Updated on 2024/03/26

写真a

 
Takemoto Shin
 
Organization
Graduate School of Science Department of Chemistry Associate Professor
School of Science Department of Chemistry
Title
Associate Professor
Affiliation
Institute of Science
Contact information
メールアドレス
Affiliation campus
Sugimoto Campus

Position

  • Graduate School of Science Department of Chemistry 

    Associate Professor  2022.04 - Now

  • School of Science Department of Chemistry 

    Associate Professor  2022.04 - Now

Degree

  • 博士(工学) ( Others )

Research Areas

  • Nanotechnology/Materials / Inorganic/coordination chemistry  / Inorganic Chemistry

Research subject summary

  • 遷移金属カーバイド錯体の合成と性質

  • 機能性配位子の創出と触媒化学への応用

Research Career

  • 新しい分子構造をもつ金属錯体の合成、構造、触媒作用に関する研究

    1996 - Now 

Professional Memberships

  • 電気化学会

    2021.08 - Now   Domestic

  • 触媒学会

    2016.05 - Now   Domestic

  • American Chemical Society

    2002.09 - Now   Overseas

  • Kinki Chemical Society Japan

    2002.09 - Now   Domestic

  • Japan Society of Coordination Chemistry

    2002.04 - Now   Domestic

  • Chemical Society of Japan

    1996.12 - Now   Domestic

▼display all

Papers

  • Linear Hydrocarbon Chain Growth from a Molecular Diruthenium Carbide Platform Reviewed

    Ohata, J.; Teramoto, A.; Fujita, H.; Takemoto, S.; Matsuzaka, H.

    Journal of the American Chemical Society 雑誌   143 ( 39 )   2021.10

     More details

    Kind of work:Joint Work  

  • Tin-Ruthenium Cooperative Catalyst for Disproportionation of Formic Acid to Methanol Reviewed

    Fujita, H.; Takemoto, S.; Matsuzaka, H.

    ACS Catalysis 雑誌   11 ( 12 )   2021.06

     More details

    Kind of work:Joint Work  

  • Metal–metal multiple bond formation induced by σ-acceptor Lewis acid ligands Reviewed

    Shin Takemoto, Kaname Yoshii, Takahiro Yamano, Akihiro Tsurusaki, Hiroyuki Matsuzaka

    Chemical Communications   2021

     More details

    Authorship:Corresponding author   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D0CC07278H

  • Metal-metal multiple bond formation induced by σ-acceptor Lewis acid ligands Reviewed

    Takemoto, S.; Yoshii, K.; Yamano, T.; Tsurusaki, A.; Matsuzaka, H.

    Chemical Communications 雑誌   57   2020.12

     More details

    Kind of work:Joint Work  

  • Parent Cyclopentadienyl Ruthenium (II) Chloride Synthon: Derivatization to CpRu Amido, Imido, and Oxo Complexes Reviewed

    Takemoto, S.; Ishii, H.; Yamaguchi, M.; Teramoto, A.; Tsujita, M.; Ozeki, D.; Matsuzaka, H.

    Organometallics   38   2019.10

     More details

    Kind of work:Joint Work  

  • Bis(bipyridine) ruthenium(II) bis(phosphido) metalloligand: synthesis of heterometallic complexes and application to catalytic (E)-selective alkyne semi-hydrogenation Reviewed

    Takemoto, S.; Kitamura, M.; Saruwatari, S.; Isono, A.; Takada, Y.; Nishimori, R.; Tsujiwaki, M.; Sakaue, N.; Matsuzaka, H.

    Dalton Transactions 雑誌   48   2019.01

     More details

    Kind of work:Joint Work  

  • Anionic Trinuclear Iridium(I) Oxo Complex: Synthesis and Reactivity as a Metal-Centered σ-Donor Ligand to Gold(I) and Silver(I) Reviewed

    Takemoto, S; Tsujimoto, T.; Matsuzaka, H.

    Organometallics 雑誌   37   2018.05

     More details

    Kind of work:Joint Work  

  • Recent topics on catalytic transformations of aromatic molecules via η6-arene transition metal complexes Reviewed

    Takemoto, S; Matsuzaka, H.

    Tetrahedron Letters 雑誌   59   2018.02

     More details

    Kind of work:Joint Work  

  • Diruthenium Carbido Complexes as N-Heterocyclic Carbene-Like C-donor Ligands to Group 11 Metals Reviewed

    Takemoto, S; Tsujita, M.; Matsuzaka, H.

    Organometallics 雑誌   36   2017.07

     More details

    Kind of work:Joint Work  

  • Ruthenium-Sulfonamide-Catalyzed Direct Dehydrative Condensation of Benzylic C-H Bonds with Aromatic Aldehydes Reviewed

    Takemoto, S; Shibata, E.; Nakajima, M.; Yumoto, Y.; Shimamoto, M.; Matsuzaka, H.

    J. Am. Chem. Soc. 雑誌   138   2016.11

     More details

    Kind of work:Joint Work  

  • Aminolysis of [Cp*Ru(μ-OEt)]2 (Cp* = η5-C5Me5) with sulfonamides: Synthesis of neutral, zwitterionic, and anionic Cp*Ru terminal sulfonamido complexes Reviewed

    Takemoto, S; Yumoto, Y.; Matsuzaka, H.

    J. Organomet. Chem. 雑誌   808   2016.02

     More details

    Kind of work:Joint Work  

  • Experimental and Theoretical Study of Si-Cl and Ge-Cl s-Bond Activation Reactions by Iridium Hydride Reviewed

    Kameo, I.; Ikeda, K.; Sakaki, S.; Takemoto, S.; Nakazawa, H.; Matsuzaka, H.

    Dalton Trans. 雑誌   45   2016.02

     More details

    Kind of work:Joint Work  

  • Transition Metal-Mediated Ge-F Activation: Inverse Electron Flow in s-Bond Metathesis Reviewed

    Kameo, H.; Ikeda, K.; Bourissou, D.; Sakaki, S.; Takemoto, S.; Nakazawa, H.; Matsuzaka, H.

    Organometallics 雑誌   35   2016.02

     More details

    Kind of work:Joint Work  

  • Metal-ligand cooperative activation of element-hydrogen bonds (element = C, N, O, Cl, B) on a dinuclear ruthenium bridging imido complex Reviewed

    Takemoto, S; Ito, T.; Yamazaki, Y.; Tsujita, M.; Matsuzaka, H.

    J. Organomet. Chem. 雑誌   812   158 - 166   2015.10

     More details

    Kind of work:Joint Work  

  • Synthesis and reactivity of dinuclear Cp*Ru tert-butylamido and cyclometallated Bis(trimethylsilyl)amido complexes Reviewed

    Shin Takemoto, Masaki Oshimo, Hiroyuki Matsuzaka

    Journal of Organometallic Chemistry 雑誌   797   2015.08

     More details

    Kind of work:Joint Work  

  • A Diruthenium μ-Carbido Complex That Shows Singlet-Carbene-like Reactivity

    S. Takemoto, J. Ohata, K. Umetani, M. Yamaguchi

    Journal of the American Chemical Society   136   15889 - 15892   2014.11

  • Nucleophile-Catalyzed, Facile, and Highly Selective C-H Activation of Fluoroform with Pd(II)

    S. Takemoto, V. V. Grushin

    Journal of the American Chemical Society   135   16837 - 16840   2013.10

  • Synthesis and N-H Reductive Elimination Study of Dinuclear Ruthenium Imido Dihydride Complexes

    S. Takemoto, Y. Yamazaki, T. Yamano, H. Matsuzaka

    Journal of the American Chemical Society   134   17027 - 17035   2012.09

  • Recent advances in the chemistry of ruthenium carbido complexes Reviewed

    S. Takemoto, H. Matsuzaka

    Coordination Chemistry Reviews 雑誌 Elsevier   256   574 - 588   2011.10

  • Dinuclear Cp*Co Amido and Alkoxo Complexes: Synthesis, Structures, and Reactivity Reviewed

    Takemoto, S.; Honma, T.; Matsuzaka, H.

    Organmetallics 雑誌 アメリカ化学会   30   1013 - 1020   2011.02

     More details

    Kind of work:Single Work  

  • Synthesis and Reactivity of Coordinatively Unsaturated Dinuclear Ruthenium Bridging Imido Complexes Reviewed

    Takemoto, S.; Kobayashi, T.; Ito, T.; Inui, A.; Karitani, K.; Katagiri, S.; Masuhara, Y.; Matsuzaka, H.

    Organmetallics 雑誌 アメリカ化学会   30   2160 - 2172   2011.01

     More details

    Kind of work:Single Work  

  • Development of photofunctional materials using TTF derivatives containing a 1,3-benzothiazole ring Reviewed

    Fujiwara, H.; Yokota, S.; Hayashi, S.; Takemoto, S.; Matsuzaka, H.

    PHYSICA B-CONDENSED MATTER 雑誌 Elsevier   405   S15 - S18   2010.06

     More details

    Kind of work:Single Work  

  • New fluorene-substituted TTF derivatives as photofunctional materials Reviewed

    Fujiwara, H.; Tsujimoto, K.; Sugishima, Y.; Takemoto, S.; Matsuzaka, H.

    PHYSICA B-CONDENSED MATTER 雑誌 Elsevier   405   S12 - S14   2010.06

     More details

    Kind of work:Single Work  

  • Transition metal carbide complex. Organometallic model of Fischer-Tropsch reaction Reviewed

    Takemoto, Shin

    Kagaku to Kogyo 雑誌   63   2010.03

     More details

    Kind of work:Single Work  

  • A Bimetallic Ru2Pt Complex Containing a Trigonal-Planar μ3-Carbido Ligand: Formation, Structure, and Reactivity Relevant to the Fischer-Tropsch Process Reviewed

    Takemoto, S.; Morita, H.; Karitani, K.; Fujiwara, H.; Matsuzaka, H.

    Journal of the American Chemical Society 雑誌 American Chemical Society   131   18026 - 18027   2009.12

     More details

    Kind of work:Joint Work  

  • Syntheses of organocatalysts with one-handed helix and their application to the kinetic resolution of second alcohol Reviewed

    Kamikawa, Ken; Shiromoto, Takayuki; Yamaguchi, Jun; Takemoto, Shin; Matsuzaka, Hiroyuki

    Research on Chemical Intermediates 雑誌   35   2009.02

     More details

    Kind of work:Joint Work  

  • Induction of one-handed helical oligo(p-benzammide)s by domino effect based on planar-axial-helical chirality relay Reviewed

    Kamikawa, K.; Fukumoto, K.; Yoshihara, K.; Furusho, M.; Uemura, M.; Takemoto, S.; Matsuzaka, H.

    Chemical Communication 雑誌   1201 - 1203   2009.01

     More details

    Kind of work:Joint Work  

  • Divalent Dirhodium Imido Complexes: Formation, Structure, and Alkyne Cycloaddition Reactivity Reviewed

    Takemoto, S.; Otsuki, S.; Kamikawa, K.; Matsuzaka, H.

    Journal of the American Chemical Society 雑誌 アメリカ化学会   130   8904 - 8905   2008.06

     More details

    Kind of work:Joint Work  

  • P-H Bond Addition to a Dinuclear Ruthenium Imido Complex: Synthesis and Reactivity of an Amido Phosphido Complex Reviewed

    Takemoto, S.; Kimura, Y.; Kamikawa, K.; Matsuzaka, H.

    Organmetallics 雑誌   27   1780 - 1785   2008.04

     More details

    Kind of work:Joint Work  

  • Synthesis of helicenes utilizing palladium-catalyzed double C-H arylation reaction Reviewed

    Kamikawa K., Takemoto I., Takemoto S., Matsuzaka H.

    Journal of Organic Chemistry 雑誌   72   7406 - 7408   2007.04

     More details

    Kind of work:Joint Work  

  • Stereoselective synthesis of both enantiomers of N-aryl indoles with axially chiral N-C bonds Reviewed

    Kamikawa K., Kinoshita S., Furusyo M., Takemoto S., Matsuzaka H., Uemura M.

    Journal of Organic Chemistry 雑誌   72   3394 - 3402   2007.04

     More details

    Kind of work:Joint Work  

  • A Diiron Amido-Imido Complex [(Cp*Fe)(m2-NHPh)(m2-NPh)]: Synthesis and a Net Hydrogen Atom Abstraction Reaction to Form a Bis(imido) Complex Reviewed

    Takemoto, S.; Ogura, S.; Yo, H.; Kamikawa, K.; Hosokoshi, Y.; Matsuzaka, H.

    Inorganic Chemistry 雑誌 アメリカ化学会   45   4871 - 4873   2006.07

     More details

    Kind of work:Joint Work  

  • Nickel-catalyzed [3+1+1] cycloaddition reactions of alkenyl Fischer carbene complexes with methylenecyclopropanes Reviewed

    Kamikawa K., Shimizu Y., Takemoto S., Matsuzaka H.

    Organic Letters 雑誌   8 ( 18 )   4011 - 4014   2006.04

     More details

    Kind of work:Joint Work  

  • Synthesis of Ru-Pt and Ru-Pd Mixed-Metal Imido Clusters from a Diruthenium Imido Methylene Scaffold [(Cp*Ru)2(m2-NPh)(m2-CH2)] Reviewed

    Takemoto, S.; Morita, H.; Kamikawa, K.; Matsuzaka, H.

    Chemical Communication 雑誌   1328 - 1330   2006.02

     More details

    Kind of work:Joint Work  

  • Dinuclear Ruthenium(II) Catecholato and Naphthalenediolato Complexes Featuring k2-Diaryloxo/h6-Arene Coordination Mode Reviewed

    Takemoto, S.; Ogura, S.; Kamikawa, K.; Matsuzaka, H.

    Inorg. Chim. Acta 雑誌 Elsevier   359   912 - 916   2006.02

     More details

    Kind of work:Joint Work  

  • Synthesis and Reactivity of A Dithiolate-Bridged Ruthenium-Rhodium Heterobimetallic Dihydride Complex Reviewed

    Takemoto, S.; Shimadzu, D.; Kamikawa, K.; Matsuzaka, H.; Nomura, R.

    Organometallics 雑誌   25   982 - 988   2006.01

     More details

    Kind of work:Joint Work  

  • Dinuclear Ruthenium(II) Diamido/Naphthalene Complexes Featuring a Coordinatively Unsaturated yet Highly pi-Basic (C5Me5)Ru Diamide Fragment Reviewed

    Takemoto, S.; Oshio, S.; Shiromoto, T.; Matsuzaka, H.

    Organometallics 雑誌 アメリカ化学会   24   801 - 804   2005.02

     More details

    Kind of work:Joint Work  

  • Olefin Polymerization Catalyzed by Titanium-Tungsten Heterobimetallic Dinitrogen Complexes Reviewed

    H. Ishino, S. Takemoto, K. Hirata, Y. Kanaizuka, M. Hidai, M. Nabika, Y. Seki, T. Miyatake, N. Suzuki

    Organometallics 雑誌 American Chemical Society   23   4544 - 4546   2004.10

     More details

    Kind of work:Joint Work  

  • Reactivity of Amido Ligand on a Dinuclear Ru(II) Center: Formation of Imido Complexes and C-N Coupling Reaction with Alkyne Reviewed

    S. Takemoto, T. Kobayashi, H. Matsuzaka

    Journal of the American Chemical Society 雑誌 American Chemical Society   126   10802 - 10803   2004.09

     More details

    Kind of work:Joint Work  

  • A Dinuclear Ruthenium(II) Amido Complex: Synthesis, Characterization, and Coupling Reaction with Carbon Monoxide Reviewed

    S. Takemoto, S. Oshio, T. Kobayashi, H. Matsuzaka, M. Hoshi, H. Okimura, M. Yamashita, H. Miyasaka, T. Ishii, M. Yamashita

    Organometallics 雑誌 American Chemical Society   23   3587 - 3589   2004.06

     More details

    Kind of work:Joint Work  

  • Ti-Mo Heterobimetallic Thiacalix[4]arene Complex Containing an Unusual a-Agostic m2-h5:h2-Cyclopentadienyl Ligand Reviewed

    S. Takemoto, S. Tanaka, Y. Mizobe, M. Hidai

    Chemical Communications 雑誌 The Royal Society of Chemistry   838 - 839   2004.03

     More details

    Kind of work:Joint Work  

  • Chemistry of Low-Valent Ruthenium Amide Clusters

    S. Takemoto, H. Matsuzaka

    Organometallc News 雑誌 Kinki Chemical Society   2   43 - 46   2004.03

     More details

    Kind of work:Joint Work  

  • Ruthenium Complexes Containing Bis(diarylamido)/thioether Ligands: Synthesis and Their Catalysis for Hydrogenation of Benzonitrile Reviewed

    S. Takemoto, H. Kawamura, Y. Yamada, T. Okada, A. Ono, E. Yoshikawa, Y. Mizobe, M. Hidai

    Organometallics 雑誌 American Chemical Society   21   3879 - 3904   2002.12

     More details

    Kind of work:Joint Work  

  • Synthesis and Structures of p-tert-butyltetrathiacalic[4]arene-Dihydrides of Mo(IV) and W(IV) Reviewed

    S. Takemoto, K. Otsuka, T. Otsuka, H. Seino, Y. Mizobe, M. Hidai

    Chemistry Letters 雑誌 The Chemical Society of Japan   6 - 7   2002.01

     More details

    Kind of work:Joint Work  

  • Formation of Ammonia in the Reactions of a Tungsten Dinitrogen with Ruthenium Dihydrogen Complexes under Mild Reaction Conditions Reviewed

    Y. Nishibayashi, S. Takemoto, S. Iwai, M. Hidai

    Inorganic Chemistry 雑誌 American Chemical Society   39   5946 - 5957   2000.12

     More details

    Kind of work:Joint Work  

  • Synthesis and Structures of 1,17-Ferrocenedithiolato-Bridged Di- and Trinuclear Ruthenium Complexes Reviewed

    S. Takemoto, S. Kuwata, Y. Nishibayashi, M. Hidai

    Organometallics 雑誌 American Chemical Society   19   3249 - 3252   2000.12

     More details

    Kind of work:Joint Work  

  • Synthesis of Heterobimetallic Fe-M (M = Ni, Pd, Pt) Complexes Containing the 1,1'-Ferrocenedithiolato Ligand and Their Conversion to Trinuclear Complexes Reviewed

    S. Takemoto, S. Kuwata, Y. Nishibayashi, M. Hidai

    Inorganic Chemistry 雑誌 American Chemical Society   37   6428 - 6434   1998.12

     More details

    Kind of work:Joint Work  

▼display all

Books and Other Publications

  • 高機能性金属錯体が拓く触媒科学 第10章 配位不飽和な二核ルテニウム錯体による分子変換

    竹本 真,松坂 裕之 ( Role: Joint author)

    化学同人  2020.03 

MISC

  • Catalytic Transformations of Aromatic Molecules via η6-Arene Complexes Invited International journal

    Shin Takemoto, Hiroyuki Matsuzaka

    Fain Kemikaru   52 ( 11 )   1 - 14   2023.11( ISSN:0913-6150

     More details

    Authorship:Lead author   Publishing type:Article, review, commentary, editorial, etc. (trade magazine, newspaper, online media)   International / domestic magazine:Domestic journal  

  • ルテニウムカーバイド錯体を起点とする直鎖状炭素鎖成長反応 Reviewed

    竹本 真, 松坂 裕之

    有機合成化学協会誌   79 ( 12 )   1136 - 1143   2021.12

     More details

  • メタロカルベンとして振舞うルテニウムカーバイド錯体の創出 Reviewed

    竹本真

    Organometallic News   2019 ( 2 )   2019.05

     More details

  • スペインICIQにおける在外研究 Reviewed

    竹本真

    Organometallic News   2015.08

     More details

  • 遷移金属カーバイド錯体 Fischer-Tropsch反応の有機金属モデル Reviewed

    竹本真

    化学と工業   63 ( 3 )   240 - 241   2010.03

     More details

Industrial Property Rights

  • オレフィンの製造方法及び金属二核錯体

    竹本真、松坂裕之

     More details

    property_type:Patent 

  • 錯体および水素生成方法

    松坂裕之、竹本真

     More details

    property_type:Patent 

  • 異種金属多核錯体およびそれを用いた触媒の製造方法

    平田裕人、永田直人、松坂裕之、竹本真

     More details

    property_type:Patent 

  • Preparation of iridium-platinum complex having controlled cluster size

    Matsuzaka, Hiroyuki; Takemoto, Shin; Hirata, Hirohito

     More details

    property_type:Patent 

    Patent/Registration no:WO 2007-JP55020 

  • Preparation of iridium-platinum complex having controlled cluster size

    Matsuzaka, Hiroyuki; Takemoto, Shin; Hirata, Hirohito

     More details

    property_type:Patent 

    Patent/Registration no:US 2009-282324 

  • Preparation of iridium-platinum complex having controlled cluster size

    Matsuzaka, Hiroyuki; Takemoto, Shin; Hirata, Hirohito

     More details

    property_type:Patent 

    Patent/Registration no:CN 2007-80008348 

  • Preparation of iridium-platinum complex having controlled cluster size

    Matsuzaka, Hiroyuki; Takemoto, Shin; Hirata, Hirohito

     More details

    property_type:Patent 

    Patent/Registration no:KR 2008-721973 

  • Preparation of iridium-platinum complex having controlled cluster size

    Matsuzaka, Hiroyuki; Takemoto, Shin; Hirata, Hirohito

     More details

    property_type:Patent 

    Patent/Registration no:EP 2007-738491 

  • Preparation of iridium-platinum complex having controlled cluster size

    Matsuzaka, Hiroyuki; Takemoto, Shin; Hirata, Hirohito

     More details

    property_type:Patent 

    Patent/Registration no:CA 2007-2645316 

  • Preparation of iridium-platinum complex having controlled cluster size

    Matsuzaka, Hiroyuki; Takemoto, Shin; Hirata, Hirohito

     More details

    property_type:Patent 

    Patent/Registration no:JP 2006-66395 

▼display all

Outline of collaborative research (seeds)

  • 有機金属錯体、多核錯体、クラスターの合成と構造および反応性の解明

Charge of on-campus class subject

  • Chemistry Laboratory I

    2021   Practical Training  

  • Inorganic Chemistry

    2021    

  • Organic Spectroscopy II

    2021    

  • English for Chemists

    2021    

  • Exercises in Inorganic Chemistry

    2021    

Social Activities

  • めずらしい炭素原子を含む金属酵素ニトロゲナーゼの仕組みを探る

    Role(s): Lecturer

    大阪公立大学理学部  2023年度理学部職員向け談話会  2023.12

     More details

    Type:Lecture

  • さくらサイエンスプラン交流会

    Role(s): Lecturer, Consultant

    2023.12

  • 堺市立堺高等学校プロフェッサーズセミナー 触媒化学への招待

    2021.04 - 2022.03

  • JST 大阪府立大学・大阪市立大学 新技術説明会

    2020.04 - 2021.03

  • さくらサイエンスプラン交流会

    2019.12

  • 大学訪問研修「プラスチックをつくる有機金属触媒のはたらき」

    2019.04 - 2020.03

  • 理学系研究科公開セミナー「進化する有機合成化学と産業への貢献」

    2016.04 - 2017.03

  • プール学院高校模擬講義 フッ素とその化合物の化学

    2015.04 - 2016.03

  • 堺市立堺高等学校プロフェッサーズセミナー 社会に役立つ触媒化学

    2014.04 - 2015.03

  • 高校生のためのサイエンスフォーラム 遷移金属の分子科学〜 化学反応の舞台をつくろう 〜

    2012.04 - 2013.03

  • りそなグループ技術懇親会 「水素発生錯体」

    2010.04 - 2011.03

  • 府大講座 レアメタルの化学

    2009.04 - 2010.03

▼display all

International exchange activities

  • Mainly in charge of experiment guidance in the "Sakura Science Program 2023", which invites National Taiwan Normal University students (9 people) and instructor (1 person) to give lectures, experiments, and presentations.

    Field category :Social contributions

    Country name :Taiwan   2023.11

  • Mainly in charge of experiment guidance in the "Sakura Science Program 2019", which invites National Taiwan Normal University students and instructor to give lectures, experiments, and presentations.

    Field category :Social contributions

    Country name :Taiwan   2019.12