene (Lim) as the 1,1-disubstituted ethylene monomers and investigated the thermal decomposition behavior of the obtained polymers. On the basis of the results of thermogravimetric (TG) analysis in nitrogen at the heating rate of 10 degrees C/min, it was revealed that the deprotection of the BOC group in the polymer side chains occurred at ca. 200 degrees C accompanying the quantitative elimination of isobutene and carbon dioxide, independent of the structures of the repeating units. The following main-chain decomposition of the residual copolymers resulted in a small amount of residue less than 1% at 500 degrees C. Poly(2-hydroxyethyl methacrylate) was synthesized via the deprotection of the BOC group of PBHEMA. (C) 2019 Elsevier Ltd. All rights reserved.

    DOI: 10.1016/j.polymdegradstab.2019.05.027

  • Adamantane-containing poly (dialkyl fumarate) s with rigid chain structures

    Nagisa Tsuji, Yasuhito Suzuki, Akikazu Matsumoto

    Polymer Journal   2019年07月

  • Relaxation behavior of random copolymers containing rigid fumarate and flexible acrylate segments by dynamic mechanical analysis 査読

    Yasuhito Suzuki, Tomoya Tsujimura, Kenji Funamoto, Akikazu Matsumoto

    Polymer Journal   2019年07月

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    担当区分:筆頭著者  

  • Dual-energy X-ray computed tomography for void detection in fiber-reinforced composites 査読

    Suzuki, Yasuhito, Cousins, Dylan S., Dorgan, John R., Stebner, Aaron P., Kappes, Branden B.

    JOURNAL OF COMPOSITE MATERIALS   53 ( 17 )   2349 - 2359   2019年07月( ISSN:0021-9983

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    掲載種別:研究論文(学術雑誌)  

    Void detection in fiber-reinforced composites traditionally relies on precise density measurements before and after the physical removal of the polymer matrix; consequently, this method only provides data on the total volume of voids within the material without information about void sizes, shapes, and distributions. Despite advances in X-ray computed tomography, it is still challenging to quantitatively and convincingly characterize void content due to the complex X-ray physics of divergent, broad-spectrum laboratory X-ray sources. Here, we demonstrate that by using aligned high-energy and low-energy X-rays, dual-energy X-ray computed tomography provides high-quality images and phase-based segmentation that allows for clear distinction between air, polymer matrix, and reinforcing fibers. We verify the method on several fiber-reinforced composite samples: epoxy-glass fiber composites fabricated by vacuum-assisted resin transfer molding and by light resin transfer molding (light resin transfer molding), and a carbon fiber composite fabricated via vacuum-assisted resin transfer molding.

    DOI: 10.1177/0021998319827091

  • Manufacturing and Flexural Characterization of Infusion-Reacted Thermoplastic Wind Turbine Blade Subcomponents

    Robynne E. Murray, Dayakar Penumadu, Dylan Cousins, Ryan Beach, David Snowberg, Derek Berry, Yasuhito Suzuki, Aaron Stebner

    APPLIED COMPOSITE MATERIALS   26 ( 3 )   945 - 961   2019年06月( ISSN:0929-189X

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    掲載種別:研究論文(学術雑誌)  

    Reactive thermoplastics are advantageous for wind turbine blades because they are recyclable at end of life, have reduced manufacturing costs, and enable thermal joining and shaping. However, there are challenges with manufacturing wind components from these new materials. This work outlines the development of manufacturing processes for a thick glass fiber-reinforced acrylic thermoplastic resin wind turbine blade spar cap, with consideration given to effects of the exothermic curing reaction on thick composite parts. Comparative elastic properties of these infusible thermoplastic materials with epoxy thermoset materials, as well as thermoplastic coupon components, are also included. Based on the results of this study it is concluded that the thermoplastic resin system is a viable candidate for the manufacturing of wind turbine blades using vacuum-assisted resin transfer molding. Significant gains in energy savings are realized avoiding heated molds, ability for recycling, and providing an opportunity for utilizing thermal welding.

    DOI: 10.1007/s10443-019-9760-2

  • Phase separation during bulk polymerization of methyl methacrylate

    Yasuhito Suzuki, Dylan S Cousins, Yuya Shinagawa, Robert T Bell, Akikazu Matsumoto, Aaron P Stebner

    2019年04月

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    担当区分:筆頭著者, 責任著者  

  • Styrene-Free, Partially Biobased Resin System for Thermoplastic Composites. I. Rheological Properties and Preliminary Panel Fabrication 査読

    Cousins, Dylan S., Tan, Bin, Howell, Jackson, Suzuki, Yasuhito, Samaniuk, Joseph R., Knauss, Daniel M., Dorgan, John R.

    ACS SUSTAINABLE CHEMISTRY & ENGINEERING   7 ( 7 )   6512 - 6521   2019年04月( ISSN:2168-0485

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    掲載種別:研究論文(学術雑誌)  

    For the first time ever, a styrene-free, biobased formulation suitable for infusion processing of thermoplastic composites is reported. Biobased polylactide (PLA) is soluble in methyl methacrylate (MMA) and this new styrene free system is suitable for fabricating composite parts. Rheology is critically important in transfer molding; therefore, single chain properties are related to concentrated solutions of PLA in MMA. Multiple angle laser light scattering (MALLS) provides molecular weights, radii of gyration, and second virial coefficients for PLAs of varying molecular weight dissolved in MMA. The Flory interaction parameter is described by chi = 0.40 +/- 0.04. Dilute solution viscometry (DSV) gives the Mark-Houwink relationship at 30 degrees C as [eta] = 0.017M(eta)(0.73). The expansion factors calculated from DSV and MALLS agree reasonably well (alpha = 1.45 +/- 0.25). The values of a, chi, and alpha indicate that MMA is a good solvent for PLA. The Carreau Yasuda viscosity and Andrade-Eyring temperature models enable a quantitative description of the specific viscosity, eta(sp), as a function of the intrinsic viscosity normalized concentration, c[eta]. The quantitative description provides a powerful and generally applicable approach to formulating resins useful for composite fabrication. A new environmentally superior resin system is used to fabricate a composite panel using vacuum-assisted resin transfer molding.

    DOI: 10.1021/acssuschemeng.8b04229

  • Phase separation during bulk polymerization of methyl methacrylate 査読

    Yasuhito Suzuki, Dylan S. Cousins, Yuya Shinagawa, Robert T. Bell, Akikazu Matsumoto, Aaron P. Stebner

    Polymer Journal   51 ( 4 )   423 - 431   2019年04月( ISSN:0032-3896

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1038/s41428-018-0142-7

  • Infusible acrylic thermoplastic resins: Tailoring of chemorheological properties

    Dylan S Cousins, Jackson Howell, Yasuhito Suzuki, Joseph R Samaniuk, Aaron P Stebner, John R Dorgan

    Journal of Applied Polymer Science   2019年03月

  • Dual-energy X-ray computed tomography for void detection in fiber-reinforced composites

    Yasuhito Suzuki, Dylan S Cousins, John R Dorgan, Aaron P Stebner, Branden B Kappes

    Journal of Composite Materials   2019年02月

  • Styrene-Free, Partially Biobased Resin System for Thermoplastic Composites. I. Rheological Properties and Preliminary Panel Fabrication

    Dylan S Cousins, Bin Tan, Jackson Howell, Yasuhito Suzuki, Joseph R Samaniuk, Daniel M Knauss, John R Dorgan

    ACS Sustainable Chemistry & Engineering   2019年02月

  • Recycling glass fiber thermoplastic composites from wind turbine blades 査読

    Cousins, Dylan S., Suzuki, Yasuhito, Murray, Robynne E., Samaniuk, Joseph R., Stebner, Aaron P.

    JOURNAL OF CLEANER PRODUCTION   209   1252 - 1263   2019年02月( ISSN:0959-6526

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    掲載種別:研究論文(学術雑誌)  

    Thermoplastic resin systems have long been discussed for use in large-scale composite parts but have yet to be exploited by the energy industry. The use of these resins versus their thermosetting counterparts can potentially introduce cost savings due to non-heated tooling, shorter manufacturing cycle times, and recovery of raw materials from the retired part. Because composite parts have high embedded energy, recovery of their constituent materials can provide substantial economic benefit. This study determines the feasibility of recycling composite wind turbine blade components that are fabricated with glass fiber reinforced Elium (R) thermoplastic resin. Several experiments are conducted to tabulate important material properties that are relevant to recycling, including thermal degradation, grinding, and dissolution of the polymer matrix to recover the constituent materials. Dissolution, which is a process unique to thermoplastic matrices, allows recovery of both the polymer matrix and full-length glass fibers, which maintain their stiffness (190 N/(mm g)) and strength (160 N/g) through the recovery process. Injection molded regrind material is stiffer (12 GPa compared to 10 GPa) and stronger (150 MPa compared to 84 MPa) than virgin material that had shorter fibers. An economic analysis of the technical data shows that recycling thermoplastic-glass fiber composites via dissolution into their constituent parts is commercially feasible under certain conditions. This analysis concludes that 50% of the glass fiber must be recovered and resold for a price of $0.28/kg. Additionally, 90% of the resin must be recovered and resold at a price of $2.50/kg. (C) 2018 Elsevier Ltd. All rights reserved.

    DOI: 10.1016/j.jclepro.2018.10.286

  • Synthesis of Transparent and Heat-Resistant Acrylic Block Copolymers by Living Radical Polymerization

    Kohei Takada, Nagisa Tsui, Yasuhito Suzuki, Akikazu Matsumoto

    KOBUNSHI RONBUNSHU   2019年01月

  • リビングラジカル重合による透明耐熱アクリル系ブロック共重合体の合成 査読

    髙田康平,辻 渚,鈴木祥仁,松本章一

    高分子論文集 雑誌   2019年

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    共著区分:共著  

  • Design of a High-Performance Dismantlable Adhesion System Using Pressure-Sensitive Adhesive Copolymers of 2-Hydroxyethyl Acrylate Protected with tert-Butoxycarbonyl Group in the Presence of Cross-Linker and Lewis Acid

    Masashi IsekiYasuhito SuzukiHideki TachiAkikazu Matsumoto*

    ACS Omega   2018年11月

  • Kinetics and temperature evolution during the bulk polymerization of methyl methacrylate for vacuum-assisted resin transfer molding

    Yasuhito Suzuki, Dylan Cousins, Jerred Wassgren, Branden B Kappes, John Dorgan, Aaron P Stebner

    Composites Part A: Applied Science and Manufacturing   2018年01月

  • Capillary Imbibition, Crystallization, and Local Dynamics of Hyperbranched Poly (ethylene oxide) Confined to Nanoporous Alumina

    Yang Yao, Yasuhito Suzuki, Jan Seiwert, Martin Steinhart, Holger Frey, Hans-Jürgen Butt, George Floudas

    Macromolecules   2017年10月

  • Crystallinity tunes permeability of polymer nanocapsules

    Isabel Schlegel, Rafael Muñoz-Espí, Patricia Renz, Ingo Lieberwirth, George Floudas, Yasuhito Suzuki, Daniel Crespy, Katharina Landfester

    Macromolecules   2017年06月

  • Photoswitching of glass transition temperatures of azobenzene-containing polymers induces reversible solid-to-liquid transitions

    Hongwei Zhou, Changguo Xue, Philipp Weis, Yasuhito Suzuki, Shilin Huang, Kaloian Koynov, Günter K Auernhammer, Rüdiger Berger, Hans-Jürgen Butt, Si Wu

    Nature Chemistry   2017年02月

  • Effects of polydispersity, additives, impurities and surfaces on the crystallization of poly (ethylene oxide)(PEO) confined to nanoporous alumina 査読

    Yasuhito Suzuki, Martin Steinhart, Michael Kappl, Hans-Jürgen Butt, George Floudas

    Polymer 雑誌   2016年09月

  • Dynamics of ice/water confined in nanoporous alumina

    Yasuhito Suzuki, Martin Steinhart, Robert Graf, Hans-Jürgen Butt, George Floudas

    The Journal of Physical Chemistry B   2015年11月

  • Kinetics of ice nucleation confined in nanoporous alumina

    Yasuhito Suzuki, Martin Steinhart, Hans-Jürgen Butt, George Floudas

    The Journal of Physical Chemistry B   2015年08月

  • Homogeneous nucleation of predominantly cubic ice confined in nanoporous alumina

    Yasuhito Suzuki, Hatice Duran, Martin Steinhart, Michael Kappl, Hans-Jürgen Butt, George Floudas

    Nano letters   2015年02月

  • Real time ligand-induced motion mappings of AChBP and nAChR using X-ray single molecule tracking

    Hiroshi Sekiguchi, Yasuhito Suzuki, Yuri Nishino, Suzuko Kobayashi, Yoshiko Shimoyama, Weiyan Cai, Kenji Nagata, Masato Okada, Kouhei Ichiyanagi, Noboru Ohta, Naoto Yagi, Atsuo Miyazawa, Tai Kubo, Yuji C Sasaki

    Scientific reports   2014年09月

  • Suppression of Poly(ethylene oxide) Crystallization in Diblock Copolymers of Poly(ethylene oxide)-b-poly(ε-caprolactone) Confined to Nanoporous Alumina

    Yasuhito Suzuki, Hatice Duran, Martin Steinhart, Hans-Jürgen Butt, George Floudas

    Macromolecules   2014年02月

  • Multiple nucleation events and local dynamics of poly (ε-caprolactone)(PCL) confined to nanoporous alumina

    Yasuhito Suzuki, Hatice Duran, Wajiha Akram, Martin Steinhart, George Floudas, Hans-Jürgen Butt

    Soft Matter   2013年

  • Homogeneous crystallization and local dynamics of poly (ethylene oxide)(PEO) confined to nanoporous alumina

    Yasuhito Suzuki, Hatice Duran, Martin Steinhart, Hans-Jürgen Butt, George Floudas

    Soft Matter   2013年

▼全件表示

書籍等出版物

  • ブット・グラフ・カペル 界面の物理と化学

    鈴木祥仁、 深尾浩次(共訳)( 担当: 共著)

    丸善出版  2016年10月 

MISC(その他記事)

  • Polymerization induced phase separation of methyl methacrylate and Trommsdorff effect

    Yasuhito Suzuki, Yuya Shinagawa, Koji Fukao, Akikazu Matsumoto

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   258   2019年08月( ISSN:0065-7727

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    掲載種別:研究発表ペーパー・要旨(国際会議)  

講演・口頭発表等

  • エポキシモノリスと共連続ネットワークポリマの引張および圧縮変形機構 国内会議

    荒岸和真,鈴木祥仁,松本章一

    第19回日本接着学会関西支部若手の会  2023年12月 

  • ポリマーブラシ側鎖官能基の保護脱保護を利用した表面濡れ性の制御 国内会議

    松並杏友加,鈴木祥仁,森藤日菜,佐藤和郎,金岡祐介,松本章一

    第19回日本接着学会関西支部若手の会  2023年12月 

  • マレイミドオキサジンと多官能チオールを用いる熱硬化物の合成と熱および機械特性評価 国内会議

    高須美菜子,杉浦幹太,杉本早紀,鈴木祥仁,松本章一

    第72回ネットワークポリマー講演討論会  2023年10月 

  • エポキシモノリスの引張および圧縮変形機構の解析 国内会議

    荒岸和真,鈴木祥仁,武田佳彦,松本章一

    第72回ネットワークポリマー講演討論会  2023年10月 

  • The Relationship between Polymerization-Induced Heterogeneity and the Reaction Acceleration during the Late Stage of Bulk Polymerization 国内会議

    2023年09月 

  • ポリマーブラシ側鎖官能基の保護脱保護を利用した親水性度の制御 国内会議

    松並杏友加,森藤日菜,鈴木祥仁,松本章一

    第72回高分子討論会  2023年09月 

  • メタクリル酸メチルの重合誘起相分離による構造形成過程 国内会議

    小野里勝大,鈴木祥仁,松本章一

    第72回高分子討論会  2023年09月 

  • ポリ置換メチレン構造を有するポリフマル酸エステルの構造制御と機能化 国内会議

    石丸諒太郎,鈴木祥仁,松本章一

    第72回高分子討論会  2023年09月 

  • Polymerization-Induced Heterogenization, Phase Separation, and Reaction Acceleration at the Vicinity of Vitrification upon Curing of Thermoplastic Resins 国際会議

    Y. Suzuki, A. Matsumoto

    14th European Adhesion Conference & 7th World Congress on Adhesion and Related Phenomena (EURADH/WCARP 2023)  2023年09月 

  • Dynamics, Amorphous Structure, and Chemical Reaction Kinetics at the Vicinity of Polymerization-Induced Vitrification 招待 国際会議

    Y. Suzuki, A. Matsumoto

    9th International Discussion Meeting on Relaxations in Complex Systems (9IDMRCS)  2023年08月 

  • Stretching and Compression Deformation Mechanism of Epoxy Monolith and Co-continuous Network Polymers 国際会議

    2023年07月 

  • メチレンスペーサーを持たないポリクロトン酸エステルの緩和挙動 国内会議

    岩上幸祐,鈴木祥仁,松本章一

    第69回高分子研究発表会(神戸)  2023年07月 

  • BOC基保護ポリメタクリル酸2-ヒドロキシエチルブラシを用いた表面パターンの作製と評価 国内会議

    森藤日菜,松並杏友加,鈴木祥仁,松本章一

    第69回高分子研究発表会(神戸)  2023年07月 

  • BOC基含有ポリマーを用いた熱応答型の易解体性エポキシ接着材料の設計 国内会議

    一藁海都,鈴木祥仁,松本章一

    第61回日本接着学会年次大会  2023年06月 

  • 重合に誘起されるガラス化近傍での不均一性、相分離および反応加速 国内会議

    鈴木祥仁,松本章一

    第72回高分子学会年次大会  2023年05月 

  • 剛直鎖ポリフマル酸エステルの凝集構造形成 国内会議

    石丸諒太郎,鈴木祥仁,松本章一

    第72回高分子学会年次大会  2023年05月 

  • BOC基保護ポリメタクリル酸2-ヒドロキシエチルブラシの作製と特性評価 国内会議

    松並杏友加,森藤日菜,鈴木祥仁,松本章一

    第72回高分子学会年次大会  2023年05月 

  • Polymerization-Induced Vitrification, Kinetic Heterogenization, and Reaction Acceleration during Bulk Polymerization of Methyl Methacrylate 国際会議

    Y. Suzuki, A. Matsumoto

    ACS Spring 2023  2023年03月  American Chemical Society

     詳細を見る

    開催地:Indianapolis  

  • エポキシモノリスおよび共連続ポリマーネットワークの変形機構の解析 国内会議

    荒岸和真,冨永 蓮,鈴木祥仁,松本章一

    第18回日本接着学会関西支部若手の会  2022年11月 

  • 化学反応に誘起される相分離,反応加速およびミクロ構造形成 国内会議

    鈴木祥仁

    大阪公立大学工学研究科記念シンポジウム  2022年11月 

  • BOC保護したヒドロキシ基を含むアクリル酸エステル共重合体を用いた易解体性粘着剤の設計 国内会議

    一藁海都,坂本龍哉,鈴木祥仁,松本章一

    第42回粘着技術研究会  2022年11月 

  • 熱酸発生剤を添加したBOC保護型ポリマーの反応制御:熱安定性の向上と迅速な熱応答脱保護反応の両立 国内会議

    赤堀涼太郎,大佐田開斗,鈴木祥仁,松本章一

    第42回粘着技術研究会  2022年11月 

  • 示差熱走査熱量測定を用いたメタクリル酸エステルのバルク重合速度解析 国内会議

    三島隆太郎,鈴木祥仁,松本章一

    第71回高分子討論会  2022年09月 

  • メタクリル酸メチルの重合誘起相分離を利用した構造形成と両疎媒性表面の作製 国内会議

    鈴木祥仁,小野里勝大,松本章一

    第71回高分子討論会  2022年09月 

  • 化学反応に誘起されるガラス化、相分離、および反応加速 招待 国内会議

    鈴木祥仁

    大阪公立大学第132回テクノラボツアー「新材料・新物質の創生を可能にする応用化学研究」  2022年08月 

  • メタクリル酸エステルのバルクラジカル重合挙動と添加剤の影響 国内会議

    三島隆太郎,鈴木祥仁,松本章一

    第68回高分子研究発表会(神戸)  2022年07月 

  • 主鎖にメチレンスペーサーを持たないポリクロトン酸tert-ブチルの緩和挙動 国内会議

    岩上幸祐,鈴木祥仁,松本章一

    第68回高分子研究発表会(神戸)  2022年07月 

  • 重合誘起相分離を利用したポリメタクリル酸メチルの構造形成と機能性表面への応用 国内会議

    小野里勝大,鈴木祥仁,松本章一

    第60回日本接着学会年次大会  2022年06月 

  • 共連続ネットワークポリマーの強度発現および破壊機構の解析 国内会議

    冨永 蓮,鈴木祥仁,松本章一

    第60回日本接着学会年次大会  2022年06月 

  • 重合誘起相分離を利用したポリメタクリル酸メチルの構造形成と撥水性表面の作製 国内会議

    小野里勝大,鈴木祥仁,松本章一

    第71回高分子学会年次大会  2022年05月 

  • 熱酸発生剤の添加によるBOC基保護ポリメタクリル酸2-ヒドロキシエチルの側鎖分解反応の制御 国内会議

    大佐田開斗,鈴木祥仁,松本章一

    第71回高分子学会年次大会  2022年05月 

  • 共連続ネットワークポリマーCNPの材料設計:第2成分ポリマーのネットワーク構造がCNP強度に及ぼす影響 国内会議

    冨永 蓮,鈴木祥仁,松本章一

    第71回高分子学会年次大会  2022年05月 

  • PEGおよびPEG修飾デンドリマーの水和状態の解析 国内会議

    児島千恵,鈴木祥仁,辻本絢子,池本友佳,田中 賢,松本章一

    第71回高分子学会年次大会  2022年05月 

  • ポリフマル酸エステルのβ緩和と非晶構造異方性 国内会議

    鈴木祥仁,深尾浩次,松本章一

    第71回高分子学会年次大会  2022年05月 

▼全件表示

産学官連携可能研究(シーズ)キーワード

  • 高分子ダイナミクス

  • バルク重合

  • 重合誘起相分離

  • 化学反応速度

科研費

  • 化学反応に誘起されるガラス化と階層的不均一性

    2023年

  • 化学反応に誘起されるガラス化と階層的不均一性

    若手研究  2022年04月

担当授業科目

  • 物質化学生命系特別研究第1

    2023年度   集中講義   大学院

  • 物質化学生命系特別演習第1

    2023年度   集中講義   大学院

  • 有機化学演習IIA

    2023年度   週間授業   大学

  • 応用化学実験III

    2023年度   週間授業   大学

  • 初年次ゼミナール

    2023年度   週間授業   大学院

  • 物質化学生命系特別演習

    2023年度   集中講義   大学院

  • 物質化学生命系特別研究

    2023年度   集中講義   大学院

  • 化学外国語演習

    2023年度   週間授業   大学

  • 有機化学演習1

    2023年度   週間授業   大学

  • 応用化学実験1

    2023年度   週間授業   大学

  • 応用化学実験IV

    2023年度   週間授業   大学

  • 応用化学実験II

    2023年度   集中講義   大学

  • 応用化学実験V

    2023年度   週間授業   大学

  • 応用化学特論3

    2023年度   週間授業   大学院

  • 物質化学生命系特別研究第2

    2023年度   集中講義   大学院

  • 物質化学生命系特別演習第2

    2023年度   集中講義   大学院

  • 高分子化学2

    2023年度   週間授業   大学

  • 化学外国語演習

    2022年度   週間授業   大学

  • 応用化学実験I

    2022年度   週間授業   大学

  • 物質化学生命系特別演習

    2022年度   集中講義   大学院

  • 物質化学生命系特別演習第1

    2022年度   集中講義   大学院

  • 応用化学実験III

    2022年度   週間授業   大学

  • 物質化学生命系特別研究 (応用化学分野)

    2022年度   集中講義   大学院

  • 物質化学生命系特別演習第2 (応用化学分野)

    2022年度   集中講義   大学院

  • 応用化学特論3 (応用化学分野)

    2022年度   週間授業   大学院

  • 応用化学実験II

    2022年度   週間授業   大学

  • 応用化学実験IV

    2022年度   週間授業   大学

  • 応用化学実験V

    2022年度   週間授業   大学

  • 高分子化学I

    2022年度   週間授業   大学

  • 有機化学演習IA

    2022年度   週間授業   大学

  • 応用化学実験II

    2021年度   実習  

  • 応用化学実験I

    2021年度   実習  

  • 応用化学実験V

    2021年度   実習  

  • 応用化学実験III

    2021年度   実習  

  • 化学外国語演習

    2021年度    

  • 応用化学実験IV

    2021年度   実習  

  • 有機化学演習IA

    2021年度    

  • 応用化学実験III

    2021年度   実習  

  • 有機化学演習IA

    2021年度    

  • 応用化学実験V

    2021年度   実習  

  • 応用化学実験IV

    2021年度   実習  

  • 応用化学実験II

    2021年度   実習  

  • 化学外国語演習

    2021年度    

  • 応用化学実験I

    2021年度   実習  

▼全件表示

FD活動

  • 工学FD集会受講  2022年度

  • 学生実験 ピア授業参観  2022年度

所属院生等の論文発表集計

  • 2023年度

    所属大学院生発表数:8件

  • 2022年度

    所属大学院生発表数:8件

論文・研究指導集計

  • 2023年度

    卒業論文指導数:3名 

  • 2022年度

    卒業論文指導数:1名 

    博士前期課程学生指導数:9名