ケイ素化学協会

アメリカ化学会

強固な結合の切断を鍵とする 触媒反応の開発

亀尾　肇

化学と工業 雑誌   74 ( 8 )   2021年08月

Synthesis, Structure, and Bonding Properties of Hypercoordinate Triorganotin Compounds Featuring Three O→Sn Interactions

Hajime Kameo, Daisuke Izumi, Hiroyuki Matsuzaka

European Journal of Inorganic Chemistry   2021年07月

Pd/Ni-Catalyzed Germa-Suzuki Coupling via Dual Ge‒F Bond Activation 査読

Hajime Kameo, Akihiro Mushiake, Tomohito Isasa, Hiroyuki Matsuzaka, Didier Bourissou

Chemical Communications   57   2021年04月

Four-Electron Reduction of Dioxygen on a Metal Surface: Models of Dissociative and Associative Mechanisms in a Homogeneous System. 査読

Kameo H, Sakaki S, Ohki Y, Uehara N, Kosukegawa T, Suzuki H, Takao T

Inorganic chemistry   60 ( 3 )   1550 - 1560   2021年02月（ ISSN:0020-1669 ）

強固な結合の切断を鍵とする 触媒反応の開発

亀尾 肇

化学と工業   74   598 - 599   2021年

Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation

Hajime Kameo, Akihiro Mushiake, Tomohito Isasa, Hiroyuki Matsuzaka, Didier Bourissou

Chemical Communications   2021年

Fluorosilane Activation by Pd/Ni→Si-F→Lewis Acid Interaction: An Entry to Catalytic Sila-Negishi Coupling. 査読

Kameo H, Yamamoto H, Ikeda K, Isasa T, Sakaki S, Matsuzaka H, García-Rodeja Y, Miqueu K, Bourissou D

Journal of the American Chemical Society   142 ( 33 )   14039 - 14044   2020年08月（ ISSN:0002-7863 ）

Counterion Dependence of Dinitrogen Activation and Functionalization by a Diniobium Hydride Anion. 査読

Suzuki S, Ishida Y, Kameo H, Sakaki S, Kawaguchi H

Angewandte Chemie (International ed. in English)   132 ( 32 )   13546 - 13552   2020年08月（ ISSN:1521-3773 ）

Experimental and Theoretical Investigation of an S_N2-type Pathway for Borate-Fluorine Bond Cleavage by Electron-Rich Late-Transition Metal Complexes. 査読

Kameo H, Baba Y, Sakaki S, Tanaka Y, Matsuzaka H

Inorganic chemistry   59 ( 7 )   4282 - 4291   2020年04月（ ISSN:0020-1669 ）

Experimental and Theoretical Investigation of an SN2-type Pathway for Borate−Fluorine Bond Cleavage by Electron-Rich Late-Transition Metal Complexes 査読

Hajime Kameo, Yuki Baba, Shigeyoshi Sakaki, Yudai Tanaka, Hiroyuki Matsuzaka

Inorganic Chemistry 雑誌 American Chemical Society   2020年01月

Innentitelbild: Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination (Angew. Chem. 52/2019) 査読

Hajime Kameo, Jun Yamamoto, Ayaka Asada, Hiroshi Nakazawa, Hiroyuki Matsuzaka, Didier Bourissou

Angewandte Chemie   131 ( 52 )   18894 - 18894   2019年12月

Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination 査読

Hajime Kameo, Jun Yamamoto, Ayaka Asada, Hiroshi Nakazawa, Hiroyuki Matsuzaka, Didier Bourissou

Angewandte Chemie   131 ( 52 )   18959 - 18963   2019年12月

Palladium-Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro-/Deutero-dechlorination. 査読

Kameo H, Yamamoto J, Asada A, Nakazawa H, Matsuzaka H, Bourissou D

Angewandte Chemie (International ed. in English)   58 ( 52 )   18783 - 18787   2019年12月（ ISSN:1433-7851 ）

Inside Cover: Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination (Angew. Chem. Int. Ed. 52/2019) 査読

Hajime Kameo, Jun Yamamoto, Ayaka Asada, Hiroshi Nakazawa, Hiroyuki Matsuzaka, Didier Bourissou

Angewandte Chemie International Edition   58 ( 52 )   18720 - 18720   2019年12月

σ電子受容性シラン、ゲルマン、スタンナン配位子を鍵とする切断反応の開発

亀尾肇

ケイ素化学協会誌 雑誌   ( 36 )   2019年11月

Modulation of the coordination geometries of NCN and NCNC Rh complexes for ambidextrous chiral catalysts 査読

Jun-ichi Ito, Takahiro Ishihara, Takaki Fukuoka, Siti Rokiah Binti Mat Napi, Hajime Kameo, Hisao Nishiyama

Chemical Communications 雑誌   2019年09月

Cover Feature: Heptacoordinate Structures of Organotin Halides with Three Phosphine Donors: Halogen-Substituent Effect on Geometry (Eur. J. Inorg. Chem. 26/2019) 査読

Hajime Kameo, Tatsuya Kawamoto, Shigeyoshi Sakaki, Didier Bourissou, Hiroshi Nakazawa

European Journal of Inorganic Chemistry   2019 ( 26 )   3035 - 3035   2019年07月

Heptacoordinate Structures of Organotin Halides with Three Phosphine Donors: Halogen‐Substituent Effect on Geometry 査読

Hajime Kameo, Tatsuya Kawamoto, Shigeyoshi Sakaki, Didier Bourissou, Hiroshi Nakazawa

European Journal of Inorganic Chemistry   2019 ( 26 )   3045 - 3052   2019年07月

Modulation of the coordination geometries of NCN and NCNC Rh complexes for ambidextrous chiral catalysts. 査読

Ito JI, Ishihara T, Fukuoka T, Binti Mat Napi SR, Kameo H, Nishiyama H

Chemical communications (Cambridge, England)   55 ( 85 )   12765 - 12768   2019年（ ISSN:1359-7345 ）

Iridium-Hydride-Mediated Stannane−Fluorine and −Chlorine sigma-Bond Activation: Reversible Switching between X-type Stannyl and Z-type Stannane Ligands

Hajime Kameo,* Yuki Baba, Shigeyoshi Sakaki, Didier Bourissou, Hiroshi Nakazawa, Hiroyuki Matsuzaka

Organometallics 雑誌   36 ( 11 )   2017年05月

Synthesis and Characterisation of Tetranuclear Ruthenium Polyhydrido Clusters with Pseudo-Tetrahedral Geometry

Hajime Kameo, Yutaka Ito, Ryuichi Shimogawa, Asuka Koizumi, Hiroki Chikamori, Junko Fujimoto, Hiroharu Suzuki, Toshiro Takao

Dalton Transactions   46 ( 12 )   2017年05月

Cooperative Catalysis of a Combined System of Transition Metal Complex with the Lewis Acid: Theoretical Understanding 査読

Wei Guan, Guixiang Zeng, Hajime Kameo, Yoshiaki Nakao, Shigeyoshi Sakaki

The Chemical Record 雑誌   16 ( 5 )   2016年10月

Saturated Heavier Group 14 Compounds as σ-Electron Acceptor (Z-type) Ligands 査読

Hajime Kameo, Hiroshi Nakazawa

The Chemical Record 雑誌   17 ( 3 )   2016年08月

Experimental and Theoretical Study of Si−Cl and Ge−Cl sigma-Bond Activation Reactions by Iridium-Hydride 査読

Hajime Kameo, Koki Ikeda, Sakaki Shigeyoshi, Hiroshi Nakazawa, Shin Takemoto, Hiroyuki Matsuzaka

Dalton Transactions 雑誌   45   2016年02月

Transition-Metal-Mediated Cleavage of Fluoro-Silanes under Mild Conditions 査読

Hajime Kameo, Tatsuya Kawamoto, Shigeyoshi Sakaki, Didier Bourissou, Hiroshi Nakazawa

Chemistry - A European Journal 雑誌   22   2016年02月

Transition Metal-Mediated Ge−F Activation: Inverse Electron Flow in sigma Bond Metathesis 査読

Hajime Kameo, Koki Ikeda, Didier Bourissou, Shigeyoshi Sakaki, Shin Takemoto, Hiroshi Nakazawa, Hiroyuki Matsuzaka

Organometallics   35   2016年02月

Activation of Strong Boron−Fluorine and Silicon−Fluorine Sigma-Bonds: Theoretical Understanding and Prediction 査読

Hajime Kameo, Shigeyoshi Sakaki

Chemistry - A European Journal 雑誌   21   2015年09月

Coordination of a Triphosphine-Silane to Gold: Formation of a Trigonal Pyramidal Complex Featuring Au+→Si Interaction 査読

Pauline Gualco, Sonia Mallet-Ladeira, Hajime Kameo, Hiroshi Nakazawa, Maxime Mercy, Laurent Maron, Abderrahmane Amgoune, Didier Bourissou

Organometallics   34 ( 8 )   2015年04月

Evaluation of the -Donation from Group 11 Metals (Cu, Ag, Au) to Silane, Germane, and Stannane Based on the Experimental / Theoretical Systematic Approach 査読

Hajime Kameo, Tatsuya Kawamoto, Didier Bourissou, Shigeyoshi Sakaki, Hiroshi Nakazawa

Organometallics 雑誌   34 ( 8 )   2015年04月

Synthesis, Geometry, and Bonding Nature of Hepta-coordinate Compounds of Silicon and Germanium Featuring Three Phosphine Donors 査読

Hajime Kameo, Tatsuya Kawamoto, Didier Bourissou, Shigeyoshi Sakaki, Hiroshi Nakazawa

Organometallics   33 ( 22 )   2014年11月

Can One σ*-Antibonding Orbital Interact with Six Electrons of Lewis Bases? Analysis of a Multiply Interacting σ* Orbital 査読

Hajime Kameo,* Tatsuya Kawamoto, Shigeyoshi Sakaki, Hiroshi Nakazawa

Organometallics 雑誌   33 ( 21 )   2014年10月

Coordination and Redox Isomerization of a Putative Divalent Uranium Arene Complex 査読

Henry S. La Pierre, Hajime Kameo, Dominik Halter, Frank W. Heinemann, Karsten Meyer

Angewandte Chemie International Edition 雑誌   53 ( 28 )   2014年07月

Recent Developments in the Coordination Chemistry of Multidentate Ligands Featuring a Boron Moiety 査読

Hajime Kameo, Hiroshi Nakazawa

Chem. Asian J. 雑誌 Wiley   8   2013年06月

Si-C Bond Cleavage by Hydride Complexes of Rhodium and Iridium: Comparison of Si-C(sp2) and Si-C(sp3) Activation 査読

Hajime Kameo, Sho Ishii, Hiroshi Nakazawa

Dalton Trans. 雑誌 Royal Society of Chemistry   42   2013年01月

Crystal Structure and Metal Atom Dynamics of the Dimethyl Stannane complex: {o-(Ph2P)C6H4}2Sn(CH3)2 査読

Hajime Kameo, Hiroshi Nakazawa, Rolfe H. Herber

Journal of Molecular Structure 雑誌   1054–1055   2013年

Synthesis of a Rhodium Complex Featuring the Rh-H-B linkage via a Hydride Migration from Rhodium to Borane: Study on the Electronic Deviation Induced by the Presence of the boron moiety 査読

Hajime Kameo, Hiroshi Nakazawa

Organometallics 雑誌 American Chemical Society   31   2012年10月

Facile Synthesis of Rhodium and Iridium Complexes Bearing a [PEP]-Type Ligand (E = Ge or Sn) via E−C Bond Cleavag 査読

Hajime Kameo, Sho Ishii, Hiroshi Nakazawa

Dalton Trans. 雑誌 Royal Society of Chemistry   41   2012年07月

Synthesis of Iridaboratranes Bearing Phosphine-Tethered Borane: Reversible CO/PR3 (R = Me, OMe, and OEt) Substitution Reaction Induced by -Electron Acceptor Borane Ligand 査読

Hajime Kameo, Yasuhiro Hashimoto, Hiroshi Nakazawa

Organometallics 雑誌 American Chemical Society   31   2012年05月

Synthesis of Iridium Complexes Bearing {(o-Ph2P)C6H4}3E Type (E = Si, Ge, and Sn) Ligand and Evaluation of Electron Donating Ability of Group 14 Elements E 査読

Hajime Kameo, Sho Ishii, Hiroshi Nakazawa

Dalton Trans. 雑誌 Royal Society of Chemistry   41   2012年04月

Structures and Reactivities of Rhodium Complexes Bearing [E(o-C6H4PPh2)3] Type Tetradentate Ligand (E = Si, Ge, Sn) 査読

Hajime Kameo, Sho Ishii, Hiroshi Nakazawa

Organometallics 雑誌 American Chemical Society   31   2012年03月

Synthesis of Rhodaboratranes Bearing Phosphine-Tethered Borane: Evaluation of Metal-Borane Interaction 査読

Hajime Kameo, Yasuhiro Hashimoto, Hiroshi Nakazawa

Organometallics 雑誌 American Chemical Society   31   2012年03月

Chemistry of Transition Metal Complex Containing Sigma Electron Acceptor (Z-type) Ligand 査読

Hajime Kameo

Bull. Chem. Soc. Coord. Chem. 雑誌 Japan Society of Coordination Chemistry   58   2011年11月

Heterometallic Effects in Nitrogen-Hydrogen Bond Cleavage by Trinuclear Mixed-Metal Polyhydrido Cluster containing Ruthenium and Osmium 査読

Hajime Kameo, Yumiko Nakajima, Kyo Namura, Hiroharu Suzuki

Organometallics 雑誌 American Chemical Society   30   2011年11月

Insights into the Mechanism of Carbonate Formation through Reductive Cleavage of Carbon Dioxide with Low-valent Uranium Centers 査読

Oahn P. Lam, Suzanne C. Bart, Hajime Kameo, Frank W. Heinemann, Karsten Meyer

Chem. Commun. 雑誌 Wiley   46   2010年04月

Synthesis and Structure of a Novel Ruthenium Hydrido-bis(dihydrogen) complex with 1,4,7-Trimethyl-1,4,7-triazacyclononane Ligand: A Useful Precursor for Synthesis of Heterometallic Complexes 査読

Takanori Shima, Kyo Namura, Hajime Kameo, Satoshi Kakuta, Hiroharu Suzuki

Organometallics 雑誌 American Chemical Society   29   2009年12月

Synthesis of Heterotrimetallic Polyhydrido Clusters Containing Ruthenium and Osmium and Their Electronic and Structural Deviation from Homometallic Systems 査読

Hajime Kameo, Takanori Shima, Yumiko Nakajima, Hiroharu Suzuki

Organometallics 雑誌 American Chemical Society   28   2009年03月

Drastic Acceleration of the Phosphine/Phosphite Incorporation into a Tetrahydrido Ru/Os Complex, and One-way Ru-Os Migration of a Phosphorus Ligand 査読

Hajime Kameo, Yumiko Nakajima, Hiroharu Suzuki

Angew. Chem. Int. Ed. 雑誌 Wiley   47   2008年11月

Synthesis of Trinuclear Osmium Polyhydrido Clusters [{(C5Me5)Os}3(-H)6]+ and {(C5Me5)Os}3(-H)3(3-H)2 and Comparison with the Ruthenium Analogues 査読

Hajime Kameo, Hiroharu Suzuki

Organometallics 雑誌 American Chemical Society   27   2008年07月

Hydrogenation of a Trinuclear 3-Imido Complex of Ruthenium: Homolytic or Heterolytic H−H Bond Cleavage? 査読

Hajime Kameo, Yumiko Nakajima, Hiroharu Suzuki

Eur. J. Inorg. Chem. 雑誌 Wiley   2007年03月

Cleavage of Nitrogen−Hydrogen Bonds of Ammonia Induced by Triruthenium Polyhydrido Cluster 査読

Yumiko Nakajima, Hajime Kameo, Hiroharu Suzuki

Angew. Chem. Int. Ed. 雑誌 Wiley   45   2005年12月

σ-電子受容性ボラン配位子を有するアニオン性 Pt(0) および Pd(0) 錯体の合成 国内会議

泉 大輔、田中悠大、亀尾 肇、松坂裕之

錯体化学会第72回討論会  2022年09月  日本化学会近畿支部

パラジウム錯体を用いたケイ素-アルコキシ結合のアリール化 国内会議

河原陽乃介、北村功樹、亀尾 肇、松坂裕之

日本化学会第102春季年会  2022年03月  日本化学会

σ電子受容性配位子を有する錯体の創製と触媒反応の開発 招待 国内会議

亀尾 肇

日本化学会第101春季年会  2021年03月 

σ電子受容性配位子を鍵とする切断反応の開発 国内会議

亀尾 肇・松坂裕之

第23回ケイ素化学協会シンポジウム   2019年11月 

パラジウム錯体を用いたケイ素-酸素結合の触媒的アリール化反応の開発 国内会議

北村功樹・ 亀尾 肇・松坂裕之

錯体化学会第69回討論会  2019年09月 

アニオン性ロジウム(-I)ボラン錯体を用いた脱フッ素化反応 国内会議

田中悠大・ 亀尾 肇・松坂裕之

錯体化学会第69回討論会  2019年09月 

Anionic Rh(-I) Borane Complexes Featuring Seesaw Geometry 国内会議

Kameo, H.; Yamamoto, J.; Matsuzaka, H.

第66回有機金属化学討論会  2019年09月 

社会に活きる科学

2021年度    

無機化学III

2021年度    

無機化学演習

2021年度    

無機化学IV

2021年度