Updated on 2024/12/11

写真a

 
KOZAKI Masatoshi
 
Organization
Graduate School of Science Department of Chemistry Professor
School of Science Department of Chemistry
Title
Professor
Affiliation
Institute of Science
Contact information
メールアドレス
Homepage
http://www.sci.osaka-cu.ac.jp/chem/phyorg/POCweb/pg18.html
Affiliation campus
Sugimoto Campus

Position

  • Graduate School of Science Department of Chemistry 

    Professor  2022.04 - Now

  • School of Science Department of Chemistry 

    Professor  2022.04 - Now

Degree

  • Doctor of Science （ The Graduate University for Advanced Studies ）

Research Areas

  • Nanotechnology/Materials / Structural organic chemistry and physical organic chemistry  / Organic Chemistry

  • Nanotechnology/Materials / Functional solid state chemistry  / Function, Properties and Materials in Chemistry

  • Nanotechnology/Materials / Polymer chemistry  / 精密構造高分子

Research Interests

  • Organic Conductors

  • Dendrimers

  • Stimuli-Responsive Molecules and Materials

  • ヘテロ原子を含む縮合多環芳香族化合物

Research subject summary

  • The physical properties of pai-conjugated molecules can be precisely controlled by structural modification. The goal of our projects is to create organic compounds with unique electronic, optical, and magnetic properties. In addition, we are developing precisely designed macromolecules such as dendrimers that can be thought of as highly organized nanostructures. From this point of view, we are conducting research on the development of efficient construction methods for pai-conjugated molecules and nanoscale molecules.

Research Career

  • Studies on the dendrimers with both conjugated and non-conjugated chains

    dendrimers, polybenzylethers, oligo(phenylene-ethynylene)  Individual

    2002.04 - Now 

  • 含窒素縮合多環芳香族化合物に関する研究

    含窒素芳香族化合物  Individual

    2017.04 - Now 

  • Development of stimuli-responsive molecules

    Stimuli-responsive, Allosteric, Porphyrin  Individual

    2010.04 - 2019.03 

  • Preparation and Properties of Novel Conjugated Systems

    Conjugated Systems  Individual

    1990.04 - 1994.03 

Professional Memberships

  • THE CHEMICAL SOCIETY OF JAPAN

      Domestic

  • The Japanese Photochemistry Association

      Domestic

  • THE SOCIETY OF SYNTHETIC ORGANIC CHEMISTRY, JAPAN

  • 有機π電子系学会

  • 基礎有機化学会

Committee Memberships (off-campus)

  • 日本化学会第99春季年会　プログラム委員   日本化学会  

    2018.12 

  • 幹事   有機π電子系学会  

    2018.12 - Now 

Job Career (off-campus)

  • University of South Carolina   Postdoctoral Researcher

    1995 - 1997

  • Institute of Molecular Science

    1994.04 - 1994.05

  • University of Alabama   Postdoctoral Researcher

    1994 - 1995

Education

  • The Graduate University for Advanced Studies   Doctor's Course  

    - 1994

  • Nagoya Institute of Technology   The first semester of doctoral program   Graduated/Completed

    1989.04 - 1991.03

  • Nagoya Institute of Technology    

    - 1989

Papers

  • Synthesis and Properties of Fused Polycyclic Donor–Acceptor Compounds Containing Carbazole and Diazapyrene Skeletons Reviewed

    Suzuho Kurimoto, Yoshimitsu Tachi, Masatoshi Kozaki

    Asian J. Org. Chem.   2024

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    Authorship：Corresponding author   International / domestic magazine：International journal  

    DOI： 10.1002/ajoc.202400289

  • Synthesis and Metal‐Complexation of a Trimer of Dendrimers with Bipyridine Cores in the Center of Conjugated Chains Reviewed

    Ayaka Sawada, Yoshimitsu Tachi, Masatoshi Kozaki

    ChemistrySelect   8 ( 47 )   2023.12（ ISSN:2365-6549 ） （ eISSN:2365-6549 ）

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)  

    Abstract

    Two types of dendrimers with a bipyridine unit in the center of their rigid backbones were prepared. One dendrimer has two azide groups and the other has one ethynyl terminal. These dendrimers were coupled by the copper‐mediated Hüisgen 1,3‐dipolar cycloadditions of the ethynyl and azide terminals to afford a trimer with three bipyridine cores. The addition of Fe(II) to a solution of the trimer resulted in an absorption change characteristic of the formation of tris(bipyridine)Fe(II) complexes. The structural properties of the tris(bipyridine)Fe(II) core are likely reflected in the conformation of the timer because the bipyridine units are attached to the rigid backbones.

    DOI： 10.1002/slct.202303500

  • Platinum octaethylporphyrin-diphenylanthracene dyad with an ethynylene linker Reviewed

    Wada, Takumi; Tachi, Yoshimitsu; Toyota, Kazuo; Kozaki, Masatoshi

    Tetrahedron Letters   108   154131   2022.10

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)   International / domestic magazine：International journal  

    DOI： 10.1016/j.tetlet.2022.154131

    DOI： 10.1016/j.tetlet.2022.154131

  • A fused polycyclic compound containing phenothiazine and diazapyrene skeletons with weak D-A interactions Reviewed

    Keito Matsumoto, Yoshimitsu Tachi, Masatoshi Kozaki

    Chemical Communications   58 ( 61 )   8572 - 8575   2022.07（ ISSN:1359-7345 ） （ eISSN:1364-548X ）

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)   International / domestic magazine：International journal  

    A small fused polycyclic molecule containing a phenothiazine and diazapyrene skeleton as the donor and acceptor, respectively, has a redox potential similar to those of the corresponding donor and acceptor molecules, indicating that the inherent electronic properties of the donor and acceptor were retained due to weak orbital interactions.

    DOI： 10.1039/d2cc02635j

    PubMed

  • Synthesis of Triazabenzo[a]pyrenes and Their Photophysical, Acid-Responsive, and Electrochemical Properties Reviewed

    Masani, Yasufumi; Omura, Yuta; Tachi, Yoshimitsu; Kozaki, Masatoshi

    Asian Journal of Organic Chemistry   11 ( 5 )   e202200015   2022.05

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)   International / domestic magazine：International journal  

    Repository URL： http://hdl.handle.net/10466/0002000355

  • Heteroatom-incorporated Trimethylenemethane: Synthesis and Properties of Triphenylphenylnitroxide–(Nitronyl Nitroxide) Dyad

    Kumagai Tasuku, Suzuki Shuichi, Kanzaki Yuki, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Tanaka Rika, Okada Keiji, Kozaki Masatoshi

    Chemistry Letters   51 ( 4 )   458 - 460   2022.04（ ISSN:03667022 ） （ eISSN:13480715 ）

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)   International / domestic magazine：International journal  

    <p>We designed and synthesized a triphenylphenylnitroxide–(nitronyl nitroxide) dyad with a structure isoelectronic with trimethylenemethane. Crystal structure analysis demonstrated that the dihedral angle between the nitroxide and nitronyl nitroxide moieties was excessively small due to the steric effects of the triphenylphenyl moiety. The coplanarity of the two radical systems induced an excessively strong ferromagnetic intramolecular interaction (2<i>J</i>/<i>k</i><sub>B</sub> ≥ +2000 K; <i>H</i> = −2<i>J</i><b>S<sub>1/2</sub></b>•<b>S<sub>1/2</sub></b>).</p>

    DOI： 10.1246/cl.220021

  • A Molecule Having 13 Unpaired Electrons: Magnetic Property of a Gadolinium(III) Complex Coordinated with Six Nitronyl Nitroxide Radicals Reviewed

    Ryu Tanimoto, Tomoyuki Wada, Keiji Okada, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Shuichi Suzuki, Takeshi Naota, Masatoshi Kozaki

    Inorganic Chemistry   61 ( 7 )   3018 - 3023   2022.02（ ISSN:0020-1669 ） （ eISSN:1520-510X ）

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)   International / domestic magazine：International journal  

    DOI： 10.1021/acs.inorgchem.1c03764

  • Intriguing Properties and Functionalities of Extremely Stable Radical Cation Species Reviewed

    Shuichi Suzuki, Masatoshi Kozaki, and Takeshi Naota

    80 ( 9 )   843 - 853   2022

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    Publishing type：Research paper (scientific journal)   International / domestic magazine：Domestic journal  

    DOI： 10.5059/yukigoseikyokaishi.80.843

  • Synthesis of Triazabenzo[ <i>a</i>]pyrenes and Their Photophysical, Acid‐Responsive, and Electrochemical Properties Reviewed

    Yasufumi Masani, Yuta Omura, Yoshimitsu Tachi, Masatoshi Kozaki

    Asian Journal of Organic Chemistry   - ( 5 )   2022（ ISSN:2193-5807 ） （ eISSN:2193-5815 ）

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/ajoc.202200015

    Other URL： https://onlinelibrary.wiley.com/doi/full-xml/10.1002/ajoc.202200015

  • Smallest Organic Tetracation in the Gas Phase: Stability of Multiply Charged Diiodoacetylene Produced in Intense Femtosecond Laser Fields Reviewed

    Kawaguchi Takashi, Kitagawa Kosei, Toyota Kazuo, Kozaki Masatoshi, Okada Keiji, Nakashima Nobuaki, Yatsuhashi Tomoyuki

    American Chemical Society (ACS)　JOURNAL OF PHYSICAL CHEMISTRY A   125 ( 36 )   8014 - 8024   2021.09（ ISSN:1089-5639 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.jpca.1c06390

    PubMed

  • Aurophilic Interactions in Multi-Radical Species: Electronic-Spin and Redox Properties of Bis- and Tris-[(Nitronyl Nitroxide)-Gold(I)] Complexes with Phosphine-Ligand Scaffolds Reviewed

    Kira Sayaka, Miyamae Takayuki, Yoshida Kohei, Kanzaki Yuki, Sugisaki Kenji, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Suzuki Shuichi, Kozaki Masatoshi, Okada Keiji

    Wiley　CHEMISTRY-A EUROPEAN JOURNAL   27 ( 44 )   11450 - 11457   2021.08（ ISSN:0947-6539 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/chem.202101483

    PubMed

    Other URL： https://onlinelibrary.wiley.com/doi/full-xml/10.1002/chem.202101483

  • Photovoltaic investigation of CPDT based small molecule for BHJ OSC devices Reviewed

    Rania Zaier, Masatoshi Kozaki, Sahbi Ayachi

    18th IEEE International Multi-Conference on Systems, Signals and Devices, SSD 2021   1345 - 1349   2021.03

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    Publishing type：Research paper (scientific journal)  

    In recent years, Bulk heterojunction organic solar cells (BHJ OSCs) based small molecules take leading position of industrialization for their considerable opto-electronic properties and uncomplicated fabrication process. Materials based on cyclopentadithiophene (CPDT) have been widely used thanks to their interesting structural and electronic characteristics. Here we report a combined experimental and theoretical investigation of a CPDT-based material namely 6,6′-(2,5-bis (hexyloxy)-1,4-phenylene) bis(2-methyl -4H- cyclopenta [2,1-b:3,4-b'] dithiophen-4-one) (CPDT-alt-BHP) as donor small molecule in a BHJ OSC. The synthesized molecule shows a rigid and planar structure with small band gap energy. The electronic properties have been investigated by means of Density Functional Theory (DFT) at B3LYP/6-31g(d) level of theory. The studied molecule displayed an optical absorption in the visible region with nm. Transition density matrix (TDM) plot was carried out to get insight into the hole-electron coherences at the first excited state. The photovoltaic parameters of CPDTBHP:[70]PCBM system were simulated using wxAMPS software. The designed BHJ OSC exhibited respectable fill factor (FF) of 81.13%, short-circuit current density (Jsc) of 6.089 mA cm-2 and power conversion efficiency (PCE) of 4.922%. The studied compound offers significant structural and optoelectronic properties that could be enhanced via judicious molecular tuning.

    DOI： 10.1109/SSD52085.2021.9429491

  • Syntheses and Properties of (Nitronyl nitroxide)-substituted Tri-phenylamine ortho-Bridged by Two Oxygen and Sulfur Atoms Reviewed

    Yokoyama Naoki, Tanaka Nobuaki, Fujimoto Natsumi, Tanaka Rika, Suzuki Shuichi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Kozaki Masatoshi, Okada Keiji

    Wiley　CHEMISTRY-AN ASIAN JOURNAL   16 ( 1 )   72 - 79   2021.01（ ISSN:1861-4728 ）

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)   Kind of work：Joint Work   International / domestic magazine：International journal  

    DOI： 10.1002/asia.202001227

    Other URL： https://onlinelibrary.wiley.com/doi/full-xml/10.1002/asia.202001227

  • Magnetic Properties of Metal Clusters Coordinated with (Nitronyl Nitroxide)-Substituted Amidinate Ligands Reviewed

    Tanimoto Ryu, Suzuki Shuichi, Kozaki Masatoshi, Kanzaki Yuki, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Tanaka Rika, Okada Keiji

    Wiley　CHEMISTRYSELECT   5 ( 36 )   11170 - 11176   2020.09（ ISSN:2365-6549 ）

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)   Kind of work：Joint Work   International / domestic magazine：International journal  

    DOI： 10.1002/slct.202002927

    Other URL： https://onlinelibrary.wiley.com/doi/full-xml/10.1002/slct.202002927

  • Condensed Phenoxazine Dimer and Its Radical Cation Reviewed

    Miyamae Takayuki, Haraguchi Makoto, Tachi Yoshimitsu, Suzuki Shuichi, Kozaki Masatoshi, Okada Keiji

    American Chemical Society (ACS)　ORGANIC LETTERS   22 ( 17 )   6790 - 6793   2020.09（ ISSN:1523-7060 ）

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)   Kind of work：Joint Work   International / domestic magazine：International journal  

    DOI： 10.1021/acs.orglett.0c02305

  • Theoretical study on electro-optical properties of cyclopentadithiophene based material for OLED

    Zaier R.

    Proceedings of the 17th International Multi-Conference on Systems, Signals and Devices, SSD 2020   609 - 611   2020.07（ ISBN:9781728110806 ）

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  • Inhibition of Ligand Binding Ability of Three Porphyrins by an Organic Effector Reviewed

    Nishimura Tomoaki, Sasaki Yoshito, Tachi Yoshimitsu, Suzuki Shuichi, Okada Keiji, Kozaki Masatoshi

    CHEMISTRY-AN ASIAN JOURNAL   2020.01（ ISSN:1861-4728 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/asia.201901711

  • Spin-dependent electron transfer dynamics in a platinum-complex−donor−acceptor triad studied by transient-absorption detected magnetic field effect Reviewed

    Tomoaki Miura, Kio Miyaji, Takafumi Horikoshi, Shuichi Suzuki, Masatoshi Kozaki, Keiji Okada, and Tadaaki Ikoma

    J. Chem. Phys.   151   234306/1 - 234306/9   2019.12

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    Publishing type：Research paper (scientific journal)   Kind of work：Joint Work  

    DOI： 10.1063/1.5127940

  • Redox‐Induced Modulation of Exchange Interaction in a High‐Spin Ground‐State Diradical/Triradical System Reviewed

    Atsuki Nagata, Shinsuke Hiraoka, Shuichi Suzuki, Masatoshi Kozaki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Rika Tanaka, Keiji Okada

    Chemistry – A European Journal   26 ( 14 )   3166 - 3172   2019.12

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    Publishing type：Research paper (scientific journal)   Kind of work：Joint Work  

    DOI： 10.1002/chem.201905465

  • Disorder-Enhanced Dimensionless Thermoelectric Figure of Merit zT of Non-stoichiometric Organic Conductor (TTT)(2)I3+delta (delta <= 0.1) Reviewed

    Yoshino Harukazu, Hasegawa Akifumi, Kuroda Natsuki, Ishikawa Manabu, Tanaka Rika, Kozaki Masatoshi, Nakano Yoshiaki, Otsuka Akihiro, Yamochi Hideki

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   88 ( 10 )   2019.10（ ISSN:0031-9015 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.7566/JPSJ.88.104708

  • Synthesis and Magnetic Properties of (Pyrrolidin-1-oxyl)-(Nitronyl Nitroxide)/(Iminonitroxide)-Dyads Reviewed

    Tsujimoto Haruki, Suzuki Shuichi, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Okada Keiji

    CHEMISTRY-AN ASIAN JOURNAL   14 ( 10 )   1801 - 1806   2019.05（ ISSN:1861-4728 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/asia.201801615

  • Triplet Diradical Cation Salts Consisting of Phenothiazine Radical Cation and Nitronyl Nitroxide Reviewed

    Takuma Tahara, Shuichi Suzuki, Masatoshi Kozaki, Daisuke Shiomi, Kenji Suigisaki, Kazunobu Sato, Takui Takeji, Yota Miyake, Yuko Hosokoshi, Hiroyuki Nojiri, Keiji Okada

    Eur. J. Chem.   25 ( 29 )   7201 - 7209   2019.03（ ISSN:0947-6539 ）

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    Publishing type：Research paper (scientific journal)   Kind of work：Joint Work  

    DOI： 10.1002/chem.201900513

  • DFT and TD-DFT studies on the electronic and optical properties of linear π-conjugated cyclopentadithiophene (CPDT) dimer for efficient blue OLED Reviewed International coauthorship

    Rania Zaier, Said Hajaji, Masatoshi Kozaki, Sahbi Ayachi

    Opt. Mater.   90   108 - 114   2019.03（ ISSN:0925-3467 ）

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    Publishing type：Research paper (scientific journal)   Kind of work：Joint Work  

    DOI： 10.1016/j.optmat.2019.03.013

  • Synthesis and Properties of Nitrogen-Containing Pyrenes Reviewed

    Yuta Omura, Yoshimitsu Tachi, Keiji Okada, Masatoshi Kozaki

    The Journal of Organic Chemistry   84 ( 4 )   2032 - 2038   2019.01

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)   Kind of work：Joint Work  

    DOI： 10.1021/acs.joc.8b02962

  • Structures and Electronic Properties of Diisopropylaminoborane Substituted with Highly Electron-Rich π-Conjugated Systems and Their Oxidized States Reviewed

    Kohei Yoshida, Shuichi Suzuki, Masatoshi Kozaki, Keiji Okada

    Bull. Chem. Soc. Jpn.   2019

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    Publishing type：Research paper (scientific journal)   Kind of work：Single Work  

    DOI： 10.1246/bcsj.20190199

  • Preparation and Properties of a Polycyclic p-Quinodimethane with Two Oxygen Bridges and its Radical Cation in Comparison with the Isomeric o-Quinodimethane Reviewed

    Chihiro Sato, Shuichi Suzuki, Keiji Okada, Masatoshi Kozaki

    Chem. Asian J.   13 ( 23 )   3729 - 3736   2018.09

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)   Kind of work：Joint Work   International / domestic magazine：International journal  

    DOI： 10.1002/asia.201801269

  • Ligand-Binding Ability of a Porphyrin Core in a Dendrimer with Rigid Branched Terminal Components Reviewed International coauthorship

    Mami Akisada, Ryo Kimura, Yoshimitsu Tachi, Shuichi Suzuki, Keiji Okada, Masatoshi Kozaki

    The Journal of Organic Chemistry   83 ( 17 )   9631 - 9640   2018.08

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)   Kind of work：Joint Work  

    DOI： 10.1021/acs.joc.8b00932

  • Chemical Stability of the 5-Mesityl-5′′-(nitronyl nitroxide)-2,2′:5′,2′′-ter(3,4-ethylenedioxythiophene) Radical Cation Reviewed

    The Chemical Society of Japan, Bull. Chem. Soc. Jpn.   91 ( 8 )   1193 - 1195   2018.08（ ISSN:0009-2673 ）

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    <p>Only a few radical-substituted <i>π</i>-donor radical cations have been reported to date. In this note, 5-mesityl-5′′-(nitronyl nitroxide)-2,2′:5′,2′′-ter(3,4-ethylenedioxythiophene) (<b>NN-TEDOT</b>) was prepared and its electrochemical and chemical oxidations were examined. The <b>NN-TEDOT</b> radical cation was moderately stable and slowly decomposed.</p>

    DOI： 10.1246/bcsj.20180078

    CiNii Article

  • Radical Metalloids with N-Heterocyclic Carbene and Phenanthroline Ligands: Synthesis, Properties, and Cross-Coupling Reaction of [(Nitronyl Nitroxide)-2-ido]metal Complexes with Aryl Halides Reviewed

    Kiyomi Yamada, Xun Zhang, Ryu Tanimoto, Shuichi Suzuki, Masatoshi Kozaki, Rika Tanaka, Keiji Okada

    公益社団法人 日本化学会　BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   91 ( 7 )   1150 - 1157   2018.07（ ISSN:0009-2673 ）

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    <p>New radical metalloids, <b>NN-AuSIMes</b> and <b>NN-Cu(bdmpphen)</b>, were prepared and their properties were investigated. They were applied to Pd(0)-mediated cross-coupling reactions with aryl halides (ArX) to produce 2-aryl (nitronyl nitroxide)s in moderate to high yields.</p>

    DOI： 10.1246/bcsj.20180033

    CiNii Article

  • Group 11 Metal Complexes Coordinated by the (Nitronyl Nitroxide)-2-ide Radical Anion: Facile Oxidation of Stable Radicals Controlled by Metal-Carbon Bonds in Radical-Metalloids Reviewed

    Ryu Tanimoto, Kiyomi Yamada, Shuichi Suzuki, Masatoshi Kozaki, Keiji Okada

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY   ( 10 )   1198 - 1203   2018.03（ ISSN:1434-1948 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/ejic.201800038

  • Chemical Stimulus-responsive Folding and Unfolding of a Dendrimeric Assembly Reviewed

    Ryo Kimura, Shuichi Suzuki, Keiji Okada, Masatoshi Kozaki

    CHEMISTRY-AN ASIAN JOURNAL   13 ( 1 )   35 - 40   2018.01（ ISSN:1861-4728 ）

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/asia.201701487

  • (Azulene-1,3-diyl)-bis(nitronyl nitroxide) and (Azulene-1,3-diyl)-bis(iminonitroxide) and Their Copper Complexes Reviewed

    Makoto Haraguchi, EvgenyTretyakov, Nina Gritsan, Galina Romanenko, Dmitry Gorbunov, Artem Bogomyakov, Kseniya Maryunina, Shuichi Suzuki, Masatoshi Kozaki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Sadafumi Nishihara, Katsuya Inoue, Keiji Okada

    CHEMISTRY-AN ASIAN JOURNAL   12 ( 22 )   2929 - 2941   2017.11（ ISSN:1861-4728 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/asia.201701085

  • Synthesis and Magnetic Properties of Trioxytriphenylamine Dimers in their Di(radical cationic) States Reviewed

    Shuichi Suzuki, Nobuaki Tanaka, Masatoshi Kozaki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Keiji Okada

    CHEMISTRY-A EUROPEAN JOURNAL   23 ( 63 )   16014 - 16025   2017.11（ ISSN:0947-6539 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/chem.201703220

  • Construction of Dendritic Element-brock Polymers Invited

    Masatoshi Kozaki

    Chemical Industry   68 ( 11 )   14(810) - 19(815)   2017.11

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    Publishing type：Research paper (scientific journal)   Kind of work：Single Work  

  • Trimeric Assembly of Dendritic Light-Harvesting Antenna with Two Kinds of Porphyrin Cores Reviewed

    Ryo Kimura, Shuichi Suzuki , Keiji Okada , Masatoshi Kozaki

    THE JOURNAL OF ORGANIC CHEMISTRY   82 ( 17 )   8917 - 8926   2017.09（ ISSN:0022-3263 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.joc.7b01275

  • An efficient synthetic method for organometallic radicals: structures and properties of gold(I)-(nitronyl nitroxide)-2-ide complexes Reviewed

    Shuichi Suzuki, Sayaka Kira, Masatoshi Kozaki, Masaki Yamamura, Toru Hasegawa, Tatsuya Nabeshima, Keiji Okada

    DALTON TRANSACTIONS   46 ( 8 )   2653 - 2659   2017.02（ ISSN:1477-9226 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1039/c6dt04685a

  • Magnetic Control of the:Charge-Separated State Lifetime Realized by Covalent Attachment of a Platinum Complex Reviewed

    Tomoaki Miura, Dai Fujiwara, Kimio Akiyama, Takafumi Horikoshi, Suzuki Shuichi, Masatoshi Kozaki, Keiji Okada, Tadaaki Ikoma

    JOURNAL OF PHYSICAL CHEMISTRY LETTERS   8 ( 3 )   661 - 665   2017.02（ ISSN:1948-7185 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.jpclett.6b02887

  • π-System Figuration for Open-shell Molecules Based on Nitronyl Nitroxide Reviewed

    Suzuki Shuichi, Kozaki Masatoshi, Okada Keiji

    The Society of Synthetic Organic Chemistry, Japan, Journal of Synthetic Organic Chemistry, Japan   75 ( 9 )   955 - 964   2017（ ISSN:0037-9980 ）

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    Publishing type：Research paper (scientific journal)   Kind of work：Joint Work  

    <p>Organic-based open-shell π-electronic molecules are promising components for next-generation electronic devices because of the diversity in their design. In the past two decades, nitronyl nitroxides and its related radicals were widely utilized for organic spin sources mainly because of their stability. These derivatives were generally prepared by the condensation reactions of a corresponding bis-hydroxylamine compound with various aldehydes followed by oxidation. However, the procedure was unsuccessful sometimes particularly when highly electron-donating or electron-accepting aromatic aldehydes were used. One of the key approaches for solving this problem is to develop metal-introduced nitronyl nitroxide at the C2 position: This radical-metal complex can be used as a stable equivalent of the C2-H deprotonated anion of the parent nitronyl nitroxide and can be applied to the cross-coupling reagent to introduce the nitronyl nitroxide skeleton in the reaction with aryl halides. We have also found that the developed radical-metal complexes have metal-dependent low oxidation potentials and one of them can be converted to a new iminonitroxide-Au trimer complex with a quartet ground state. Here, we report recent progress of synthetic methods of new functional nitronyl nitroxides as "π-system figuration for open-shell molecules" and their unique electrochemical and magnetic properties.</p>

    DOI： 10.5059/yukigoseikyokaishi.75.955

    CiNii Article

  • Stereoelectronic control of oxidation potentials of 3,7-bis(diarylamino)phenothiazines Reviewed

    Ayumu Karimata, Shuichi Suzuki, Masatoshi Kozaki, Keiji Okada

    RSC ADVANCES   7 ( 88 )   56144 - 56152   2017（ ISSN:2046-2069 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1039/c7ra12600j

  • ESR Investigation for Q1D Organic Conductor (TTT)<sub>2</sub>I<sub>3</sub>

    Nakamura Toshikazu, Asada Mizue, Hasegawa Akifumi, Kuroda Natsuki, Kozaki Masatoshi, Yoshino Harukazu

    Meeting Abstracts of the Physical Society of Japan   72.2 ( 0 )   1467 - 1467   2017（ eISSN:21890803 ）

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  • Very Long-Lived Photoinduced Charge-Separated States of Triphenylamine-Naphthalenediimide Dyads in Polymer Matrices Reviewed

    Kimoto Kenshi, Satoh Tsubasa, Iwamura Munetaka, Nozaki Koichi, Horikoshi Takafumi, Suzuki Shuichi, Kozaki Masatoshi, Okada Keiji

    JOURNAL OF PHYSICAL CHEMISTRY A   120 ( 41 )   8093 - 8103   2016.10（ ISSN:1089-5639 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.jpca.6b07705

  • Intact Four-atom Organic Tetracation Stabilized by Charge Localization in the Gas Phase Reviewed

    Yatsuhashi Tomoyuki, Toyota Kazuo, Mitsubayashi Naoya, Kozaki Masatoshi, Okada Keiji, Nakashima Nobuaki

    CHEMPHYSCHEM   17 ( 19 )   2977 - 2981   2016.10（ ISSN:1439-4235 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/cphc.201600555

  • A tight 1:1 complex between an allosteric receptor and an organic effector with hydrogen and coordination bonds Reviewed

    Sasaki Yoshito, Suzuki Shuichi, Okada Keiji, Kozaki Masatoshi

    TETRAHEDRON LETTERS   57 ( 36 )   4082 - 4085   2016.09（ ISSN:0040-4039 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1016/j.tetlet.2016.07.088

  • Cyclic Triradicals Composed of Iminonitroxide-Gold(I) with Intramolecular Ferromagnetic Interactions Reviewed

    Suzuki Shuich, Wada Tomoyuki, Tanimoto Ryu, Kozaki Masatoshi, Shiomi Daisuke, Sugisaki Kenji, Sato Kazunobu, Takui Takeji, Miyake Yota, Hosokoshi Yuko, Okada Keiji

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   55 ( 36 )   10791 - 10794   2016.08（ ISSN:1433-7851 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/anie.201604320

  • Anisotropic Coulomb explosion of acetylene and diacetylene derivatives Reviewed

    Mitsubayashi Naoya, Yatsuhashi Tomoyuki, Tanaka Hiroki, Furukawa Satoshi, Kozaki Masatoshi, Okada Keiji, Nakashima Nobuaki

    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY   403   43 - 52   2016.06（ ISSN:1387-3806 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1016/j.ijms.2016.03.011

  • 2,11-Dibromo-13,14-dimesityl-5,8-dioxapentaphene: A Stable and Twisted Polycyclic System Containing the o-Quinodimethane Skeleton Reviewed

    Sato Chihiro, Suzuki Shuichi, Kozaki Masatoshi, Okada Keiji

    ORGANIC LETTERS   18 ( 5 )   1052 - 1055   2016.03（ ISSN:1523-7060 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.orglett.6b00171

  • <i>N</i>,<i>N</i>'-Diphenylbenzothiazinophenothiazine Dication: Singlet Ground State Species Reviewed

    Yoshida Kohei, Suzuki Shuichi, Kozaki Masatoshi, Okada Keiji

    The Chemical Society of Japan　Chemistry Letters   0 ( 0 )   2016（ ISSN:0366-7022 ）

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    Publishing type：Research paper (scientific journal)  

    <i>N</i>,<i>N</i>'-Diphenylbenzothiazinophenothiazine exhibited two reversible oxidation waves at −0.06 V and +0.42 V vs Fc/Fc<sup>+</sup> in CH<sub>2</sub>Cl<sub>2</sub>. Chemical oxidation using two equivalents of tris(4-bromophenyl)aminium hexafluoroantimonate produced a stable dication species, which was characterized by NMR signals in the 8.53−5.80 ppm region, a quinoid structure in the X-ray analysis, and theoretical calculations, showing a singlet ground state.

    DOI： 10.1246/cl.151032

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  • Synthesis and Higher-Order Structure of Linear Dendrimeric Assemblies Reviewed

    Nishioka Saori, Morita Shirou, Okada Keiji, Suzuki Shuichi, Kozaki Masatoshi

    ORGANIC LETTERS   17 ( 11 )   2720 - 2723   2015.06（ ISSN:1523-7060 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.orglett.5b01137

  • Substitution effects on optical properties of iminonitroxide- substituted iminonitroxide diradical Reviewed

    Nakamura Ryota, Shigeta Yasuteru, Okuno Katsuki, Hasegawa Miki, Fukushima Mayuko, Suzuki Shuichi, Kozaki Masatoshi, Okada Keiji, Nakano Masayoshi

    MOLECULAR PHYSICS   113 ( 3-4 )   267 - 273   2015.02（ ISSN:0026-8976 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1080/00268976.2014.937777

  • Direct Observation of Hole Shift and Characterization of Spin States in Radical Ion Pairs Generated from Photoinduced Electron Transfer of (Phenothiazine)(n) Anthraquinone (n=1, 3) Dyads Reviewed

    Karimata Ayumu, Suzuki Shuichi, Kozaki Masatoshi, Kimoto Kenshi, Nozaki Koichi, Matsushita Hironori, Ikeda Noriaki, Akiyama Kimio, Kosumi Daisuke, Hashimoto Hideki, Okada Keiji

    JOURNAL OF PHYSICAL CHEMISTRY A   118 ( 47 )   11262 - 11271   2014.11（ ISSN:1089-5639 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/jp509643q

  • Allosteric Regulation of the Ligand-Binding Ability of Zinc Porphyrins with Sterically Bulky Shielding Units by Metal Complexation Reviewed

    Ninomiya Yoshikazu, Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    The Chemical Society of Japan　BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   87 ( 11 )   1195 - 1201   2014.11（ ISSN:0009-2673 ）

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    Publishing type：Research paper (scientific journal)  

    An artificial allosteric system composed of a zinc porphyrin moiety as a ligand-binding site, diphenylanthracene moieties as sterically bulky shielding units, and bipyridine terminals as Fe(II) ion-binding sites, was designed, synthesized, and characterized. The allosteric system forms an [Fe(bpy)<sub>3</sub>]-type complex in the presence of Fe(II) ions and induces a large conformational change in the alkyl side chains and shielding units, in which the anthracene groups would cover both the top and bottom of the porphyrin Zn(II) center. Consequently, the ligand-binding ability of the zinc porphyrin unit was allosterically suppressed. We found that the formation of the Fe(II) complex resulted in a 9.5-fold reduction in the binding constant between the zinc porphyrin and 3,5-bis(3,5-di-<i>tert</i>-butylphenyl)pyridine at 20 °C. Comparisons of entropy and enthalpy changes in the absence and presence of Fe(II) ions led to the conclusion that the allosteric suppression was mainly due to the destabilization of the Zn(II)-coordinated complex owing to the steric repulsion between the ligand and the shielding unit.

    DOI： 10.1246/bcsj.20140197

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  • Synthesis and Properties of a Bis[(nitronyl nitroxide)-2-ide radical anion]-Palladium Complex Reviewed

    Suzuki Shuichi, Yokoi Hiroyuki, Kozaki Masatoshi, Kanzaki Yuki, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Okada Keiji

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY   ( 28 )   4740 - 4744   2014.10（ ISSN:1434-1948 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/ejic.201402564

  • Nitronyl Nitroxide as a Coupling Partner: Pd-Mediated Cross-coupling of (Nitronyl nitroxide-2-ido)(triphenylphosphine)gold(I) with Aryl Halides Reviewed

    Tanimoto Ryu, Suzuki Shuichi, Kozaki Masatoshi, Okada Keiji

    The Chemical Society of Japan　CHEMISTRY LETTERS   43 ( 5 )   678 - 680   2014.05（ ISSN:0366-7022 ）

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    Publishing type：Research paper (scientific journal)  

    A cross-coupling reaction using nitronyl nitroxide (NN) as a coupling partner was developed: Refluxing a mixture of [Au<sup>I</sup>(NN-2-ido)(PPh<sub>3</sub>)] and aryl iodide (Ar–I) in THF in the presence of 10 mol % [Pd(PPh<sub>3</sub>)<sub>4</sub>] produced a cross-coupling product NN-Ar in a high yield. This method allowed the direct introduction of the NN radical onto various poly- and heterocyclic aromatic rings.

    DOI： 10.1246/cl.131162

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  • Synthesis and Magnetic Properties of Nitronyl Nitroxides with an Adjacent Chiral Group Reviewed

    Tanimoto Ryu, Suzuki Shuichi, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Okada Keiji

    The Chemical Society of Japan　BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   87 ( 2 )   314 - 322   2014.02（ ISSN:0009-2673 ）

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    We have designed and synthesized chiral molecules with nitronyl nitroxide (NN) radicals directly bound to the chiral centers, (<i>S</i>)-1,3-dioxolane-4-NN (<b>1</b>) and (<i>R</i>)-oxazolidine-4-NN (<b>2</b>). These radicals were synthesized from <small>D</small>-mannitol in four steps for <b>1</b> and from <small>L</small>-serine in six steps for <b>2</b> in moderate yields. They were characterized by means of mass spectrometry, electron spin resonance, elemental analyses, and X-ray crystal structure analyses. Their magnetic properties were also investigated using a SQUID magnetometer. The temperature dependence of paramagnetic susceptibility (χ<sub>p</sub>) indicates the presence of a weak antiferromagnetic intermolecular interaction with <i>J</i>/<i>k</i><sub>B</sub> = −3.1 K and <i>θ</i> = −5.5 K for <b>1</b>, and a weak ferromagnetic intermolecular interaction with <i>J</i>/<i>k</i><sub>B</sub> = +0.5 K for <b>2</b>. We also succeeded in preparing the metal complex [Mn(hfac)<sub>2</sub>(<b>2</b>)]<sub>2</sub>–[Cu(hfac)<sub>2</sub>], which was characterized by a strong antiferromagnetic interaction (<i>J</i>/<i>k</i><sub>B</sub> = −140 K) between [Mn(hfac)<sub>2</sub>] and <b>2</b> along with a much weaker antiferromagnetic interaction (<i>J</i>/<i>k</i><sub>B</sub> = −0.11 K) between the [Mn(hfac)<sub>2</sub>(<b>2</b>)] unit and [Cu(hfac)<sub>2</sub>].

    DOI： 10.1246/bcsj.20130264

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  • Preparation and Magnetic Properties of Metal-Complexes from N-t-Butyl-N-oxidanyl-2-amino-(nitronyl nitroxide) Reviewed

    Furui Takanori, Suzuki Shuichi, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Okada Keiji, Tretyakov Evgeny V., Tolstikov Svyatoslav E., Romanenko Galina V., Ovcharenko Victor I.

    INORGANIC CHEMISTRY   53 ( 2 )   802 - 809   2014.01（ ISSN:0020-1669 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/ic4020898

  • Dendritic Light-harvesting Antennas with Excitation Energy Gradients Reviewed

    Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    The Chemical Society of Japan　CHEMISTRY LETTERS   42 ( 10 )   1112 - 1118   2013.10（ ISSN:0366-7022 ）

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    Dendritic architectures provide attractive scaffolds for the precise arrangement of considerable numbers of antenna chromophores. Multichromophoric antennas are advantageous for obtaining intense absorption over the entire visible light spectrum. The strategic arrangement of various antenna chromophores produces the lowest excitation energy gradient for efficient energy transfer. Large light-harvesting systems can be constructed by the proper arrangement of the antennas.

    DOI： 10.1246/cl.130654

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  • Photoinduced Charge Separation of 10-Phenyl-10H-phenothiazine-2-Phenylanthraquinone Dyad Bridged by Bicyclo[2.2.2]octane Reviewed

    Karimata Ayumu, Kawauchi Hidetoshi, Suzuki Shuichi, Kozaki Masatoshi, Ikeda Noriaki, Keyaki Kazutoshi, Nozaki Koichi, Akiyama Kimio, Okada Keiji

    The Chemical Society of Japan　CHEMISTRY LETTERS   42 ( 8 )   794 - 796   2013.08（ ISSN:0366-7022 ）

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    Photoinduced charge separation of a phenothiazine–anthraquinone dyad <b>1</b> with a rigid bicyclo[2.2.2]octane spacer was investigated by means of picosecond and nanosecond transient absorption and time-resolved ESR spectroscopies. Irradiation of the anthraquinone chromophore in <b>1</b> produced the charge-separated (CS) state in THF. Time constants of the formation and the decay of the CS state were determined to be 1.3 ns and 1.0 µs, respectively. Time-resolved ESR showed spin-polarized all-emission signals due to the formation of the CS state via the triplet mechanism.

    DOI： 10.1246/cl.130062

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  • Allosteric regulation of the ligand-binding ability of Zn-porphyrin by metal complexation Reviewed

    Kozaki Masatoshi, Ninomiya Yoshikazu, Suzuki Shuichi, Okada Keiji

    TETRAHEDRON LETTERS   54 ( 28 )   3658 - 3661   2013.07（ ISSN:0040-4039 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1016/j.tetlet.2013.04.130

  • Energy Transfer from iminonitroxide diradicals to a series of lanthanide ion Reviewed

    FUKUSHIMA Mayuko, TAKEUCHI Toshiaki, SUZUKI Shuichi, KOZAKI Masatoshi, OKADA Keiji, SHIGETA Yasuteru, HASEGAWA Miki

    ( 62 )   188 - 189   2013.05（ ISSN:09102205 ）

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    CiNii Article

  • Reassociation of All-trans-3,4-Dihydroanhydrorhodovibrin with LH1 Subunits Isolated from Rhodospirillum rubrum : Selective Binding of All-trans Isomer from Mixture of cis- and trans-Isomers Reviewed

    Yamamoto Mai, Horibe Tomoko, Nishisaka Yoshiaki, SUZUKI Shuichi, KOZAKI Masatoshi, FUJII Ritsuko, DOE Matsumi, NANGO Mamoru, OKADA Keiji, HASHIMOTO Hideki

    Chemical Society of Japan　Bulletin of the Chemical Society of Japan   86 ( 1 )   121 - 128   2013.01（ ISSN:00092673 ）

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  • Photoinduced charge separation of phenothiazine-platinum-naphthalene diimide triads linked by twisted phenylene bridges Reviewed

    Sugimura Ryoji, Suzuki Shuichi, Kozaki Masatoshi, Keyaki Kazutoshi, Nozaki Koichi, Matsushita Hironori, Ikeda Noriaki, Okada Keiji

    RESEARCH ON CHEMICAL INTERMEDIATES   39 ( 1 )   185 - 204   2013.01（ ISSN:0922-6168 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1007/s11164-012-0642-6

  • Syntheses and Structural Studies of Tris(N-phenothiazinyl)borane and Its Radical Cation Reviewed

    Suzuki Shuichi, Yoshida Kohei, Kozaki Masatoshi, Okada Keiji

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   52 ( 9 )   2499 - 2502   2013（ ISSN:1433-7851 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/anie.201208392

  • Photoinduced electron transfer of platinum(II) bipyridine diacetylides linked by triphenylamine- and naphthaleneimide-derivatives and their application to photoelectric conversion systems Reviewed

    Suzuki Shuichi, Matsumoto Yuma, Tsubamoto Mai, Sugimura Ryoji, Kozaki Masatoshi, Kimoto Kenshi, Iwamura Munetaka, Nozaki Koichi, Senju Naoki, Uragami Chiasa, Hashimoto Hideki, Muramatsu Yohei, Konno Akinori, Okada Keiji

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   15 ( 21 )   8088 - 8094   2013（ ISSN:1463-9076 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1039/c3cp50182e

  • Energy Transfer from iminonitroxide diradicals to a series of lanthanide ion Reviewed International coauthorship

    Mayuko Fukushima, Toshiaki Takeuchi, Shuichi Suzuki, Masatoshi Kozaki, Keiji Okada, Yasuteru Shigeta, Miki Hasegawa

    Kidorui   62   188 - 189   2013

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    Publishing type：Research paper (scientific journal)   Kind of work：Joint Work  

  • Construction of Snowflake-Shaped Dendritic Covalent Assemblies with Rigid Conjugated Networks Reviewed

    Kozaki Masatoshi, Morita Shirou, Suzuki Shuichi, Okada Keiji

    JOURNAL OF ORGANIC CHEMISTRY   77 ( 21 )   9447 - 9457   2012.11（ ISSN:0022-3263 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/jo3014512

  • NCN Pincer-Pt Complexes Coordinated by (Nitronyl Nitroxide)-2-ide Radical Anion Reviewed

    Zhang Xun, Suzuki Shuichi, Kozaki Masatoshi, Okada Keiji

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   134 ( 43 )   17866 - 17868   2012.10（ ISSN:0002-7863 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/ja308103g

  • (Nitronyl Nitroxide)-Substituted Trioxytriphenylamine Radical Cation Tetrachlorogallate Salt: A 2p-Electron-Based Weak Ferromagnet Composed of a Triplet Diradical Cation Reviewed

    Kuratsu Masato, Suzuki Shuichi, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Kanzawa Tsuneki, Hosokoshi Yuko, Lan Xiao-Zheng, Miyazaki Yuji, Inaba Akira, Okada Keiji

    CHEMISTRY-AN ASIAN JOURNAL   7 ( 7 )   1604 - 1609   2012.06（ ISSN:1861-4728 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/asia.201200084

  • Synthesis and properties of Zn-porphyrin with bipyridine-terminated side chains: large conformational change induced by metal complexation Reviewed

    Kato Mutsumi, Hashimoto Erika, Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    TETRAHEDRON LETTERS   53 ( 3 )   309 - 312   2012.01（ ISSN:0040-4039 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1016/j.tetlet.2011.11.041

  • Trinitroxide-Trioxytriphenylamine: Spin-State Conversion from Triradical Doublet to Diradical Cation Triplet by Oxidative Modulation of a p-Conjugated System Reviewed

    Suzuki Shuichi, Nagata Atsuki, Kuratsu Masato, Kozaki Masatoshi, Tanaka Rika, Shiomi Daisuke, Sugisaki Kenji, Toyota Kazuo, Sato Kazunobu, Takui Takeji, Okada Keiji

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   51 ( 13 )   3193 - 3197   2012（ ISSN:1433-7851 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/anie.201107265

  • Recent progress in controlling photophysical processes of donor-acceptor arrays involving perylene diimides and boron-dipyrromethenes Reviewed

    Suzuki Shuichi, Kozaki Masatoshi, Nozaki Koichi, Okada Keiji

    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS   12 ( 4 )   269 - 292   2011.12（ ISSN:1389-5567 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1016/j.jphotochemrev.2011.10.001

  • Construction and Functionalization of Dendrimers with Conjugated Backbones Reviewed

    KOZAKI Masatoshi, OKADA Keiji

    The Society of Synthetic Organic Chemistry, Japan, Journal of Synthetic Organic Chemistry, Japan   69 ( 10 )   1145 - 1157   2011.10（ ISSN:00379980 ）

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    Dendrimers containing rigid conjugated backbones were prepared by a convergent method where the attachment of dendritic branches and the extension of phenylene-ethynylene units were alternatively manipulated on the structure of AB<sub>2</sub> substituted phenylacetylene in a combination with Suzuki-Miyaura and Sonogashira cross-coupling reactions. These dendrimer structures were applied for the construction of several light-harvesting antennas and charge-separating systems. The conjugated network inside the dendritic structure was shown to play an important role as a mediator in both the photoinduced energy- and electron-transfer processes. In addition, we describe a novel methodology for the stepwise construction of shape-persistent assemblies using the dendrimers with conjugated backbones as the key modular building blocks. These examples demonstrate advantage of the dendrimer with conjugated backbones for the construction of nanoscale molecular devices such as artificial photosynthetic systems.

    DOI： 10.5059/yukigoseikyokaishi.69.1145

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  • Efficient Light-Harvesting Antenna with a Multi-Porphyrin Cascade Reviewed

    Uetomo Atsuhiro, Kozaki Masatoshi, Suzuki Shuichi, Yamanaka Ken-ichi, Ito Osamu, Okada Keiji

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   133 ( 34 )   13276 - 13279   2011.08（ ISSN:0002-7863 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/ja2050343

  • Persistence of Iodines and Deformation of Molecular Structure in Highly Charged Diiodoacetylene: Anisotropic Carbon Ion Emission Reviewed

    Yatsuhashi Tomoyuki, Mitsubayashi Naoya, Itsukashi Masako, Kozaki Masatoshi, Okada Keiji, Nakashima Nobuaki

    CHEMPHYSCHEM   12 ( 1 )   122 - 126   2011.01（ ISSN:1439-4235 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/cphc.201000756

  • Synthesis and Magnetic Properties of Dimethylmethylenebis(iminonitroxide) Diradical Reviewed

    SUZUKI Shuichi, ITOH Noriyuki, FURUICHI Kimiaki, KOZAKI Masatoshi, SHIOMI Daisuke, SATO Kazunobu, TAKUI Takeji, OHI Hiromi, ITOH Shinobu, OKADA Keiji

    Chemistry letters   40 ( 1 )   22 - 24   2011.01（ ISSN:03667022 ）

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  • Photoinduced Charge Separation in Donor-Acceptor Systems Sensitized by Platinum Porphyrin Reviewed

    Sugimura Ryoji, Suzuki Shuichi, Naitoh Takahiro, Kozaki Masatoshi, Kimoto Kenshi, Nozaki Koichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2011 ( 0 )   194 - 194   2011

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    Publishing type：Research paper (scientific journal)  

    Photoinduced charge transfer is one of the important processes for the conversion of solar energy into chemical and/or electric energies. Recently, various studies including multi-step electron transfer processes have investigated. However, these systems do not always exhibit efficient, long-lived CS states. One of the most promising strategies to obtain long-lived CS states seems to be a spin control approach. Here, we report on photoinduced charge-separation of a Pt-porphyrin-viologen dyad and a triphenylamine-Pt-porphyrin-naphthalenediimide triad. In these complexes, the Pt-porphyrin moiety acts as a triplet photosensitizer. The transient absorption spectra in nano-second laser flash photolysis exhibited absorption bands assignable to the donor radical cation and the acceptor radical anion, indicating the generation of the CS states with relatively long lifetime.

    DOI： 10.11494/kisoyuki.2011.0.194.0

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  • Highly Efficient Photoproduction of Long-lived Charge Separated States in Diacetylide Platinum Complexes Linked with Electron Donor and Acceptor Moieties Reviewed

    SUGIMURA Ryoji, SUZUKI Shuichi, KOZAKI Masatoshi, KEYAKI Kazutoshi, NOZAKI Koichi, IKEDA Noriaki, AKIYAMA Kimio, OKADA Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2010 ( 0 )   C25 - C25   2011

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    Recently, a number of electron donor and acceptor dyads and triads have been designed and synthesized in order to search for systems of long-lived radical ion pairs. Here, we have designed and synthesized a new system of bipyridine-diacetylide platinum linked with electron donor and acceptor moieties. Bipyridine-diacetylide platinum complexes are known as good phosphors at room temperature, which can be utilized as a triplet photosensitizer. We have succeeded in highly efficient generation of spin-correlated charge separated states with relatively long lifetime by the excitation of the platinum complex moiety.

    DOI： 10.11494/kisoyuki.2010.0.C25.0

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  • Syntheses and Properties of Nitronyl-nitroxide Directly-linked to Platinum Complexes Reviewed

    Zhang Xun, Suzuki Shuichi, Kozaki Masatoshi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2011 ( 0 )   355 - 355   2011

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    Publishing type：Research paper (scientific journal)  

    Pincer-type Pt-complexes have attracted much attention as new materials possibly applied to molecular electronics. In order to add a new functionality to pincer type Pt-complexes, we designed and synthesized (nitronyl nitroxide)-directly introduced Pt-complexes. The oxidation of these radical-Pt-complexes selectively produced the tetravalent Pt(IV) complex or the cationic (nitrosonium nitroxide)-Pt(II) complex, depending on the oxidation conditions. We report the detailed synthetic procedures and crystal structures of these complexes.

    DOI： 10.11494/kisoyuki.2011.0.355.0

    CiNii Article

  • Structures and Magnetic Properties of New Stable High-spin Diradicals Composed of Two Types of Nitroxide Radicals Reviewed

    Furui Takanori, Kuratsu Masato, Suzuki Shuichi, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2010 ( 0 )   2P50 - 2P50   2011

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    Organic high-spin molecules have attracted continuing attention as important building blocks of molecule-based magnets. Nitronyl nitroxide radical (<B>NN</B>), imino nitroxide radical (<B>IN</B>) and tert-butyl nitroxide radical (<B><SUP><I>t</I></SUP>BuNO</B>) have been well studied as components of organic high-spin molecules because of their stabilities and metal-complexation abilities. For the creations of new high-spin building blocks with extraordinary strong intermolecular spin-spin interactions, we have designed and synthesized a directly-linked (nitronyl nitroxide)-nitroxide diradical (<B>NN-<SUP><I>t</I></SUP>BuNO</B>) and (imino nitroxide)-nitroxide diradical (<B>IN-<SUP><I>t</I></SUP>BuNO</B>). These diradicals are very stable even in aerated conditions. ESR spectra in frozen diethyl phthalate at low temperature showed clearly spin-allowed and spin-forbidden transition signals assigned to triplet species of diradicals. The measurements of magnetic susceptibility demonstrated that the diradical are in a triplet ground state with a large intramolecular exchange interaction.

    DOI： 10.11494/kisoyuki.2010.0.2P50.0

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  • Photo-induced Electron Transfer of Triphenylamine-Naphthaldiimide Dyads with Twisted Oligophenylene Spacers Reviewed

    Nakatsuka Shoichi, Suzuki Shuichi, Horikoshi Takafumi, Sugimura Ryoji, Kozaki Masatoshi, Kimoto Kenshi, Nozaki Koichi, Matsusita Hironori, Ikeda Noriaki, Akiyama Kimio, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2011 ( 0 )   297 - 297   2011

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    Recently, we have shown that simple triphenylamine-naphthaldiimide dyads using highly twisted (diphenylethynyl)benzene spacers give long-lived charge separated states of microsecond order with high efficiencies. For understanding the photophysical properties of these dyads, we have designed and synthesized similar triphenylamine-naphthaldiimide dyads linked with non-twisted or twisted oligophenylene as spacers whose lengthes are shorter than those of diphenylethynyl)benzene. In the twisted dyad system, it was found that triplet charge separated state was generated via the intersystem crossing within the radical ion pair.

    DOI： 10.11494/kisoyuki.2011.0.297.0

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  • Generation of Long-Lived Charge Separated State in Photoinduced Electron Transfer of Twisted <I>m-</I> and <I>p-</I>Di(phenylethynyl)benzene-Linked Triphenylamine-Naphthaldiimide Dyads Reviewed

    Horikoshi Takafumi, Suzuki Shuichi, Sugimura Ryoji, Kozaki Masatoshi, Kimoto Kenshi, Nozaki Koichi, Matsushita Hironori, Ikeda Noriaki, Akiyama Kimio, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2011 ( 0 )   296 - 296   2011

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    Recently, photo-induced charge separation of various donor-acceptor dyads has been actively investigated. The construction of artificial systems that enable the efficient formation of long-lived charge separated (CS) states with large chemical potentials is an important goal in these studies. We report that simple triphenylamine-naphthaldimide dyads using highly twisted <I>m-</I> and <I>p-</I>di(phenylethynyl)benzene spacers cleanly generate long-lived CS states over a microsecond lifetime with high efficiencies. The CS states were shown to be derived via intersystem crossing within singlet CS states.

    DOI： 10.11494/kisoyuki.2011.0.296.0

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  • Synthesis and properties of a porphyrin array composed of rigid backbone with an excitation energy gradient Reviewed

    Uetomo Atsuhiro, Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2010 ( 0 )   3P38 - 3P38   2011

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    Previously we reported a light-harvesting array containing rigid backbones, peripherally positioned Zn-porphyrin terminals, and a free-base porphyrin core. Here we prepared a similar array that has three kinds of porphyrins with different substitution numbers of ethynyl-groups were arranged to form an excitation energy gradient. The array has strong absorption bands throughout the visible wavelength region. Highly effective intramolecular singlet energy-transfer from the peripheral porphyrin units to the porphyrin core was observed. Detailed synthetic procedure and properties of the porphyrin array are reported.

    DOI： 10.11494/kisoyuki.2010.0.3P38.0

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  • Preparation and Properties of a Ladder-Type Assembly of Porphyrin Trimers with Excitation Energy Gradient Reviewed

    Tsutsumi Akiko, Uetomo Atsuhiro, Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2011 ( 0 )   198 - 198   2011

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    We synthesized a linear porphyrin trimer (TPP-DEP-TPP) that has a meso-diethynyl Zn-porphyrin unit (DEP) and two tetraphenyl Zn-porphyrin terminals (TPP). The trimer formed stable 1:3 and 2:3 complexes in chloroform with 4-phenylpyridine and 4,4'-biphyridine, respectively. The complexation of the trimer was investigated by means of UV-vis titration. The detailed synthetic procedure and complexation of the trimer with several ligands will be presented.

    DOI： 10.11494/kisoyuki.2011.0.198.0

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  • Reassociation of Anhydrorhodovibrin Analogue to the LH1 Anntena Pigment-Protein Complex from a Purple Photosynthetic Bacterium for the Understanding of Functional Mechanism Reviewed

    Yamamoto Mai, Suzuki Shuichi, Kozaki Masatoshi, Okada Keiji, Horibe Tomoko, Nishisaka Yoshiaki, Fujii Ritsuko, Nango Mamoru, Hashimoto Hideki

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2010 ( 0 )   1P67 - 1P67   2011

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    In order to clarify the structure-function relationship of carotenoids bound to LH1 antenna pigment-protein complex from purple photosynthetic bacteria, we performed the re-association experiments using a synthetic carotenoid analogue, 3,4-dihydroanhydrorhodovibrin. Spectroscopic properties and energy transfer efficiency from carotenoid to BChl <I>a</I> are described.

    DOI： 10.11494/kisoyuki.2010.0.1P67.0

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  • Allosteric Control in Binding of Axial Ligands to Zinc Porphyrin Reviewed

    Hashimoto Erika, Kato Mutsumi, Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2011 ( 0 )   383 - 383   2011

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    Previously we prepared zinc porphyrin derivatives possessing 2,2'-bipyridyl units at the peripheral end of both conjugated and alkyl side chains. The formation of the [Fe(II)(bpy)3]-type complexes induced a large conformational change, which further induced a slight increase in the binding between zinc porphyrin and imidazole axial ligand. Sterically bulky substituents were incorporated at meso-positions to enhance steric demand around the axial coordination sites. We investigated the steric effect of meso-substituents on the axial binding constant after and before the Fe(II) complexation.

    DOI： 10.11494/kisoyuki.2011.0.383.0

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  • Highly efficient light-harvesting using cascade-type energy transfer involving three kinds of porphyrins Reviewed

    Uetomo Atsuhiro, Kozaki Masatoshi, Suzuki Shuichi, Yamanaka Kenichi, Ito Osamu, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2011 ( 0 )   57 - 57   2011

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    Here, we prepared a light-harvesting antenna composed of three kinds of porphyrins with different numbers of ethynyl groups at their meso-positions. The antenna has strong absorption throughout the visible region, up to 750 nm. Highly efficient singlet energy transfer (>90%) from the peripheral porphyrins to the central porphyrin was observed. The energy transfer process was investigated by means of time-resolved fluorescence spectroscopy.

    DOI： 10.11494/kisoyuki.2011.0.57.0

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  • Syntheses and Magnetic Properties of Bis (Nitronyl-nitroxides) Substituted Dihydrophenazine Radical Cations Reviewed

    Nagata Atsuki, Suzuki Shuichi, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2011 ( 0 )   162 - 162   2011

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    We have recently reported that (nitronyl nitroxide)-substituted dihydrophenazine radical cations exhibit interesting magnetic properties. For further development of this system, we have designed and synthesized a neutral dihydrophenazine derivative with two nitronyl nitroxides at 2,7-positions and its oxidized cationic species. We clarified 1) the neutral diradical species shows a weak ferromagnetic interaction between the two nitronyl nitroxides, 2) the cationic species exhibits a strong ferromagnetic interaction between the dihydrophenazine radical cation and the two nitronyl nitroxides. The structures and properties of these species will be described.

    DOI： 10.11494/kisoyuki.2011.0.162.0

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  • Synthesis and Photo-induced Electron Transfer Reaction of Phenothiazine Trimer and Anthraquinone Dyad Linked by Bicyclo[2.2.2]octane. Reviewed

    Karimata Ayumu, Kawauchi Hidehito, Suzuki Syuichi, Kozaki Masatoshi, Keyaki Kazutoshi, Kimoto Kenshi, Nozaki Kouichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2010 ( 0 )   1P68 - 1P68   2011

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    The oxidation of organic compounds sometimes accompanies considerable geometrical change when compared to their neutral states. Photochemical electron transfer reactions provide a good tool to investigate such system. We have previously shown that phenothiazine trimer radical cation exhibits a strong intramolecular CT band because of its unique structure. When the phenothiazine trimer framework is incorporated in an intramolecular electron transfer system, the initially formed radical ion pair as well as the geometrically relaxed radical ion may be observed. In this presentation, we report photo-induced electron transfer reactions of (phenothiazine monomer and phenothiazine trimer)-anthraquinone dyad bridged by bicycle[2.2.2]octane.

    DOI： 10.11494/kisoyuki.2010.0.1P68.0

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  • Photo-induced Electron Transfer of Platinum Complexes Coordinated Phenylacetylene Unit Linked Triphenylamine and Naphthaldiimide Moieties Reviewed

    Horikoshi Takafumi, Suzuki Shuichi, Sugimura Ryoji, Kozaki Masatoshi, Kimoto Kenshi, Nozaki Koichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2010 ( 0 )   1P51 - 1P51   2011

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    Publishing type：Research paper (scientific journal)  

    We have recently reported a long-lived charge separated state (spin-coorelated radical ion pair) of bipyridine-platinum complexes with high quantum yields using triphenylamine as an electron donor (D) and naphthaldimide as an electron acceptor (A). In order to clarify the effect of distance from platinum atom to the donor/acceptor moieties, we have designed and synthesized a new pendent type platinum complex, in which the dipyridylbenzene-platinum complex is bound to 3,5-D-, A- substituted phenylacetylene moiety. We report sysnthetic detail and photophysical properties including emission spectra and transient absorption spectra.

    DOI： 10.11494/kisoyuki.2010.0.1P51.0

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  • Syntheses and Magnetic Properties of Trioxitriphenylamine Radical Cation Substituted with Three <I>t</I>-Butyl Nitroxides Reviewed

    Nagata Atsuki, Suzuki Shuichi, Kuratsu Masato, Kozaki Masatoshi, Sato Kazunobu, Takui Takeji, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2010 ( 0 )   2P51 - 2P51   2011

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    We have recently reported that radical-substituted trioxytriphenylamine (<B>TOT</B>) radical cation salts exhibit interesting magnetic properties such as weakferromagnetic phase transition. For the development of the <B>TOT</B> system, we have designed a (tri-<I>t</I>-butylnitroxide)-substituted <B>TOT</B> derivative, whose one electron-oxidation product is expected to have a triplet ground state. The one-electron oxidation product is obtained by treatmentum with a chemical oxidant such as thianthrene radical cation or triphenylamine radical cation. The ESR spectrum of this species in frozen diethyl phthalate showed a spin-allowed and a spin-forbidden transition signals assigned to triplet species. The syntheses and magnetic properties of the neutral triradical and its one-electron oxidized species are reported in detail.

    DOI： 10.11494/kisoyuki.2010.0.2P51.0

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  • Application of Azido-Alkyne Click Chemistry to the Construction of Dendritic Assemblies with Linear Conjugated Chains Reviewed

    Morita Shirou, Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2010 ( 0 )   2P77 - 2P77   2011

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    Previously, we reported stepwise construction of a covalent assembly of snowflake-shaped dendrimers using a Sonogashira coupling reaction. However, modest yields in this reaction prevented further development to construct larger sizes of assemblies. Here, we studied on the applicability of azido-alkyne click chemistry (Huisgen reaction) to construction of dendritic assemblies. First, we synthesized both an azido-terminated dendrimer and an ethynyl-terminated dendrimer using convergent method for snowflake shaped dendrimers. These dendrimers were reacted at room temperature under nitrogen in the presence of catalytic amount of copper iodide to afford a dimeric product in 71 % yield. The product was unambiguously characterized by means of NMR and MALDI-TOF mass (M+ = 4355.9) spectroscopy. The detailed synthetic procedure and properties of the assembly will be presented.

    DOI： 10.11494/kisoyuki.2010.0.2P77.0

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  • The Structure-Function Relationship of Carotenoids Bound to the LH1 Antenna Pigment-Protein Complex in Photosynthesis Reviewed

    Yamamoto Mai, Suzuki Shuichi, Kozaki Masatoshi, Okada Keiji, Horibe Tomoko, Fujii Ritsuko, Nango Mamoru, Hashimoto Hideki

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2011 ( 0 )   460 - 460   2011

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    Publishing type：Research paper (scientific journal)  

    In order to clarify the structure-function relationship of carotenoids bound to the LH1 antenna pigment-protein complex, we studied the re-association between synthetic carotenoids and carotenoid-depleted LH1. The spectroscopic properties of the re-associated complexes and the energy transfer efficiency from carotenoids to BChl <I>a</I> were clarified and discussed in comparison to previous experiments. Moreover, we studied the selectivity of carotenoids in the LH1 complex formation.

    DOI： 10.11494/kisoyuki.2011.0.460.0

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  • Syntheses and Properties of (Diarylamino)borane Derivatives and Their Radical Cations Reviewed

    Yoshida Kohei, Suzuki Shuichi, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2011 ( 0 )   326 - 326   2011

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    Publishing type：Research paper (scientific journal)  

    Recently, pi-conjugated compounds containing typical elements other than carbon, nitrogen and oxygen atoms have attracted much attention because they have unique electronic and photophysical properties. Diarylamine substituted boranes are interesting compounds in the view point of B-N double bond character and its influence on the molecular properties. We have succeeded in synthesizing of borane derivatives substituted two or three diarylamine moieties including phenothiazine and dihydrophenazine. These compounds are easily oxidized and give stable radical cations in the crystalline states. We here report their structures and properties.

    DOI： 10.11494/kisoyuki.2011.0.326.0

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  • Nitroxide-Substituted Nitronyl Nitroxide and Iminonitroxide Reviewed

    Suzuki Shuichi, Furui Takanori, Kuratsu Masato, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Okada Keiji

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   132 ( 45 )   15908 - 15910   2010.11（ ISSN:0002-7863 ）

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    DOI： 10.1021/ja107769z

  • Diaminotriazine-substituted nitronyl nitroxide: a novel building block for organic magnets having multiple hydrogen bonding substituents as structure-determining supramolecular synthons Reviewed

    Tanaka Hiroyuki, Shiomi Daisuke, Suzuki Shuichi, Kozaki Masatoshi, Okada Keiji, Sato Kazunobu, Takui Takeji

    CRYSTENGCOMM   12 ( 2 )   526 - 531   2010（ ISSN:1466-8033 ）

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    DOI： 10.1039/b909757k

  • Radical-Substituted Dihydrophenazine Radical Cation Salts: Molecular Packing Structure and Bulk Magnetic Property Reviewed

    Pure Appl. Chem.   82 ( 4 )   1025 - 1032   2010

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    Publishing type：Research paper (scientific journal)   Kind of work：Joint Work  

  • Photoinduced Charge Separation after Excited Energy Transfer in Snowflake-Shaped Zn-Porphyrin Dendrimer with Anthraquinone Terminals: Enhancement of the Electron-Transfer Rates by "Dendrimer Effect"

    Bull. Chem. Soc. Jpn.   83 ( 10 )   1223 - 1237   2010

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  • Pyrene-Dihydrophenazine Bis(Radical Cation) in a Singlet Ground State Reviewed

    Suzuki Shuichi, Takeda Takuma, Kuratsu Masato, Kozaki Masatoshi, Sato Kazunobu, Shiomi Daisuke, Takui Takeji, Okada Keiji

    ORGANIC LETTERS   11 ( 13 )   2816 - 2818   2009.07（ ISSN:1523-7060 ）

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    DOI： 10.1021/ol9009927

  • Ambipolar Organic Field-Effect Transistors from Cross-Conjugated Aromatic Quaterthiophenes; Comparisons with Quinoidal Parent Materials Reviewed

    Ortiz Rocio Ponce, Facchetti Antonio, Marks Tobin J., Casado Juan, Zgierski Marek Z., Kozaki Masatoshi, Hernandez Victor, Lopez Navarrete Juan T.

    ADVANCED FUNCTIONAL MATERIALS   19 ( 3 )   386 - 394   2009.02（ ISSN:1616-301X ）

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    DOI： 10.1002/adfm.200801066

  • Preparation and Properties of a covalent assembly of snowflake shaped dendrimers Reviewed

    Morita Shirou, Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2009 ( 0 )   246 - 246   2009

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    We will report the stepwise construction of a light-harvesting assembly using second-generation snowflake-shaped dendrimers as novel building blocks. First, A2B-type dendrimer with a 1,3,5-triphenylene core and an iodopenyl-terminal and A4-type free-base porphyrin dendrimer with ethynyl-terminals were synthesized using the Sonogashira coupling reaction in the key steps. The preparation of the assembly was achieved by the copper free Sonogashira coupling reaction (Pd(dba)2 • CHCl3, AsPh3) of A2B-type dendrimers and the A4-type dendrimer. The assembly was soluble in various organic solvents such as dichloromethane and THF and could be unambiguously characterized by NMR and MALDI-TOF mass (M+ = 29737) spectroscopy. Detailed synthetic procedure and light-harvesting properties of the assembly will be presented.

    DOI： 10.11494/kisoyuki.2009.0.246.0

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  • Synthesis and Conformation Control of Porphyrin Dendrimers with Rigid Reviewed

    Kato Mutsumi, Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2009 ( 0 )   160 - 160   2009

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    We prepared a porphyrin dendrimer with rigid conjugated chains and flexible C11-alkyl side chains. 2,2'-Bipyridyl terminals were incorporated in both the conjugated and the side chains to control the conformation of flexible side chains by metal complexation. The porphyrin dendrimer was synthesized in 64% yield by Suzuki-Miyaura cross-coupling reaction of <I>meso, meso'</I>-diboryl porphyrin and iodinated phenylene-ethynylene with the bipyridyl terminal and bipyridyl-terminated side chains. When the porphyrin dendrimer was mixed with a solution of FeCl<SUB>2</SUB> at room temperature in toluene-methanol (1:1), the color was changed into deep red. The UV-vis spectra of the solution show MLCT bands around 500 nm characteristic for a [Fe(II)(bpy) <SUB>3</SUB> ] <SUP>2+</SUP> type complex. In addition,a molecular ion peak for the 1:2 complex was observed at <I>m</I>/<I>z</I> = 1069.4 in ESI-MS. Detailed synthetic procedure and structure of the Fe complex will be presented.

    DOI： 10.11494/kisoyuki.2009.0.160.0

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  • Association behavior of amphiphilic porphyrin dendrimers with rigid backbones Reviewed

    YAGI Sadayuki, KOZAKI Masatoshi, SUZUKI Shuichi, OKADA Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2009 ( 0 )   247 - 247   2009

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    We synthesized an amphiphilic porphyrin dendrimer that possesses hydrophilic triethylene glycol chains at the end of rigid backbones and dendritic side chains. The Sonogashira coupling reaction of diethynyl Zn porphyrin and oligo(phenylene-ethylene) with hydrophilic triethylene glycol terminals afford the expected dendrimer in 80% yield, that is characterized by NMR and MALDI-TOF mass (M<SUP>+</SUP> = 5971) spectroscopy. The aggregation behavior of this dendrimer in THF/water was monitored by UV-vis spectroscopy. Upon addition of water in the THF solution, broadening with red shifts of absorption bands were observed. These phenomena suggest the formation of aggregates of the dendrimers. Moreover, wire-shaped aggregations (about 5 nm diameter) in THF/water = 1/9 were observed by TEM. Detailed synthetic procedure and aggregation behaviors of the dendrimer will be presented.

    DOI： 10.11494/kisoyuki.2009.0.247.0

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  • Molecular Magnets based on Radical-Substituted Radical Ions Reviewed

    Kuratsu Masato, Suzuki Shuichi, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Lan Xiao-Zheng, Miyazaki Yuji, Inaba Akira, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2009 ( 0 )   60 - 60   2009

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    In connection with our previous study of (nitronyl nitroxide)-substituted dihydrophenazine radical cation tetrabromoferrate, we report preparation and magnetic property of (nitronyl nitroxide)-substituted trioxytriphenylamine radical cation tetrachloroferrate (NNTOT+FeCl4-) and tetrachlorogallate (NNTOT+GaCl4-). NNTOT+FeCl4- exhibitted a successive phase transition at 2.9 K and 0.8 K. The higher temperture transition is due to the organic NNTOT+ magnets, whereas the lower one involves Fe(III) spins.

    DOI： 10.11494/kisoyuki.2009.0.60.0

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  • Structure and Electronic Properties of a Stable Diradical Directly Linked Nitronyl-Nitroxide and Nitroxide Moieties Reviewed

    Furui Takanori, Kuratsu Masato, Suzuki Shuichi, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2009 ( 0 )   231 - 231   2009

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    Organic high-spin molecules are important spin building blocks in materials science. In connection with our studies for the development of new magnetic materials using radical-substituted radical ions, we have designed and synthesized a new neutral diradical (NN-tBuNO) by combination of typical stable radicals, nitronyl nitroxide (NN) and tert-butyl nitroxide (tBuNO). NN-tBuNO was stable under aerated conditions at room temperature in the crystalline state and exhibited a spin-allowed and a spin-forbidden transition EPR signals in frozen butyronitrile. The magnetic susceptibility measurement showed a large intramolecular ferromagnetic interaction between NN and tBuNO. Synthesis, structure, magnetic properties, and preparation of metal complexes will be reported.

    DOI： 10.11494/kisoyuki.2009.0.231.0

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  • Spin-Controlled Photoinduced Electron Transfer of Diacetylide Platinum Complex as a Triplet Photosensitizer Linked with Electron Donor and Acceptor Moieties Reviewed

    SUGIMURA Ryoji, SUZUKI Shuichi, KOZAKI Masatoshi, KEYAKI Kazutoshi, NOZAKI Koichi, IKEDA Noriaki, AKIYAMA Kimio, OKADA Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2009 ( 0 )   189 - 189   2009

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    Publishing type：Research paper (scientific journal)  

    Recently, a number of electron donor and acceptor dyads and triads have been designed and synthesized in order to search for systems of long-lived radical ion pairs. Here, we have designed a new system of bipyridine-diacetylide platinum linked with electron donor and acceptor moieties. A bipyridine-diacetylide platinum chromophore is known as a good phosphor at room temperature. Here, we utilized this chromophore as a triplet photosensitizer. Excitation (355 nm) of the bipyridine-diacetylide Pt (II) moiety produced a long-lived charge separated state with a high quantum efficiency. In this presentation, we report their details including the study of time resolved EPR measurement.

    DOI： 10.11494/kisoyuki.2009.0.189.0

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  • Electronic Structure of Nitronyl Nitroxide Linked with 2,4,6-Triphenylphenylnitroxide Reviewed

    KUMAGAI Tasuku, KURATSU Masato, SUZUKI Shuichi, KOZAKI Masatoshi, OKADA Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2009 ( 0 )   232 - 232   2009

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    Nitroxyl radicals have played important roles as building-blocks of molecule-based magnets because of their stability and metal-coordinated ability. Recently, we have designed and synthesized a new nitroxyl-diradical composed of nitronylnitroxide (NN) and tert-butylnitoxide (<I>t</I>BuNO). Temperature dependence of magnetic susceptibility showed that the diradical has a triplet ground state with ca. <I>J</I> = +300 K. An X-ray crystal analysis of the diradical showed that the dihedral angle between NN and <I>t</I>BuNO is 65 degree. A much stronger magnetic interaction can be expected by decreasing the dihedral angle between two radicals. For the realization of stronger exchange interaction, we have designed a new diradical, NN-triplenylphenylnitroxide (TPPNO). Computer calculation suggested that NN-TPPNO has a considerably small dihedral angle between NN and TPPNO (ca. 21 degree) due to the moderate steric hindrance. In this presentation, we report the synthetic study of NN-TPPNO and its magnetic properties.

    DOI： 10.11494/kisoyuki.2009.0.232.0

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  • Highly Efficient Photoproduction of Charge-Separated States in Donor-Acceptor-Linked Bis(acetylide) Platinum Complexes

    J. Am. Chem. Soc.   131 ( 30 )   10374 - 10375   2009

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  • Preparation and magnetic properties of verdazylsubstituted dihydrophenazine radical cation tetrachloroferrate salts

    Polyhedron   28 ( 9-10 )   1950 - 1954   2009

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  • A New Ferrimagnet Based on a Radical-substituted Radical Cation Salt

    J. Am. Chem. Soc.   131 ( 13 )   4670 - 4673   2009

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  • Conformation Control of Snowflake Shaped Dendrimers by Metal Complexations Reviewed

    Kato Mutsumi, Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2008 ( 0 )   168 - 168   2008

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    We prepared a rigid conjugated oligomer with flexible C11 alkyl side chains as novel building brocks for snowflake-shaped dendrimers. 2,2'-Bipyridyl terminals were incorporated in both the conjugated and the side chains to control a conformation of flexible side chains by metal complexation. The oligomer was mixed with FeCl<SUB>2</SUB> at room temperature in toluene-methanol (1:1) to form deep red solution. The UV-vis spectra of the solution show MLCT bands around 500 nm characteristic for a [Fe(II)(bpy) <SUB>3</SUB>]<SUP>2+</SUP> type complex. The UV-vis spectroscopic titration indicated almost quantitative formation of the 1:1 complex. In addition, ESI-MS showed molecular ion peak for the 1:1 complex at <I>m</I>/<I>z</I> = 656. The detailed properties and structure of complexes will be presented.

    DOI： 10.11494/kisoyuki.2008.0.168.0

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  • Photo-induced Charge Separation of Platinum Diacetylide Complexes Linked with Electron Donor and Acceptor Moieties Reviewed

    Sugimura Ryoji, Suzuki Shuichi, Kozaki Masatoshi, Keyaki Kazutoshi, Nozaki Koichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2008 ( 0 )   166 - 166   2008

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    Recently, a number of electron donor and acceptor dyads and triads have been designed and synthesized in order to search for systems of long-lived radical ion pairs. Here, we have designed a new system with bipyridine-diacetylide platinum linked by electron donor and acceptor moieties. The bipyridine-diacetylide platinum complex is known as a molecule emitting phosphorescence at room temperature, which is utilized as triplet photo-sensitizer in our proposed system. The desired platinum complexes have been prepared from a corresponding donor (triphenylamine) and acceptor (naphthaldiimide) acetylene derivatives, and bipyridine-platinum complex by mixing them in dichloromethane. With the nanosecond laser excitation at 355 nm, the absorption band assigned to the triphenylamine radical cation species and that of the naphthaldiimide radical anion species were observed in the transient absorption spectra of the platinum complex, which indicates the generation of the charge-separated state. The charge-recombination lifetime was estimated to approximately 200 ns. In the presentation, we discuss detailed photophysical properties of those platinum complexes.

    DOI： 10.11494/kisoyuki.2008.0.166.0

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  • Molecular Magnets Based on Radical-Substituted Radical Cations Reviewed

    Masuda Yuki, Kuratsu Masato, Suzuki Shuichi, Kozaki Masatoshi, Ezaki Toshiaki, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Hosokoshi Yuko, Miyazaki Yuji, Lan Xiaocheng, Inaba Akira, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2008 ( 0 )   381 - 381   2008

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    Radical-substituted radical cations are attractive species as spin-building blocks of molecular magnets or spin-electronic devices. In spite of considerable effort, there has been no report of ferri- or ferromagnets based on the methodology of radical-substituted radical cations. We report the first ferrimagnet using nitronyl nitroxide substituted dihydrophenazine radical cation tetrabromoferrate salt (NNDPP··+FeBr4-), which consists of unique three heterospins, nitronyl nitroxide, dihydrophenazine radical ion, and Fe(III) spins.

    DOI： 10.11494/kisoyuki.2008.0.381.0

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  • electron transfer in porphyrin-anthraquinone dyads bridged by conjugated chains with polar substituents Reviewed

    Taihaku Keisuke, Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2008 ( 0 )   167 - 167   2008

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    We prepared Zn porphyrin-anthraquinone dyads with polar and less-polar substituents (1a and 1b, respectively) on the conjugated bridge. A series of model compounds, 2a and 2b, were also synthesized to investigate the effect of the dipole moment of the substituents on the electron transfer rate. To evaluate the efficiency of electron transfer, the fluorescence study was examined in dichloromethane. The model compounds with a phenyl terminal (2a and 2b) showed an identical fluorescence spectrum with strong intensity. This result indicates that the fluorescence intensity is independent on the dipole moment of the substituents for the phenyl terminal dyads (2a and 2b). On the other hands, the fluorescence was effectively quenched in the anthraquinone derivatives (1a and 1b). 1a revealed a lower fluorescence intensity than 1b, indicating that the presence of polar substituents effectively enhances the quenching efficiency. The detailed synthetic procedure and photo-physical properties of the dyad 1 will be presented.

    DOI： 10.11494/kisoyuki.2008.0.167.0

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  • Syntheses and Properties of Benzobisdioxoles Linked with Nitronyl Nitroxide Reviewed

    KUMAGAI Tasuku, KURATSU Masato, SUZUKI Shuichi, KOZAKI Masatoshi, OKADA Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2008 ( 0 )   170 - 170   2008

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    Design and synthesis of radical-substituted electron-donors are important subjects in molecule-based magnetic materials. So far, we have succeeded in the syntheses and isolations of diradical cations such as trioxytriphenylamine and dihydrophenazine derivatives as stable crystals. In order to develop much compact systems, we have focused on benzobisdioxoles. We report syntheses, properties, and stabilities of the nitronyl-nitroxide substituted neutral benzobisdioxole derivatives and their radical cations. Similar studies of the sulfur-bridged analogues will also be described.

    DOI： 10.11494/kisoyuki.2008.0.170.0

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  • Heterospin Molecule-based Magnets Possessing Trioxytriphenylamine (TOT) Moiety Reviewed

    Kuratsu Masato, Suzuki Shuichi, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Lan Xiaozheng, Miyazaki Yuji, Inaba Akira, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2008 ( 0 )   278 - 278   2008

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    Radical-substituted radical cations are attractive compounds as spin building blocks of molecule-based magnets. We now report syntheses and magnetic behaviors of <B>NN-TOT</B><SUP>•+</SUP>MX<SUB>4</SUB><SUP>-</SUP> (M = Fe, Ga; X = Cl, Br). <B>NN-TOT</B><SUP>•+</SUP>MX<SUB>4</SUB><SUP>-</SUP> was synthesized by chemical oxidation of neutral <B>NN-TOT</B>. <B>NN-TOT</B><SUP>•+</SUP>FeCl<SUB>4</SUB><SUP>-</SUP> showed a magnetic phase transition at 3 K with a magnetic hysteresis, whereas <B>NN-TOT</B><SUP>•+</SUP>FeBr<SUB>4</SUB><SUP>-</SUP> showed a magnetic phase transition at 4 K without a magnetic hysteresis. These results suggest that <B>NN-TOT</B><SUP>•+</SUP>FeCl<SUB>4</SUB><SUP>-</SUP> and <B>NN-TOT</B><SUP>•+</SUP>FeBr<SUB>4</SUB><SUP>-</SUP> are transformed into a ferrimagnet and a meta magnet, respectively. Detailed studies for all compounds will be discussed.

    DOI： 10.11494/kisoyuki.2008.0.278.0

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  • Synthesis and electronic structure of dihydrophenazine-linked pyrene diradical dication Reviewed

    TAKEDA Takuma, KURATSU Masato, SUZUKI Shuichi, KOZAKI Masatoshi, SHIOMI Daisuke, SATO Kazunobu, TAKUI Takeji, OKADA Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2008 ( 0 )   181 - 181   2008

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    We have studied on electronic and magnetic properties of radical-substituted radical cations. Pyrene structure has unique electronic properties; the HOMO and LUMO of pyrene has a nodal plane passing through C2 and C7 atoms. For the developments of new stable high spin species of diradical dication, we have designed and synthesized a 1,3-bis(dialkylamino)pyrene derivative linked with dihydrophenazine moiety on C7 atom. In the ESR spectrum of the diradical dication species, we have observed the allowed and forbidden signals derived from triplet state. In this presentation, we discuss the synthetic method and the electronic structure of the diradical dication.

    DOI： 10.11494/kisoyuki.2008.0.181.0

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  • Structures and magnetic properties of calcogen-atom-introduced trioxytriphenylamine radical cation tetrabromoferrates. Reviewed

    Ezaki Toshiaki, Kuratsu Masato, Suzuki Shuichi, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   2008 ( 0 )   180 - 180   2008

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    Trioxytriphenylamine (TOT) radical cations are stable species with planar triphenylamine structure. We have recently shown that TOT•FeBr4 salt shows a phase transition into an antiferromagnet at TN ~ 7 K. In order to increase the dimension of magnetic interactions, we have designed and synthesized calcogen-atom-introduced TOT. Tri-(methylthio)-substituted TOT radical cation tetrabromoferrate salts was found to exhibit a phase transition into a meta-magnet around 5 K. The detailed crystal structures and properties of this and related calcogen-atom-introduced TOT radical cation salts will be presented.

    DOI： 10.11494/kisoyuki.2008.0.180.0

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  • A Light Harvesting Array Composed of Porphyrins and Rigid Backbones

    Org. Lett.   10   4477 - 4480   2008

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  • Photoinduced Electron Transfer Reactions of Highly Twisted 1-Donor-substituted 2,4,6-Triphenylpyridinium Cations

    J. Photochem. and Photobio. A: Chem.   194   254 - 260   2008

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  • Photoinduced Electron-Transfer and Electron-Mediating Processes of Fullerenes and Phenothiazine Oligomers in Polar Solvent

    Bull. Chem. Soc. Jpn.   81 ( 1 )   103 - 109   2008

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  • Photoinduced Electron Transfer of N-[(3- and 4-Diarylamino)phenyl]-1,8- Naphthalimide Dyads: Orbital-orthogonal Approach in a Short-linked D-A System

    J. Phys. Chem. A   112   2533 - 2542   2008

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  • Stepwise construction of a cross-shaped covalent assembly of dendrimers

    Tetrahedron Lett.   49   2931 - 2934   2008

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  • Photoinduced Charge-Separation and Charge-Recombination Processes of Fullerene[60] Dyads Covalently Connected with Phenothiazine and its Trimer

    J. Phys. Chem. A   112   5878 - 5884   2008

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  • Magnetic interaction of tri- and di-oxytriphenylamine radical cation FeCI4 salts Reviewed

    Kuratsu Masato, Suzuki Shuichi, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Okada Keiji

    INORGANIC CHEMISTRY   46 ( 24 )   10153 - 10157   2007.11（ ISSN:0020-1669 ）

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    DOI： 10.1021/ic7012649

  • Construction and Properties of Pentameric Assembly of Snowflake-Shaped Dendrimers Reviewed

    Tsujimura Hitoshi, Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   37 ( 0 )   90 - 90   2007

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    Snowflake-shaped dendrimers are advantageous to assemble multiple functional groups and provide attractive building blocks for the construction of nano-scale molecular devices and machines. Here, we prepared a covalently linked assembly of the five snowflake-shaped dendrimers and investigated photo-physical properties.Sonogashira coupling reactions of the snowflake-shaped dendrimers with an iodo and three phenyl terminals and four ethynyl terminals at the end of conjugated chains afforded the desired assembly. The UV-vis spectrum of the assembly in THF showed characteristic bands for porphyrin units (lambda max = 433 nm, 519, 559, 601, 649 nm). Fluorescence at 614, 657, and 719 nm (phi<SUB>f</SUB> = 0.063) is observed for the assembly in THF by excitation at 571 nm. From the shape and intensity of the fluorescence spectra of the assembly and model compounds, the efficient energy transfer process from the outer Zn-porphyrin units to the inner free-base porphyrin unit was clarified.

    DOI： 10.11494/kisoyuki.37.0.90.0

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  • Syntheses and Magnetic Behaviors of Radical Cation Salts Based on Trioxytriphenylamine (TOT) Reviewed

    KURATSU Masato, SUZUKI Shuichi, KOZAKI Masatoshi, SHIOMI Daisuke, SATO Kazunobu, TAKUI Takeji, OKADA Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   37 ( 0 )   11 - 11   2007

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    Radical-substituted radical cations with strong intramolecular ferromagnetic interactions are attractive compounds as spin building blocks of magnetic materials. We now report syntheses and magnetic behaviors of <B>TOT</B><SUP>·+</SUP>, <B>TOTNN</B><SUP>·+</SUP> and <B>TOTIN</B><SUP>·+</SUP> with the magnetic- (FeCl<SUB>4</SUB><SUP>-</SUP>, FeBr<SUB>4</SUB><SUP>-</SUP>) or non-magnetic (GaCl<SUB>4</SUB><SUP>-</SUP>, GaBr<SUB>4</SUB><SUP>-</SUP>) anions. <B>TOTMX<SUB>4</SUB></B> (M = Ga, Fe; X = Cl, Br) were synthesized by chemical oxidation of <B>TOT</B> using thianthrene radical cations with the corresponding counter anions. <B>TOTFeBr<SUB>4</SUB></B> and <B>TOTNNFeCl<SUB>4</SUB></B> showed interesting magnetic behaviors at low temperature. Detailed studies are in progress.

    DOI： 10.11494/kisoyuki.37.0.11.0

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  • Preparation and properties of porphyrin-anthraquinone dyads bridged by conjugated chains with polar substituents Reviewed

    Taihaku Keisuke, Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   37 ( 0 )   80 - 80   2007

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    Recently we demonstrated that covering of the conjugated chain enhances the electron transfer in Zn porphyrin-anthraquinone dyad bridged with oligo(phenylene-ethynylene)s. Here we prepared similar Zn porphyrin-anthraquinone dyad 1 with polar substituents on the conjugated bridge and investigated the effect of a dipole moment on the electron transfer rate.The synthesis of the dyad 1 was started from the preparation of triphenylamine derivatives with electron withdrawing groups at para positions. The triphenylamine derivative was bonded to conjugated chain as the polar substituent using Suzuki-Miyaura cross coupling reaction. The conjugated chain was terminated with anthraquinolyl and porphyrin units using Sonogashira cross coupling reactions. The detailed synthetic procedure and photo-physical properties of the dyad 1 will be presented.

    DOI： 10.11494/kisoyuki.37.0.80.0

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  • Structure and Magnetic Properties of Radical-Substituted Dihydrophenazine Radical Cations Reviewed

    Masuda Yuki, Kuratsu Masato, Suzuki Shuichi, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   37 ( 0 )   188 - 188   2007

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    Radical-substituted radical cations are attractive spin-building blocks of magnetic materials. We report synthesis and magnetic properties of nitronyl nitroxide substituted 9,10-diphenyldihydrophenazine radical cation, NNDP<SUP>+</SUP>, FeX<SUB>4</SUB><SUP>-</SUP> (S = 5/2) and GaX<SUB>4</SUB><SUP>-</SUP> (S = 0) salts. We have also examined verdazyl-substituted analogues VzDPMX<SUB>4</SUB>. The crystal structure of NNDP-MX<SUB>4</SUB> salts (M = Fe and Ga, X = Cl and Br) showed alternate stacks consisting of NNDP<SUP>+</SUP> and FeX<SUB>4</SUB><SUP>-</SUP>. For the X = Cl salts, the short contacts between nitroxide oxygen atoms belonging to the adjacent columns were observed. For the X = Br salt, the distance between the nitroxide oxygen atoms was found to be considerable long. The verdazyl salts showed a different crystal packing structure.

    DOI： 10.11494/kisoyuki.37.0.188.0

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  • Preparation and Metal Complexation of Snowflake-shaped Dendrimers with Terpyridine Terminal Reviewed

    Matsumoto Hitonari, Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   37 ( 0 )   91 - 91   2007

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    Recently, we have reported a covalently linked cross-type assembly consisting of the five snowflake-shaped dendrimers. Here, we have prepared snowflake-shaped porphyrin dendrimer 1 with a terpyridine unit at the end of conjugated chain to assemble dendrimers with coordination bonds.Preparation of dendron 2 with terpyridinyl terminal was achieved by the condensation of an aldehyde with 2-acetylpyridine in the presence of NH4OH under basic conditions. Dendron 2 and phenyl-terminated dendron were sequentially connected with tetraphenyl Zn porphyrin core using Sonogashira coupling reactions to afford dendrimer 1. Dendrimer 1 was characterized by means of NMR and MALDI-TOF mass spectroscopy, UV-Vis spectroscopy. We will present the detailed synthetic procedure and the formation of metal complexes of dendrimer 1.

    DOI： 10.11494/kisoyuki.37.0.91.0

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  • Preparation, structure, and magnetic interaction of a Mn(hfac)(2)-bridged [2-(3-pyridyl)(nitronyl nitroxide)-Mn(hfac)(2)](2) chain complex Reviewed

    Okada Keiji, Beppu Shiori, Tanaka Koichiro, Kuratsu Masato, Furuichi Kimiaki, Kozaki Masatoshi, Suzuki Shuichi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Kitagawa Yasutaka, Yamaguchi Kizashi

    CHEMICAL COMMUNICATIONS   ( 24 )   2485 - 2487   2007（ ISSN:1359-7345 ）

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    DOI： 10.1039/b618682c

  • Preparation and magnetic properties of 4,6-bis(iminonitroxide)-substituted resorcinol and its Cu-complex Reviewed International coauthorship

    Koichiro Tanaka, Kimiaki Furuichi, Masatoshi Kozaki, Shuichi Suzuki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Keiji Okada

    Polyhedron   26 ( 9-11 )   2021 - 2026   2007

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    Publishing type：Research paper (scientific journal)   Kind of work：Joint Work  

  • Enhanced Electron Transfer by Dendritic Architecture: Energy Transfer and Electron Transfer in Snowflake-Shaped Zn Porphyrin Dendrimers

    Org. Lett.   9 ( 8 )   1509 - 1512   2007

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  • Construction of a Rigid Zn Porphyrin-C60 Dyad within Dendritic Structure: Dendrimer Effect on Singlet Energy-Transfer

    Org. Lett.   9   3315 - 3318   2007

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  • Detection of a diradical intermediate in the cis-trans isomerization of 5,5 '-bis(4,5-diphenyl-2H-imidazol-2-ylidene)-5,5 '-dihydro-Delta(2,2 ')-bithiophene Reviewed

    Kozaki Masatoshi, Isoyama Asuka, Okada Keiji

    TETRAHEDRON LETTERS   47 ( 30 )   5375 - 5378   2006.07（ ISSN:0040-4039 ）

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    DOI： 10.1016/j.tetlet.2006.05.084

  • Synthesis and Properties of Radical Cation Salts and Charge Transfer Complexes Based on Verdazyl-Substituted Dihydrophenazine Derivatives Reviewed

    Masuda Yuki, Kuratsu Masato, Takeda Hirotaka, Suzuki Shuichi, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   18 ( 0 )   267 - 267   2006

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    We have studied on electronic and magnetic properties of radical-substituted dihydrophenazine radical cations. When verdazyl was used as a stable radical, the radical cation were not stable. We have improved the stability of the radical cation by introducing methyl group at 7,8-position of dihydrophenazine skeleton or by using 1,5-diphenyl-6-oxoverdazyl group. The synthesis, magnetic properties, and conductivity of stable radical cation salts and related charge transfer complexes derived from the modified verdazyl-substituted dihydrophenazines are presented.

    DOI： 10.11494/kisoyuki.18.0.267.0

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  • Synthesis of Snowflake-Like Dendrimer Clusters Reviewed

    Tsujimura Hitoshi, Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   18 ( 0 )   140 - 140   2006

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    We prepared both A3B and A4 type snowflake-shaped porphyrin dendrimers to obtain a dendrimer cluster with a rigid pi-conjugated network. First, the A3B type porphyrin was synthesized by the condensation of pyrrole with 4-ethynylbenzaldehydes protected with TMS or 2-(2-hydroxypropyl) groups. Incorporation of dendritic branches using a Sonogashira cross-coupling reactions and selective removal of the protecting groups were alternatively performed on the A3B type porphyrin to afford the A3B dendrimers. The A4 type porphyrin dendrimer synthesized with the similar method. The detailed synthetic procedure and the coupling reaction of the A3B with the A4 type porphyrin dendrimers will be presented.

    DOI： 10.11494/kisoyuki.18.0.140.0

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  • Conformation Control of Branched Chains in Dendimers by Metal Complexations Reviewed

    KUNIKAWA Tomoki, KOZAKI Masatoshi, SUZUKI Shuichi, OKADA Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   18 ( 0 )   319 - 319   2006

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    We prepared the dendron with a rigid conjugated chain and flexible dendric chains.2,2'-Bipyridyl groups were incorporated in terminals of both the conjugated and dendritic chains to control a conformation of flexible chains by metal complexations. An attachment of dendritic branches and an extension of phenylacetylenic units were alternatively manipulated on the substituted diphenylacetylene using a combination of Suzuki- and Sonogashira cross-coupling reactions. The dendron was mixed with FeCl2 at room temperature in CHCl3-DMSO(1:1) to form [Fe(II)(bpy)3]2+ complex as well as the absorption of the dendron at 287, 257 nm. The detailed synthetic procedure and properties of the dendron will be presented.

    DOI： 10.11494/kisoyuki.18.0.319.0

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  • Oxygen-Bridged Triphenylamine Radical Cation Salts; Structure and Magnetic Property Reviewed

    Kuratsu Masato, Suzuki Shuichi, Kozaki Masatoshi, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   18 ( 0 )   177 - 177   2006

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    Recently, we have prepared new oxygen-bridged triphenylamines. We now report syntheses, structures, and magnetic properties of FeCl<SUB>4</SUB><SUP>-</SUP> and GaCl<SUB>4</SUB><SUP>-</SUP> salts of the oxygen-bridged triphenylamines. These salts were synthesized by the oxidation of the neutral triphenylamines using thianthrenium radical cation salts (FeCl<SUB>4</SUB><SUP>-</SUP> and GaCl<SUB>4</SUB><SUP>-</SUP>) as an oxidant. From the X-ray structure analysis, the followings became apparent, 1) the structures of FeCl<SUB>4</SUB><SUP>-</SUP> and GaCl<SUB>4</SUB><SUP>-</SUP> salts were isostructural each other, 2) intermolecular short contacts were observed between the adjacent radical cations or between the radical cations and counter ions. We report the structures and magnetic properties of these salts.

    DOI： 10.11494/kisoyuki.18.0.177.0

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  • Synthesis and photoinduced electron-transfer of a snow-flake type porphyrin dendrimer with fullerene terminals Reviewed

    Akita Kogen, Kozaki Masatoshi, Suzuki Shuichi, Okada Keiji

    The Society of Physical Organic Chemistry, Japan, Abstracts of Symposium on Physical Organic Chemistry   18 ( 0 )   230 - 230   2006

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    We prepared the dendron 1 with both Zn porphyrin and C60 terminals from the previously reported dendron 2. Incorporation of the C60 terminals was achieved by the coupling reaction of C60 with acetylide anion. The anion was generated from dendron 1 using LHMDS as a base. The UV-vis absorption spectrum of dendron 1 in DMF has characteristic absorption bands for the Zn porphyrin unit (Soret band: lmax = 430 nm, Q-bands: 562, 603 nm) as well as the C60 absorption band at ca. 330nm accompanied with weak long-wavelength bands. The detailed synthetic procedure and photophysical properties will be presented.

    DOI： 10.11494/kisoyuki.18.0.230.0

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  • Preparation, Properties, and Reduction of a Novel TCNQ-type Thienoquinoid

    Org. Lett.   8   5235 - 5238   2006

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  • Exchange Interaction of 5,5'-(m- and p-Phenylene)bis(10-phenyl-5,10-dihydrophenazine) Dications and Related Analogues Reviewed International coauthorship

    Eriko Terada, Toshihiro Okamoto, Masatoshi Kozaki, Miyuki Eiraku Masaki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Keiji Okada

    THE JOURNAL OF ORGANIC CHEMISTRY   70 ( 24 )   10073 - 10081   2005.11

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  • Magnetic ordering in a genuine organic crystal with triangular antiferromagnetic spin units Reviewed

    Takeda K, Yoshida Y, Inanaga Y, Kawae T, Shiomi D, Ise T, Kozaki M, Okada K, Sato K, Takui T

    PHYSICAL REVIEW B   72 ( 2 )   2005.07（ ISSN:2469-9950 ）

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    DOI： 10.1103/PhysRevB.72.024435

  • 2,2 ': 6 ',2 '': 6 '',6-trioxytriphenylamine: Synthesis and properties of the radical cation and neutral species Reviewed

    Kuratsu M, Kozaki M, Okada K

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   44 ( 26 )   4056 - 4058   2005（ ISSN:1433-7851 ）

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    DOI： 10.1002/anie.200500397

  • One-dimensional void-space arrays constructed from a coordination polymer with bowl-like frameworks of cavitands Reviewed

    Tadokoro M, Mizugaki S, Kozaki M, Okada K

    CHEMICAL COMMUNICATIONS   ( 9 )   1140 - 1142   2005（ ISSN:1359-7345 ）

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    DOI： 10.1039/b415374j

  • Preparation, properties, and reduction of heteroaromatic quinoids with 1,4-diazacyclo-pentadien-2-ylidene terminals

    Org. Lett.   7 ( 1 )   115 - 118   2005

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  • 1,4-Benzoxazino[2,3-b]phenoxazine and Its Sulfur Analogues: Synthesis, Properties, and Application to Organic Light-Emitting Diodes

    Chem. Mater.   17   5504 - 5511   2005

  • Amphoteric Quinone-azine-cyclopentadithiophene System

    Chem. Lett.   33   156 - 157   2004

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  • Synthesis, Structure, and Electron-Donating Ability of 2,2':6',2"-Dioxatriphenylamine and Its Sulfur Analogue

    Chem. Lett.   33   1174 - 1175   2004

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    Publishing type：Research paper (scientific journal)  

  • Remarkable Structure Deformation in Phenothiazine Trimer Radical Cation

    Org. Lett.   6 ( 20 )   3493 - 3496   2004

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    Publishing type：Research paper (scientific journal)  

  • Snowflake&#8211;like Dendrimers via Site-Selective Synthesis of Dendrons

    Org. Lett.   6   485 - 488   2004

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    Publishing type：Research paper (scientific journal)  

  • A Stable Radical-Substituted Radical Cation with Strongly Ferromagnetic Interaction: Nitronyl Nitroxide-Substituted 5,10-Diphenyl-5,10-dihydrophenazine Radical Cation

    J. Am. Chem. Soc.   126   58 - 59   2004

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    Publishing type：Research paper (scientific journal)  

  • Facile Synthesis of 5,10-Diaryl-5,10-dihydrophenazines and Application to EL-devices

    Organic Letters   5   373 - 376   2003

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    Publishing type：Research paper (scientific journal)  

  • Preparation and magnetic interaction of a polymer pendent nitroxide with a bulky protecting group

    Synthetic Metals   135-136   95 - 96   2003

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    Publishing type：Research paper (scientific journal)  

  • Syntheis and magnetic properties of an iminonitroxide-substituted phenolate-Cu complex

    Polyhedron   22   1803 - 1808   2003

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    Publishing type：Research paper (scientific journal)  

  • Preparation and Magnetic Properties of Mn(hfac)2-Complexes of 2-(5-Pyrimidinyl)- and 2-(3-Pyridyl)-Substituted Nitronyl Nitroxides

    ,Inorg. Chem.   42 ( 10 )   3221 - 3228   2003

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    Publishing type：Research paper (scientific journal)  

  • Novel cyclopentadithiophene dimers with small HOMO-LUMO gaps

    Synthetic Metals   135-136   107 - 108   2003

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    Publishing type：Research paper (scientific journal)  

  • Synthesis and properties of thiophene oligomers containing o-quinoid skeleton

    Synth. Met.   135-136   85 - 86   2003

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    Publishing type：Research paper (scientific journal)  

  • ortho-Disubstitution reactions of aromatic rings with homo-conjugated bicyclo[2.2.2]octa-2,5-diene derivatives in the presence of palladium(II) acetate

    Tetrahedron   58   9081 - 9088   2002

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    Publishing type：Research paper (scientific journal)  

  • Molecular and electronic spin structures of high-spin polyphenylene-based oligonitrenes with high symmetry; a semiempirical approach to fine-structure tensors

    Mol. Cryst. Liq. Cryst.   376   501 - 506   2002

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    Publishing type：Research paper (scientific journal)  

  • Cyclopentadithiophene (CPDT)-dimer dication; bipolaron model for quaterthiophenes

    Organic Letters   4   4535 - 4538   2002

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    Publishing type：Research paper (scientific journal)  

  • Magnetic Behavior of a Manganese(II) Complex of a Nitroxide-Substituted 1,3-Di(4-pyridyl)benzene

    Polyhedron   20   1653 - 1658   2001

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    Publishing type：Research paper (scientific journal)  

  • Synthesis and Properties of a New-Type Nitroxide Radical with Bulky 2,4,6-Triphenylphenyl Substituent

    Synth. Met.   121   1808 - 1809   2001

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    Publishing type：Research paper (scientific journal)  

  • Benzoxazinophenoxazines: neutral and charged species

    Tetrahedron Lett.   42   7591 - 7594   2001

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    Publishing type：Research paper (scientific journal)  

  • Synthesis and preliminary testing of molecular wires and devices

    Chem.-Eur. J.   7   5118 - 5134   2001

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    Publishing type：Research paper (scientific journal)  

  • Highly Synthetic High-Spin Oligonitrenes; Molecular Design for Super High Spin Systems with Robust p-spin Polarization

    Synth. Met.   121   1840 - 1841   2001

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    Publishing type：Research paper (scientific journal)  

  • Magnetic Behavior of Copper(II) Complexes of a Nitronyl Nitroxide-Substituted Pyrimidine

    Polyhedron   20   1663 - 1668   2001

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    Publishing type：Research paper (scientific journal)  

  • Preparation and properties of oligomers containing cyclopentadithiophene

    Synth. Met.   119   99 - 100   2001

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    Publishing type：Research paper (scientific journal)  

  • Synthesis and Properties of Benzooxazino-phenoxazine and the Related Compounds

    Synth. Met.   120   933 - 934   2001

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    Publishing type：Research paper (scientific journal)  

  • Carbazole Oligomers and the Dimer-Derived DPPH-type Diradical

    Synth. Met.   119   2001   2001

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    Publishing type：Research paper (scientific journal)  

  • Benzoic Acid and Phenol Derivatives of Nitronyl Nitroxide Biradical as Building Blocks of Organic Molecule-Based Ferrimagnets

    Applied Masgnetic Resonance   19   45 - 57   2000

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    Publishing type：Research paper (scientific journal)  

  • Exchange Interaction of Some Thianthrene-Derived Dications

    T. Nakai, K. Sato, D. Shiomi, T. Takui, K. Itoh et al.

    Mol. Cryst. Liq. Cryst.   334   139 - 148   1999

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    Publishing type：Research paper (scientific journal)  

  • Generation and Reactivity of 2,4,6-Triphenylpyridinyl Radicals Linked by Alkyl Chains Reviewed International coauthorship

    Kouzo Matsumoto, Masaji Oda, Masatoshi Kozaki, Kazunobu Sato, Takeji Takui, Keiji Okada

    Synthetic Metals   103   2304 - 2305   1999

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    Publishing type：Research paper (international conference proceedings)   Kind of work：Joint Work  

  • Structure and Photolysis of the Dimer of 2,2'-(m-Phenylene)bis(4,5-diphenylimidazole-2-yl) Diradical Reviewed International coauthorship

    Keiji Okada, Kunihiko Imamura, Masaji Oda, A. Kajiwara, K. Kamachi, K. Isino, K. Tashiro, Masatoshi Kozaki, Kazunobu Sato, Takeji Takui

    Synthetic Metals   103   2306 - 2307   1999

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    Publishing type：Research paper (international conference proceedings)   Kind of work：Joint Work  

  • Preparation and Exchange Interaction of DPPH-Derived Polyradicals

    Mol. Cryst. Liq. Cryst.   334   131 - 138   1999

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    Publishing type：Research paper (scientific journal)  

  • High-Spin Nitrenes with s-Triazine Skeleton

    Mol. Cryst. Liq. Cryst.   334   157 - 166   1999

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    Publishing type：Research paper (scientific journal)  

  • Preparation and Characterization of Novel DPPH-based Diradicals

    Tetrahedron Letters   39   5979   1998

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    Publishing type：Research paper (scientific journal)  

  • Preparation and Properties of Novel Polythiophenes Containing 1,3-Dithiol-2-ylidene Moieties

    Journal of Organic Chemistry   59 ( 2 )   442 - 450   1994

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    Publishing type：Research paper (scientific journal)  

  • Studies on Novel Polythiophene Derivatives Containing Cyclopentadithiophene Moieties

    The Graduate University for Advanced Studies   1 - 104   1994

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    Kind of work：Single Work  

  • Reaction of Strained Homoconjugated Compounds with Benzene in the Presence of Palladium(II) Acetate

    Chemistry Letters   1769 - 1772   1994

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    Publishing type：Research paper (scientific journal)  

  • Preparation and Properties of 7-(1,3-dithiol-2-ylidene)-7H-cyclopenta[1,2-b ; 4,3-b"] dithiophene and Their Polymers

    Chemistry Letters   533 - 536   1993

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    Publishing type：Research paper (scientific journal)  

  • Aromatization and Hydrogen-Shift of 7-Substituted 1,3,5-Cycloheptatrienes in the Presence of Palladium(II) Acetate

    Chemical and Pharmaceutical Bulletin   41 ( 12 )   2187 - 2189   1993

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    Publishing type：Research paper (scientific journal)  

  • Preparation and Properties of Poly-4-(1,3-dithiol-2-ylidene)-4H-cyclopenta[2,1-b ; 3,4-b"] dithiophene and It"s Derivatives

    Journal of Chemical Society, Chemical Communications   16   1137 - 1138   1992

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    Publishing type：Research paper (scientific journal)  

  • Introduction of Acetoxyl Group in Tropone and Azulene Nuclei Using Palladium(II) Acetate : Reactions of 2-Aminotropones and Azulene with Palladium(II) Acetate

    Chemical and Pharmaceutical Bulletin   39 ( 7 )   1843 - 1845   1991

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    Publishing type：Research paper (scientific journal)  

  • Reaction of Azepin with Palladium(II) Acetate : Formation of Mucondialdehyde and Dihydroazepine Derivative

    Heterocycles   31 ( 8 )   1491 - 1496   1990

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    Publishing type：Research paper (scientific journal)  

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Books and Other Publications

  • 高校生・化学宣言〈PART14〉 高校化学グランドコンテストドキュメンタリー

    中沢浩、小嵜正敏（ Role： Supervisor (editorial) ,  監修）

    遊タイム出版  2022.06  （ ISBN:4860103637 ）

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    Total pages：156   Book type：General book, introductory book for general audience Participation form：Second Author

  • 魅惑の香りで化学の世界に誘い，生物の化学コミュニケーションを学ぶ

    小嵜正敏（ Role： Sole author）

    化学と教育  2021 

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    Responsible for pages：2  

  • 高校生・化学宣言〈PART13〉 高校化学グランドコンテストドキュメンタリー

    中沢　浩，小嵜　正敏，笹森　貴裕　（ Role： Supervisor (editorial)）

    遊タイム出版  2020.06  （ ISBN: 978-4-860103583 ）

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    Total pages：212   Book type：General book, introductory book for general audience

    化学の甲子園と呼ばれる「高校化学グランドコンテスト」に参加した国内、国外高校生のコンテストまでの奮闘を収録したシリーズ第12弾。

    Other Link： https://images-na.ssl-images-amazon.com/images/I/71uGf7BIIyL.jpg

  • Polymers for Light-emitting Devices and Displays

    Rania Zaier, Said Hajaji, Masatoshi Kozaki, Sahbi Ayachi（ Role： Joint author ,  Chapter 3）

    Wiley-Scrivener  2020.05  （ ISBN:1119654602 ）

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    Total pages：268   Book type：Scholarly book

  • DFT Computational Modeling and Design of New Cyclopentadithiophene (CPDT) Derivatives for Highly Efficient Blue Emitters in OLEDs

    Zaier R.

    Polymers for Light-Emitting Devices and Displays  2020.01  （ ISBN:9781119654605 ）

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  • 高校生・化学宣言〈PART12〉 高校化学グランドコンテストドキュメンタリー

    中沢　浩，小嵜　正敏，笹森　貴裕　（ Role： Supervisor (editorial)）

    遊タイム出版  2019.06  （ ISBN: 978-4-860103583 ）

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    Total pages：234   Book type：General book, introductory book for general audience

    化学の甲子園と呼ばれる「高校化学グランドコンテスト」に参加した国内、国外高校生のコンテストまでの奮闘を収録したシリーズ第12弾。

    Other Link： https://images-na.ssl-images-amazon.com/images/I/71uGf7BIIyL.jpg

  • 高校生・化学宣言〈PART11〉 高校化学グランドコンテストドキュメンタリー

    中沢　浩，小嵜　正敏，笹森　貴裕　（ Role： Supervisor (editorial)）

    遊タイム出版  2018.03  （ ISBN:978-4-86010-357-6 ）

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    Total pages：209   Book type：General book, introductory book for general audience

  • 高校生・化学宣言〈PART10〉 高校化学グランドコンテストドキュメンタリー

    中沢　浩 小嵜　正敏（ Role： Supervisor (editorial)）

    遊タイム出版  2017.06 

  • 次世代共役ポリマーの超階層制御と革新機能

    小嵜正敏（ Role： Sole author ,  第15章 デンドリマー集積による共役ネットワークの構築とその特性）

    シーエムシー出版  2009  （ ISBN:4781300731 ）

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    Book type：Scholarly book

  • 「デンドリマー集積による共役ネットワークの構築とその特性」“次世代共役ポリマーの超階層制御と革新機能"、第15章、赤木和夫監修

    -（ Role： Sole author）

    シーエムシー出版  2009  （ ISBN:4781300731 ）

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    Book type：Scholarly book

  • 高校生・化学宣言PART3 : 高校化学グランドコンテストドキュメンタリー

    中沢 浩, 松坂 裕之, 小嵜 正敏（ Role： Sole author）

    遊タイム出版  2008  （ ISBN:9784860102623 ）

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    Book type：Scholarly book

    CiNii Books

  • Introduction to Organic Spectroscopy

    （ Role： Joint translator）

    Kagakudojin  1999  （ ISBN:ISBN4-7598-0828-0 ）

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    Book type：Scholarly book

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MISC

  • 非対称ペンタピリジン二核鉄(III)錯体を触媒とする不活性C‐Hの酸素化反応 Reviewed

    山崎実香子, 小嵜正敏, 舘祥光

    錯体化学会討論会講演要旨集   69th   202   2019.09

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    Publishing type：Article, review, commentary, editorial, etc. (scientific journal)  

    J-GLOBAL

  • Creation of new π-electron conjugate compounds and the investigation of their functions

    Kozaki Masatoshi

    5   9 - 9   2016

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  • 3,4‐ジヒドロアンヒドロロドビブリンと紅色光合成細菌Rs.rubrum由来LH1サブユニットの再会合と評価 Reviewed

    山元麻衣, 鈴木修一, 小嵜正敏, 岡田惠次, 堀部智子, 西坂好晃, 藤井律子, 南後守, 橋本秀樹

    日本化学会講演予稿集   91st ( 3 )   721   2011.03（ ISSN:0285-7626 ）

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    Publishing type：Article, review, commentary, editorial, etc. (scientific journal)  

    J-GLOBAL

  • 光合成でのLH1アンテナ色素蛋白複合体へのアンヒドロロドビブリンアナログ体の再会合と評価 Reviewed

    山元麻衣, 鈴木修一, 小嵜正敏, 岡田惠次, 堀部智子, 西坂好晃, 藤井律子, 中川勝統, 南後守, 橋本秀樹

    日本化学会講演予稿集   90th ( 3 )   984   2010.03（ ISSN:0285-7626 ）

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    Publishing type：Article, review, commentary, editorial, etc. (scientific journal)  

    J-GLOBAL

  • Synthesis and Properties of Stable Organic Open-shell Molecule with Helicenic Giant π-Electronic System

    上田顕, 森田靖, 鈴木修一, 小嵜正敏, 岡田惠次, 西田辰介, 伊瀬智章, 塩見大輔, 佐藤和信, 工位武治, 中筋一弘

    日本化学会講演予稿集   89th ( 2 )   2009（ ISSN:0285-7626 ）

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  • π共役系を拡張した1,6-ジアザフェナレニルラジカルの合成と物性の解明

    箱井雄太郎, 上田顕, 鈴木修一, 小嵜正敏, 岡田惠次, 西田辰介, 吉野共広, 佐藤和信, 工位武治, 森田靖, 中筋一弘

    日本化学会講演予稿集   88th ( 2 )   2008（ ISSN:0285-7626 ）

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  • 19pXA-14 Magnetic Ordering in a Genuine Organic Crystal of Tri-Radical Reviewed

    Inanaga Y, Saito K, Takui T, Yoshida Y, Kinoshita K, Kawae T, Takeda K, Shiomi D, Ise T, Kosaki M, Okada K

    The Physical Society of Japan, Meeting Abstracts of the Physical Society of Japan   60 ( 0 )   2005

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    Publishing type：Article, review, commentary, editorial, etc. (scientific journal)  

    CiNii Article

  • 27aYK-6 Magnetic Ordering in a Genuine Organic Crystal of Tri-Radical Reviewed

    Inanaga Y, Sato K, Takui T, Yoshida Y, Kinoshita K, Kawae T, Takeda K, Shiomi D, Ise T, Kosaki M, Okada K

    The Physical Society of Japan, Meeting Abstracts of the Physical Society of Japan   60 ( 0 )   2005

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    Publishing type：Article, review, commentary, editorial, etc. (scientific journal)  

    CiNii Article

  • 4,4-(Trimethylene)bis(2,6-di-t-butylphenoxy)Diradical : An Application of the Sequential Redox-Solid State Photolysis (SRSSP)Method((Multiple Authorship))

    Chemistry Letters   845   1998

  • Preparation and Characterization of Novel High-Spin Organoborane Dianions((Multiple Authorship))

    Tetrahedron Letters   39   6483   1998

  • Novel Dimers of 2,2"-(m-Phenylene)bis(4,5-diphenyl-1-imidazoly)Diradical((Multiple Authorship))

    Chemistry Letters   891 - 892   1998

  • Evolution of Strategies for Self Assembly and Hookup of Molecule-Based Devices((Multiple Authorship))

    Annals of the New York Academy of Science   852   349 - 370   1998

  • Tribenzo-1,4,5,8,9,12-hexathiatriphenylene Dication and Dibenzo-1,4,5,8-tetrathiaphenanthrene Dication((Multiple Authorship))

    Chemistry Letters   933 - 934   1998

  • Molecular Scale Electronics : A Synthetic/Computational Approach to Digital Computing((Multiple Authorship))

    Journal of American Chemical Society   120 ( 33 )   8489 - 8493   1998

  • Exchange Interaction of Bispyridinyl Diradicals Linked by σ-Frames

    Tetrahedron Letters   39   6307   1998

  • A New Photochemical Approach to Benzylic Polyradicals through C-N Bond Cleavage of a Pyridiny Radical((Multiple Authorship))

    Tetrahedron Letters   39   6315   1998

  • New Thiopene-Pyrrole-Derived Annulenes Containing 6 and 10 Heterocyclic Units ((Multiple Authorship))

    Journal of Organic Chemistry   61 ( 11 )   3657 - 3661   1996

  • Geometrically Constrained Thiopene-Pyrrole Oligomers ((Multiple Authorship))

    Tetrahedron Letters   36 ( 38 )   6835 - 6838   1995

▼display all

Presentations

  • Synthesis of N-Benzimidazolyl Tetrahydro-β-Carboline Domestic conference

    YUHAO PU, Yoshimitsu Tachi, Masatoshi Kozaki

    The 51st Symposium on Main Group Element Chemistry  2024.12 

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    Presentation type：Poster presentation  

  • ラジカル置換トリオキシフェニルアミンラジカルカチオンを基盤とする安定基底五重項の研究 Domestic conference

    遠山丈瑠、直田健、尾向宏介、谷本理勇、塩見大輔、佐藤和信、工位武治、小嵜正敏、岡田恵次、鈴木修一

    第34回基礎有機化学討論会  2024.09  基礎有機化学会

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    Presentation type：Poster presentation  

    Venue：札幌  

  • Syntheses and Properties of Diazaperopyrenes with Electron-donating Groups Domestic conference

    Hotsuma Inada, Yasufumi Masani, Yoshimitsu Tachi, Masatoshi Kozaki

    The 104th CSJ Annual Meeting  2024.03  The Chemical Society of Japan

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    Presentation type：Oral presentation (general)  

    Venue：Funabashi Campus, Nihon University  

  • Syntheses of heteropolycyclic aromatic compounds with tetrahydro-β-carboline structures Domestic conference

    Takuma Yuba, Yoshimitsu Tachi, Masatoshi Kozaki

    The 104th CSJ Annual Meeting  2024.03  The Chemical Society of Japan

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    Presentation type：Oral presentation (general)  

    Venue：Funabashi Campus, Nihon University  

  • Syntheses and properties of donor-acceptor type fused polycyclic compounds with a triphenylamine skeleton as a donor unit Domestic conference

    Katsutaka Nishiyama, Yoshimitsu Tachi, Masatoshi Kozaki

    The 104th CSJ Annual Meeting  2024.03  The Chemical Society of Japan

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    Presentation type：Poster presentation  

    Venue：Funabashi Campus, Nihon University  

  • Syntheses and properties of 2-azapyrene derivatives with electron-donating groups at the 7-position Domestic conference

    Takashi Hazama, Yoshimitsu Tachi, Masatoshi Kozaki

    2023.09 

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    Presentation type：Poster presentation  

  • 天然アミノ酸を用いた複素多環芳香族化合物の合成および発光特性 Domestic conference

    舘祥光、前田泰聖、小嵜正敏

    日本化学会第103春季年会  2023.03  日本化学会

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    Presentation type：Poster presentation  

    Venue：東京理科大学　野田キャンパス  

  • Synthesis and Properties of Peropyrene Derivatives with Nitrogen Atoms in Conjugating Frameworks Domestic conference

    Hotsuma Inada, Yoshimitsu Tachi, Masatoshi Kozaki

    the 103rd CSJ Annual Meeting (Nenkai)  2023.03  The Chemical Society of Japan

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    Presentation type：Poster presentation  

    Venue：Noda Campus, Tokyo University of Science  

  • 電子供与性基を７位に有する分極型2-アザピレン誘導体の合成と性質 Domestic conference

    硲隆史、舘祥光、小嵜正敏

    第1回学際化学若手育成シンポジウム  2023.03  大阪公立大学大学院理学研究科化学専攻

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    Presentation type：Poster presentation  

    Venue：大阪公立大学 杉本キャンパス 学術情報総合センター  

  • ジケトピペラジン環を有する複素多環芳香族化合物の発光特性 Domestic conference

    前田泰聖・小嵜正敏・舘 祥光

    第32回基礎有機化学討論会  2022.09  基礎有機化学会

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    Presentation type：Poster presentation  

    Venue：京都パルスプラザ  

  • Syntheses and Properties of Fused-Polycyclic Compounds with Diazapyrene and Carbazole Skeletons Domestic conference

    Suzuho Kurimoto, Yoshimitsu Tachi, Masatoshi Kozaki

    The 32nd Symposium on Physical Organic Chemistry   2022.09  The Society of Physical Organic Chemistry

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    Presentation type：Poster presentation  

    Venue：Kyoto Pulse Plaza  

  • Synthesis of cyclic porphyrin dendrimers with conjugated backbones Domestic conference

    Takumi Nakao, Yoshimitsu Tachi, and Masatoshi Kozaki

    The 32nd Symposium on Physical Organic Chemistry   2022.09  The Society of Physical Organic Chemistry

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    Presentation type：Poster presentation  

    Venue：Kyoto Pulse Plaza  

  • ビス（ニトロニルニトロキシド）金(I)錯体が配位した希土類(III)錯体の合成と磁気的性質 Domestic conference

    谷本理勇，鈴木修一，塩見大輔，田中里佳，直田健，小嵜正敏，岡田惠次

    日本化学会第102春季年会  2022.03 

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    Presentation type：Oral presentation (general)  

  • 天然アミノ酸由来ジケトピペラジン環を有する複素多環芳香族化合物の合成と物性 Domestic conference

    前田泰聖，小嵜正敏，舘祥光

    日本化学会第102春季年会  2022.03 

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    Presentation type：Oral presentation (general)  

  • フェノチアジンおよびジアザピレン骨格を有する縮合多環化合物の合成と性質 Domestic conference

    小嵜正敏，松本圭登，舘祥光

    日本化学会第102春季年会  2022.03 

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    Presentation type：Poster presentation  

  • 含窒素ペロピレン誘導体の合成と性質 Domestic conference

    政二康文，大村祐太，舘祥光，小嵜正敏

    日本化学会第102春季年会  2022.03 

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    Presentation type：Poster presentation  

  • ヘテロ原子を導入した縮合多環芳香族化合物の合成と性質 Invited Domestic conference

    小嵜正敏

    電気化学会第89大会  2022.03 

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    Presentation type：Oral presentation (invited, special)  

  • 共役鎖内包型ポルフィリンデンドリマー環状三量体の合成 Domestic conference

    中尾拓巳，舘祥光，小嵜正敏

    第31回基礎有機化学討論会  2021.09 

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    Presentation type：Poster presentation  

  • 2,2’-ビピリジン核を有するデンドリマーから構成される三量体の合成と性質 Domestic conference

    澤田彩加，舘祥光，小嵜正敏

    第31回基礎有機化学討論会  2021.09 

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    Presentation type：Poster presentation  

  • ビス(ニトロニルニトロキシド)金(I)錯体が配位したガドリニウム(III)錯体の合成と磁気的性質 Domestic conference

    谷本理勇，鈴木修一，塩見大輔，田中里佳，直田健，小嵜正敏，岡田惠次

    第31回基礎有機化学討論会  2021.09 

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    Presentation type：Poster presentation  

  • 拡張型共役系を有するジアザピレン誘導体 Domestic conference

    政二康文、大村祐太、小嵜正敏、舘　祥光

    日本化学会第101春季年会  2021.03 

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    Presentation type：Oral presentation (general)  

  • ペンタピリジン型アルキルアミン系二核鉄錯体の触媒反応のメカニズム解明 Domestic conference

    山崎実香子，小嵜正敏，舘 祥光

    第101回日本化学会春季年会  2021.03 

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    Presentation type：Oral presentation (general)  

  • 三角形型のトリアリール配位子を用いた遷移金属錯体の合成とその物性 Domestic conference

    力丸 心哉，小嵜正敏，舘 祥光

    第101回日本化学会春季年会  2021.03 

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    Presentation type：Poster presentation  

  • 共役系拡張型含窒素ピレン誘導体の合成と性質 Domestic conference

    政二 康文， 大村 祐太，舘 祥光，小嵜 正敏

    第14回有機π電子系シンポジウム  2021.01 

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    Presentation type：Oral presentation (general)  

  • 非対称型二核鉄錯体を触媒とするシクロアルカンの 酸化反応 Domestic conference

    山崎実香子，小嵜正敏，舘 祥光

    第 53 回酸化反応討論会  2020.11 

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    Presentation type：Oral presentation (general)  

  • 非対称型二核鉄錯体によるアルカンの水酸化反応 触媒活性の検討 Domestic conference

    山崎実香子，小嵜正敏，舘 祥光

    第10 回CSJ 化学フェスタ2020  2020.10 

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    Presentation type：Oral presentation (general)  

  • 環拡張型4,10-ジアザピレン誘導体の合成と性質 Domestic conference

    政二 康文， 大村 祐太，舘 祥光，小嵜 正敏

    第10 回CSJ 化学フェスタ2020  2020.10 

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    Presentation type：Poster presentation  

  • 非対称型配位子を用いた二核銅-酸素錯体の 合成と性質 Domestic conference

    泉川紅葉，鎌田泰成，小嵜正敏，舘 祥光

    錯体化学会第 70 回討論会  2020.09 

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    Presentation type：Poster presentation  

  • Effects of Alkyl Chains of Ligands on the Alkane Oxygenation of Diiron(III) Complexes with Asymmetric Pentapyridine Ligands Domestic conference

    Mikako Yamasaki, Masatoshi Kozaki, Yoshimitsu Tachi

    The 70th Conference of Japan Society of Coordination Chemistry  2020.09 

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    Presentation type：Oral presentation (general)  

  • 芳香環が縮環したジアザピレン誘導体の合成と性質 Domestic conference

    政二康文，小嵜正敏，舘　祥光

    日本化学会第100春季年会  2020.03 

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    Presentation type：Poster presentation  

  • 非対称型ペンタピリジン配位子を用いた二核鉄錯体の触媒活性の検討 Domestic conference

    山崎実香子，小嵜正敏，舘　祥光

    日本化学会第100春季年会  2020.03 

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    Presentation type：Oral presentation (general)  

  • ビス(ニトロニルニトロキシド)金(I)錯体の電気化学的および磁気的性質 Domestic conference

    大野智也，和田知之，鈴木修一，小嵜正敏，岡田惠次，佐藤和信，塩見大輔，工位武治，直田　健

    日本化学会第100春季年会  2020.03 

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    Presentation type：Oral presentation (general)  

  • 非対称ピリジルアルキルアミン系配位子の3座配位部位による酸素活性化の制御 Domestic conference

    鎌田泰成，小嵜正敏，舘　祥光

    日本化学会第100春季年会  2020.03 

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    Presentation type：Oral presentation (general)  

  • ジケトピペラジン骨格を含む複素環式芳香族化合物の合成と性質 Domestic conference

    前田航佑，小嵜正敏，舘　祥光

    日本化学会第100春季年会  2020.03 

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    Presentation type：Oral presentation (general)  

  • 三重項励起エネルギー勾配を持つデンドリマーの合成 Domestic conference

    和田拓巳，岡本直也，舘 祥光，小嵜正敏

    第30回基礎有機化学討論会  2019.09 

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    Presentation type：Oral presentation (general)  

  • ピリジルアルキルアミン系非対称型配位子を用いた二核銅錯体の合成と反応性 Domestic conference

    鎌田泰成，小嵜正敏，舘　祥光

    錯体化学第69回討論会  2019.09 

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    Presentation type：Poster presentation  

  • 非対称ペンタピリジン二核鉄(III)錯体を触媒とする不活性C-H の酸素化反応 Domestic conference

    山崎　実香子，小嵜 正敏，舘 祥光

    錯体化学第69回討論会  2019.09 

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    Presentation type：Poster presentation  

  • Short-step Syntheses and Photophysical Properties of Nitrogen-Containing Pyrenes Invited International conference

    Masatoshi Kozaki, Yuta Omura, Yoshimitsu Tachi, Keiji Okada

    The 6th Awaji International Workshop on “Electron Spin Science & Technology: Biological and Materials Science Oriented Applications” (6th AWEST 2019)  2019.06 

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    Presentation type：Oral presentation (invited, special)  

    Venue：Awaji Yumebutai International Conference Center, Awaji Island, Japan  

  • Synthesis and Properties of Trioxytriphenylamine Monoimino-Analogues Domestic conference

    Naoki　Yokoyama, Keiji　Okada, Masatoshi　Kozaki

    The 99th Annual Meeting 2019 of CSJ   2019.03  The Chemical Society of Japan

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    Presentation type：Oral presentation (general)  

    Venue：Okamoto Campus, Konan University, Kobe, Japan  

  • Synthesis and properties of isoquinacridone derivatives with pyridine rings Domestic conference

    Chihiro Hori, Masatoshi Kozaki, Yoshimitsu Tachi

    日本化学会第99春季年会  2019.03  日本化学会

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    Presentation type：Poster presentation  

    Venue：甲南大学　岡本キャンパス  

  • Synthesis and Properties of Dinuclear Copper Complex with Unsymmetric Coordination Environment Domestic conference

    Yasunari Kamada, Masatoshi Kozaki, Yoshimitsu Tachi

    日本化学会第99春季年会  2019.03  日本化学会

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    Presentation type：Poster presentation  

    Venue：甲南大学　岡本キャンパス  

  • Synthesis and Properties of Unsymmetrical Dinuclear Copper Complex International conference

    Yasunari Kamada, Masatoshi Kozaki, and Yoshimitsu Tachi

    The 10th OCARINA International Meeting  2019.03 

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    Presentation type：Poster presentation  

    Venue：大阪市立大学  

  • Synthesis and Properties of Ortho-bridged Triphenylamines by Two Oxygens and Sulfur or Nitrogen Atoms International conference

    Naoki Yokoyama, Nobuaki Tanaka, Masatoshi Kozaki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, and Keiji Okada

    The 10th OCARINA International Meeting  2019.03 

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    Presentation type：Poster presentation  

    Venue：大阪市立大学  

  • Synthesis and Properties of Condensed Phenoxazine Dimer International conference

    Takayuki Miyamae, Makoto Haraguchi, Yoshimitsu Tachi, Masatoshi Kozaki, and Keiji Okada

    The 10th OCARINA International Meeting  2019.03 

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    Presentation type：Poster presentation  

    Venue：大阪市立大学  

  • Regulation of catalytic activity of N-methylpyrrolidine by the stimulus-responsive zinc porphyrin receptor International conference

    Tomoaki Nishimura, Yoshito Sasaki, Yoshimitsu Tachi, Keiji Okada, and Masatoshi Kozaki

    The 10th OCARINA International Meeting  2019.03 

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    Presentation type：Poster presentation  

    Venue：大阪市立大学  

  • Regulation of catalytic activity of <i>N</i>-methylpyrrolidine by the stimulus-responsive zinc porphyrin receptor International conference

    Tomoaki Nishimura, Yoshito Sasaki, Yoshimitsu Tachi, Keiji Okada, Masatoshi Kozaki

    The 10th OCARINA International Meeting  2019.03 

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    Presentation type：Poster presentation  

    Venue：大阪市立大学  

  • デンドリマー多量体の合成、高次構造、性質 Invited Domestic conference

    小嵜　正敏、西岡　沙織、木村　僚、秋定　真弥、舘　祥光、鈴木　修一、岡田　惠次

    第12回有機π電子系シンポジウム  2018.11 

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    Presentation type：Oral presentation (invited, special)  

    Venue：アクティプラザ琵琶  

  • 三点連結型フェノキサジン二量体の合成と性質 Domestic conference

    宮前　嵩之，原口　誠，鈴木　修一，舘　祥光，岡田　惠次，小嵜　正敏

    第12回有機π電子系シンポジウム  2018.11 

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    Presentation type：Oral presentation (general)  

    Venue：アクティプラザ琵琶  

  • 分子刺激応答性亜鉛ポルフィリンレセプターの機能制御 Domestic conference

    西村　知晃，佐々木　義人，舘　祥光，岡田　惠次，小嵜　正敏

    第12回有機π電子系シンポジウム  2018.11  有機π電子学会

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    Presentation type：Oral presentation (general)  

    Venue：アクティプラザ琵琶  

  • 含窒素ピレン類の短段階合成と物性 Domestic conference

    大村　祐太，舘　祥光，岡田　惠次，小嵜　正敏

    第12回有機π電子系シンポジウム  2018.11  有機π電子学会

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    Presentation type：Oral presentation (general)  

    Venue：アクティプラザ琵琶  

  • 非対称型活性酸素種を活用した触媒開発を目的とする二核銅錯体の合成 Domestic conference

    鎌田　泰成，小嵜　正敏，舘　祥光

    第8回CSJ化学フェスタ2018  2018.10  日本化学会

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    Venue：タワーホール船堀  

  • Synthesis and Properties of Nitrogen-Containing Pyrenes Domestic conference

    Yuta Omura, Yoshimitsu Tachi, Keiji Okada, and Masatoshi Kozaki

    29th Symposium on Physical Organic Chemistry  2018.09  The Society of Physical Organic Chemistry, Japan

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    Presentation type：Oral presentation (general)  

    Venue：Tokyo Institute of Technology, Ookayama Campus  

  • Synthesis and Properties of 1,1',9,9',10,10'-biphenoxazine Domestic conference

    Takayuki Miyamae, Makoto Haraguchi, Shuichi Suzuki, Yoshimitsu Tachi, Masatoshi Kozaki, Keiji Okada

    日本化学会第98春季年会  2018.03 

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    Presentation type：Poster presentation  

  • 可溶性ビス(トリオキシトリフェニルアミン)誘導体の合成と性質 Domestic conference

    下出　健人，鈴木　修一，小嵜　正敏，岡田　惠次

    日本化学会第98春季年会  2018.03 

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    Presentation type：Oral presentation (general)  

  • Synthesis and Properties of Trioxytriphenylamine Monothio- and Monoimino- Analogues Domestic conference

    Naoki Yokoyama, Nobuaki Tanaka, Shuichi Suzuki, Masatoshi Kozaki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui Keiji Okada

    日本化学会第98春季年会  2018.03 

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    Presentation type：Poster presentation  

  • Sample Dependence of Thermoelectric Figure of Merit of Quasi-One-Dimensional Organic Conductor (TTT)3I3+δ (δ < 0.1) Domestic conference

    2018.03 

  • Synthesis, Properties, and Reactivities of (Nitronyl Nitroxide-2-ide)Copper Complex Bearing Phenanthroline ligand International conference

    Kiyomi Yamada, Shuichi Suzuki, Masatoshi Kozaki, and Keiji Okada

    The 9th OCARINA International Meeting, Joint mini-symposiums on Structural Biology and Catalysis  2018.03 

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    Presentation type：Poster presentation  

  • The Allosteric Receptor Containing a Zn-porphyrin and a Recognition Site for a Photo-responsive Stimulus Molecule International conference

    Chisato Okamoto, Yoshimitsu Tachi, Shuichi Suzuki, Keiji Okada, and Masatoshi Kozaki

    The 9th OCARINA International Meeting, Joint mini-symposiums on Structural Biology and Catalysis  2018.03 

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    Presentation type：Poster presentation  

  • Allosteric effect of a zinc porphyrin receptor with sterically bulky shielding unit International conference

    Tomoaki Nishimura, Yoshito Sasaki, Yoshimitsu Tachi, Keiji Okada, and Masatoshi Kozaki

    The 9th OCARINA International Meeting, Joint mini-symposiums on Structural Biology and Catalysis  2018.03 

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    Presentation type：Poster presentation  

  • The Short Step Synthesis and Properties of Triazapyrene Derivatives International conference

    Yuta Omura, Yoshimitsu Tachi, Keiji Okada, and Masatoshi Kozaki

    The 9th OCARINA International Meeting, Joint mini-symposiums on Structural Biology and Catalysis  2018.03 

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    Presentation type：Poster presentation  

  • Synthesis of Soluble Bis(trioxytriphenylamine) Derivatives International conference

    Kento Shimode, Shuichi Suzuki, Masatoshi Kozaki, and Keiji Okada

    The 9th OCARINA International Meeting, Joint mini-symposiums on Structural Biology and Catalysis  2018.03 

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    Presentation type：Poster presentation  

  • Structure and Magnetic Properties of Triangular Iminonitroxide-gold(I) Complex International conference

    Kohei Yoshida, Tomoyuki Wada, Shuichi Suzuki, Masatoshi Kozaki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Yota Miyake, Yuko Hosokoshi, Keiji Okada

    The 11th Japanese-Russian International Workshop on Open Shell Compounds and Molecular Spin Devices  2017.11 

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    Presentation type：Poster presentation  

  • Polynuclear [(Nitronyl nitroxide)-2-ide](arylphosphine)gold(I) Complexes Invited International conference

    Keiji Okada, Sayaka Kira, Shuichi Suzaki, Kazunobu Sato, Takeji Takui, Masatoshi Kozaki

    The 11th Japanese-Russian International Workshop on Open Shell Compounds and Molecular Spin Devices  2017.11 

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    Presentation type：Oral presentation (invited, special)  

  • 共役鎖内包型デンドリマー三量体の高次構造変化 Domestic conference

    小嵜　正敏，木村　僚，秋定　真弥，鈴木　修一，岡田　惠次

    第27回基礎有機化学討論会  2017.09 

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    Presentation type：Oral presentation (general)  

  • トリアザピレン誘導体の合成と性質 Domestic conference

    大村　祐太，舘　祥光，岡田　惠次，小嵜　正敏

    第27回基礎有機化学討論会  2017.09  基礎有機化学会

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    Presentation type：Poster presentation  

    Venue：九州大学　伊都キャンパス  

  • かさ高い遮蔽部を持つ亜鉛ポルフィリンレセプターの分子刺激応答性 Domestic conference

    西村　知晃，佐々木　義人，舘　祥光，岡田　惠次，小嵜　正敏

    第27回基礎有機化学討論会  2017.09 

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    Presentation type：Poster presentation  

  • 非極性溶媒中におけるジフェニレンエチニレンベンゼン架橋D-A 二元系の電荷分離状態の短寿命化メカニズム Domestic conference

    木本　健嗣，堀越　敬史，鈴木　修一，小嵜　正敏，岡田　惠次，岩村　宗高，野崎　浩一

    2017年光化学討論会  2017.09 

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    Presentation type：Oral presentation (general)  

  • ポルフィリン－軸配位子結合のアロステリック制御 Invited Domestic conference

    小嵜　正敏

    錯体化学若手の会 第56回近畿支部勉強会  2017.06 

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    Presentation type：Oral presentation (invited, special)  

  • Stable Polycyclic Systems Containing an Quinodimethane skeleton Invited International conference

    Chihiro Sato, Masatoshi Kozaki*, Shuichi Suzuki, and Keiji Okada

    The 20th Osaka City University (OCU) International Conference on Molecular Spins and Quantum Technology  2016.08 

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    Presentation type：Oral presentation (invited, special)  

    Venue：大阪市立大学  

  • Construction and Functionalization of Novel π-Conjugated Materials Invited International conference

    Masatoshi Kozaki, Shuichi Suzuki, and Keiji Okada

    The 2015 OCARINA Annual International Meeting  2016.03 

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    Presentation type：Oral presentation (invited, special)  

    Venue：Osaka City University  

  • 2,11-Dibromo-13,14-dimesityl- 5,8-dioxapenthaphene: Stable and Twisting Polycyclic System Containing an o-Quinodimethane Skeleton Invited International conference

    Chihiro Sato, Masatoshi Kozaki*, Shuichi Suzuki, and Keiji Okada

    The 9th Japanese-Russian Workshop on Open Shell Compounds and Molecular Spin Devices  2015.11 

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    Presentation type：Oral presentation (invited, special)  

    Venue：Awaji Yumebutai International Conference Center, Awaji Island, Japan  

  • Construction of Well-organized Assemblies of Dendrimers Invited International conference

    Masatoshi Kozaki*, Saori Nishioka, Shiro Morita, Shuichi Suzuki, and Keiji Okada

    The Collaborative Conference on 3D & Materials Research (CC3DMR) 2015  2015.06 

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    Presentation type：Oral presentation (invited, special)  

    Venue：Busan, South Korea  

  • Construction, Functionalization, and Organization of Dendrimer with Conjugated Backbones Invited International conference

    Masatoshi Kozaki, Shuichi Suzuki, Keiji Okada

    The 4th International Conference on Nanotek and Expo  2014.12 

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    Presentation type：Oral presentation (invited, special)  

    Venue：DoubleTree by Hilton Hotel San Francisco Airport, San Francisco, USA  

  • 共役鎖内包型デンドリマーの合成，集積，光機能探索 Invited Domestic conference

    小嵜正敏，鈴木修一，岡田惠次

    第16回機能性分子シンポジウム  2013.01 

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    Presentation type：Oral presentation (invited, special)  

    Venue：筑波大学  

  • 共役鎖内包型デンドリマーの合成，集積，機能探索 Invited Domestic conference

    小嵜正敏，鈴木修一，岡田惠次

    日本学術振興会142委員会ABC合同研究会  2012.11 

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    Presentation type：Oral presentation (invited, special)  

    Venue：東京理科大学  

  • Preparation and Application of Dendrimers with Conjugated Backbones Invited International conference

    Massatoshi Kozaki, Kogen Akita, Atsuhiro Uetomo, Shirou Morita, Shuichi Suzuki, Keiji Okada

    The 1st International Conference on Emerging Advanced Nanomaterials  2012.10 

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    Presentation type：Oral presentation (invited, special)  

    Venue：Brisbane, Australia  

  • 共役鎖内包型デンドリマーの合成と応用 Invited Domestic conference

    小嵜正敏

    構造有機化学若手の会  2009.08 

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    Presentation type：Oral presentation (invited, special)  

    Venue：加太，和歌山  

  • 共役鎖内包型デンドリマーの合成と応用 Invited Domestic conference

    小嵜正敏

    プラットホーム関西シンポジウム  2009.01 

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    Presentation type：Oral presentation (invited, special)  

    Venue：大阪府立大学  

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Industrial Property Rights

  • 銅錯体化合物、銅錯体化合物の製造方法、医療診断用蛍光色素、太陽電池、並びに、発光素子

    岡田惠次、小嵜正敏、鈴木修一、神原隆介、植野光代、石山 泰

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    property_type：Patent 

    Application no：特願2013-110756 

    Announcement no：特開2014-227408 

    Publication no：特開2014-227408 

  • 銅錯体化合物、銅錯体化合物の製造方法、医療診断用蛍光色素、太陽電池、並びに、発光素子

    岡田惠次, 小嵜正敏, 鈴木修一, 神原隆介, 植野光代, 石山 泰

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    property_type：Patent 

    Application no：特願2013-110756 

    Announcement no：特開2014-227408 

    Publication no：特開2014-227408 

  • ジヒドロフェナジン誘導体を陽極バッファー層に含有する有機電界発光素子

    藤下雄一、内田　学、菊川伸午、岡田惠次、小嵜正敏、岡本敏宏

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    property_type：Patent 

    Application no：特願2002-307189 

    Announcement no：特開2004-146110 

    Publication no：特開2004-146110 

  • 非対称ジヒドロフェナジン誘導体及びその製造方法

    岡本敏宏、小嵜正敏、岡田惠次

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    property_type：Patent 

    Application no：特願2002-262360 

    Announcement no：特開2004-99496 

    Publication no：特開2004-99496 

  • ジアザペンタセン誘導体を含有する電荷輸送材料、発光材料およびこれらを用いた有機電界発光素子

    内田 学、王　国防、中野隆治、古川顕治、岡田惠次、小嵜正敏

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    property_type：Patent 

    Application no：P2002-508872 

    Announcement no：WO02/005599 

    Publication no：WO02/005599 

  • Use of molecular electrostatic potential to process electronic signals

    TOUR JAMES M, SEMINARIO JORGE M, KOZAKI MASATOSHI

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    property_type：Patent 

    Application no：US19990360814 

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Collaborative research (seeds) keywords

  • 有機電子デバイス

    Category：Chemicals / Nano-technology / Materials 

Outline of collaborative research (seeds)

  • 有機電子デバイス

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    Request for collaborative research：Universities etc. Research institutes

    Type of research exchange：Joint research

    有機半導体特性をもつ縮合多環化合物の開発

  • 高機能性巨大分子の構築

    2003-

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    Request for collaborative research：The private sector, such as other institutions

    Type of research exchange：Joint research

    Application fields / methods etc：基板と分子を結合させることにより、従来よりもさらに小さなピコメータースケールの構造を基板上に作ることが可能となる。

    Core knowledge, technology, information etc：巨大分子システムの合成

    Expected ripple effect：単分子デバイス

    Detail description：現在の微細加工技術、無機半導体技術は、将来的に非常に多くの問題(環境、経済性、物理的限界など)を抱えている。この問題を解決する方法のひとつに単一分子を機能性材料として用いることが検討されている。しかし、現在研究対象とされている分子のサイズは非常に小さく基板との接続に関してはまだ多くの問題がある。本研究では、分子のサイズを大きくするボトムアップのアプローチによりこの問題を解決することを目標としている。そのために効率の高い巨大分子合成法の開発を行う。現在、一次元の単分子ワイヤーに関してはすでに長さがマイクロメーターのものまで作られている。しかし、3時限的な構造を持つ分子の構築にはより高度な合成技術が必要となってくる。微細加工技術の目標を機能性分子のサイズとすれば、分子のサイズを一桁大きくすることがこの目標をより近くすることになる。リソグラフィーによる加工限界を一桁小さくするためにかかるコストを考えると、これがいかに重要か理解できる。特に本研究ではカプセル型の分子を研究対象とし、このカプセルにより分子と基板上の微小金属端子をつなぐことを目指している。また、このカプセルは将来、不安定分子の貯蔵、運搬や分子素子などの高機能性分子を外部空間より隔離することに応用できる。

    有機合成はナノスケール構造体を作る優れた技術である。しかし、分子があまりにも小さいため、バルクな基板との接続が困難である。このサイズギャップの問題をボトムアップアプローチにより解決することを目指す。

Grant-in-Aid for Scientific Research

  • Construction of donor-acceptor type fused polycyclic compounds with multiple functions by incorporation of heteroatoms

    Grant-in-Aid for Scientific Research(C)  2026

  • Construction of donor-acceptor type fused polycyclic compounds with multiple functions by incorporation of heteroatoms

    Grant-in-Aid for Scientific Research(C)  2025

  • Construction of donor-acceptor type fused polycyclic compounds with multiple functions by incorporation of heteroatoms

    Grant-in-Aid for Scientific Research(C)  2024

  • Construction of donor-acceptor type fused polycyclic compounds with multiple functions by incorporation of heteroatoms

    Grant-in-Aid for Scientific Research(C)  2023.04

  • デンドリマー三量体のフォールディングによる精密ナノ構造の創出と機能発現

    Grant-in-Aid for Scientific Research(C)  2022.04

  • グラフェンフラグメントへの窒素原子ドーピングによる n 型有機半導体の開発

    Grant-in-Aid for Scientific Research(C)  2017.04

  • デンドリマー型元素ブロック高分子の構築と機能探索

    Grant-in-Aid for Scientific Research on Innovative Areas  2013.04

  • ポルフィリン精密集積による光合成モデル分子デバイスの開発

    Grant-in-Aid for Scientific Research(B)  2011.04

  • デンドリマー自己組織化による機能性人工膜の作製

    Grant-in-Aid for Challenging Research (Pioneering)/(Exploratory)  2007.04

  • デンドリマー集積による共役ネットワーク構築とその特性

    Grant-in-Aid for Scientific Research on Priority Areas  2006.04

  • 機能連動型デンドリマーに関する研究

    Grant-in-Aid for Scientific Research(C)  2005.04

  • 円錐型基板接続部を持つ単分子ワイヤーの開発

    Grant-in-Aid for Young Scientists(B)  2002.04

▼display all

Other subsidies, etc.

  • ヘテロ原子ドーピング法によるグラフェンフラグメントの電子状態チューニングと溶液プロセスでのデバイス作製

    大学  2017.04

Acceptance of Researcher

  • 2023  Number of researchers：1

  • 2022  Number of researchers：1

Outline of education staff

  • To acquire basic knowledge of organic chemistry

Charge of on-campus class subject

  • 化学実験1

    2024   Weekly class   Undergraduate

  • 有機化学1

    2024   Weekly class   Undergraduate

  • 化学特別研究1A

    2024   Intensive lecture   Graduate school

  • 研究企画ゼミナール

    2024   Intensive lecture   Graduate school

  • 化学特別演習2A

    2024   Intensive lecture   Graduate school

  • 化学特別演習1A

    2024   Intensive lecture   Graduate school

  • 化学特別研究2A

    2024   Intensive lecture   Graduate school

  • 化学特別演習4A

    2024   Intensive lecture   Graduate school

  • 化学特別演習3A

    2024   Intensive lecture   Graduate school

  • 化学特別研究5A

    2024   Intensive lecture   Graduate school

  • 化学特別研究4A

    2024   Intensive lecture   Graduate school

  • 化学特別研究3A

    2024   Intensive lecture   Graduate school

  • 化学特別演習5A

    2024   Intensive lecture   Graduate school

  • 化学実験Ⅱ

    2024   Weekly class   Undergraduate

  • 化学実験Ⅰ

    2024   Weekly class   Undergraduate

  • 海外特別研究2

    2023   Intensive lecture   Graduate school

  • 海外特別研究1

    2023   Intensive lecture   Graduate school

  • 化学特別演習2A

    2023   Intensive lecture   Graduate school

  • 化学特別演習1A

    2023   Intensive lecture   Graduate school

  • 化学特別研究2A

    2023   Intensive lecture   Graduate school

  • 化学特別研究1A

    2023   Intensive lecture   Graduate school

  • 研究企画ゼミナール

    2023   Intensive lecture   Graduate school

  • 有機化学1

    2023   Weekly class   Undergraduate

  • 海外特別研究4

    2023   Intensive lecture   Graduate school

  • 海外特別研究3

    2023   Intensive lecture   Graduate school

  • 化学特別演習4A

    2023   Intensive lecture   Graduate school

  • 化学特別演習3A

    2023   Intensive lecture   Graduate school

  • 化学特別研究4A

    2023   Intensive lecture   Graduate school

  • 化学特別研究3A

    2023   Intensive lecture   Graduate school

  • プロポーザルディフェンス

    2023   Intensive lecture   Graduate school

  • 前期海外特別研究１

    2023   Intensive lecture   Graduate school

  • 化学前期特別研究Ⅱ

    2023   Intensive lecture   Graduate school

  • 化学前期特別研究Ⅰ

    2023   Intensive lecture   Graduate school

  • 機能分子科学演習

    2023   Intensive lecture   Graduate school

  • 創成分子科学演習

    2023   Intensive lecture   Graduate school

  • 基幹有機化学

    2023   Intensive lecture   Graduate school

  • 後期海外特別研究２

    2023   Intensive lecture   Graduate school

  • 特別指導論

    2023   Intensive lecture   Graduate school

  • 機能分子科学ゼミナール

    2023   Intensive lecture   Graduate school

  • 創成分子科学ゼミナール

    2023   Intensive lecture   Graduate school

  • 海外特別研究

    2023   Intensive lecture   Undergraduate

  • 特別研究

    2023   Intensive lecture   Undergraduate

  • 機能分子化学特論B

    2023   Weekly class   Graduate school

  • 化学特別演習2B

    2023   Intensive lecture   Graduate school

  • 化学特別演習1B

    2023   Intensive lecture   Graduate school

  • 化学特別研究2B

    2023   Intensive lecture   Graduate school

  • 化学特別研究1B

    2023   Intensive lecture   Graduate school

  • 化学実験Ｓ

    2023   Intensive lecture   Undergraduate

  • 化学実験Ⅲ

    2023   Weekly class   Undergraduate

  • 化学特別演習4B

    2023   Intensive lecture   Graduate school

  • 化学特別演習3B

    2023   Intensive lecture   Graduate school

  • 化学特別研究4B

    2023   Intensive lecture   Graduate school

  • 化学特別研究3B

    2023   Intensive lecture   Graduate school

  • 化学特別研究3A

    2022   Intensive lecture   Graduate school

  • 化学特別演習3A

    2022   Intensive lecture   Graduate school

  • 化学特別研究1A

    2022   Intensive lecture   Graduate school

  • 研究企画ゼミナール

    2022   Intensive lecture   Graduate school

  • 基幹有機化学

    2022   Intensive lecture   Graduate school

  • 有機化学１

    2022   Weekly class   Undergraduate

  • 化学特別演習3B （杉本）

    2022   Intensive lecture   Graduate school

  • 化学特別研究3B （杉本）

    2022   Intensive lecture   Graduate school

  • 海外特別研究3 （杉本）

    2022   Intensive lecture   Graduate school

  • プロポーザルディフェンス （杉本）

    2022   Intensive lecture   Graduate school

  • 海外特別研究1 （杉本）

    2022   Intensive lecture   Graduate school

  • 機能分子化学特論B

    2022   Weekly class   Graduate school

  • 化学特別演習1B （杉本）

    2022   Intensive lecture   Graduate school

  • 化学特別研究1B （杉本）

    2022   Intensive lecture   Graduate school

  • 化学前期特別研究 II（M２）

    2022   Intensive lecture   Graduate school

  • 化学前期特別研究 I（M１）

    2022   Intensive lecture   Graduate school

  • 機能分子科学演習（M２）

    2022   Intensive lecture   Graduate school

  • 後期海外特別研究１（物質分子系）

    2022   Intensive lecture   Graduate school

  • 後期特別研究（Ｄ２物質分子系）

    2022   Intensive lecture   Graduate school

  • 特別指導論

    2022   Intensive lecture   Graduate school

  • 機能分子科学ゼミナール

    2022   Intensive lecture   Graduate school

  • 創成分子科学ゼミナール

    2022   Intensive lecture   Graduate school

  • 後期特別研究（Ｄ３物質分子系）

    2022   Intensive lecture   Graduate school

  • 海外特別研究（化学）

    2022   Intensive lecture   Undergraduate

  • 化学実験Ⅲ

    2022   Weekly class   Undergraduate

  • 特別研究（化学）

    2022   Intensive lecture   Undergraduate

  • 化学実験Ｓ

    2022   Intensive lecture   Undergraduate

  • 前期海外特別研究２（物質分子系）

    2022   Intensive lecture   Graduate school

  • 機能分子科学演習（M１）

    2022   Intensive lecture   Graduate school

  • 創成分子科学演習（M２）

    2022   Intensive lecture   Graduate school

  • 創成分子科学演習（M１）

    2022   Intensive lecture   Graduate school

  • Exercises in Functional Molecular Science

    2021     Graduate school

  • Seminar in Functional Molecular Science

    2021     Graduate school

  • Seminar in Creative Molecular Science

    2021     Graduate school

  • Exercises in Creative Molecular Science

    2021     Graduate school

  • Advanced Research Course for Master's Thesis of Science

    2021     Graduate school

  • Advanced Experiments in Chemistry, III

    2021     Undergraduate

  • Senior Thesis Project

    2021     Undergraduate

  • Advanced Research Course for Doctoral Thesis of Science

    2021     Graduate school

  • Core Organic Chemistry

    2021     Graduate school

  • Basic Experiments in Chemistry I

    2021     Undergraduate

  • Organic Chemistry 1

    2021     Undergraduate

  • General Experiments in Chemistry, S

    2021     Undergraduate

  • Organic Chemistry 1

    2020     Undergraduate

  • Basic Experiments in Chemistry I

    2020     Undergraduate

  • Core Organic Chemistry

    2020     Graduate school

  • Advanced Research Course for Doctoral Thesis of Science

    2020     Graduate school

  • Senior Thesis Project

    2020     Undergraduate

  • International Advanced Research Course

    2020     Graduate school

  • Seminar in Creative Molecular Science

    2020     Graduate school

  • Seminar in Functional Molecular Science

    2020     Graduate school

  • Advanced Research Course for Master's Thesis of Science

    2020     Graduate school

  • Exercises in Creative Molecular Science

    2020     Graduate school

  • Advanced Experiments in Chemistry, III

    2020     Undergraduate

  • General Experiments in Chemistry, S

    2020     Undergraduate

  • 後期特別研究

    2019     Graduate school

  • 特別指導論

    2019     Graduate school

  • 創成分子科学ゼミナール

    2019     Graduate school

  • 前期特別研究

    2019     Graduate school

  • 創成分子科学演習

    2019     Graduate school

  • 創成有機分子科学特論 Ⅰ

    2019     Graduate school

  • 特別研究（化学）

    2019     Undergraduate

  • 化学実験Ⅲ

    2019     Undergraduate

  • 有機化学４

    2019     Undergraduate

  • 有機化学２

    2019     Undergraduate

  • 基礎化学実験 I

    2019     Undergraduate

  • Organic Chemistry 2

    2018     Undergraduate

  • Organic Chemistry 4

    2018     Undergraduate

  • Basic Chemistry Experiments II

    2018     Undergraduate

  • Basci Chemistry Experiments I

    2018     Undergraduate

  • Advanced Experiments in Chemistry III

    2018     Undergraduate

  • Senior Thesis Project

    2018     Undergraduate

  • Leadership Training Program

    2018     Graduate school

  • Advanced Research Course for Master's Thesis of Science

    2018     Graduate school

  • Exercises in Creativre Molecular Science

    2018     Graduate school

  • Advanced Experiments in Chemistry III

    2017     Undergraduate

  • 構造有機化学

    2017     Undergraduate

  • Senior Thesis Project

    2017     Undergraduate

  • World of Modern Chemistry

    2017     Undergraduate

  • Basic Chemistry Experiments I

    2017     Undergraduate

  • Advanced Experiments in Chemistry III

    2016     Undergraduate

  • 基礎化学実験Ⅰ

    2016     Undergraduate

  • 基礎化学実験Ⅰ

    2015     Undergraduate

  • 基礎化学実験Ⅰ

    2014     Undergraduate

  • 基礎有機化学Ⅱ

    1900     Undergraduate

  • 構造有機化学

    1900     Undergraduate

▼display all

Charge of off-campus class subject

  • 構造有機化学

    Institution：Osaka City University

  • 有機化学

    Institution：Osaka City University

  • 基礎有機化学

    Institution：Osaka City University

  • 基礎化学実験

    Institution：Osaka City University

  • 化学実験（有機実験）

    Institution：Osaka City University

  • 化学の世界

    Institution：Osaka City University

▼display all

Faculty development activities

  • FD活動への貢献  2017

    　More details

    ＦＤ研究会（11月2日）、第19回教育支援のためのFDワークショップ（12月19日)参加

Number of papers published by graduate students

  • 2024

    Number of graduate students presentations：1

  • 2023

    Number of graduate students presentations：1

  • 2022

    Number of undergraduate student / college student presentations：1  Number of graduate students presentations：4

Number of instructed thesis, researches

  • 2023

    Number of instructed the graduation thesis：2  Number of graduation thesis reviews：2

    [Number of instructed the Master's Program] (previous term)：0  [Number of instructed the Master's Program] (letter term)：0

    [Number of master's thesis reviews] (chief)：0  [Number of master's thesis reviews] (vice-chief)：3

    [Number of doctoral thesis reviews] (chief)：0  [Number of doctoral thesis reviews] (vice-chief)：0

  • 2022

    Number of instructed the graduation thesis：2  Number of graduation thesis reviews：2

    [Number of instructed the Master's Program] (previous term)：3  [Number of instructed the Master's Program] (letter term)：1

    [Number of master's thesis reviews] (chief)：3  [Number of master's thesis reviews] (vice-chief)：3

    [Number of doctoral thesis reviews] (chief)：1  [Number of doctoral thesis reviews] (vice-chief)：1

Original item・Special report (Education Activity)

  • 2023

    　 More details

    Original item：化学科四年生のクラス担任として学習相談、学習指導を実施した。

  • 2022

    　 More details

    Original item：特定のオフィスアワーは設けていないが常に質問を受け付けている。

  • 2022

    　 More details

    Original item：化学科三年生のクラス担任として学習相談、学習指導を実施した。

  • 2021

    　 More details

    Original item：特定のオフィスアワーは設けていないが常に質問を受け付けている。

  • 2021

    　 More details

    Original item：科学技術振興機構さくらサイエンスプランオンラインプログラムを独自財源で実施した。

  • 2021

    　 More details

    Original item：化学科二年生のクラス担任として学習相談、学習指導を実施した。

  • 2020

    　 More details

    Original item：化学科一年生のクラス担任および化学科主任として学習相談、学習指導を実施した。

  • 2020

    　 More details

    Original item：特定のオフィスアワーは設けていないが常に質問を受け付けている。

  • 2020

    　 More details

    Original item：科学技術振興機構さくらサイエンスプランを申請し採択された。

  • 2019

    　 More details

    Original item：科学技術振興機構さくらサイエンスプランの支援を受けて「地球・生活を救う環境科学人材を育む研究教育の体験と交流」を実施主担当者 として実施した。

  • 2019

    　 More details

    Original item：大阪市立大学の特色となる教育体制への支援事業の支援を受けて「研究科横断型での国際化教育推進による科学技術人材育成」を代表者として実施した。

  • 2019

    　 More details

    Original item：特定のオフィスアワーは設けていないが常に質問を受け付けている。

  • 2018

    　 More details

    Original item：理学研究科英語修了コース設置準備に将来計画委員として貢献した。

  • 2018

    　 More details

    Original item：特定のオフィスアワーは設けていないが常に質問を受け付けている。

  • 2018

    　 More details

    Original item：大阪市立大学　化学セミナー　講師、一時間

  • 2017

    　 More details

    Original item：理学研究科英語修了コース設置準備に将来計画委員として貢献した。

  • 2017

    　 More details

    Original item：特定のオフィスアワーは設けていないが常に質問を受け付けている。

  • 2017

    　 More details

    Original item：日本化学工業協会「化学人材育成プログラム」の実施に貢献した。

▼display all

Social Activities　⇒ Link to the list of Social Activities

  • Laboratory visits (lab tours, lectures)

    Role(s)： Lecturer

    Ritsumeikan High School  2024.12

    　More details

    SDGs：

    Number of participants：17（人）

  • Laboratory visits (lab tours, lectures)

    Role(s)： Lecturer

    Ritsumeikan High School  2023.12

    　More details

    SDGs：

    Number of participants：14（人）

  • 海外サイエンスフェアへの高校生派遣

    Role(s)： Planner,　Logistic support

    Type： University open house,　Cooperation business with The administrative, educational institutions, etc.

    高校化学グランドコンテスト総括事業委員会  2022.10 - 2023.02

    　More details

    SDGs：

    Number of participants：9（人）

  • 海外サイエンスフェアへの高校生派遣

    Role(s)： Planner,　Logistic support

    高校化学グランドコンテスト総括事業委員会  2022.10 - 2023.02

  • 高校化学グランドコンテスト事業総括

    Role(s)： Logistic support

    高校化学グランドコンテスト総括事業委員会  2022.05 - Now

    　More details

    SDGs：

  • 高校化学グランドコンテスト事業総括

    Role(s)： Logistic support

    高校化学グランドコンテスト総括事業委員会  2022.05 - Now

  • 第17回高校化学グランドコンテスト

    Role(s)： Media coverage,　Planner,　Logistic support,　Report author

    Type： Seminar, workshop

    大阪市立大学，横浜市立大学，読売新聞社  大阪市立大学  2021.10

    　More details

    Audience： High school students,　Teachers,　Parents/Guardians,　General public,　Company,　Media

    Number of participants：400（人）

  • 第17回高校化学グランドコンテスト

    Role(s)： Media coverage,　Planner,　Logistic support,　Report author

    Type： Seminar, workshop

    大阪市立大学，横浜市立大学，読売新聞社  大阪市立大学  2021.10

    　More details

    Audience： High school students,　Teachers,　Parents/Guardians,　General public,　Company,　Media

  • 海外国際サイエンスフェアー参加高校生選抜・参加支援

    Role(s)： Consultant,　Official expert,　Logistic support

    Type： University open house,　Cooperation business with The administrative, educational institutions, etc.

    シンガポール・ホァーチョンインスティチューション、国立台湾科学教育センター  2020.10 - 2021.03

    　More details

    Audience： High school students,　Teachers

    Number of participants：12（人）

    シンガポールのホァーチョンインスティチューション主催 International Science Youth Forum, Digital @ Singapore 2021（一校、教員1名、生徒2名参加），国立台湾科学教育センター主催 Taiwan International Science Fair 2021 (TISF2021)（二校、教員3名、高校生6名）に参加する高校生を選抜し参加支援を実施した．TISF2021では福島成蹊高等学校がEnvironmental Engineering部門3等賞，宮城県仙台第三高等学校がChemistry部門3等賞を受賞した．

  • 海外国際サイエンスフェアー参加高校生選抜・参加支援

    Role(s)： Consultant,　Official expert,　Logistic support

    シンガポール・ホァーチョンインスティチューション、国立台湾科学教育センター  2020.10 - 2021.03

    　More details

    Audience： High school students,　Teachers

    シンガポールのホァーチョンインスティチューション主催 International Science Youth Forum, Digital @ Singapore 2021（一校、教員1名、生徒2名参加），国立台湾科学教育センター主催 Taiwan International Science Fair 2021 (TISF2021)（二校、教員3名、高校生6名）に参加する高校生を選抜し参加支援を実施した．TISF2021では福島成蹊高等学校がEnvironmental Engineering部門3等賞，宮城県仙台第三高等学校がChemistry部門3等賞を受賞した．

  • 高校化学グランドコンテストオンライン配信活動

    Role(s)： Lecturer,　Planner,　Logistic support

    Type： Internet

    大阪市立大学  2020.04 - 2021.03

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    Audience： High school students,　Teachers,　Parents/Guardians,　General public

  • 高校化学グランドコンテストオンライン配信活動

    Role(s)： Lecturer,　Planner,　Logistic support

    Type： Internet

    大阪市立大学  2020.04 - 2021.03

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    Audience： High school students,　Teachers,　Parents/Guardians,　General public

  • 第16回高校化学グランドコンテスト

    Role(s)： Media coverage,　Planner,　Logistic support,　Report author

    Type： Seminar, workshop

    大阪市立大学，名古屋市立大学，横浜市立大学，読売新聞社  大阪市立大学  2019.10

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    Audience： High school students,　Teachers,　Parents/Guardians,　General public,　Company,　Media

    Number of participants：400（人）

  • 第16回高校化学グランドコンテスト

    Role(s)： Media coverage,　Planner,　Logistic support,　Report author

    Type： Seminar, workshop

    大阪市立大学，名古屋市立大学，横浜市立大学，読売新聞社  大阪市立大学  2019.10

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    Audience： High school students,　Teachers,　Parents/Guardians,　General public,　Company,　Media

  • 模擬講義（熊本北高等学校）講師

    Role(s)： Lecturer

    Type： Seminar, workshop

    大阪市立大学  大阪市立大学　理学研究科  2018.09

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    Audience： High school students

    Number of participants：50（人）

    模擬講義（熊本北高等学校）講師

  • 模擬講義（熊本北高等学校）講師

    Role(s)： Lecturer

    Type： Seminar, workshop

    大阪市立大学  大阪市立大学 理学研究科  2018.09

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    Audience： High school students

    模擬講義（熊本北高等学校）講師

  • The 15th Grand Constest on Chemistry for High School Students

    Role(s)： Planner,　Logistic support

    Type： Science festival

    The 15th Grand Constest on Chemistry for High School Students  Nagoya City University  2018.04 - 2018.10

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    Audience： High school students,　Teachers,　Parents/Guardians,　General public

    Number of participants：600（人）

  • 第14回高校化学グランドコンテスト

    Role(s)： Planner,　Logistic support

    Type： Science festival

    大阪市立大学、名古屋市立大学、横浜市立大学、読売新聞社  第15回高校化学グランドコンテスト  2017.04 - 2017.10

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    Audience： High school students,　Teachers,　Parents/Guardians,　General public

    Number of participants：600（人）

    第14回高校化学グランドコンテスト実行委員、一次審査委員、ポスター審査員、研究サポート（清水東高等学校、豊橋東高等学校、飯山高等学校）

  • 第13回高校化学グランドコンテスト

    Role(s)： Logistic support

    Type： Science festival

    大阪市立大学、名古屋市立大学、横浜市立大学、読売新聞社  2016

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Visiting Lectures　⇒ Link to the list of Visiting Lectures

  • 身の回りで活躍する最先端機能性有機分子

    Category：Modern system science (knowledge information system, environmental system, educational welfare, psychology),　Commerce (management, public management),　Economics,　Law (law, politics, administration),　Literature (literature, philosophy, history, art, human behavior, language, culture, society / gender),　Science (mathematics, physics, chemistry, biology, geology, biochemistry),　Engineering (machinery, electronics / physics, electrical / electronics, electrical information, chemical biotechnology, architecture, cities (civil engineering / environment), material chemistry, aerospace, marine systems, applied chemistry, chemistry, materials),　Life sciences (food, nutrition science, living environment, human welfare),　Agricultural science (applied biology, biofunctional chemistry, green space environmental science),　Medicine (medical care, rehabilitation, health exercise science, physical fitness / training, sports practice science),　Nursing (nursing, sex education),　Veterinary

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    Audience：High school students,　College students

    有機分子は最先端の電子材料として注目されています。高校化学からすこし背伸びをすることで、最先端機能性有機分子が働く仕組みを理解することができます。有機発光性素子、有機半導体、有機太陽電池の仕組みを簡単に解説します。

  • 香りを感じて生き物たちの世界を化学の目で見つめよう！

    Category：Modern system science (knowledge information system, environmental system, educational welfare, psychology),　Commerce (management, public management),　Economics,　Law (law, politics, administration),　Literature (literature, philosophy, history, art, human behavior, language, culture, society / gender),　Science (mathematics, physics, chemistry, biology, geology, biochemistry),　Engineering (machinery, electronics / physics, electrical / electronics, electrical information, chemical biotechnology, architecture, cities (civil engineering / environment), material chemistry, aerospace, marine systems, applied chemistry, chemistry, materials),　Life sciences (food, nutrition science, living environment, human welfare),　Agricultural science (applied biology, biofunctional chemistry, green space environmental science),　Medicine (medical care, rehabilitation, health exercise science, physical fitness / training, sports practice science),　Nursing (nursing, sex education),　Veterinary

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    Audience：High school students

    私たちの周りにはさまざまな香りがあります。香りの分子に注目することで、自然の中の隠された神秘をのぞき見ることができます。自然の中では生き物たちが、化学物質の特性をいかして巧みに利用しています。香りの分子を用いて昆虫や植物と会話することができます。また、私たちを含めて生物の体の中でも、分子を使用した情報交換が行われています。化学を学び、化学物質を知ることで、いまだに明らかにされていない自然の神秘を解明できます。

Academic Activities

  • Paper Peer Review

    Role(s)： Peer review

    Wiley-VCH GmbH  2023.12 - 2024.02

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    Type：Peer review 

  • 論文査読

    Role(s)： Peer review

    2022.12

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    Type：Peer review 

Foreigner acceptance

  • 2024

    International Students :2

  • 2023

    International Students :2

International exchange activities

  • 「JSTサクラサイエンスプラン」の支援を受けて台湾、シンガポールから高校生及び高校教員を本学に招へいした。

    Field category :Social contributions

    Country name :Taiwan, Singapore   2019.10

Job title

  • Job title within the department

    Graduate School of Science 

    副研究院長  2022.04

  • Job title within the department

    School of Science 

    副学部長  2022.04

  • Job title within the department

    Graduate School of Science 

    副研究科長  2022.04

Other

  • Job Career

    2015.04

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    Osaka City University

  • Job Career

    2007

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    Osaka City University

  • Job Career

    2006

    　 More details

    Osaka City University

  • Job Career

    1999

    　 More details

    Osaka City University

  • Job Career

    1997 - 1999

    　 More details

    Osaka City University