Updated on 2023/06/28
Graduate School of Science Department of Chemistry
Associate Professor 2022.04 - Now
School of Science Department of Chemistry
Associate Professor 2022.04 - Now
博士（工学） （ Tokyo Institute of Technology ）
Nanotechnology/Materials / Inorganic/coordination chemistry / Inorganic Chemistry
Nanotechnology/Materials / Inorganic/coordination chemistry
Inorganic Chemistry
錯体化学
遷移金属クラスター錯体の化学
σ電子受容性配位子の化学
Chemestry of simga acceptor ligand
transition metal, complex, Lewis acid, ligand, borane Individual
2013 - Now
Chemestry of transition metal cluster compounds
transition metal, multi-nuclear complex, cluster, ligand, hydride Individual
2013 - Now
アメリカ化学会
2018.08 - Now Overseas
錯体化学会
近畿化学協会
有機合成化学協会
日本化学会
ケイ素化学協会
アメリカ化学会
Young Researcher's Award
2020 The Society of Silicon Chemistry Japan
若い世代の特別講演会
2020 日本化学会
Seiichi tejima Doctoral Dissertation Award
2010.02 Tokyo Institute of Technology
Catalytic stannane–fluorine activation triggered by Pd → Sn–F interaction
Hajime Kameo, Yuki Baba, Hiroyuki Matsuzaka
Polyhedron 2023.09
Square-Planar Anionic Pt(0) Complexes.
Hajime Kameo, Yudai Tanaka, Yoshihiro Shimoyama, Daisuke Izumi, Hiroyuki Matsuzaka, Yumiko Nakajima, Pierre Lavedan, Arnaud Le Gac, Didier Bourissou
Angewandte Chemie (International ed. in English) 62 ( 20 ) e202301509 2023.02（ ISSN:1433-7851 ）
Ni/Pd-Catalyzed Selective Transformations of Chlorosilanes
Naganawa Yuki, Kameo Hajime, Nakajima Yumiko
Journal of Synthetic Organic Chemistry, Japan 81 ( 1 ) 14 - 24 2023.01（ ISSN:00379980 ）
Development of Catalytic Cross-Coupling Reactions Based on Transition Metal→Z-type Ligand Interactions Invited Reviewed
Hajime Kameo
J. Synth. Org. Chem. Jpn. 雑誌 有機合成化学協会 80 ( 5 ) 451 - 458 2022.05
Theoretical Study on Si−Cl Bond Activation in Pd‐Catalyzed Cross‐Coupling of Chlorosilanes with Organoaluminum Invited Reviewed
Yuki Naganawa, Yumiko Nakajima, Shigeyoshi Sakaki, Hajime Kameo
European Journal of Organic Chemistry 2022 ( 6 ) 2022.02（ ISSN:1434-193X ）
強固な結合の切断を鍵とする 触媒反応の開発
亀尾 肇
化学と工業 雑誌 74 ( 8 ) 2021.08
Synthesis, Structure, and Bonding Properties of Hypercoordinate Triorganotin Compounds Featuring Three O→Sn Interactions
Hajime Kameo, Daisuke Izumi, Hiroyuki Matsuzaka
European Journal of Inorganic Chemistry 2021.07
Pd/Ni-Catalyzed Germa-Suzuki Coupling via Dual Ge‒F Bond Activation Reviewed
Hajime Kameo, Akihiro Mushiake, Tomohito Isasa, Hiroyuki Matsuzaka, Didier Bourissou
Chemical Communications 57 2021.04
Hajime Kameo, Shigeyoshi Sakaki, Yasuhiro Ohki, Naoki Uehara, Takuya Kosukegawa, Hiroharu Suzuki, Toshiro Takao
Inorganic Chemistry 60 ( 3 ) 1550 - 1560 2021.02（ ISSN:0020-1669 ）
強固な結合の切断を鍵とする 触媒反応の開発
亀尾 肇
化学と工業 74 598 - 599 2021
Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation
Hajime Kameo, Akihiro Mushiake, Tomohito Isasa, Hiroyuki Matsuzaka, Didier Bourissou
Chemical Communications 2021
Fluorosilane Activation by Pd/Ni→Si–F→Lewis Acid Interaction: An Entry to Catalytic Sila-Negishi Coupling Reviewed
Hajime Kameo, Hiroki Yamamoto, Koki Ikeda, Tomohito Isasa, Shigeyoshi Sakaki, Hiroyuki Matsuzaka, Yago García-Rodeja, Karinne Miqueu, Didier Bourissou
Journal of the American Chemical Society 142 ( 33 ) 14039 - 14044 2020.08（ ISSN:0002-7863 ）
Counterion Dependence of Dinitrogen Activation and Functionalization by a Diniobium Hydride Anion Reviewed
Shoi Suzuki, Yutaka Ishida, Hajime Kameo, Shigeyoshi Sakaki, Hiroyuki Kawaguchi
Angewandte Chemie International Edition 132 ( 32 ) 13546 - 13552 2020.08（ ISSN:1521-3773 ）
Experimental and Theoretical Investigation of an SN2-type Pathway for Borate–Fluorine Bond Cleavage by Electron-Rich Late-Transition Metal Complexes Reviewed
Hajime Kameo, Yuki Baba, Shigeyoshi Sakaki, Yudai Tanaka, Hiroyuki Matsuzaka
Inorganic Chemistry 59 ( 7 ) 4282 - 4291 2020.04（ ISSN:0020-1669 ）
Experimental and Theoretical Investigation of an SN2-type Pathway for Borate−Fluorine Bond Cleavage by Electron-Rich Late-Transition Metal Complexes Reviewed
Hajime Kameo, Yuki Baba, Shigeyoshi Sakaki, Yudai Tanaka, Hiroyuki Matsuzaka
Inorganic Chemistry 雑誌 American Chemical Society 2020.01
Innentitelbild: Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination (Angew. Chem. 52/2019) Reviewed
Hajime Kameo, Jun Yamamoto, Ayaka Asada, Hiroshi Nakazawa, Hiroyuki Matsuzaka, Didier Bourissou
Angewandte Chemie 131 ( 52 ) 18894 - 18894 2019.12
Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination Reviewed
Hajime Kameo, Jun Yamamoto, Ayaka Asada, Hiroshi Nakazawa, Hiroyuki Matsuzaka, Didier Bourissou
Angewandte Chemie 131 ( 52 ) 18959 - 18963 2019.12
Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination Reviewed
Hajime Kameo, Jun Yamamoto, Ayaka Asada, Hiroshi Nakazawa, Hiroyuki Matsuzaka, Didier Bourissou
Angewandte Chemie International Edition 58 ( 52 ) 18783 - 18787 2019.12（ ISSN:1433-7851 ）
Inside Cover: Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination (Angew. Chem. Int. Ed. 52/2019) Reviewed
Hajime Kameo, Jun Yamamoto, Ayaka Asada, Hiroshi Nakazawa, Hiroyuki Matsuzaka, Didier Bourissou
Angewandte Chemie International Edition 58 ( 52 ) 18720 - 18720 2019.12
σ電子受容性シラン、ゲルマン、スタンナン配位子を鍵とする切断反応の開発
亀尾肇
ケイ素化学協会誌 雑誌 ( 36 ) 2019.11
Modulation of the coordination geometries of NCN and NCNC Rh complexes for ambidextrous chiral catalysts Reviewed
Jun-ichi Ito, Takahiro Ishihara, Takaki Fukuoka, Siti Rokiah Binti Mat Napi, Hajime Kameo, Hisao Nishiyama
Chemical Communications 雑誌 2019.09
Cover Feature: Heptacoordinate Structures of Organotin Halides with Three Phosphine Donors: Halogen-Substituent Effect on Geometry (Eur. J. Inorg. Chem. 26/2019) Reviewed
Hajime Kameo, Tatsuya Kawamoto, Shigeyoshi Sakaki, Didier Bourissou, Hiroshi Nakazawa
European Journal of Inorganic Chemistry 2019 ( 26 ) 3035 - 3035 2019.07
Heptacoordinate Structures of Organotin Halides with Three Phosphine Donors: Halogen‐Substituent Effect on Geometry Reviewed
Hajime Kameo, Tatsuya Kawamoto, Shigeyoshi Sakaki, Didier Bourissou, Hiroshi Nakazawa
European Journal of Inorganic Chemistry 2019 ( 26 ) 3045 - 3052 2019.07
Modulation of the coordination geometries of NCN and NCNC Rh complexes for ambidextrous chiral catalysts Reviewed
Jun-ichi Ito, Takahiro Ishihara, Takaki Fukuoka, Siti Rokiah Binti Mat Napi, Hajime Kameo, Hisao Nishiyama
Chemical Communications 55 ( 85 ) 12765 - 12768 2019（ ISSN:1359-7345 ）
Iridium-Hydride-Mediated Stannane−Fluorine and −Chlorine sigma-Bond Activation: Reversible Switching between X-type Stannyl and Z-type Stannane Ligands
Hajime Kameo,* Yuki Baba, Shigeyoshi Sakaki, Didier Bourissou, Hiroshi Nakazawa, Hiroyuki Matsuzaka
Organometallics 雑誌 36 ( 11 ) 2017.05
Synthesis and Characterisation of Tetranuclear Ruthenium Polyhydrido Clusters with Pseudo-Tetrahedral Geometry
Hajime Kameo, Yutaka Ito, Ryuichi Shimogawa, Asuka Koizumi, Hiroki Chikamori, Junko Fujimoto, Hiroharu Suzuki, Toshiro Takao
Dalton Transactions 46 ( 12 ) 2017.05
Cooperative Catalysis of a Combined System of Transition Metal Complex with the Lewis Acid: Theoretical Understanding Reviewed
Wei Guan, Guixiang Zeng, Hajime Kameo, Yoshiaki Nakao, Shigeyoshi Sakaki
The Chemical Record 雑誌 16 ( 5 ) 2016.10
Saturated Heavier Group 14 Compounds as σ-Electron Acceptor (Z-type) Ligands Reviewed
Hajime Kameo, Hiroshi Nakazawa
The Chemical Record 雑誌 17 ( 3 ) 2016.08
Experimental and Theoretical Study of Si−Cl and Ge−Cl sigma-Bond Activation Reactions by Iridium-Hydride Reviewed
Hajime Kameo, Koki Ikeda, Sakaki Shigeyoshi, Hiroshi Nakazawa, Shin Takemoto, Hiroyuki Matsuzaka
Dalton Transactions 雑誌 45 2016.02
Transition-Metal-Mediated Cleavage of Fluoro-Silanes under Mild Conditions Reviewed
Hajime Kameo, Tatsuya Kawamoto, Shigeyoshi Sakaki, Didier Bourissou, Hiroshi Nakazawa
Chemistry - A European Journal 雑誌 22 2016.02
Transition Metal-Mediated Ge−F Activation: Inverse Electron Flow in sigma Bond Metathesis Reviewed
Hajime Kameo, Koki Ikeda, Didier Bourissou, Shigeyoshi Sakaki, Shin Takemoto, Hiroshi Nakazawa, Hiroyuki Matsuzaka
Organometallics 35 2016.02
Activation of Strong Boron−Fluorine and Silicon−Fluorine Sigma-Bonds: Theoretical Understanding and Prediction Reviewed
Hajime Kameo, Shigeyoshi Sakaki
Chemistry - A European Journal 雑誌 21 2015.09
Coordination of a Triphosphine-Silane to Gold: Formation of a Trigonal Pyramidal Complex Featuring Au+→Si Interaction Reviewed
Pauline Gualco, Sonia Mallet-Ladeira, Hajime Kameo, Hiroshi Nakazawa, Maxime Mercy, Laurent Maron, Abderrahmane Amgoune, Didier Bourissou
Organometallics 34 ( 8 ) 2015.04
Evaluation of the -Donation from Group 11 Metals (Cu, Ag, Au) to Silane, Germane, and Stannane Based on the Experimental / Theoretical Systematic Approach Reviewed
Hajime Kameo, Tatsuya Kawamoto, Didier Bourissou, Shigeyoshi Sakaki, Hiroshi Nakazawa
Organometallics 雑誌 34 ( 8 ) 2015.04
Synthesis, Geometry, and Bonding Nature of Hepta-coordinate Compounds of Silicon and Germanium Featuring Three Phosphine Donors Reviewed
Hajime Kameo, Tatsuya Kawamoto, Didier Bourissou, Shigeyoshi Sakaki, Hiroshi Nakazawa
Organometallics 33 ( 22 ) 2014.11
Can One σ*-Antibonding Orbital Interact with Six Electrons of Lewis Bases? Analysis of a Multiply Interacting σ* Orbital Reviewed
Hajime Kameo,* Tatsuya Kawamoto, Shigeyoshi Sakaki, Hiroshi Nakazawa
Organometallics 雑誌 33 ( 21 ) 2014.10
Coordination and Redox Isomerization of a Putative Divalent Uranium Arene Complex Reviewed
Henry S. La Pierre, Hajime Kameo, Dominik Halter, Frank W. Heinemann, Karsten Meyer
Angewandte Chemie International Edition 雑誌 53 ( 28 ) 2014.07
Recent Developments in the Coordination Chemistry of Multidentate Ligands Featuring a Boron Moiety Reviewed
Hajime Kameo, Hiroshi Nakazawa
Chem. Asian J. 雑誌 Wiley 8 2013.06
Si-C Bond Cleavage by Hydride Complexes of Rhodium and Iridium: Comparison of Si-C(sp2) and Si-C(sp3) Activation Reviewed
Hajime Kameo, Sho Ishii, Hiroshi Nakazawa
Dalton Trans. 雑誌 Royal Society of Chemistry 42 2013.01
Crystal Structure and Metal Atom Dynamics of the Dimethyl Stannane complex: {o-(Ph2P)C6H4}2Sn(CH3)2 Reviewed
Hajime Kameo, Hiroshi Nakazawa, Rolfe H. Herber
Journal of Molecular Structure 雑誌 1054–1055 2013
Synthesis of a Rhodium Complex Featuring the Rh-H-B linkage via a Hydride Migration from Rhodium to Borane: Study on the Electronic Deviation Induced by the Presence of the boron moiety Reviewed
Hajime Kameo, Hiroshi Nakazawa
Organometallics 雑誌 American Chemical Society 31 2012.10
Facile Synthesis of Rhodium and Iridium Complexes Bearing a [PEP]-Type Ligand (E = Ge or Sn) via E−C Bond Cleavag Reviewed
Hajime Kameo, Sho Ishii, Hiroshi Nakazawa
Dalton Trans. 雑誌 Royal Society of Chemistry 41 2012.07
Synthesis of Iridaboratranes Bearing Phosphine-Tethered Borane: Reversible CO/PR3 (R = Me, OMe, and OEt) Substitution Reaction Induced by -Electron Acceptor Borane Ligand Reviewed
Hajime Kameo, Yasuhiro Hashimoto, Hiroshi Nakazawa
Organometallics 雑誌 American Chemical Society 31 2012.05
Synthesis of Iridium Complexes Bearing {(o-Ph2P)C6H4}3E Type (E = Si, Ge, and Sn) Ligand and Evaluation of Electron Donating Ability of Group 14 Elements E Reviewed
Hajime Kameo, Sho Ishii, Hiroshi Nakazawa
Dalton Trans. 雑誌 Royal Society of Chemistry 41 2012.04
Structures and Reactivities of Rhodium Complexes Bearing [E(o-C6H4PPh2)3] Type Tetradentate Ligand (E = Si, Ge, Sn) Reviewed
Hajime Kameo, Sho Ishii, Hiroshi Nakazawa
Organometallics 雑誌 American Chemical Society 31 2012.03
Synthesis of Rhodaboratranes Bearing Phosphine-Tethered Borane: Evaluation of Metal-Borane Interaction Reviewed
Hajime Kameo, Yasuhiro Hashimoto, Hiroshi Nakazawa
Organometallics 雑誌 American Chemical Society 31 2012.03
Chemistry of Transition Metal Complex Containing Sigma Electron Acceptor (Z-type) Ligand Reviewed
Hajime Kameo
Bull. Chem. Soc. Coord. Chem. 雑誌 Japan Society of Coordination Chemistry 58 2011.11
Heterometallic Effects in Nitrogen-Hydrogen Bond Cleavage by Trinuclear Mixed-Metal Polyhydrido Cluster containing Ruthenium and Osmium Reviewed
Hajime Kameo, Yumiko Nakajima, Kyo Namura, Hiroharu Suzuki
Organometallics 雑誌 American Chemical Society 30 2011.11
Insights into the Mechanism of Carbonate Formation through Reductive Cleavage of Carbon Dioxide with Low-valent Uranium Centers Reviewed
Oahn P. Lam, Suzanne C. Bart, Hajime Kameo, Frank W. Heinemann, Karsten Meyer
Chem. Commun. 雑誌 Wiley 46 2010.04
Synthesis and Structure of a Novel Ruthenium Hydrido-bis(dihydrogen) complex with 1,4,7-Trimethyl-1,4,7-triazacyclononane Ligand: A Useful Precursor for Synthesis of Heterometallic Complexes Reviewed
Takanori Shima, Kyo Namura, Hajime Kameo, Satoshi Kakuta, Hiroharu Suzuki
Organometallics 雑誌 American Chemical Society 29 2009.12
Synthesis of Heterotrimetallic Polyhydrido Clusters Containing Ruthenium and Osmium and Their Electronic and Structural Deviation from Homometallic Systems Reviewed
Hajime Kameo, Takanori Shima, Yumiko Nakajima, Hiroharu Suzuki
Organometallics 雑誌 American Chemical Society 28 2009.03
Drastic Acceleration of the Phosphine/Phosphite Incorporation into a Tetrahydrido Ru/Os Complex, and One-way Ru-Os Migration of a Phosphorus Ligand Reviewed
Hajime Kameo, Yumiko Nakajima, Hiroharu Suzuki
Angew. Chem. Int. Ed. 雑誌 Wiley 47 2008.11
Synthesis of Trinuclear Osmium Polyhydrido Clusters [{(C5Me5)Os}3(-H)6]+ and {(C5Me5)Os}3(-H)3(3-H)2 and Comparison with the Ruthenium Analogues Reviewed
Hajime Kameo, Hiroharu Suzuki
Organometallics 雑誌 American Chemical Society 27 2008.07
Hydrogenation of a Trinuclear 3-Imido Complex of Ruthenium: Homolytic or Heterolytic H−H Bond Cleavage? Reviewed
Hajime Kameo, Yumiko Nakajima, Hiroharu Suzuki
Eur. J. Inorg. Chem. 雑誌 Wiley 2007.03
Cleavage of Nitrogen−Hydrogen Bonds of Ammonia Induced by Triruthenium Polyhydrido Cluster Reviewed
Yumiko Nakajima, Hajime Kameo, Hiroharu Suzuki
Angew. Chem. Int. Ed. 雑誌 Wiley 45 2005.12
非共有結合性相互作用 Z型配位子相互作用 反復クロスカップリング ノンフォトレドックス
國信 洋一郎, 亀尾 肇, 吉田 拡人, 稲垣 昭子
有機合成化学協会誌 80 ( 5 ) 517 - 517 2022.05（ ISSN:0037-9980 ） （ eISSN:1883-6526 ）
強固な結合の切断を鍵とする触媒反応の開発 M→Z(Z型配位子)σ結合を介した求核的活性化
亀尾肇
化学と工業 74 ( 8 ) 2021（ ISSN:0022-7684 ）
Co(III) オキシラジカルを鍵とする触媒反応 International journal
亀尾肇
Organometallic News 2019.03
昨日今日そして明日のケイ素化学 σ電子受容性シラン,ゲルマン,スタンナン配位子を鍵とする切断反応の開発
亀尾肇
ケイ素化学協会誌 ( 36 ) 2019
酸化亜鉛ラジカルカチオンを用いたメタンの活性化 International journal
亀尾肇
月刊「化学」 2017.11
αシアノカルバニオン配位子を有するπ共役系ニッケル錯体の合成 Domestic conference
松田光二、 山本大貴、亀尾 肇、松坂裕之
日本化学会第103春季年会 2023.03 日本化学会
Bond Cleavage and Catalysis Based on Nucleophilic Activation via Metal→Z-type Silane Ligand Interaction Invited International conference
Hajime Kameo
2023.03
パラジウム錯体を用いた ゲルマニウム－炭素結合のアリール化 Domestic conference
大石貫太、 虫明陽大、亀尾 肇、松坂裕之
日本化学会第103春季年会 2023.03 日本化学会
Catalytic Activation of Fluorosilane and Fluorogermane via TM→Si/Ge–F→Lewis Acid Interaction Invited International conference
Hajime Kameo
The 5th NYCU Conference on Advanced Organic Synthesis (CAOS-5) 2022.11 National Yang Ming Chiao Tung University
Ni/Pd-Catalyzed Coupling with Fluorosilanes and Fluorogermanes Based on Z-type Interaction International conference
8th Asia Silicon Symposium 2022.10
σ-電子受容性ボラン配位子を有するアニオン性 Pt(0) および Pd(0) 錯体の合成 Domestic conference
泉 大輔、田中悠大、亀尾 肇、松坂裕之
錯体化学会第72回討論会 2022.09 日本化学会近畿支部
パラジウム錯体を用いたケイ素-アルコキシ結合のアリール化 Domestic conference
河原陽乃介、北村功樹、亀尾 肇、松坂裕之
日本化学会第102春季年会 2022.03 日本化学会
σ電子受容性配位子を有する錯体の創製と触媒反応の開発 Invited Domestic conference
亀尾 肇
日本化学会第101春季年会 2021.03
σ電子受容性配位子を鍵とする切断反応の開発 Domestic conference
亀尾 肇・松坂裕之
第23回ケイ素化学協会シンポジウム 2019.11
パラジウム錯体を用いたケイ素-酸素結合の触媒的アリール化反応の開発 Domestic conference
北村功樹・ 亀尾 肇・松坂裕之
錯体化学会第69回討論会 2019.09
アニオン性ロジウム(-I)ボラン錯体を用いた脱フッ素化反応 Domestic conference
田中悠大・ 亀尾 肇・松坂裕之
錯体化学会第69回討論会 2019.09
Anionic Rh(-I) Borane Complexes Featuring Seesaw Geometry Domestic conference
Kameo, H.; Yamamoto, J.; Matsuzaka, H.
第66回有機金属化学討論会 2019.09
有機金属錯体の合成およびそれらを用いた反応開発
分子科学実験II
2021 Practical Training
Chemistry Laboratory I
2021 Practical Training
First Year Seminar
2021
First Year Seminar
2021
Inorganic Chemistry
2021
Sciences in Community
2021
Inorganic Chemistry III
2021
Exercises in Inorganic Chemistry
2021
Inorganic Chemistry IV
2021
Organometallic Chemistry
Level：Postgraduate Country：France
2020
Number of instructed the graduation thesis：2
2019
Number of instructed the graduation thesis：2
泉北高校 オンライン大学訪問研修 触媒化学の歴史と今後の課題
2020.04 - 2021.03
第７１回錯体化学討論会 実行委員会委員
2020 - 2021.09
泉北高校 高大連携事業
2018.04 - 2019.03
堺市立堺高等学校 プロフェッサーズセミナー
2017.04 - 2018.03
堺市立堺高等学校 サマーサイエンスセミナー
2016.04 - 2017.03
2022
SDGs：
Original item：Visiting Research Professor (Paul Sabatier University - Toulouse III)
Special report：Paul Sabatier University - Toulouse III の Visiting Research Professor として活動し、３週間の間に講義やディスカッション等を行った。