Updated on 2024/03/19

写真a

 
KODAMA Shintaro
 
Organization
Graduate School of Engineering Division of Science and Engineering for Materials, Chemistry and Biology Assistant Professor
School of Engineering Department of Applied Chemistry
Title
Assistant Professor
Affiliation
Institute of Engineering
Contact information
メールアドレス

Position

  • Graduate School of Engineering Division of Science and Engineering for Materials, Chemistry and Biology 

    Assistant Professor  2022.04 - Now

  • School of Engineering Department of Applied Chemistry 

    Assistant Professor  2022.04 - Now

Degree

  • 博士(工学) ( Osaka Prefecture University )

Research Areas

  • Life Science / Bioorganic chemistry

  • Nanotechnology/Materials / Green sustainable chemistry and environmental chemistry

  • Nanotechnology/Materials / Structural organic chemistry and physical organic chemistry

  • Nanotechnology/Materials / Inorganic/coordination chemistry

  • Life Science / Bioorganic chemistry

Research Interests

  • Cluster Complex

  • Vanadium

  • Heteroatom Compound

  • Photofunction

  • Photoacid Generator

  • Organic Synthesis

  • Environmentally Friendly

  • Catalyst

  • Transition Metal

  • Oxidation Reaction

  • Complex

Research subject summary

  • 可視光感光性金属錯体の開発

  • 有機配位子を活用する遷移金属酸化物クラスター合成とその応用

  • 金属との錯形成を鍵とする有機分子骨格変換

Research Career

  • 金属との錯形成を鍵とする有機分子骨格変換

    遷移金属、錯形成、配向基、高効率合成 

    2013.04 - Now 

  • 有機配位子を活用する遷移金属酸化物クラスター合成とその応用

    遷移金属酸化物クラスター、有機配位子、脱水縮合、酸化還元反応  Individual

    2012.04 - Now 

  • 可視光感光性金属錯体の開発

    金属錯体、超強酸、光吸収  Individual

    2012.04 - Now 

Professional Memberships

  • American Chemical Society

    2020.11 - Now   Overseas

  • The Society of Iodine Science

    2020.08 - Now   Domestic

  • The Society of Synthetic Organic Chemistry, Japan

    2018.04 - Now   Domestic

  • Japan Society of Coordination Chemistry

    2017.11 - Now   Domestic

  • Catalysis Society of Japan

    2016.04 - Now   Domestic

  • Kinka Chemical Society, Japan

    2014.11 - Now   Domestic

  • The Chemical Society of Japan

    2011.04 - Now   Domestic

▼display all

Job Career (off-campus)

  • Osaka Metropolitan University   Graduate School of Engineering

    2022.04 - Now

  • Osaka Prefecture University   Graduate School of Engineering

    2019.04 - Now

  • Osaka Prefecture University   Graduate School of Engineering   Postdoctoral Fellow

    2017.04 - 2019.03

Papers

  • Crystal structure of (μ-hydrogen disulfato)-μ-oxido-bis[(4,4′-di-tert-butyl-2,2′-bipyridine)oxidovanadium(IV/V)] acetonitrile monosolvate Reviewed

    Shintaro Kodama , Terushi Hashiguchi , Akihiro Nomoto

    Acta Crystallographica Section E Crystallographic Communications   E79 ( Pt 11 )   1055 - 1058   2023.11

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    Publishing type:Research paper (scientific journal)   International / domestic magazine:International journal  

    DOI: 10.1107/S2056989023009040

    DOI: 10.1107/S2056989023009040

  • A Nonionic Octanuclear Vanadium(V) Oxide Cluster Complex as a Precatalyst for Visible-Light Photooxidation of Alcohols under O<sub>2</sub> Atmosphere Reviewed

    Shintaro Kodama, Terushi Hashiguchi, Akira Okumura, Akihiro Nomoto, Akiya Ogawa

    Chemistry Letters   52 ( 6 )   473 - 476   2023.05( ISSN:0366-7022

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/cl.230144

  • Innovative Green Oxidation of Amines to Imines under Atmospheric Oxygen Reviewed

    Yuki Yamamoto, Shintaro Kodama, Akihiro Nomoto, Akiya Ogawa

    Organic & Biomolecular Chemistry   2022.09( ISSN:1477-0520

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    Authorship:Corresponding author   Publishing type:Research paper (scientific journal)  

    In recent years, the development of environmentally benign molecular construction methods has been of great importance, and especially, resource recycling, high atomic efficiency, and low environmental impact are strongly demanded....

    DOI: 10.1039/d2ob01421a

  • Photoinduced Bisphosphination of Alkynes with Phosphorus Interelement Compounds and Its Application to Double-Bond Isomerization Reviewed

    Yuki Yamamoto, Ryo Tanaka, Shintaro Kodama, Akihiro Nomoto, Akiya Ogawa

    Molecules   27 ( 4 )   1284 - 1284   2022.02

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.3390/molecules27041284

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  • Transition-Metal-Free Synthesis of Unsymmetrical Diaryl Tellurides via SH2 Reaction of Aryl Radicals on Tellurium Reviewed

    Yuki Yamamoto, Fumiya Sato, Qiqi Chen, Shintaro Kodama, Akihiro Nomoto, Akiya Ogawa

    Molecules   27 ( 3 )   2022.01

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.3390/molecules27030809

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  • Excellent Catalytic Performances of a Au/C–CuO Binary System in the Selective Oxidation of Benzylamines to Imines under Atmospheric Oxygen Reviewed

    Yuki Yamamoto, Miyuto Ota, Shintaro Kodama, Michio Ueshima, Akihiro Nomoto, Akiya Ogawa, Mitsunori Furuya, Kiminori Kawakami

    ACS Omega   6 ( 50 )   34339 - 34346   2021.12( ISSN:2470-1343

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsomega.1c04046

    PubMed

  • A two-phase bromination process using tetraalkylammonium hydroxide for the practical synthesis of α-bromolactones from lactones Reviewed

    Yuki Yamamoto, Akihiro Tabuchi, Kazumi Hosono, Takanori Ochi, Kento Yamazaki, Shintaro Kodama, Akihiro Nomoto and Akiya Ogawa

    Beilstein Journal of Organic Chemistry   17   2021.12

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    Kind of work:Joint Work  

  • trans-Bis[8-(benzylsulfanyl)quinoline-κ2 N,S]dichloridocobalt(II) Reviewed

    Shintaro Kodama, Kazuki Bunno, Akihiro Nomoto, Akiya Ogawa

    IUCrData   2021.10

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1107/S2414314621009925

  • Clarification on the Reactivity of Diaryl Diselenides toward Hexacyclohexyldilead under Light Reviewed

    Vu Thai Hung, Cong Chi Tran, Yuki Yamamoto, Shintaro Kodama, Akihiro nomoto, Akiya Ogawa

    Molecules   26 ( 20 )   2021.10

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.3390/molecules26206265

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  • 2,2-Bis(phenylselanyl)-1-(p-tolyl)vinyl 2-Oxo-2-(p-tolyl)acetate Reviewed

    Shintaro Kodama, Vu Thai Hung, Tomokazu Saeki, Kei Mihara, Yuki Yamamoto, Motohiro Sonoda, Akihiro Nomoto, Akiya Ogawa

    Molbank   2021 ( 4 )   M1283 - M1283   2021.09

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    Publishing type:Research paper (scientific journal)  

    2,2-Bis(phenylselanyl)-1-(p-tolyl)vinyl 2-oxo-2-(p-tolyl)acetate was synthesized via the reaction of p-tolylacetylene with diphenyl diselenide and benzoyl peroxide in benzene under atmospheric conditions. The molecular structure of the synthesized compound was evaluated using single-crystal X-ray analysis and spectral analyses. The process reported here provides a rare example of the direct and selective transformation of a terminal alkyne to the corresponding geminal diseleno-substituted alkene.

    DOI: 10.3390/M1283

  • One-Pot Construction of Diverse β-Lactam Scaffolds via the Green Oxidation of Amines and Its Application to the Diastereoselective Synthesis of β-Amino Acids Reviewed

    Yuki Yamamoto, Shintaro Kodama, Riku Nishimura, Akihiro Nomoto, Michio Ueshima, Akiya Ogawa

    The Journal of Organic Chemistry   86 ( 17 )   11571 - 11582   2021.09( ISSN:0022-3263

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.joc.1c01128

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  • Oxidative Synthesis of Acid Blue 7 Dye Catalyzed by CuO/Silicotungstic Acid in Water-Phase Reviewed

    Akihiro Nomoto, Tomoya Okada, Yuki Yamamoto, Shota Kuroda, Kuniaki Marui, Mika Yamamoto, Hidetaka Tsujimoto, Michio Ueshima, Tamotsu Nishigahana, Keiji Itoh, Gohei Kobata, Shintaro Kodama, Akiya Ogawa

    Materials   14 ( 16 )   4505 - 4505   2021.08

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    Publishing type:Research paper (scientific journal)  

    A catalytic oxidation reaction for Acid Blue 7 dye synthesis was evaluated in water. Without lead oxide or manganese oxide derivatives as oxidants, polyoxometalate catalysts were investigated to reduce the usage of harmful heavy metal. A catalyst was prepared by mixing silicotungstic acid with copper oxide, and aqueous hydrogen peroxide (30%) was used as an oxidizing agent. This reaction proceeded to produce Acid Blue 7 from the corresponding leuco acid after 45 min at 95 °C and was viable for a 10 g-scale synthesis.

    DOI: 10.3390/ma14164505

    PubMed

  • Transition-Metal-Catalyzed Diarylation of Isocyanides with Triarylbismuthines for the Selective Synthesis of Imine Derivatives Reviewed

    Shintaro Kodama, Yuki Yamamoto, Yohsuke Kobiki, Hitomi Matsubara, Cong Chi Tran, Shin-ichi Kawaguchi, Akihiro Nomoto, Akiya Ogawa

    Materials   14 ( 15 )   4271 - 4271   2021.07

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    Publishing type:Research paper (scientific journal)  

    The transition-metal-catalyzed diarylation of isocyanides with triarylbismuthines was investigated in detail, and rhodium catalysts such as [RhCl(nbd)]2 were found to selectively afford N-alkyl diaryl ketimines. On the other hand, palladium-catalyzed diarylation proceeded with the incorporation of two molecules of isocyanide, preferentially yielding N,N’-dialkyl or N,N’-diaryl α-diimines. In addition, a cascade synthesis of 2,3-diarylquinoxalines starting from the palladium-catalyzed diarylation of isocyanides with triarylbismuthines was successfully achieved.

    DOI: 10.3390/ma14154271

    PubMed

  • 4,4′-Di-tert-butyl-2,2′-bipyridinium Trifluoromethanesulfonate Reviewed

    Shintaro Kodama, Kazuki Bunno, Akihiro Nomoto, Akiya Ogawa

    Molbank   2021 ( 3 )   2021.07

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.3390/M1261

  • Photoinduced selective hydrophosphinylation of allylic compounds with diphenylphosphine oxide leading to γ-functionalized P-ligand precursors Reviewed

    Dat Phuc Tran, Yuki Sato, Yuki Yamamoto, Shin-ichi Kawaguchi, Shintaro Kodama, Akihiro Nomoto, Akiya Ogawa

    Research on Chemical Intermediates   2021.04( ISSN:0922-6168

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1007/s11164-021-04433-7

    Other URL: http://link.springer.com/article/10.1007/s11164-021-04433-7/fulltext.html

  • Highly regio- and stereoselective phosphinylphosphination of terminal alkynes with tetraphenyldiphosphine monoxide under radical conditions Reviewed

    Dat Phuc Tran, Yuki Sato, Yuki Yamamoto, Shin-ichi Kawaguchi, Shintaro Kodama, Akihiro Nomoto, Akiya Ogawa

    Beilstein Journal of Organic Chemistry   2021.04

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    Kind of work:Joint Work  

  • Large-scale synthesis of thio-glucose-conjugated chlorin E6 for photodynamic therapy Reviewed

    Akihiro Nomoto, Hiroaki Yamaguchi, Masato Masuda, Keisuke Hyakumura, Shintaro Kodama, Tomohiro Osaki, Yoshiharu Okamoto, Mamoru Tanaka, Hiromi Kataoka, Atsushi Narumi, Tomokazu Yoshimura, Shigenobu Yano, Akiya Ogawa

    Heterocycles   103 ( 2 )   2021.03( ISSN:0385-5414

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    Publishing type:Research paper (scientific journal)  

    Chlorin e6 is a heterocycle exhibiting spectral absorption in the 600-700 nm wavelength range used for photodynamic therapy (PDT). Herein, a sugar-conjugated chlorin e6 derivative was synthesized on a large scale. An alkyl spacer was fabricated by controlling the alkoxylation conditions between the thio-sugar and chlorin e6 and thio-glucose-conjugated chlorin e6 was successfully synthesized.

    DOI: 10.3987/COM-20-S(K)73

  • Au/Ag/Cu-Mixed Catalysts for the Eco-Friendly Oxidation of 5-Hydroxymethylfurfural and Related Compounds to Carboxylic Acids under Atmospheric Oxygen in Water Reviewed

    Yuki Yamamoto, Miyuto Ota, Shintaro Kodama, Kazuki Michimoto, Akihiro Nomoto, Akiya Ogawa, Mitsunori Furuya, Kiminori Kawakami

    ACS Omega   6 ( 3 )   2239 - 2247   2021.01( ISSN:2470-1343

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsomega.0c05526

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  • Metal-Free Synthesis of 2-Substituted Quinazolines via Green Oxidation of o-Aminobenzylamines: Practical Construction of N-Containing Heterocycles Based on a Salicylic Acid-Catalyzed Oxidation System Reviewed

    Yuki Yamamoto, Chihiro Yamakawa, Riku Nishimura, Chun-Ping Dong, Shintaro Kodama, Akihiro Nomoto, Michio Ueshima, Akiya Ogawa

    Frontiers in Chemistry   9   822841   2021

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    Publishing type:Research paper (scientific journal)  

    Conventional quinazoline synthesis methods involve a highly multistep reaction, and often require excess amounts of substrate to control the product selectivity, leading to significant resource wastage. Hence, in this study, from the viewpoint of green chemistry, we developed a novel metal-free synthetic method for 2-substituted quinazoline derivatives by the 4,6-dihydroxysalicylic acid-catalyzed oxidative condensation of <italic>o</italic>-aminobenzylamines and benzylamines using atmospheric oxygen. In this system, the use of a catalytic amount of BF<sub>3</sub>‧Et<sub>2</sub>O (10 mol%) as a Lewis acid successfully led to the efficient oxidative condensation and intramolecular cyclization of these amines, followed by aromatization to afford the corresponding 2-arylquinazolines in up to 81% yield with excellent atom economy and environmental factor. Furthermore, to expand this green oxidation method to gram-scale synthesis, we investigated the development of an oxidation process using salicylic acid itself as an organocatalyst, and established a method for the practical green synthesis of a series of nitrogen-containing heterocycles. We expect that the findings will contribute to the development of practical synthesis methods for pharmaceutical manufacturing and industrial applications, along with further advancements in green chemistry.

    DOI: 10.3389/fchem.2021.822841

    PubMed

  • Photoinduced Syntheses and Reactivities of Phosphorus-Containing Interelement Compounds Reviewed

    Yuki Yamamoto, Ryo Tanaka, Miyuto Ota, Misaki Nishimura, Cong Chi Tran, Shin-ichi Kawaguchi, Shintaro Kodama, Akihiro Nomoto, Akiya Ogawa

    The Journal of Organic Chemistry   85 ( 22 )   14708 - 14719   2020.11( ISSN:0022-3263

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.joc.0c02014

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  • Highly Selective Hydroiodination of Carbon–Carbon Double or Triple Bonds Reviewed

    Yuki Yamamoto, Shin-ichi Kawaguchi, Shintaro Kodama, Akihiro Nomoto, Akiya Ogawa

    Current Organic Chemistry   24 ( 18 )   2153 - 2168   2020.11

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    Kind of work:Joint Work  

  • Tris(4,4′-di-tert-butyl-2,2′-bipyridine)(trans-4-tert-butylcyclohexanolato)deca-μ-oxido-heptaoxidoheptavanadium acetonitrile monosolvate including another unknown solvent molecule Reviewed

    Shintaro Kodama, Shota Kondo, Akihiro Nomoto, Akiya Ogawa

    IUCrData   5 ( 4 )   2020.04

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1107/S2414314620004496

  • Metal- and base-free synthesis of aryl bromides from arylhydrazines Reviewed

    Dat Phuc Tran, Akihiro Nomoto, Soichiro Mita, Chun-ping Dong, Shintaro Kodama, Takumi Mizuno, Akiya Ogawa

    Tetrahedron Letters   151959 - 151959   2020.04

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.tetlet.2020.151959

  • Palladium-Catalyzed Diarylation of Isocyanides with Tetraarylleads for the Selective Synthesis of Imines and α-Diimines Reviewed

    Cong Chi Tran, Shin-ichi Kawaguchi, Yohsuke Kobiki, Hitomi Matsubara, Dat Phuc Tran, Shintaro Kodama, Akihiro Nomoto, Akiya Ogawa

    The Journal of Organic Chemistry   84 ( 18 )   11741 - 11751   2019.09( ISSN:0022-3263

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  • 2,4,6-Trihydroxybenzoic Acid-Catalyzed Oxidative Ugi Reactions with Molecular Oxygen via Homo- and Cross-Coupling of Amines Reviewed

    Chun-Ping Dong, Akinori Uematsu, Shun Kumazawa, Yuki Yamamoto, Shintaro Kodama, Akihiro Nomoto, Michio Ueshima, Akiya Ogawa

    The Journal of Organic Chemistry   84 ( 18 )   11562 - 11571   2019.09( ISSN:0022-3263

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.joc.9b01422

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  • 4,6-Dihydroxysalicylic Acid-Catalyzed Oxidative Condensation of Benzylic Amines and Aromatic Ketones for the Preparation of 2,4,6-Trisubstituted Pyridines and Its Application to Metal-Free Synthesis of G-Quadruplex Binding Ligands Reviewed

    Chun Ping Dong, Shintaro Kodama, Akihiro Nomoto, Michio Ueshima, Akiya Ogawa

    ACS Omega   4 ( 5 )   9029 - 9040   2019.05

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    © 2019 American Chemical Society. 4,6-Dihydroxysalicylic acid was activated under air to catalyze the one-pot oxidative condensation reaction of benzylamines with acetophenones in the presence of BF3·Et2O, affording 2,4,6-trisubstituted pyridines in yields of 59-91%. During this metal-free oxidative condensation reaction, the benzylamines not only provided the aryl moiety at the 4-position of the pyridines but also acted as the nitrogen donor. This method can be applied to the metal-free synthesis of G-quadruplex binding ligands by the sequential addition of 4-chlorobutyryl chloride and pyrrolidine to the reaction system of the 2,4,6-trisubstituted pyridine synthesis.

    DOI: 10.1021/acsomega.9b00999

    PubMed

  • Molybdenum-Mediated Vinylidene Rearrangement of Internal Acylalkynes and Sulfonylalkynes Reviewed

    Takuya Kuwabara, Kousuke Sakajiri, Yousuke Oyama, Shintaro Kodama, Youichi Ishii

    Organometallics   2019.03

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  • Reaction of arylhydrazines with diaryl ditellurides in the air: Insight into bimolecular homolytic substitution on tellurium via Aryl-Te bond cleavage Reviewed

    Yuki Yamamoto, Fumiya Sato, Shintaro Kodama, Akihiro Nomoto, Akiya Ogawa

    Heteroatom Chemistry   29 ( 5-6 )   e21471 - e21471   2019.01( ISSN:1042-7163

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/hc.21471

  • Dinuclear Nickel Complexes Doubly Bridged by Hydrogencyanamido Ligands: Synthesis, Structures and Magnetic Properties Reviewed

    Takuya Kuwabara, Natsumi Shiga, Shintaro Kodama, Hirohiko Sato, Hirohiko Houjou, Youichi Ishii

    European Journal of Inorganic Chemistry   2018.08

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    Kind of work:Joint Work  

  • Synthesis of Aryl Iodides from Arylhydrazines and Iodine Reviewed

    Chun-ping Dong, Kentaro Nakamura, Toshihide Taniguchi, Soichiro Mita, Shintaro Kodama, Shin-ichi Kawaguchi, Akihiro Nomoto, Akiya Ogawa, Takumi Mizuno

    ACS Omega   2018.08

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    Kind of work:Joint Work  

  • Ring Slippage and Dissociation of Pentamethylcyclopentadienyl Ligand in an (η5-Cp*)Ir Complex with a κ3-O,C,O Tridentate Calix[4]arene Ligand under Mild Conditions Reviewed

    Takuya Kuwabara, Ryogen Tezuka, Mikiya Ishikawa, Takuya Yamazaki, Shintaro Kodama, Youichi Ishii

    Organometallics   2018.06

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    Kind of work:Joint Work  

  • Reductive Formation of a Vanadium(IV/V) Oxide Cluster Complex [V8O19(4,4′-tBubpy)3] Having a C3-Symmetric Propeller-Shaped Nonionic V8O19 Core Reviewed

    Yuta Inoue, Shintaro Kodama, Nobuto Taya, Hirohiko Sato, Katsuyoshi Oh-ishi, Youichi Ishii

    Inorganic Chemistry   2018.06

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    Kind of work:Joint Work  

  • Visible-Light-Sensitive Sulfonium Photoacid Generators Bearing a Ferrocenyl Chromophore Reviewed

    Yukihiro Takahashi, Shintaro Kodama, Youichi Ishii

    Organometallics   2018.05

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    Kind of work:Joint Work  

  • P–C reductive elimination in Ru(II) complexes to convert triarylphosphine ligands into five- or six-membered phosphacycles Reviewed

    Takuya Kuwabara, Takahiro Kato, Kouichi Takano, Shintaro Kodama, Yuuka Manabe, Noriko Tsuchida, Keiko Takano, Yasunori Minami, Tamejiro Hiyama, Youichi Ishii

    Chemical Communications   2018.05

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    Kind of work:Joint Work  

  • Metal-Free Synthesis of N-Containing Heterocycles from o-Substituted Aniline Derivatives via 2,4,6-Trihydroxybenzoic Acid-Catalyzed Oxidative Dehydrogenation of Benzylamines under Oxygen Atmosphere Reviewed

    Shun Kumazawa, Akinori Uematsu, Chun-ping Dong, Shintaro Kodama, Akihiro Nomoto, Michio Ueshima, Akiya Ogawa

    HETEROCYCLES   2018.04

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    Kind of work:Joint Work  

  • Palladium-Catalyzed Cyanothiolation of Internal Alkynes Using Organic Disulfides and tert-Butyl Isocyanide Reviewed

    Shinya Higashimae, Daichi Kurata, Shin-ichi Kawaguchi, Shintaro Kodama, Motohiro Sonoda, Akihiro Nomoto, Akiya Ogawa

    The Journal of Organic Chemistry   2018.04

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    Kind of work:Joint Work  

  • A Benzoyl Peroxide/Diphenyl Diselenide Binary System for Functionalization of Alkynes Leading to Alkenyl and Alkynyl Selenides Reviewed

    Shintaro Kodama, Tomokazu Saeki, Kei Mihara, Shinya Higashimae, Shin-ichi Kawaguchi, Motohiro Sonoda, Akihiro Nomoto, Akiya Ogawa

    The Journal of Organic Chemistry   2017.11

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    Kind of work:Joint Work  

  • Metal-Free Blue Dye Synthesis: Oxidative Coupling of Benzylamines and N,N-Dimethylanilines to Yield 4,4′-Diaminotriarylmethanes in the Presence of Salicylic Acid as a Co-oxidant Reviewed

    Chun-ping Dong, Shintaro Kodama, Akinori Uematsu, Akihiro Nomoto, Michio Ueshima, Akiya Ogawa

    The Journal of Organic Chemistry   2017.11

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  • Activation of a Carbon–Carbon Bond in Internal Alkynes: Vinylidene Rearrangement of Disubstituted Alkynes at an Ir Complex Reviewed

    Takuya Kuwabara, Shuhei Takamori, Satoshi Kishi, Takahiro Watanabe, Yousuke Ikeda, Shintaro Kodama, Yasunori Minami, Tamejiro Hiyama, Youichi Ishii

    Synlett   2017.10

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    Kind of work:Joint Work  

  • (2-Deoxy-2-{[2-(2-pyridinyl-κN)-4-thiazolecarbonyl-κN3]amino}-α-d-glucopyranose)dichloropalladium(II) Methanol Solvate Reviewed

    Shintaro Kodama, Akihiro Nomoto, Yuta Sakai, Shouhei Katao, Kiyomi Kakiuchi, Shigenobu Yano, Akiya Ogawa

    Molbank   2017.09

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    Kind of work:Joint Work  

  • Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir(III) complex Reviewed

    Takahashi H, Kodama S, Ishii Y.

    Dalton Transactions   2017.08

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    Kind of work:Joint Work  

  • An oxidovanadium(IV) complex having a perrhenato ligand: An efficient catalyst for aerobic oxidation reactions of benzylic and propargylic alcohols Reviewed

    Kobayashi D, Kodama S, Ishii Y.

    Tetrahedron Letters   2017.07

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    Kind of work:Joint Work  

  • Synthesis and Interconversion of V4, V7, and V8 Oxide Clusters: Unexpected Formation of Neutral Heptanuclear Oxido(alkoxido)vanadium(V) Clusters [V7O17(OR)(4,4′-tBubpy)3] (R = Et, MeOC2H4) Reviewed

    Kodama S, Taya N, Inoue Y, Ishii Y.

    Inorganic Chemistry   2016.06

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    Kind of work:Joint Work  

  • Competition between vinylidene rearrangement and 1,2-insertion of carbon-disubstituted internal alkynes at a Cp∗Ir(III) complex Reviewed

    Ikeda Y, Kodama S, Tsuchida N, Ishii Y.

    Dalton Transactions   2015.08

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    Kind of work:Joint Work  

  • I-Line sensitive PAGs and their application to photocrosslinking system Reviewed

    Okamura H, Ashida T, Kodama S, Shirai M.

    Macromolecular Symposia   2015.03

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    Kind of work:Joint Work  

  • Remote rearrangement of the metal center in a (η6-C6Me6)Ru(II) complex Reviewed

    Takano K, Ikeda Y, Kodama S, Ishii Y.

    Chemical Communications   2015.01

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    Kind of work:Joint Work  

  • 1,4- and 1,3-Metal Migration in a Cp*IrIII Complex: Experimental Evidence of Direct 1,3-Metal Migration Reviewed

    Ikeda Y, Takano K, Kodama S, Ishii Y.

    Organometallics   2014.07

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    Kind of work:Joint Work  

  • Reversibility of 1,4-metal migration in Cp*RhIII and Cp*IrIII Complexes Reviewed

    Ikeda Y, Takano K, Waragai M, Kodama S, Tsuchida N, Takano K, Ishii Y.

    Organometallics   2014.04

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  • A novel octanuclear vanadium(V) oxide cluster complex having an unprecedented neutral V8O20 core functionalized with 4,4′-di-tert -butyl-2,2′-bipyridine Reviewed

    Kodama S, Taya N, Ishii Y.

    Inorganic Chemistry   2014.02

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    Kind of work:Joint Work  

  • Vanadium-catalyzed green oxidation of benzylic alcohols in water under air atmosphere Reviewed

    Marui K, Higashiura Y, Kodama S, Hashidate S, Nomoto A, Yano S, Ueshima M, Ogawa A.

    Tetrahedron   2014.02

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  • 1,4-Metal migration in a Cp*Rh(III) complex Reviewed

    Ikeda Y, Takano K, Kodama S, Ishii Y.

    Chemical Communications   2013.10

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    Kind of work:Joint Work  

  • Synthesis and properties of novel i-and g-line sensitive photoacid generators based on 9-fluorenone derivatives with arylethynyl units Reviewed

    Kodama S, Okamura H, Shirai M.

    Chemistry Letters   2012.05

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    Kind of work:Joint Work  

  • Amination of benzoxazoles and 1,3,4-oxadiazoles using 2,2,6,6- tetramethylpiperidine-N-oxoammonium tetrafluoroborate as an organic oxidant Reviewed

    Wertz S, Kodama S, Studer A.

    Angewandte Chemie - International Edition   2011.10

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    Kind of work:Joint Work  

  • Novel Heterotetranuclear V2Mo2 or V2W2 Complexes with 4,4′-Di-tert-butyl-2,2′-bipyridine: Syntheses, Crystal Structures, and Catalytic Activities Reviewed

    Kodama S, Nomoto A, Yano S, Ueshima M, Ogawa A.

    Inorganic Chemistry   2011.09

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    Kind of work:Joint Work  

  • Vanadium-catalyzed atmospheric oxidation of benzyl alcohols using water as solvent Reviewed

    Kodama S, Hashidate S, Nomoto A, Yano S, Ueshima M, Ogawa A.

    Chemistry Letters   2011.04

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    Kind of work:Joint Work  

  • Direct conversion of benzylamines to imines via atmospheric oxidation in the presence of VO(Hhpic)2 catalyst Reviewed

    Kodama S, Yoshida J, Nomoto A, Ueta Y, Yano S, Ueshima M, Ogawa A.

    Tetrahedron Letters   2010.03

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    Kind of work:Joint Work  

  • Tetranuclear vanadium complex, (VO)4(hpic)4: a recyclable catalyst for oxidation of benzyl alcohols with molecular oxygen Reviewed

    Kodama S, Ueta Y, Yoshida J, Nomoto A, Yano S, Ueshima M, Ogawa A.

    Dalton Transactions   2009.09

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    Kind of work:Joint Work  

  • Transition-metal-catalyzed hydrothiolation of cyclohexylallene with benzenethiol or diphenyl disulfide Reviewed

    Kodama S, Nomoto A, Kajitani M, Nishinaka E, Sonoda M, Ogawa A.

    Journal of Sulfur Chemistry   2009.06

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    Kind of work:Joint Work  

  • A novel palladium(0)-catalyzed addition of diphenyl disulfide to allenes leading to vicinal disulfides and its application to carbonylation with carbon monoxide Reviewed

    Kodama S, Nishinaka E, Nomoto A, Sonoda M, Ogawa A.

    Tetrahedron Letters   2007.07

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    Kind of work:Joint Work  

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Books and Other Publications

  • サリチル酸を有機分子触媒に用いた酸化反応

    小玉 晋太朗,小川 昭弥( Role: Joint author)

    公益社団法人日本化学会・化学と教育  2023.12 

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    Responsible for pages:548-551  

  • 水中有機化学反応プロセスの開発動向「第2章 遷移金属触媒によるアルコールおよびアミンの水中酸化反応」

    小玉晋太朗,小川昭弥( Role: Joint author)

    株式会社シーエムシー出版  2022.03 

  • 環境にやさしい触媒的液相系酸化反応の開発と有機触媒の適用

    野元 昭宏,小玉 晋太朗,小川 昭弥( Role: Joint author)

    公益社団法人 石油学会  2020.10 

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    Responsible for pages:697-702  

  • UV硬化樹脂の配合設計、物性評価と新しい応用「第3節 有機―金属複合型光酸発生剤の構造と物性」

    小玉 晋太朗,石井 洋一( Role: Joint author)

    株式会社 技術情報協会  2017.11 

  • 金属との錯形成により感光波長を変更できる配位子型光酸発生剤の開発

    小玉 晋太朗,木曽川 悠太,石井 洋一( Role: Joint author)

    株式会社 化学工業社  2014.12 

Presentations

  • Metal-Free Syntheses of 2,4,6-Trisubstituted Pyridines and Dipeptides Based on 2,4,6-Trihydroxybenzoic Acid- Catalyzed Oxidation of Benzylic Amines with O2 as an Oxidant Invited

    Shintaro Kodama, Chun-ping Dong, Akinori Uematsu, Shun Kumazawa, Yuki Yamamoto, Akihiro Nomoto, Michio Ueshima, Akiya Ogawa

    The 8th TKU ECUST OPU KIST UH IHU KMITL UTAR TNU Joint Symposium on Advanced Materials and Applications  2019.11 

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    Presentation type:Oral presentation (invited, special)  

Industrial Property Rights

  • 金属錯体、その製造方法、それに用いるオキシムスルホネート系化合物、およびそれを用いた光酸発生剤

    小玉 晋太朗、 木曽川 悠太、 石井 洋一

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    property_type:Patent 

  • 異種金属4核錯体及び酸化物の製造方法

    小川 昭弥、 小玉 晋太朗、 野元 昭宏、 植嶌 陸男

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    property_type:Patent 

Charge of on-campus class subject

  • 化学外国語演習

    2023   Weekly class   Undergraduate

  • 有機化学演習IIA

    2023   Weekly class   Undergraduate

  • 応用化学実験III

    2023   Weekly class   Undergraduate

  • 物質化学生命系特別演習

    2023   Intensive lecture   Graduate school

  • 物質化学生命系特別研究第1

    2023   Intensive lecture   Graduate school

  • 物質化学生命系特別演習第1

    2023   Intensive lecture   Graduate school

  • 応用化学実験IV

    2023   Weekly class   Undergraduate

  • 物質化学生命系特別研究

    2023   Intensive lecture   Graduate school

  • 応用化学特論3

    2023   Weekly class   Graduate school

  • 物質化学生命系特別研究第2

    2023   Intensive lecture   Graduate school

  • 物質化学生命系特別演習第2

    2023   Intensive lecture   Graduate school

  • 化学外国語演習

    2023   Weekly class   Undergraduate

  • 有機化学演習1

    2023   Weekly class   Undergraduate

  • 応用化学実験1

    2023   Weekly class   Undergraduate

  • 応用化学実験II

    2023   Intensive lecture   Undergraduate

  • 応用化学実験V

    2023   Weekly class   Undergraduate

  • 物質化学生命系特別演習第1

    2022   Intensive lecture   Graduate school

  • 有機化学演習IIA

    2022   Weekly class   Undergraduate

  • 応用化学実験I

    2022   Weekly class   Undergraduate

  • 応用化学実験III

    2022   Weekly class   Undergraduate

  • 物質化学生命系特別演習

    2022   Intensive lecture   Graduate school

  • 物質化学生命系特別研究 (応用化学分野)

    2022   Intensive lecture   Graduate school

  • 物質化学生命系特別演習第2 (応用化学分野)

    2022   Intensive lecture   Graduate school

  • 応用化学特論3 (応用化学分野)

    2022   Weekly class   Graduate school

  • 応用化学実験II

    2022   Weekly class   Undergraduate

  • 応用化学実験IV

    2022   Weekly class   Undergraduate

  • 応用化学実験V

    2022   Weekly class   Undergraduate

  • 有機化学演習IA

    2022   Weekly class   Undergraduate

  • Laboratory Exercises for Applied Chemistry II

    2021   Practical Training  

  • Laboratory Exercises for Applied Chemistry I

    2021   Practical Training  

  • Laboratory Exercises for Applied Chemistry V

    2021   Practical Training  

  • Laboratory Exercises for Applied Chemistry III

    2021   Practical Training  

  • Laboratory Exercises for Applied Chemistry IV

    2021   Practical Training  

  • Exercises in Organic Chemistry IIA

    2021    

  • Exercises in Organic Chemistry IA

    2021    

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