Updated on 2023/03/27

写真a

 
OHASHI Masato
 
Organization
Graduate School of Science Department of Chemistry Professor
School of Science Department of Chemistry
Title
Professor
Affiliation
Institute of Science
Affiliation campus
Nakamozu Campus

Position

  • Graduate School of Science Department of Chemistry 

    Professor  2022.04 - Now

  • School of Science Department of Chemistry 

    Professor  2022.04 - Now

Degree

  • Ph.D. (Engineering) ( Tokyo Institute of Technology )

Research Areas

  • Nanotechnology/Materials / Synthetic organic chemistry  / organometallic chemistry, coordination chemistry, catalytic chemistry, organofluorine chemistry

  • Nanotechnology/Materials / Structural organic chemistry and physical organic chemistry  / organometallic chemistry, coordination chemistry, catalytic chemistry, organofluorine chemistry

  • Nanotechnology/Materials / Inorganic/coordination chemistry  / 有機金属化学、錯体化学、触媒化学、有機フッ素化学

Research Interests

  • 錯体化学

  • 機能材料・デバイス

  • 有機金属化学

Research subject summary

  • フッ素の特異な性質を活用した遷移金属活性種の創製と分子変換反応への応用

Professional Memberships

  • The Society of Fluorine Chemsitry, Japan

    2019.06 - Now   Domestic

  • 近畿化学協会 有機金属部会

    2007.11 - Now

  • 日本化学会

    1998.02 - Now

  • 錯体化学会

      Domestic

Awards

  • Thieme Chemistry Journals Award 2016

    2016.01   Thieme  

  • 2015 Banyu Chemist Award(BCA)

    2015.10   万有生命科学振興国際交流財団(現:公益財団法人 MSD生命科学財団)  

  • 第4回大阪大学総長奨励賞

    2015.07   大阪大学  

  • 第3回大阪大学総長奨励賞

    2014.07   大阪大学  

  • 2012 Organometallics Fellow

    2012.08   American Chemical Society  

Papers

  • Synthesis of Fluoroalkyl Sulfides via Additive-Free Hydrothiolation and Sequential Functionalization Reactions Reviewed

    Denise E. Sunagawa, Naoyoshi Ishida, Hiroaki Iwamoto, Masato Ohashi, Corinne Fruit, Sensuke Ogoshi

    The Journal of Organic Chemsitry 雑誌 American Chemical Society   86 ( 8 )   2021.03

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    Kind of work:Joint Work  

  • Copper(I)-Mediated C–N/C–C Bond-Forming Reaction with Tetrafluoroethylene for the Synthesis of N-Fluoroalkyl Heteroarenes via an Azacupration/Coupling Mechanism Reviewed

    N. Ishida, T. Adachi, H. Iwamoto, M. Ohashi, S. Ogoshi

    Chemistry Letters 雑誌 Chemical Society of Japan   50   2020.12

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    Kind of work:Joint Work  

  • CsF-Catalyzed Fluoroacylation of Tetrafluoroethylene Using Acyl Fluorides for the Synthesis of Pentafluoroethyl Ketones Reviewed

    N. Ishida, H. Iwamoto, D. E. Sunagawa, M. Ohashi, S. Ogoshi

    Synthesis 雑誌 Thieme Chemistry   52   2020.10

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    Kind of work:Joint Work  

  • Cleavage of C(sp3)–F Bonds in Trifluoromethylarenes Using a Bis(NHC)nickel(0) Complex Reviewed

    H. Iwamoto, H. Imiya, M. Ohashi, S. Ogoshi

    Journal of the American Chemical Society 雑誌 American Chemical Society   142 ( 45 )   2020.10

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    Kind of work:Joint Work  

  • Direct Transformation of Tetrafluoroethylene to Trifluorovinylzinc via sp2 C–F Bond Activation Reviewed

    K. Kikushima, Y. Etou, R. Kamura, I. Takeda, H. Ito, M. Ohashi, S. Ogoshi

    Organic Letters 雑誌 American Chemical Society   22 ( 20 )   2020.09

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    Kind of work:Joint Work  

  • Enantioselective Synthesis of Polycyclic γ-Lactams with Multiple Chiral Carbon Centers via Ni(0)-Catalyzed Asymmetric Carbonylative Cycloadditions without Stirring Reviewed

    K. Ashida, Y. Hoshimoto, N. Tohnai, D. Scott, M. Ohashi, H. Imaizumi, Y. Tsuchiya and S. Ogoshi

    Journal of the American Chemical Society 雑誌 American Chemical Society   142 ( 3 )   2019.12

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    Kind of work:Joint Work  

  • Ni(0)-Catalyzed Three-Component Coupling Reaction of Tetrafluoroethylene and N-Sulfonyl-Substituted Imines with Silanes via Aza-Nickelacycles Reviewed

    Hiroshi Shirataki, Takafumi Ono, Masato Ohashi, Sensuke Ogoshi

    Organic Letters 雑誌 American Chemical Society   21   2019.02

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    Kind of work:Joint Work  

  • Nickel-catalyzed Three-component Coupling Reaction of Tetrafluoroethylene and Aldehydes with Silanes via Oxa-Nickelacycles Reviewed

    Hiroshi Shirataki, Masato Ohashi, Sensuke Ogoshi

    European Journal of Organic Chemistry 雑誌 Wiley-VCH   9   2019.01

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    Kind of work:Joint Work  

  • Selective Catalytic Formation of Cross-Tetramers from Tetrafluoroethylene, Ethylene, Alkynes, and Aldehydes via Nickelacycles as Key Reaction Intermediates Reviewed

    Takuya Kawashima, Masato Ohashi, Sensuke Ogoshi

    Journal of the American Chemical Society 雑誌 American Chemical Society   140   2018.11

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    Kind of work:Joint Work  

  • Main-Group-Catalyzed Reductive Alkylation of Multiply Substituted Amines with Aldehydes Using H2 Reviewed

    Yoichi Hoshimoto, Takuya Kinoshita, Sunit Hazra, Masato Ohashi, Sensuke Ogoshi

    Journal of the American Chemical Society 雑誌 American Chemical Society   140   2018.06

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    Kind of work:Joint Work  

  • Cu(I)-Catalyzed Pentafluoroethylation of Aryl Iodides in the Presence of Tetrafluoroethylene and Cesium Fluoride: Determining the Route to the Key Pentafluoroethyl Cu(I) Intermediate Reviewed

    Masato Ohashi, Naoyoshi Ishida, Kota Ando, Yu Hashimoto, Anna Shigaki, Kotaro Kikushima, Sensuke Ogoshi

    Chemistry A European Journal 雑誌 Wiley-VCH   24   2018.05

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    Kind of work:Joint Work  

  • Fluorinated Vinylsilanes from the Copper-Catalyzed Defluorosilylation of Fluoroalkene Feedstocks Reviewed

    Hironobu Sakaguchi, Masato Ohashi, Sensuke Ogoshi

    Angewandte Chemie International Edition 雑誌 Wiley-VCH   57   2018.01

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    Kind of work:Joint Work  

  • Nickel-Catalyzed Formation of 1,3-Dienes via a Highly Selective Cross-Tetramerization of Tetrafluoroethylene, Styrenes, Alkynes, and Ethylene Reviewed

    Takuya Kawashima, Masato Ohashi, Sensuke Ogoshi

    Journal of the American Chemical Society 雑誌 American Chemical Society   139   2017.11

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    Kind of work:Joint Work  

  • Transition-Metal-Free Catalytic Hydrodefluorination of Polyfluoroarenes by Concerted Nucleophilic Aromatic Substitution with a Hydrosilicate Reviewed

    Kotaro Kikushima, Mary Grellier, Masato Ohashi, Sensuke Ogoshi

    Angewandte Chemie International Edition 雑誌 Wiley-VCH   56   2017.10

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    Kind of work:Joint Work  

  • Copper-Catalyzed Regioselective Monodefluoroborylation of Polyfluoroalkenes en Route to Diverse Fluoroalkenes Reviewed

    Hironobu Sakaguchi, Yuta Uetake, Masato Ohashi, Takashi Niwa, Sensuke Ogoshi, Takamitsu Hosoya

    Journal of the American Chemical Society 雑誌 American Chemical Society   139 ( 36 )   2017.09

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    Kind of work:Joint Work  

  • Efficient Synthesis of Polycyclic γ-Lactams by Catalytic Carbonylation of Ene-Imines via Nickelacycle Intermediate Reviewed

    Yoichi Hoshimoto, Keita Ashida, Yukari Sasaoka, Ravindra Kumar, Ken Kamikawa, Xavier Verdaguer, Antoni Riera, Masato Ohashi, Sensuke Ogoshi

    Angewandte Chemie International Edition 雑誌 Wiley-VCH   56 ( 28 )   2017.07

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    Kind of work:Joint Work  

  • Synthesis and Reactivity of Fluoroalkyl Copper Complexes by the Oxycupration of Tetrafluoroehtylene Reviewed

    Masato Ohashi, Takuya Adachi, Naoyoshi Ishida, Kotaro Kikushima, Sensuke Ogoshi

    Angewandte Chemie International Edition 雑誌 Wiley-VCH   56 ( 39 )   2017.07

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    Kind of work:Joint Work  

  • Two-step synthesis of chiral fused tricyclic scaffolds from phenols via desymmetrization on nickel Reviewed

    Ravindra Kumar, Yoichi Hoshimoto, Eri Tamai, Masato Ohashi, Sensuke Ogoshi

    Nature Communications 雑誌 Nature Publishing Group   8 ( 32 )   2017.06

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    Kind of work:Joint Work  

  • Phosphorylation of Isocyanates and Aldehydes Mediated by Multifunctional N-Phosphine Oxide-substituted Imidazolylidenes Reviewed

    Yoichi Hoshimoto, Takahiro Asada, Sunit Hazra, Masato Ohashi, Sensuke Ogoshi

    Chemistry Letters 雑誌 Chemical Society of Japan   46   2017.05

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    Kind of work:Joint Work  

  • Nickel(0)-Catalyzed Coupling Reactions of Carbonyls and Alkenes with Reducing Reagents Giving Six- and Seven-Membered Benzocycloalkanols Reviewed

    Yukari Hayashi, Yoichi Hoshimoto, Ravindra Kumar, Masato Ohashi, Sensuke Ogoshi

    Chemistry Letters 雑誌 Chemical Society of Japan   46 ( 8 )   2017.05

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    Kind of work:Joint Work  

  • Kinetic and Theoretical Studies on Ni(0)/N-Heterocyclic Carbene-Catalyzed Intramolecular Alkene Hydroacylation Reviewed

    Yoichi Hoshimoto, Yukari Hayashi, Masato Ohashi, Sensuke Ogoshi

    Chemistry an Asian Journal 雑誌 Wiley-VCH   12 ( 3 )   2017.01

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    Kind of work:Joint Work  

  • Nickel(0)-Mediated Transformation of Tetrafluoroethylene and Vinylarenes into Fluorinated Cyclobutyl Compounds Reviewed

    Masato Ohashi, Yuta Ueda, Sensuke Ogoshi

    Angewandte Chemie International Edition 雑誌 Wiley-VCH   56 ( 9 )   2017.01

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    Kind of work:Joint Work  

  • Strategic Utilization of Multifunctional Carbene for Direct Synthesis of Carboxylic-Phosphinic Mixed Anhydride from CO2 Reviewed

    Yoichi Hoshimoto, Takahiro Asada, Sunit Hazra, Takuya Kinoshita, Panukorn Sombut, Ravindra Kumar, Masato Ohashi, Sensuke Ogoshi

    Angewandte Chemie International Edition 雑誌 Wiley-VCH   55 ( 52 )   2016.11

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    Kind of work:Joint Work  

  • Transition-Metal Mediated Transformation of Tetrafluoroethylene into Various Polyfluorinated Organic Compounds Reviewed

    Masato Ohashi, Sensuke Ogoshi

    有機合成化学協会誌 雑誌 有機合成化学協会   74 ( 11 )   2016.11

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    Kind of work:Joint Work  

  • Nickel-Catalyzed Enantioselective Synthesis of Cyclobutenes via [2+2] Cycloaddition of α,β-Unsaturated Carbonyls with 1,3-Enynes Reviewed

    Ravindra Kumar, Eri Tamai, Akira Ohnishi, Akira Nishimura, Yoichi Hoshimoto, Masato Ohashi, Sensuke Ogoshi

    Synthesis 雑誌 Thieme Chemistry   48 ( 17 )   2016.09

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    Kind of work:Joint Work  

  • Ni(0)-catalyzed intramolecular reductive coupling of alkenes and aldehydes or ketones with hydrosilane Reviewed

    Yukari Hayashi, Yoichi Hoshimoto, Ravindra Kumar, Masato Ohashi, Sensuke Ogoshi

    Chemical Communications 雑誌 Royal Society of Chemistry   52 ( 37 )   2016.04

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    Kind of work:Joint Work  

  • Nickel(0)/N-Heterocyclic Carbene-Catalyzed Asymmetric [2+2+2] Cycloaddition of Two Enones and an Alkyne: Access to Cyclohexenes with Four Contiguous Stereogenic Centers Reviewed

    Ravindra Kumar, Hiromu Tokura, Akira Nishimura, Tadashi Mori, Yoichi Hoshimoto, Masato Ohashi, Sensuke Ogoshi

    Organic Letters 雑誌 American Chemical Society   17 ( 24 )   2015.11

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    Kind of work:Joint Work  

  • Copper-Catalyzed Reaction of Trifluoromethylketones with Aldehydes via a Copper Difluoroenolate Reviewed

    Ryohei Doi, Masato Ohashi, Sensuke Ogoshi

    Angewandte Chemie International Edition 雑誌 Wiley-VCH   55 ( 1 )   2015.10

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    Kind of work:Joint Work  

  • Nickel(0)-Catalyzed Enantio- and Diastereoselective Synthesis of Benzoxasiloles: Ligand-Controlled Switching from Inter- to Intramolecular Aryl-Transfer Process Reviewed

    Ravindra Kumar, Yoichi Hoshimoto, Hayato Yabuki, Masato Ohashi, Sensuke Ogoshi

    Journal of the American Chemical Society 雑誌 American Chemical Society   137 ( 36 )   2015.08

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  • A Strategy to Control the Revival of Frustrated Lewis Pairs from Shelf-Stable Carbene-Borane Complexes Reviewed

    Yoichi Hoshimoto, Takuya Kinoshita, Masato Ohashi, Sensuke Ogoshi

    Angewandte Chemie International Edition 雑誌 Wiley-VCH   54 ( 40 )   2015.08

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    Kind of work:Joint Work  

  • Nickel-Catalyzed Formation of Fluorine-Containing Ketones via the Selective Cross-Trimerization Reaction of Tetrafluoroethylene, Ethylene, and Aldehydes Reviewed

    Masato Ohashi, Hiroshi. Shirataki, Kotaro Kikushima, Sensuke Ogoshi

    Journal of the American Chemical Society 雑誌 American Chemical Society   137 ( 20 )   2015.05

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  • Copper-Mediated One-Pot Synthesis of Trifluorostyrene Derivatives from Tetrafluoroethlene and Arylboronate Reviewed

    Kotaro Kikushima, Hironobu Sakaguchi, Hiroki Saijo, Masato Ohashi, Sensuke Ogoshi

    Chemistry Letters 雑誌 Chemical Society of Japan   44 ( 7 )   2015.05

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    Kind of work:Joint Work  

  • Catalytic Transformation of Aldehydes with Nickel Complexes through eta-2 Coordination and Oxidative Cyclization Reviewed

    Yoichi Hoshimoto, Masato Ohashi, Sensuke Ogoshi

    Accounts of Chemical Research 雑誌 American Chemical Society   48 ( 6 )   2015.05

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    Kind of work:Joint Work  

  • Aza-Nickelacycle Key Intermediate in Nickel(0)-Catalyzed Transformation Reactions Reviewed

    Masato Ohashi, Yoichi Hoshimoto, Sensuke Ogoshi

    Dalton Transactions 雑誌 Royal Society of Chemistry   44 ( 27 )   2015.04

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  • 2,2,3,3-Tetrafluoronickelacyclopentanes Generated via the Oxidative Cyclization of Tetrafluoroethylene and Simple Alkenes: A Key Intermediate in Nickel-Catalyzed C-C Bond-Forming Reactions Reviewed

    Masato Ohashi, Takuya Kawashima, Tomoaki Taniguchi, Kotaro Kikushima, Sensuke Ogoshi

    Organometallics 雑誌 American Chemical Society   34 ( 9 )   2015.04

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  • Synthesis, Characterization, and Unique Catalytic Activities of a Fluorinated Nickel Enolate Reviewed

    Ryohei Doi, Kotaro Kikushima, Masato Ohashi, Sensuke Ogoshi

    Journal of the American Chemical Society 雑誌 American Chemical Society   137   2015.02

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  • Highly Efficient Activation of Organosilanes with eta(2)-Aldehyde Nickel Complexes: Key for Catalytic Syntheses of Aryl-, Vinyl-, and Alkynyl-Benzoxasiloles Reviewed

    Hoshimoto Yoichi, Yabuki Hayato, Kumar Ravindra, Suzuki Haruka, Ohashi Masato, Ogoshi Sensuke

    Journal of the American Chemical Society 雑誌 American Chemical Society   136 ( 48 )   2014.11

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    Kind of work:Joint Work  

  • Nickel(0)-Catalyzed [2+2+1] Carbonylative Cycloaddition of Imines and Alkynes or Norbornene Leading to gamma-Lactams Reviewed

    Hoshimoto Yoichi, Ohata Tomoya, Sasaoka Yukari, Ohashi Masato, Ogoshi Sensuke

    Journal of the American Chemical Society 雑誌 American Chemical Society   136 ( 45 )   2014.11

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    Kind of work:Joint Work  

  • Regioselective C-F Bond Activation of Hexafluoropropylene on Pd(0): Formation of a Cationic η2-Perfluoroallylpalladium Complex Reviewed

    M. Ohashi, M. Shibata, and S. Ogoshi

    Angewandte Chemie International Edition 雑誌 Wiley-VCH   53 ( 49 )   2014.10

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    Kind of work:Joint Work  

  • Fluoroalkylcopper(I) Complexes Generated by the Carbocupration of Tetrafluoroethylene: Construction of a Tetrafluoroethylene-Bridging Structure Reviewed

    Hiroki Saijo, Masato Ohashi, Sensuke Ogoshi

    Journal of the American Chemical Society 雑誌 American Chemical Society   136 ( 43 )   2014.10

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    Kind of work:Joint Work  

  • Palladium-Catalyzed Cross-Coupling Reactions of Perfluoro Organic Compounds Reviewed

    Masato Ohashi, Sensuke Ogoshi

    Catalysts 雑誌 MDPI   4 ( 3 )   2014.09

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    Kind of work:Joint Work  

  • Base-Free Hiyama Coupling Reaction via a Group 10 Metal Fluoride Intermediate Generated by C–F Bond Activation Reviewed

    Hiroki Saijo, Hironobu Sakaguchi, Masato Ohashi, Sensuke Ogoshi

    Organometallics 雑誌 American Chemical Society   33 ( 14 )   2014.07

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  • Synthesis of Cyclobutenes and Allenes via Cobalt-Catalyzed Cross-Dimerization of Simple Alkenes with 1,3-Enynes Reviewed

    Akira Nishimura, Eri Tamai, Masato Ohashi, Sensuke Ogoshi

    Chemistry - A European Journal 雑誌 Wiley-VCH   20 ( 22 )   2014.05

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  • Nickel-Catalyzed Synthesis of N-Aryl-1,2-dihydropyridines by [2+2+2] Cycloaddition of Imines with Alkynes through T-Shaped 14-Electron Aza-Nickelacycle Key Intermediates Reviewed

    Hoshimoto Yoichi, Ohata Tomoya, Ohashi Masato, Ogoshi Sensuke

    Chemistry - A European Journal 雑誌 Wiley-VCH   20 ( 14 )   2014.04

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  • One-Pot, Single-Step, and Gram-Scale Synthesis of Mononuclear [(eta(6)-arene)Ni(N-heterocyclic carbene)] Complexes: Useful Precursors of the Ni-0-NHC Unit Reviewed

    Hoshimoto Yoichi, Hayashi Yukari, Suzuki Haruka, Ohashi Masato, Ogoshi Sensuke

    Organometallics 雑誌 American Chemical Society   33 ( 5 )   2014.03

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    Kind of work:Joint Work  

  • Palladium-Catalyzed Coupling Reaction of Perfluoroarenes with Diarylzinc Compounds Reviewed

    M. Ohashi, R. Doi, and S. Ogoshi

    Chemistry - A European Journal 雑誌 Wiley-VCH   20 ( 7 )   2014.01

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    Kind of work:Joint Work  

  • Carbon-Fluorine Bond Activation of Tetrafluoroethylene on Palladium(0) and Nickel(0): Heat or Lewis Acidic Additive Promoted Oxidative Addition Reviewed

    M. Ohashi, M. Shibata, H. Saijo, T. Kambara, and S. Ogoshi

    Organometallics 雑誌 American Chemical Society   32 ( 13 )   2013.06

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  • Nickel-catalyzed [2+2] Cycloaddition Reaction of Bulky Enones with Simple Alkynes. Effect of Bulkiness of Substituent Attached at β-Carbon Reviewed

    A. Abulimiti, A. Nishimura, M. Ohashi, and S. Ogoshi

    Chemistry Letters 雑誌 Chemical Society of Japan   42 ( 8 )   2013.05

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  • Preparation of Trifluorovinyl Compounds by Lithium Salt Promoted Monoalkylation of Tetrafluoroethylene Reviewed

    M. Ohashi, R. Kamura, R. Doi, and S. Ogoshi

    Chemistry Letters 雑誌 Chemical Society of Japan   42 ( 8 )   2013.05

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  • Ni-Catalyzed [4+3+2] Cycloaddition of Ethyl Cyclopropylideneacetate and Dienynes: Scope and Mechanistic Insights Reviewed

    R. Yamasaki, M. Ohashi, K. Maeda, T. Kitamura, M. Nakagawa, K. Kato, T. Fujita, R. Kamura, K. Kinoshita, H. Masu, I. Azumaya, S. Ogoshi, and S. Saito

    Chemistry - A European Journal 雑誌 Wiley-VCH   19 ( 10 )   2013.01

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  • Palladium-Catalyzed Base-Free Suzuki–Miyaura Coupling Reactions of Fluorinated Alkenes and Arenes via a Palladium Fluoride Key Intermediate Reviewed

    M. Ohashi, H. Saijo, M. Shibata, and S. Ogoshi

    European Journal Organic Chemistry 雑誌 Wiley-VCH   2012.11

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  • Nickel-Catalyzed Intermolecular [2 + 2] Cycloaddition of Conjugated Enynes with Alkenes Reviewed

    A, Nishimura, M. Ohashi, and S. Ogoshi

    Journal of the American Chemical Society 雑誌 American Chemical Society   134   2012.09

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  • Synthesis and Structure of a Mixed-Ligand Dinuclear Ruthenium Trihydrido Complex Supported by Cn* and Cp* Ligands (Cn* = 1,4,7-Trimethyl-1,4,7-triazacyclononane, Cp* = η5-C5Me5): Enhancement of Reactivity toward CO2 by Introduction of the Cn* Ligand Reviewed

    Namura, Kyo; Ohashi, Masato; Suzuki, Hiroharu

    Organometallics 雑誌 American Chemical Society   31 ( 17 )   2012.08

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  • Synthesis of Five- and Six-Membered Benzocyclic Ketones through Intramolecular Alkene Hydroacylation Catalyzed by Nickel(0)/N-Heterocyclic Carbenes Reviewed

    Hoshimoto Yoichi, Hayashi Yukari, Suzuki Haruka, Ohashi Masato, Ogoshi Sensuke

    Angewandte Chemie International Edition 雑誌 Wiley-VCH   51 ( 43 )   2012.04

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  • [3+2] Cycloaddition Reaction of Cyclopropyl Ketones with Alkynes Catalyzed by Nickel/Me2AlCl Reviewed

    T. Tamaki, M. Ohashi, and S. Ogoshi

    Angewandte Chemie International Edition 雑誌 Wiley-VCH   50   2011.10

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  • Nickel-catalyzed Dehydrogenative [4 + 2] Cycloaddition of 1,3-Dienes with Nitriles Reviewed

    M. Ohashi, I. Takeda, M. Ikawa, and S. Ogoshi

    Journal of the American Chemical Society 雑誌 American Chemical Society   133 ( 45 )   2011.10

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  • Nickel-Catalyzed Formation of Cyclopentenone Derivatives via the Unique Cycloaddition of α,β-Unsaturated Phenyl Esters with Alkynes Reviewed

    M. Ohashi, T. Taniguchi, and S. Ogoshi

    Journal of the American Chemical Society 雑誌 American Chemical Society   133   2011.08

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  • Intramolecular Oxidative Cyclization of Alkenes and Nitriles with Nickel(0) Reviewed

    M. Ohashi, M. Ikawa, and S. Ogoshi

    Organometallics 雑誌 American Chemical Society   30   2011.04

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  • Nickel-Catalyzed Selective Conversion of Two Different Aldehydes to Cross-Coupled Esters Reviewed

    Hoshimoto Yoichi, Ohashi Masato, Ogoshi Sensuke

    Journal of the American Chemical Society 雑誌 American Chemical Society   133   2011.04

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  • Palladium-Catalyzed Coupling Reactions of Tetrafluoroethylene with Arylzinc Compounds Reviewed

    Ohashi, Masato; Kambara, Tadashi; Hatanaka, Tsubasa; Saijo Hiroki; Doi, Ryohei; Ogoshi, Sensuke

    Journal of the American Chemical Society 雑誌 American Chemical Society   133 ( 10 )   2011.02

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  • Formation of Six-membered Aza-nickelacycles by Oxidative Addition of Cyclopropyl Imines to Nickel(0) Reviewed

    T. Tamaki, M. Ohashi, and S. Ogoshi

    Chemistry Letters 雑誌 Chemical Society of Japan   40 ( 3 )   2011.02

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  • Rational Synthesis of Supramolecular Assemblies Based on Tetraplatinum Units: Synthesis, Characterization, and Selective Substitution Reactions of Four Different Pt4 Clusters Reviewed

    Tanaka, Shinji; Yagyu, Akihiro; Kikugawa, Masashi; Ohashi, Masato; Yamagata, Tsuneaki; Mashima, Kazushi

    Chemistry - A European Journal 雑誌 Wiley-VCH   17 ( 13 )   2011.02

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  • Nickel(0)-Catalyzed Formation of Oxaaluminacyclopentenes via an Oxanickelacyclopentene Key Intermediate: Me2AlOTf-Assisted Oxidative Cyclization of an Aldehyde and an Alkyne with Nickel(0) Reviewed

    M. Ohashi, H. Saijo, T. Arai, and S. Ogoshi

    Organometallics 雑誌 American Chemical Society   29   2010.10

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  • Nickel-Catalyzed Reactions of Enones with Ethylene Reviewed

    A. Nishimura, T. Haba, M. Ohashi, and S. Ogoshi

    Journal of Physics: Conference Series 雑誌 IOP Publishing   2010.09

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  • Nickel/Lewis Acid-Catalyzed Cyanoesterification and Cyanocarbamoylation of Alkynes Reviewed

    Y. Hirata, A. Yada, E. Morita, Y. Nakao, T. Hiyama, M. Ohashi, and S. Ogoshi

    Journal of the American Chemical Society 雑誌 American Chemical Society   132   2010.09

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  • Nickel-catalyzed [2+2+2] Cycloaddition of Two Enones and an Alkyne Reviewed

    S. Ogoshi, A. Nishimura, and M. Ohashi

    Organic Letters 雑誌 American Chemical Society   12   2010.09

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  • Ni(0) Catalyzed [3 + 3] cyclodimerization of methylenecyclopropanes Reviewed

    T. Taniguchi, M. Ohashi, and S. Ogoshi

    Journal of Physics: Conference Series 雑誌 IOP Publishing   2010.09

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  • Hydrofluoroarylation of Alkynes with Fluoroarenes Reviewed

    K. S. Kanyiva, N. Kashihara, Y. Nakao, T. Hiyama, M. Ohashi and S. Ogoshi

    Dalton Transactions 雑誌 Royal Society of Chemistry   39   2010.08

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  • [3 + 3] Cyclodimerization of Methylenecyclopropanes: Stoichiometric and Catalytic Reactions of Nickel(0) with Electron-Deficient Alkylidenecyclopropanes Reviewed

    M. Ohashi, T. Tomoaki and S. Ogoshi

    Organometallics 雑誌 American Chemical Society   29 ( 11 )   2010.06

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  • Nickel-catalyzed Tishchenko reaction via hetero-nickelacycles by oxidative cyclization of aldehydes with nickel(0) complex Reviewed

    S. Ogoshi, Y. Hoshimoto and M. Ohashi

    Chemical Communications 雑誌 Royal Society of Chemistry   46   2010.05

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    Kind of work:Joint Work  

  • Nickel-catalyzed Reactions between Enone and Two Ethylenes Reviewed

    S. Ogoshi, A. Nishimura, T. Haba and M. Ohashi

    Chemistry Letters 雑誌 Chemical Society of Japan   38   2009.12

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    Kind of work:Joint Work  

  • Synthesis and Reactivity of Six-Membered Hetero-Nickelacycles: Ring-Opening Reaction of Cyclopropyl Ketones Reviewed

    Tamaki, TakashiNagata, MidueOhashi, MasatoOgoshi, Sensuke

    Chemistry - A European Journal 雑誌 Wiley-VCH   15   2009.08

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    Kind of work:Joint Work  

  • Nickel-Catalyzed Direct Conjugate Addition of Simple Alkenes to Enones Reviewed

    Sensuke Ogoshi, Toshifumi Haba, Masato Ohashi

    Journal of the American Chemical Society 雑誌 American Chemical Society   131   2009.07

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    Kind of work:Joint Work  

  • Ni(0)-Catalyzed Formation of Azaaluminacyclopentenes via Azanickelacyclopentenes: A Unique Nickel/Aluminum Double Transmetalation Reaction Reviewed

    Masato Ohashi, Osamu Kishizaki, Haruo Ikeda and Sensuke Ogoshi

    Journal of the American Chemical Society 雑誌 American Chemical Society   131 ( 26 )   2009.06

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    Kind of work:Joint Work  

  • Rare-Earth Metal Alkyl and Hydride Complexes Stabilized by a Cyclen-Derived [NNNN] Macrocyclic Ancillary Ligand Reviewed

    M. Ohashi, M. Konkol, I. Del Rosal, R. Poteau, L. Maron, J. Okuda

    Journal of the American Chemical Society 雑誌 American Chemical Society   130   2008.06

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    Kind of work:Joint Work  

  • Formation of Acylruthenium Promoted by Coordination of AlMe3 to (eta4-Cyclopentadienone)Ru(CO)3 Reviewed

    S. Ogoshi, T. Kato, M. Ohashi, H. Kurosawa

    Dalton Transactions 雑誌 Royal Society of Chemistry   2008.05

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    Kind of work:Joint Work  

  • Nickeladihydrofuran. Key Intermediate for Nickel-catalyzed Reaction of Alkyne and Aldehyde Reviewed

    Ogoshi, Sensuke. Arai, Tomoya. Ohashi, Msato. Kurosawa, Hideo

    Chemical Communications 雑誌 Royal Society of Chemistry   2008.04

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    Kind of work:Joint Work  

  • Linear Metal-Metal Bonded Tetranuclear M-Mo-Mo-M Complexes (M = Ir and Rh): Oxidative Metal-Metal Bond Formation in a Tetrametallic System and 1,4-Addition Reaction of Alkyl Halides. Reviewed

    M. Ohashi, A. Shima, T. Rueffer, H. Mizomoto, Y. Kaneda, K. Mashima

    Inorganic Chemistry 雑誌 American Chemical Society   46   2007.08

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    Kind of work:Joint Work  

  • Tetraplatinum Precursors for Supramolecular Assemblies: Syntheses, Crystal Structures, and Stereoselective Self-Assemblies of [Pt4(myu-OCOCH3)6(kappa4-N4-DArBp)] (DArBp = 1,3-Bis(arylbenzamidinate)propane) Reviewed

    M. Ohashi, A. Yagyu, T. Yamagata, K. Mashima

    Chemical Communications 雑誌 Royal Society of Chemistry   2007.08

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    Kind of work:Joint Work  

  • Ruthenium Polyhydrido Clusters Having a Bridging Alkylzinc Groups, [(eta5-C5Me5)Ru(myu-H)]3(myu3-ZnR)n(myu3-H)2-n and [(eta5-C5Me5)Ru]2(myu-ZnR)n(myu-H)4-n (R = Me and Et; n = 1 and 2) Reviewed

    M. Ohashi, K. Matsubara, H. Suzuki

    Organometallics 雑誌 American Chemical Society   26   2007.04

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    Kind of work:Joint Work  

  • Formation of Dative Bond between Pt and Mo(II) in Linear Pt-Mo(II)-Mo(II)-Pt Complexes, Mo(II)2Pt2(pyphos)4(PR3)2, and Unique 1,4-Oxidative Addition Reaction of Diaryl Disulfides Giving Mo(II)2Pt(I)2(pyphos)4(SAr)2 (pyphos = 6-Diphenylphsphino-2-pyridonato). Reviewed

    K. Mashima, Y. Simoyama, Y. Kusumi, A. Fukumoto, T. Yamagata, M. Ohashi

    European Journal of Inorganic Chemistry 雑誌 Wiley-VCH   2007.01

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    Kind of work:Joint Work  

  • Surface Modification and Photoelectronic Characteristics of the n-Si Electrodes with Brominated and Sulfonylated Alkyl Chains. Reviewed

    M. Ohashi, Y. Nakato, K. Mashima

    Chemistry Letters 雑誌 Chemical Society of Japan   35   2006.12

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    Kind of work:Joint Work  

  • Modification of the n-Si(111) Surface with Alkyl Chains Having the Terminal C=C Double Bond Reviewed

    M. Ohashi, S. Takabayashi, K. Mashima, Y. Nakato

    Chemistry Letters 雑誌 Chemical Society of Japan   35   2006.08

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    Kind of work:Joint Work  

  • Metathesis Approach to Linkage of Two Tetraplatinum Cluster Units: Synthesis, Characterization, and Dimerization of [Pt4(myu-OCOCH3)7(myu-OCO(CH2)nCH=CH2)] (n = 0-3) Reviewed

    M. Ohashi, A. Yagyu, Q. Xu, K. Mashima

    Chemistry Letters 雑誌 Chemical Society of Japan   35   2006.08

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    Kind of work:Joint Work  

  • Hexapalladium Cluster: Unique Cluster Construction Reaction of Cyclic Pd3(CNC6H3Me2-2,6)6 and Linear [Pd3(CNC6H3Me2-2,6)8]2+ Reviewed

    M. Ohashi, J.-J. Yi, D. Shimizu, T. Yamagata, T. Ohshima, and K. Mashima

    Journal of Organometallic Chemistry 雑誌 Elsevier   691   2006.05

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    Kind of work:Joint Work  

  • Surface Structures, Photovoltages, and Stability of n-Si(111) Electrodes Surface Modified with Metal Nano-Dots and Various Organic Groups Reviewed

    S. Takabayashi, M. Ohashi, K. Mashima, Y. Liu, S. Yamazaki, Y. Nakato

    Langmuir 雑誌 American Chemical Society   21   2005.09

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    Kind of work:Joint Work  

  • An Infinite Zigzag Chain of Alternating Cl-Pd-Pd-Cl and Mo-Mo Units Reviewed

    J.-J. Yi, T. Miyabayashi, M. Ohashi, T. Yamagata, K. Mashima

    Inorganic Chemistry 雑誌 American Chemical Society   43   2004.10

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    Kind of work:Joint Work  

  • Unique Oxidative Metal-Metal Bond Formation of Linearly Aligned Tetranuclear Rh-Mo-Mo-Rh Clusters. Reviewed

    T. Rueffer, M. Ohashi, A. Shima, H. Mizomoto, Y. Kaneda, K. Mashima

    Journal of the American Chemical Society 雑誌 American Chemical Society   126   2004.10

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    Kind of work:Joint Work  

  • Trinuclear Ruthenium Polyhydride Complexes with a Triply Bridging Ligand:[{(eta5-C5Me5)Ru}3(myu3-M)(myu-H)3(myu3-H)] (M = Li, MgiPr, and ZnEt) and [{(eta5-C5Me5)Ru}3(myu3-M)(myu-H)3] (M = AlEt and GaMe) Reviewed

    M. Ohashi, K. Matsubara, T. Iizuka, H. Suzuki

    Angewandte Chemie International Edition 雑誌 Wiley-VCH   42   2003.02

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    Kind of work:Joint Work  

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Books and Other Publications

  • 化学便覧 基礎編 改訂6版

    生越 専介、大橋 理人、星本 陽一、菊島 孝太郎、他( Role: Joint author)

    丸善出版  2021.01  ( ISBN:978-4-621-30521-8

  • Nickel Catalysis in Organic Synthesis: Methods and Reactions

    Masato Ohashi( Role: Sole author)

    Wiley-VCH  2020.03  ( ISBN:978-3-527-34407-9

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    Responsible for pages:29-38  

  • 1,2,2-トリフルオロスチレン、フッ素化学入門2015 フッ素化合物の合成法

    生越 専介、大橋 理人( Role: Joint author)

    三共出版  2015.03  ( ISBN:978-4-7827-0727-2

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    Responsible for pages:175-177  

  • Catalytic Transformations of Fluorinated Olefins, in Organometallic Fluorine Chemistry

    Masato Ohashi, Sensuke Ogoshi( Role: Joint author)

    Springer, Cham  2014.12  ( ISBN:978-3-319-22095-6

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    Responsible for pages:197-216  

Charge of on-campus class subject

  • 化学特別研究3A

    2022   Intensive lecture   Graduate school

  • 化学特別演習3A

    2022   Intensive lecture   Graduate school

  • 化学特別研究1A

    2022   Intensive lecture   Graduate school

  • 研究企画ゼミナール

    2022   Intensive lecture   Graduate school

  • 有機化学I

    2022   Weekly class   Undergraduate

  • 化学特別演習3B (中百舌鳥)

    2022   Intensive lecture   Graduate school

  • 化学特別研究3B (中百舌鳥)

    2022   Intensive lecture   Graduate school

  • プロポーザルディフェンス (中百舌鳥)

    2022   Intensive lecture   Graduate school

  • 海外特別研究3 (中百舌鳥)

    2022   Intensive lecture   Graduate school

  • 海外特別研究1 (中百舌鳥)

    2022   Intensive lecture   Graduate school

  • 有機金属化学特論

    2022   Weekly class   Graduate school

  • 化学特別演習1B (中百舌鳥)

    2022   Intensive lecture   Graduate school

  • 化学特別研究1B (中百舌鳥)

    2022   Intensive lecture   Graduate school

  • 分子構造解析I

    2022   Weekly class   Undergraduate

  • 機能物質化学II

    2022   Weekly class   Undergraduate

  • 英語分子科学

    2022   Intensive lecture   Undergraduate

  • サイエンスコミュニケーションI(分子科学)

    2022   Intensive lecture   Graduate school

  • サイエンスコミュニケーションII(分子科学)

    2022   Intensive lecture   Graduate school

  • Science Communication II(Molecular Science)

    2021    

  • Science Communication I(Molecular Science)

    2021    

  • Molecular Science in English

    2021    

  • First Year Seminar

    2021    

  • First Year Seminar

    2021    

  • Materials Chemistry II

    2021    

  • Organic Spectroscopy I

    2021    

  • Organic Chemistry I

    2021    

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Number of instructed thesis, researches

  • 2022

    Number of instructed the graduation thesis:Number of graduation thesis reviews:6

    [Number of instructed the Master's Program] (previous term):14  [Number of instructed the Master's Program] (letter term):3

    [Number of master's thesis reviews] (chief):[Number of master's thesis reviews] (vice-chief):13

    [Number of doctoral thesis reviews] (chief):[Number of doctoral thesis reviews] (vice-chief):0

Academic Activities

  • 有機合成化学協会誌

    2021.04 - 2023.03

  • Organometallic News

    2017.01 - 2018.12