Updated on 2024/08/06

写真a

 
Kameo Hajime
 
Organization
Graduate School of Science Department of Chemistry Associate Professor
School of Science Department of Chemistry
Title
Associate Professor
Affiliation
Institute of Science
Contact information
メールアドレス

Position

  • Graduate School of Science Department of Chemistry 

    Associate Professor  2022.04 - Now

  • School of Science Department of Chemistry 

    Associate Professor  2022.04 - Now

Degree

  • 博士（工学） （ Tokyo Institute of Technology ）

Research Areas

  • Nanotechnology/Materials / Inorganic/coordination chemistry  / Inorganic Chemistry

  • Nanotechnology/Materials / Inorganic/coordination chemistry

Research Interests

  • Inorganic Chemistry

  • 錯体化学

Research subject summary

  • 遷移金属クラスター錯体の化学

  • σ電子受容性配位子の化学

Research Career

  • Chemestry of simga acceptor ligand

    transition metal, complex, Lewis acid, ligand, borane  Individual

    2013 - Now 

  • Chemestry of transition metal cluster compounds

    transition metal, multi-nuclear complex, cluster, ligand, hydride  Individual

    2013 - Now 

Professional Memberships

  • アメリカ化学会

    2018.08 - Now   Overseas

  • 錯体化学会

  • 近畿化学協会

  • 有機合成化学協会

  • 日本化学会

  • ケイ素化学協会

  • アメリカ化学会

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Awards

  • Young Researcher's Award

    2020   The Society of Silicon Chemistry Japan  

  • 若い世代の特別講演会

    2020   日本化学会  

  • Seiichi tejima Doctoral Dissertation Award

    2010.02   Tokyo Institute of Technology  

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    Country：Japan

Papers

  • Trigonal-Bipyramidal Pt(0) and Pd(0) Anions

    Hajime Kameo, Tokoro Miyazaki, Yoshihiro Shimoyama, Ayaka Asada, Daisuke Izumi, Hiroyuki Matsuzaka, Didier Bourissou

    Inorganic Chemistry   63 ( 29 )   13186 - 13190   2024.07（ ISSN:00201669 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.inorgchem.4c01884

    PubMed

  • Catalytic stannane–fluorine activation triggered by Pd → Sn–F interaction

    Hajime Kameo, Yuki Baba, Hiroyuki Matsuzaka

    Polyhedron   2023.09

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1016/j.poly.2023.116504

  • Square-Planar Anionic Pt(0) Complexes.

    Hajime Kameo, Yudai Tanaka, Yoshihiro Shimoyama, Daisuke Izumi, Hiroyuki Matsuzaka, Yumiko Nakajima, Pierre Lavedan, Arnaud Le Gac, Didier Bourissou

    Angewandte Chemie (International ed. in English)   62 ( 20 )   e202301509   2023.02（ ISSN:1433-7851 ）

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    Publishing type：Research paper (scientific journal)   International / domestic magazine：International journal  

    A T-shaped Pt(0) complex with a diphosphine-borane (DPB) ligand was prepared. The Pt→B interaction enhances the electrophilicity of the metal and triggers the addition of Lewis bases to give the corresponding tetracoordinate complexes. For the first time, anionic Pt(0) complexes are isolated and structurally authenticated. X-ray diffraction analyses show the anionic complexes [(DPB)PtX]- (X = CN, Cl, Br, I) to be square-planar. The d10 configuration and Pt(0) oxidation state of the metal were unambiguously established by X-ray photoelectron spectroscopy and DFT calculations. The coordination of Lewis acids as Z-type ligands is a powerful mean to stabilize elusive electron-rich metal complexes and achieve uncommon geometry.

    DOI： 10.1002/anie.202301509

    PubMed

  • Ni/Pd-Catalyzed Selective Transformations of Chlorosilanes

    Naganawa Yuki, Kameo Hajime, Nakajima Yumiko

    Journal of Synthetic Organic Chemistry, Japan   81 ( 1 )   14 - 24   2023.01（ ISSN:00379980 ） （ eISSN:18836526 ）

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    <p>Industrially-produced chlorosilanes are cheap and abundant silicon feedstocks. To obtain various useful organosilicon compounds directly from these chlorosilanes, classical nucleophilic substitution reactions (Kipping method) with reactive organometallic reagents such as Grignard reagents and organolithium are often employed. In contrast, their direct catalytic transformation into beneficial organosilicon compounds remains challenging due to difficulty in cleaving the strong Si-Cl bond(s). To address this issue, we hypothesized that the activation of chlorosilanes with transition metal catalysts could be achieved with the cooperative assistance of Lewis acids by stabilizing the transition state or products. We initially developed Ni-catalyzed silyl-Heck reaction of chlorosilanes and styrenes. The aid of trimethylaluminum dramatically assisted silyl-Heck reaction to afford the corresponding alkenylsilanes. Successively, we also achieved the Ni-catalyzed cross-coupling reaction of chlorosilanes with trialkylaluminum species. Interestingly, the selective monoalkylation of dichlorosilanes was achieved to form various monochrolosilanes with a variety of alkyl substituents, which are useful raw materials for silicones. To further broaden the scope of this cross-coupling reaction, we then developed Pd-catalyzed cross-coupling reaction of chlorosilanes with dimethylaluminum chloride. The broader generality of di-, tri- and tetrachlorosilanes was revealed in the selective methylation to provide the corresponding methylmonochlorosilanes. Finally, we demonstrated computational study on the activation of Si-Cl bond by the cooperation of palladium and aluminum Lewis acid.</p>

    DOI： 10.5059/yukigoseikyokaishi.81.14

  • Development of Catalytic Cross-Coupling Reactions Based on Transition Metal→Z-type Ligand Interactions Invited Reviewed

    Hajime Kameo

    J. Synth. Org. Chem. Jpn. 雑誌 有機合成化学協会   80 ( 5 )   451 - 458   2022.05

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    Authorship：Lead author,　Last author,　Corresponding author   Publishing type：Research paper (scientific journal)   Kind of work：Single Work   International / domestic magazine：Domestic journal  

    DOI： 10.5059/yukigoseikyokaishi.80.451

  • Theoretical Study on Si−Cl Bond Activation in Pd‐Catalyzed Cross‐Coupling of Chlorosilanes with Organoaluminum Invited Reviewed

    Yuki Naganawa, Yumiko Nakajima, Shigeyoshi Sakaki, Hajime Kameo

    European Journal of Organic Chemistry   2022 ( 6 )   2022.02（ ISSN:1434-193X ） （ eISSN:1099-0690 ）

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    Authorship：Last author,　Corresponding author   Publishing type：Research paper (scientific journal)  

    The catalytic cross-coupling of chlorosilanes has recently emerged as an efficient method for the synthesis of organic silicon compounds. Direct Si-Cl bond activation by transition metals is a key elementary reaction in these methods. This theoretical study aimed to elucidate the mechanism of activation of the strong Si-Cl bond in Pd-catalyzed coupling reaction to gain insights for rational catalyst design. Our results suggest two plausible pathways for the bond activation: (i) trans-oxidative addition and (ii) S(N)2-type oxidative addition assisted by a Lewis acid. With an increase in Cl substituents of chlorosilanes, trans-oxidative addition highly feasible due to their higher Lewis acidities, in which the facile formation of the Pd -> Si interaction enables the smooth activation of the Si-Cl bond. The general mechanism of direct Si-Cl bond activation presented here may prove useful for the rational design of catalysis in the future.

    DOI： 10.1002/ejoc.202101477

  • 強固な結合の切断を鍵とする 触媒反応の開発

    亀尾　肇

    化学と工業 雑誌   74 ( 8 )   2021.08

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    Kind of work：Single Work  

  • Synthesis, Structure, and Bonding Properties of Hypercoordinate Triorganotin Compounds Featuring Three O→Sn Interactions

    Hajime Kameo, Daisuke Izumi, Hiroyuki Matsuzaka

    European Journal of Inorganic Chemistry   2021.07

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/ejic.202100334

  • Pd/Ni-Catalyzed Germa-Suzuki Coupling via Dual Ge‒F Bond Activation Reviewed

    Hajime Kameo, Akihiro Mushiake, Tomohito Isasa, Hiroyuki Matsuzaka, Didier Bourissou

    Chemical Communications   57   2021.04

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    Kind of work：Joint Work  

  • Four-Electron Reduction of Dioxygen on a Metal Surface: Models of Dissociative and Associative Mechanisms in a Homogeneous System Reviewed

    Hajime Kameo, Shigeyoshi Sakaki, Yasuhiro Ohki, Naoki Uehara, Takuya Kosukegawa, Hiroharu Suzuki, Toshiro Takao

    Inorganic Chemistry   60 ( 3 )   1550 - 1560   2021.02（ ISSN:0020-1669 ） （ eISSN:1520-510X ）

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    Publishing type：Research paper (scientific journal)  

    Two different four-electron reductions of dioxygen (O2) on a metal surface are reproduced in homogeneous systems. The reaction of the highly unsaturated (56-electron) tetraruthenium tetrahydride complex 1 with O2 readily afforded the bis(μ3-oxo) complex 3 via a dissociative mechanism that includes large electronic and geometric changes, i.e., a four-electron oxidation of the metal centers and an increase of 8 in the number of valence electrons. In contrast, the tetraruthenium hexahydride complex 2 induces a smooth H-atom transfer to the incorporated O2 species, and the O-OH bond is cleaved to afford the mono(μ3-oxo) complex 4 via an associative mechanism. Density functional theory calculations suggest that the higher degree of unsaturation in the tetrahydride system induces a significant interaction between the tetraruthenium core and the O2 moiety, enabling the large changes required for the dissociative mechanism.

    DOI： 10.1021/acs.inorgchem.0c02936

    PubMed

  • 強固な結合の切断を鍵とする 触媒反応の開発

    亀尾 肇

    化学と工業   74   598 - 599   2021

  • Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation

    Hajime Kameo, Akihiro Mushiake, Tomohito Isasa, Hiroyuki Matsuzaka, Didier Bourissou

    Chemical Communications   2021

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1039/D1CC01392K

  • Fluorosilane Activation by Pd/Ni→Si–F→Lewis Acid Interaction: An Entry to Catalytic Sila-Negishi Coupling Reviewed

    Hajime Kameo, Hiroki Yamamoto, Koki Ikeda, Tomohito Isasa, Shigeyoshi Sakaki, Hiroyuki Matsuzaka, Yago García-Rodeja, Karinne Miqueu, Didier Bourissou

    Journal of the American Chemical Society   142 ( 33 )   14039 - 14044   2020.08（ ISSN:0002-7863 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/jacs.0c04690

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  • Counterion Dependence of Dinitrogen Activation and Functionalization by a Diniobium Hydride Anion Reviewed

    Shoi Suzuki, Yutaka Ishida, Hajime Kameo, Shigeyoshi Sakaki, Hiroyuki Kawaguchi

    Angewandte Chemie International Edition   132 ( 32 )   13546 - 13552   2020.08（ ISSN:1521-3773 ） （ eISSN:1521-3773 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/anie.202006039

    PubMed

    Other URL： https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.202006039

  • Experimental and Theoretical Investigation of an SN2-type Pathway for Borate–Fluorine Bond Cleavage by Electron-Rich Late-Transition Metal Complexes Reviewed

    Hajime Kameo, Yuki Baba, Shigeyoshi Sakaki, Yudai Tanaka, Hiroyuki Matsuzaka

    Inorganic Chemistry   59 ( 7 )   4282 - 4291   2020.04（ ISSN:0020-1669 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.inorgchem.9b03053

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  • Experimental and Theoretical Investigation of an SN2-type Pathway for Borate−Fluorine Bond Cleavage by Electron-Rich Late-Transition Metal Complexes Reviewed

    Hajime Kameo, Yuki Baba, Shigeyoshi Sakaki, Yudai Tanaka, Hiroyuki Matsuzaka

    Inorganic Chemistry 雑誌 American Chemical Society   2020.01

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    Kind of work：Joint Work  

  • Innentitelbild: Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination (Angew. Chem. 52/2019) Reviewed

    Hajime Kameo, Jun Yamamoto, Ayaka Asada, Hiroshi Nakazawa, Hiroyuki Matsuzaka, Didier Bourissou

    Angewandte Chemie   131 ( 52 )   18894 - 18894   2019.12

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/ange.201914554

  • Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination Reviewed

    Hajime Kameo, Jun Yamamoto, Ayaka Asada, Hiroshi Nakazawa, Hiroyuki Matsuzaka, Didier Bourissou

    Angewandte Chemie   131 ( 52 )   18959 - 18963   2019.12

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/ange.201909675

  • Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination Reviewed

    Hajime Kameo, Jun Yamamoto, Ayaka Asada, Hiroshi Nakazawa, Hiroyuki Matsuzaka, Didier Bourissou

    Angewandte Chemie International Edition   58 ( 52 )   18783 - 18787   2019.12（ ISSN:1433-7851 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/anie.201909675

    PubMed

  • Inside Cover: Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination (Angew. Chem. Int. Ed. 52/2019) Reviewed

    Hajime Kameo, Jun Yamamoto, Ayaka Asada, Hiroshi Nakazawa, Hiroyuki Matsuzaka, Didier Bourissou

    Angewandte Chemie International Edition   58 ( 52 )   18720 - 18720   2019.12

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/anie.201914554

  • σ電子受容性シラン、ゲルマン、スタンナン配位子を鍵とする切断反応の開発

    亀尾肇

    ケイ素化学協会誌 雑誌   ( 36 )   2019.11

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    Kind of work：Single Work  

  • Modulation of the coordination geometries of NCN and NCNC Rh complexes for ambidextrous chiral catalysts Reviewed

    Jun-ichi Ito, Takahiro Ishihara, Takaki Fukuoka, Siti Rokiah Binti Mat Napi, Hajime Kameo, Hisao Nishiyama

    Chemical Communications 雑誌   2019.09

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    Kind of work：Joint Work  

  • Cover Feature: Heptacoordinate Structures of Organotin Halides with Three Phosphine Donors: Halogen-Substituent Effect on Geometry (Eur. J. Inorg. Chem. 26/2019) Reviewed

    Hajime Kameo, Tatsuya Kawamoto, Shigeyoshi Sakaki, Didier Bourissou, Hiroshi Nakazawa

    European Journal of Inorganic Chemistry   2019 ( 26 )   3035 - 3035   2019.07

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/ejic.201900717

  • Heptacoordinate Structures of Organotin Halides with Three Phosphine Donors: Halogen‐Substituent Effect on Geometry Reviewed

    Hajime Kameo, Tatsuya Kawamoto, Shigeyoshi Sakaki, Didier Bourissou, Hiroshi Nakazawa

    European Journal of Inorganic Chemistry   2019 ( 26 )   3045 - 3052   2019.07

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/ejic.201900524

  • Modulation of the coordination geometries of NCN and NCNC Rh complexes for ambidextrous chiral catalysts Reviewed

    Jun-ichi Ito, Takahiro Ishihara, Takaki Fukuoka, Siti Rokiah Binti Mat Napi, Hajime Kameo, Hisao Nishiyama

    Chemical Communications   55 ( 85 )   12765 - 12768   2019（ ISSN:1359-7345 ）

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1039/C9CC06520B

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  • Iridium-Hydride-Mediated Stannane−Fluorine and −Chlorine sigma-Bond Activation: Reversible Switching between X-type Stannyl and Z-type Stannane Ligands

    Hajime Kameo,* Yuki Baba, Shigeyoshi Sakaki, Didier Bourissou, Hiroshi Nakazawa, Hiroyuki Matsuzaka

    Organometallics 雑誌   36 ( 11 )   2017.05

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    Kind of work：Joint Work  

  • Synthesis and Characterisation of Tetranuclear Ruthenium Polyhydrido Clusters with Pseudo-Tetrahedral Geometry

    Hajime Kameo, Yutaka Ito, Ryuichi Shimogawa, Asuka Koizumi, Hiroki Chikamori, Junko Fujimoto, Hiroharu Suzuki, Toshiro Takao

    Dalton Transactions   46 ( 12 )   2017.05

  • Cooperative Catalysis of a Combined System of Transition Metal Complex with the Lewis Acid: Theoretical Understanding Reviewed

    Wei Guan, Guixiang Zeng, Hajime Kameo, Yoshiaki Nakao, Shigeyoshi Sakaki

    The Chemical Record 雑誌   16 ( 5 )   2016.10

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    Kind of work：Joint Work  

  • Saturated Heavier Group 14 Compounds as σ-Electron Acceptor (Z-type) Ligands Reviewed

    Hajime Kameo, Hiroshi Nakazawa

    The Chemical Record 雑誌   17 ( 3 )   2016.08

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    Kind of work：Joint Work  

  • Experimental and Theoretical Study of Si−Cl and Ge−Cl sigma-Bond Activation Reactions by Iridium-Hydride Reviewed

    Hajime Kameo, Koki Ikeda, Sakaki Shigeyoshi, Hiroshi Nakazawa, Shin Takemoto, Hiroyuki Matsuzaka

    Dalton Transactions 雑誌   45   2016.02

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    Kind of work：Joint Work  

  • Transition-Metal-Mediated Cleavage of Fluoro-Silanes under Mild Conditions Reviewed

    Hajime Kameo, Tatsuya Kawamoto, Shigeyoshi Sakaki, Didier Bourissou, Hiroshi Nakazawa

    Chemistry - A European Journal 雑誌   22   2016.02

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    Kind of work：Joint Work  

  • Transition Metal-Mediated Ge−F Activation: Inverse Electron Flow in sigma Bond Metathesis Reviewed

    Hajime Kameo, Koki Ikeda, Didier Bourissou, Shigeyoshi Sakaki, Shin Takemoto, Hiroshi Nakazawa, Hiroyuki Matsuzaka

    Organometallics   35   2016.02

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    Kind of work：Joint Work  

  • Activation of Strong Boron−Fluorine and Silicon−Fluorine Sigma-Bonds: Theoretical Understanding and Prediction Reviewed

    Hajime Kameo, Shigeyoshi Sakaki

    Chemistry - A European Journal 雑誌   21   2015.09

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    Kind of work：Joint Work  

  • Coordination of a Triphosphine-Silane to Gold: Formation of a Trigonal Pyramidal Complex Featuring Au+→Si Interaction Reviewed

    Pauline Gualco, Sonia Mallet-Ladeira, Hajime Kameo, Hiroshi Nakazawa, Maxime Mercy, Laurent Maron, Abderrahmane Amgoune, Didier Bourissou

    Organometallics   34 ( 8 )   2015.04

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    Kind of work：Joint Work  

  • Evaluation of the -Donation from Group 11 Metals (Cu, Ag, Au) to Silane, Germane, and Stannane Based on the Experimental / Theoretical Systematic Approach Reviewed

    Hajime Kameo, Tatsuya Kawamoto, Didier Bourissou, Shigeyoshi Sakaki, Hiroshi Nakazawa

    Organometallics 雑誌   34 ( 8 )   2015.04

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    Kind of work：Joint Work  

  • Synthesis, Geometry, and Bonding Nature of Hepta-coordinate Compounds of Silicon and Germanium Featuring Three Phosphine Donors Reviewed

    Hajime Kameo, Tatsuya Kawamoto, Didier Bourissou, Shigeyoshi Sakaki, Hiroshi Nakazawa

    Organometallics   33 ( 22 )   2014.11

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    Kind of work：Joint Work  

  • Can One σ*-Antibonding Orbital Interact with Six Electrons of Lewis Bases? Analysis of a Multiply Interacting σ* Orbital Reviewed

    Hajime Kameo,* Tatsuya Kawamoto, Shigeyoshi Sakaki, Hiroshi Nakazawa

    Organometallics 雑誌   33 ( 21 )   2014.10

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    Kind of work：Joint Work  

  • Coordination and Redox Isomerization of a Putative Divalent Uranium Arene Complex Reviewed

    Henry S. La Pierre, Hajime Kameo, Dominik Halter, Frank W. Heinemann, Karsten Meyer

    Angewandte Chemie International Edition 雑誌   53 ( 28 )   2014.07

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    Kind of work：Joint Work  

  • Recent Developments in the Coordination Chemistry of Multidentate Ligands Featuring a Boron Moiety Reviewed

    Hajime Kameo, Hiroshi Nakazawa

    Chem. Asian J. 雑誌 Wiley   8   2013.06

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    Kind of work：Joint Work  

  • Si-C Bond Cleavage by Hydride Complexes of Rhodium and Iridium: Comparison of Si-C(sp2) and Si-C(sp3) Activation Reviewed

    Hajime Kameo, Sho Ishii, Hiroshi Nakazawa

    Dalton Trans. 雑誌 Royal Society of Chemistry   42   2013.01

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    Kind of work：Joint Work  

  • Crystal Structure and Metal Atom Dynamics of the Dimethyl Stannane complex: {o-(Ph2P)C6H4}2Sn(CH3)2 Reviewed

    Hajime Kameo, Hiroshi Nakazawa, Rolfe H. Herber

    Journal of Molecular Structure 雑誌   1054–1055   2013

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    Kind of work：Joint Work  

  • Synthesis of a Rhodium Complex Featuring the Rh-H-B linkage via a Hydride Migration from Rhodium to Borane: Study on the Electronic Deviation Induced by the Presence of the boron moiety Reviewed

    Hajime Kameo, Hiroshi Nakazawa

    Organometallics 雑誌 American Chemical Society   31   2012.10

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    Kind of work：Joint Work  

  • Facile Synthesis of Rhodium and Iridium Complexes Bearing a [PEP]-Type Ligand (E = Ge or Sn) via E−C Bond Cleavag Reviewed

    Hajime Kameo, Sho Ishii, Hiroshi Nakazawa

    Dalton Trans. 雑誌 Royal Society of Chemistry   41   2012.07

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    Kind of work：Joint Work  

  • Synthesis of Iridaboratranes Bearing Phosphine-Tethered Borane: Reversible CO/PR3 (R = Me, OMe, and OEt) Substitution Reaction Induced by -Electron Acceptor Borane Ligand Reviewed

    Hajime Kameo, Yasuhiro Hashimoto, Hiroshi Nakazawa

    Organometallics 雑誌 American Chemical Society   31   2012.05

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    Kind of work：Joint Work  

  • Synthesis of Iridium Complexes Bearing {(o-Ph2P)C6H4}3E Type (E = Si, Ge, and Sn) Ligand and Evaluation of Electron Donating Ability of Group 14 Elements E Reviewed

    Hajime Kameo, Sho Ishii, Hiroshi Nakazawa

    Dalton Trans. 雑誌 Royal Society of Chemistry   41   2012.04

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    Kind of work：Joint Work  

  • Structures and Reactivities of Rhodium Complexes Bearing [E(o-C6H4PPh2)3] Type Tetradentate Ligand (E = Si, Ge, Sn) Reviewed

    Hajime Kameo, Sho Ishii, Hiroshi Nakazawa

    Organometallics 雑誌 American Chemical Society   31   2012.03

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    Kind of work：Joint Work  

  • Synthesis of Rhodaboratranes Bearing Phosphine-Tethered Borane: Evaluation of Metal-Borane Interaction Reviewed

    Hajime Kameo, Yasuhiro Hashimoto, Hiroshi Nakazawa

    Organometallics 雑誌 American Chemical Society   31   2012.03

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    Kind of work：Joint Work  

  • Chemistry of Transition Metal Complex Containing Sigma Electron Acceptor (Z-type) Ligand Reviewed

    Hajime Kameo

    Bull. Chem. Soc. Coord. Chem. 雑誌 Japan Society of Coordination Chemistry   58   2011.11

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    Kind of work：Single Work  

  • Heterometallic Effects in Nitrogen-Hydrogen Bond Cleavage by Trinuclear Mixed-Metal Polyhydrido Cluster containing Ruthenium and Osmium Reviewed

    Hajime Kameo, Yumiko Nakajima, Kyo Namura, Hiroharu Suzuki

    Organometallics 雑誌 American Chemical Society   30   2011.11

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    Kind of work：Joint Work  

  • Insights into the Mechanism of Carbonate Formation through Reductive Cleavage of Carbon Dioxide with Low-valent Uranium Centers Reviewed

    Oahn P. Lam, Suzanne C. Bart, Hajime Kameo, Frank W. Heinemann, Karsten Meyer

    Chem. Commun. 雑誌 Wiley   46   2010.04

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    Kind of work：Joint Work  

  • Synthesis and Structure of a Novel Ruthenium Hydrido-bis(dihydrogen) complex with 1,4,7-Trimethyl-1,4,7-triazacyclononane Ligand: A Useful Precursor for Synthesis of Heterometallic Complexes Reviewed

    Takanori Shima, Kyo Namura, Hajime Kameo, Satoshi Kakuta, Hiroharu Suzuki

    Organometallics 雑誌 American Chemical Society   29   2009.12

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    Kind of work：Joint Work  

  • Synthesis of Heterotrimetallic Polyhydrido Clusters Containing Ruthenium and Osmium and Their Electronic and Structural Deviation from Homometallic Systems Reviewed

    Hajime Kameo, Takanori Shima, Yumiko Nakajima, Hiroharu Suzuki

    Organometallics 雑誌 American Chemical Society   28   2009.03

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    Kind of work：Joint Work  

  • Drastic Acceleration of the Phosphine/Phosphite Incorporation into a Tetrahydrido Ru/Os Complex, and One-way Ru-Os Migration of a Phosphorus Ligand Reviewed

    Hajime Kameo, Yumiko Nakajima, Hiroharu Suzuki

    Angew. Chem. Int. Ed. 雑誌 Wiley   47   2008.11

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    Kind of work：Joint Work  

  • Synthesis of Trinuclear Osmium Polyhydrido Clusters [{(C5Me5)Os}3(-H)6]+ and {(C5Me5)Os}3(-H)3(3-H)2 and Comparison with the Ruthenium Analogues Reviewed

    Hajime Kameo, Hiroharu Suzuki

    Organometallics 雑誌 American Chemical Society   27   2008.07

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    Kind of work：Joint Work  

  • Hydrogenation of a Trinuclear 3-Imido Complex of Ruthenium: Homolytic or Heterolytic H−H Bond Cleavage? Reviewed

    Hajime Kameo, Yumiko Nakajima, Hiroharu Suzuki

    Eur. J. Inorg. Chem. 雑誌 Wiley   2007.03

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    Kind of work：Joint Work  

  • Cleavage of Nitrogen−Hydrogen Bonds of Ammonia Induced by Triruthenium Polyhydrido Cluster Reviewed

    Yumiko Nakajima, Hajime Kameo, Hiroharu Suzuki

    Angew. Chem. Int. Ed. 雑誌 Wiley   45   2005.12

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    Kind of work：Joint Work  

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MISC

  • 非共有結合性相互作用 Z型配位子相互作用 反復クロスカップリング ノンフォトレドックス

    國信 洋一郎, 亀尾 肇, 吉田 拡人, 稲垣 昭子

    有機合成化学協会誌   80 ( 5 )   517 - 517   2022.05（ ISSN:0037-9980 ） （ eISSN:1883-6526 ）

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  • 強固な結合の切断を鍵とする触媒反応の開発 M→Z(Z型配位子)σ結合を介した求核的活性化

    亀尾肇

    化学と工業   74 ( 8 )   2021（ ISSN:0022-7684 ）

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  • Co(III) オキシラジカルを鍵とする触媒反応 International journal

    亀尾肇

    Organometallic News   2019.03

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    Authorship：Lead author,　Last author,　Corresponding author   Kind of work：Single Work   International / domestic magazine：Domestic journal  

  • 昨日今日そして明日のケイ素化学 σ電子受容性シラン,ゲルマン,スタンナン配位子を鍵とする切断反応の開発

    亀尾肇

    ケイ素化学協会誌   ( 36 )   2019

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  • 酸化亜鉛ラジカルカチオンを用いたメタンの活性化 International journal

    亀尾肇

    月刊「化学」   2017.11

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Presentations

  • αシアノカルバニオン配位子を有するπ共役系ニッケル錯体の合成 Domestic conference

    松田光二、 山本大貴、亀尾 肇、松坂裕之

    日本化学会第103春季年会  2023.03  日本化学会

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    Presentation type：Oral presentation (general)  

    Venue：東京理科大学野田キャンパス  

  • Bond Cleavage and Catalysis Based on Nucleophilic Activation via Metal→Z-type Silane Ligand Interaction Invited International conference

    Hajime Kameo

    2023.03 

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    Presentation type：Oral presentation (invited, special)  

  • パラジウム錯体を用いた ゲルマニウム－炭素結合のアリール化 Domestic conference

    大石貫太、 虫明陽大、亀尾 肇、松坂裕之

    日本化学会第103春季年会  2023.03  日本化学会

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    Presentation type：Oral presentation (general)  

    Venue：東京理科大学野田キャンパス  

  • Catalytic Activation of Fluorosilane and Fluorogermane via TM→Si/Ge–F→Lewis Acid Interaction Invited International conference

    Hajime Kameo

    The 5th NYCU Conference on Advanced Organic Synthesis (CAOS-5)  2022.11  National Yang Ming Chiao Tung University

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    Presentation type：Oral presentation (invited, special)  

    Venue：National Yang Ming Chiao Tung University  

  • Ni/Pd-Catalyzed Coupling with Fluorosilanes and Fluorogermanes Based on Z-type Interaction International conference

    8th Asia Silicon Symposium  2022.10 

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    Presentation type：Oral presentation (general)  

  • σ-電子受容性ボラン配位子を有するアニオン性 Pt(0) および Pd(0) 錯体の合成 Domestic conference

    泉 大輔、田中悠大、亀尾 肇、松坂裕之

    錯体化学会第72回討論会  2022.09  日本化学会近畿支部

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    Presentation type：Oral presentation (general)  

    Venue：九州大学糸キャンパス  

  • パラジウム錯体を用いたケイ素-アルコキシ結合のアリール化 Domestic conference

    河原陽乃介、北村功樹、亀尾 肇、松坂裕之

    日本化学会第102春季年会  2022.03  日本化学会

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    Presentation type：Oral presentation (general)  

    Venue：オンライン  

  • σ電子受容性配位子を有する錯体の創製と触媒反応の開発 Invited Domestic conference

    亀尾 肇

    日本化学会第101春季年会  2021.03 

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    Presentation type：Oral presentation (invited, special)  

  • σ電子受容性配位子を鍵とする切断反応の開発 Domestic conference

    亀尾 肇・松坂裕之

    第23回ケイ素化学協会シンポジウム   2019.11 

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    Presentation type：Oral presentation (invited, special)  

  • パラジウム錯体を用いたケイ素-酸素結合の触媒的アリール化反応の開発 Domestic conference

    北村功樹・ 亀尾 肇・松坂裕之

    錯体化学会第69回討論会  2019.09 

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    Presentation type：Oral presentation (invited, special)  

  • アニオン性ロジウム(-I)ボラン錯体を用いた脱フッ素化反応 Domestic conference

    田中悠大・ 亀尾 肇・松坂裕之

    錯体化学会第69回討論会  2019.09 

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    Presentation type：Oral presentation (invited, special)  

  • Anionic Rh(-I) Borane Complexes Featuring Seesaw Geometry Domestic conference

    Kameo, H.; Yamamoto, J.; Matsuzaka, H.

    第66回有機金属化学討論会  2019.09 

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    Presentation type：Oral presentation (invited, special)  

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Outline of collaborative research (seeds)

  • 有機金属錯体の合成およびそれらを用いた反応開発

Grant-in-Aid for Scientific Research

  • Innovative Transition Metal Anions Enabled by Inverted Ligand Field

    Grant-in-Aid for Challenging Research (Exploratory)  2026

  • Innovative Transition Metal Anions Enabled by Inverted Ligand Field

    Grant-in-Aid for Challenging Research (Exploratory)  2025

  • Innovative catalysis enabled by nucleophilic activation of silanes

    Grant-in-Aid for Scientific Research(B)  2024

  • Innovative Transition Metal Anions Enabled by Inverted Ligand Field

    Grant-in-Aid for Challenging Research (Exploratory)  2024

Charge of on-campus class subject

  • 化学実験1

    2024   Weekly class   Undergraduate

  • 化学特別演習2A

    2024   Intensive lecture   Graduate school

  • 化学特別演習1A

    2024   Intensive lecture   Graduate school

  • 化学特別研究2A

    2024   Intensive lecture   Graduate school

  • 化学特別研究1A

    2024   Intensive lecture   Graduate school

  • 研究企画ゼミナール

    2024   Intensive lecture   Graduate school

  • 化学特別演習3A

    2024   Intensive lecture   Graduate school

  • 化学特別研究5A

    2024   Intensive lecture   Graduate school

  • 化学特別研究4A

    2024   Intensive lecture   Graduate school

  • 化学特別研究3A

    2024   Intensive lecture   Graduate school

  • 化学特別演習5A

    2024   Intensive lecture   Graduate school

  • 化学特別演習4A

    2024   Intensive lecture   Graduate school

  • 化学実験Ⅱ

    2024   Weekly class   Undergraduate

  • 化学実験Ⅰ

    2024   Weekly class   Undergraduate

  • 基礎化学実験

    2024   Weekly class   Graduate school

  • 先端研究探索

    2024   Weekly class   Undergraduate

  • 化学実験2

    2024   Weekly class   Undergraduate

  • 無機化学演習

    2024   Weekly class   Undergraduate

  • 海外特別研究2

    2024   Intensive lecture   Graduate school

  • 海外特別研究1

    2024   Intensive lecture   Graduate school

  • 有機金属化学特論

    2024   Weekly class   Graduate school

  • 化学特別演習2B

    2024   Intensive lecture   Graduate school

  • 化学特別演習1B

    2024   Intensive lecture   Graduate school

  • 化学特別研究2B

    2024   Intensive lecture   Graduate school

  • 化学特別研究1B

    2024   Intensive lecture   Graduate school

  • サイエンスフロンティアB（化学）

    2024   Intensive lecture   Graduate school

  • サイエンスフロンティアA（化学）

    2024   Intensive lecture   Graduate school

  • 海外特別研究5

    2024   Intensive lecture   Graduate school

  • 海外特別研究5

    2024   Intensive lecture   Graduate school

  • 海外特別研究4

    2024   Intensive lecture   Graduate school

  • 海外特別研究4

    2024   Intensive lecture   Graduate school

  • 海外特別研究3

    2024   Intensive lecture   Graduate school

  • 海外特別研究3

    2024   Intensive lecture   Graduate school

  • 化学特別演習5B

    2024   Intensive lecture   Graduate school

  • 化学特別演習4B

    2024   Intensive lecture   Graduate school

  • 化学特別演習3B

    2024   Intensive lecture   Graduate school

  • 化学特別研究5B

    2024   Intensive lecture   Graduate school

  • 化学特別研究4B

    2024   Intensive lecture   Graduate school

  • 化学特別研究3B

    2024   Intensive lecture   Graduate school

  • プロポーザルディフェンス

    2024   Intensive lecture   Graduate school

  • プロポーザルディフェンス

    2024   Intensive lecture   Graduate school

  • 基礎化学実験

    2024   Weekly class   Graduate school

  • 化学実験Ⅳ

    2024   Intensive lecture   Undergraduate

  • 化学実験Ⅲ

    2024   Weekly class   Undergraduate

  • 分子科学実験II

    2021   Practical Training  

  • Chemistry Laboratory I

    2021   Practical Training  

  • First Year Seminar

    2021    

  • First Year Seminar

    2021    

  • Inorganic Chemistry

    2021    

  • Sciences in Community

    2021    

  • Inorganic Chemistry III

    2021    

  • Exercises in Inorganic Chemistry

    2021    

  • Inorganic Chemistry IV

    2021    

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Charge of off-campus class subject

  • Organometallic Chemistry

    2022.09
    Institution：Paul Sabatier University Toulouse III

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    Level：Postgraduate  Country：France

Number of instructed thesis, researches

  • 2020

    Number of instructed the graduation thesis：2 

  • 2019

    Number of instructed the graduation thesis：2 

Social Activities　⇒ Link to the list of Social Activities

  • 泉北高校　オンライン大学訪問研修 触媒化学の歴史と今後の課題

    2020.04 - 2021.03

  • 第７１回錯体化学討論会　実行委員会委員

    2020 - 2021.09

  • 泉北高校　高大連携事業

    2018.04 - 2019.03

  • 堺市立堺高等学校 プロフェッサーズセミナー

    2017.04 - 2018.03

  • 堺市立堺高等学校 サマーサイエンスセミナー

    2016.04 - 2017.03

Original item・Special report (Social Activity)

  • 2022

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    SDGs：

    Original item：Visiting Research Professor (Paul Sabatier University - Toulouse III)

    Special report：Paul Sabatier University - Toulouse III の Visiting Research Professor として活動し、３週間の間に講義やディスカッション等を行った。